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Surfaces, Volume 2, Issue 2

2019 June - 16 articles

Cover Story: Synchrotron-based scanning photoelectron microscopy (SPEM) has opened unique opportunities for exploiting processes occurring at surfaces and interfaces where issues of chemical and morphological complexity at microscopic length scales can be faced and understood. In particular, SPEM can be used to address hot topics in the fields of electrochemical energy storage and electrochemical fabrication. We discuss a selection of the recent results on three different systems: (i) an in-depth analysis of Ag–In electrodeposited alloys exhibiting dynamic pattern formation, (ii) the analysis of electrochemical processes at the electrodes of a self-driven solid oxide fuel cell, and (iii) an operando characterization of a single-chamber solid oxide fuel cell. The last two examples have been performed at near-ambient pressure conditions using unique specially designed setups which extend photoemission microscopes into operating conditions. View paper

Articles (16)

  • Article
  • Open Access
27 Citations
6,532 Views
11 Pages

13 June 2019

In many reports, cellulose and nanocellulose have been carbamated using 2,4-toluene diisocyanate (2,4-TDI) to allow the grafting of molecules or polymers onto their surfaces. Such a process usually involves the reaction of the more reactive isocyanat...

  • Article
  • Open Access
19 Citations
3,693 Views
12 Pages

Tuning the Electrical Properties of Electrospun Nanofibers with Hybrid Nanomaterials for Detecting Isoborneol in Water Using an Electronic Tongue

  • Fernanda L. Migliorini,
  • Kelcilene B. R. Teodoro,
  • Vanessa P. Scagion,
  • Danilo M. dos Santos,
  • Fernando J. Fonseca,
  • Luiz H. C. Mattoso and
  • Daniel S. Correa

11 June 2019

The presence of contaminants in water is a subject of paramount importance nowadays, which can make water improper to human consumption even when these contaminants are present at very low concentrations, causing health issues and economic losses. In...

  • Article
  • Open Access
7 Citations
4,559 Views
17 Pages

Local Surface Electric Field’s Effect on Adsorbed Proteins’ Orientation

  • Larbi Filali,
  • Yamina Brahmi,
  • Jamal Dine Sib,
  • Yahya Bouizem,
  • Djamel Benlakehal,
  • Kacem Zellama,
  • Nathalie Lemée,
  • Ahmed Bouhekka,
  • Fatiha Kail and
  • Larbi Chahed
  • + 1 author

20 May 2019

Hydrogenated nanocrystalline silicon, while being non-charged and non-polar, could be an ideal candidate for the non-covalent and orientation-controlled immobilization of biomolecules thanks to local electric fields around nanocrystals. To that effec...

  • Article
  • Open Access
18 Citations
7,367 Views
20 Pages

17 May 2019

Background: The study of processes in the drying drops of biological fluids (dried drop patterns) and the method of dynamic surface tensiometry can be attributed to integral methods of assessing the state of the organism. Research objective: to estab...

  • Article
  • Open Access
1 Citations
3,435 Views
8 Pages

Investigation of Photoelectron Properties of Polymer Films with Silicon Nanoparticles

  • Elizaveta A. Konstantinova,
  • Alexander S. Vorontsov and
  • Pavel A. Forsh

13 May 2019

Hybrid samples consisting of polymer poly-3(hexylthiophene) (P3HT) and silicon nanoparticles were prepared. It was found that the obtained samples were polymer matrixes with conglomerates of silicon nanoparticles of different sizes (10–104 nm)....

  • Article
  • Open Access
6 Citations
5,757 Views
15 Pages

10 May 2019

Cubic, octahedral, and rhombic dodecahedral gold nanocrystals enclosed by {100}, {111}, and {110} facets, respectively, were prepared by a seed-mediated growth method at the room temperature. Palladium thin films were coated on these Au nanocrystals...

  • Review
  • Open Access
141 Citations
16,841 Views
23 Pages

Controlled Surface Wettability by Plasma Polymer Surface Modification

  • Muzammil Iqbal,
  • Duy Khoe Dinh,
  • Qasim Abbas,
  • Muhammad Imran,
  • Harse Sattar and
  • Aqrab Ul Ahmad

9 May 2019

Inspired by nature, tunable wettability has attracted a lot of attention in both academia and industry. Various methods of polymer surface tailoring have been studied to control the changes in wetting behavior. Polymers with a precisely controlled we...

  • Article
  • Open Access
31 Citations
8,265 Views
13 Pages

Sputtered Platinum Thin-films for Oxygen Reduction in Gas Diffusion Electrodes: A Model System for Studies under Realistic Reaction Conditions

  • Gustav W. Sievers,
  • Anders W. Jensen,
  • Volker Brüser,
  • Matthias Arenz and
  • María Escudero-Escribano

28 April 2019

The development of catalysts for the oxygen reduction reaction in low-temperature fuel cells depends on efficient and accurate electrochemical characterization methods. Currently, two primary techniques exist: rotating disk electrode (RDE) measuremen...

  • Article
  • Open Access
26 Citations
5,601 Views
11 Pages

19 April 2019

Ultrasonic machining has been used over a decade to enhance the surface finishing and overall processing characteristics of conventional technologies. The benefits that are usually associated to this approach generate an increasing interest in both a...

  • Article
  • Open Access
7 Citations
5,682 Views
11 Pages

16 April 2019

The electro-oxidation of CO on Pt surface is not only fundamentally important in electrochemistry, but also practically important in residential fuel cells for avoiding the poisoning of Pt catalysts by CO. We carried out cyclic voltammetry on Pt(111)...

  • Article
  • Open Access
5 Citations
4,966 Views
20 Pages

Spatially Resolved XPS Characterization of Electrochemical Surfaces

  • Benedetto Bozzini,
  • Danjela Kuscer,
  • Matteo Amati,
  • Luca Gregoratti,
  • Patrick Zeller,
  • Tsvetina Dobrovolska and
  • Ivan Krastev

15 April 2019

Synchrotron-based scanning photoelectron microscopy (SPEM) has opened unique opportunities for exploiting processes occurring at surfaces and interfaces, which control the properties of materials for electrochemical devices, where issues of chemical...

  • Article
  • Open Access
1 Citations
3,691 Views
18 Pages

12 April 2019

The self-organized formation of nanoscale laser-induced periodic surface structures (LIPSS) is still not fully understood with respect to the dynamics and interplay of contributing complex mechanisms. The transition from randomness to order and the s...

  • Article
  • Open Access
51 Citations
12,998 Views
20 Pages

9 April 2019

The advances in material science have led to the development of novel and various materials as nanoparticles or thin films. Underpotential deposition (upd) of transition metals appears to be a very sensitive method for probing the surfaces of noble m...

  • Article
  • Open Access
5 Citations
7,223 Views
13 Pages

An Electrochemical Route for Hot Alkaline Blackening of Steel: A Nitrite Free Approach

  • Maximilian Eckl,
  • Steve Zaubitzer,
  • Carsten Köntje,
  • Attila Farkas,
  • Ludwig A. Kibler and
  • Timo Jacob

29 March 2019

Blackening belongs to the predominant technological processes in preserving steel surfaces from corrosion by generating a protective magnetite overlayer. In place of the commonly used dipping-procedure into nitrite-containing blackening baths at boil...

  • Article
  • Open Access
14 Citations
4,550 Views
12 Pages

Nitrogen-Doped Ordered Mesoporous Carbons Supported Co3O4 Composite as a Bifunctional Oxygen Electrode Catalyst

  • Jing Wang,
  • Shuwei Zhang,
  • Haihong Zhong,
  • Nicolas Alonso-Vante,
  • Dianqing Li,
  • Pinggui Tang and
  • Yongjun Feng

29 March 2019

It is increasingly useful to develop bifunctional catalysts for oxygen reduction and oxygen evolution reaction (ORR and OER) for fuel cells, metal-air rechargeable batteries, and unitized regenerative cells. Here, based on the excellent conductivity...

  • Article
  • Open Access
5 Citations
5,610 Views
16 Pages

Interface Behaviour and Work Function Modification of Self-Assembled Monolayers on Sn-Doped In2O3

  • Andreas H. Hubmann,
  • Dominik Dietz,
  • Joachim Brötz and
  • Andreas Klein

29 March 2019

The modification of the work function of Sn-doped In2O3 (ITO) by vacuum adsorption of 4-(Dimethylamino)benzoic acid (4-DMABA) has been studied using in situ photoelectron spectroscopy. Adsorption of 4-DMABA is self-limited with an approximate thickne...

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Surfaces - ISSN 2571-9637