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Microwave Synthesis of Oxide Materials

A special issue of Applied Sciences (ISSN 2076-3417). This special issue belongs to the section "Materials Science and Engineering".

Deadline for manuscript submissions: closed (31 December 2020) | Viewed by 2982

Special Issue Editors


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Guest Editor
Complutense University of Madrid, Spain
Interests: electroceramics; complex oxides; impedance spectroscopy; multiferroics; dielectrics

E-Mail Website
Guest Editor
Complutense University of Madrid, Spain
Interests: solid state chemistry; microwave-assisted synthesis; materials for energy; 2D-materials; thermoelectricity
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Special Issue Information

Dear Colleagues,

The general topic of energy is regarded as one of the most important areas for any research and development activities at the start of the twenty-first century. In this context, considerable research efforts have recently been dedicated to renovating the conventional synthetic chemical industry by introducing new green chemistry concepts, where the energy requirements for chemical processing or synthesis are drastically reduced. In this context, a vast number of novel chemical synthesis techniques have been developed during recent decades. Such innovative techniques include combustion, sol–gel and co-precipitation methods, sono-chemistry, hydrothermal synthesis, and microwave-assisted techniques.

This Special Issue is dedicated to microwave-assisted synthesis techniques for oxide materials. The technique of microwave-assisted synthesis as well as oxide materials are two fields of research that have attracted massive attention recently. Microwave synthesis techniques are involved with massive reductions in synthesis temperature and time compared to conventional solid-state synthesis and can thus be classified as a green chemistry technique due to the resulting reduced energy consumption. Oxide materials, on the other hand, are a class of materials that offer a waste range of possible functional properties such as ferromagnetism, ferroelectricity, ionic conductivity, and superconductivity to only name a few. The assessment of the feasibility to synthesize certain oxides by microwave-assisted techniques requires that not only the phase purity of the resulting products be functional but also the respective oxide be present, e.g., magnetic oxides should not display inferior magnetic properties if synthesized by microwave compared to conventional synthesis. The same needs to be true for ferroelectric, ionically conductive, superconducting, or any other functional oxides.

This Special Issue is aimed at receiving submissions in the field of microwave-assisted synthesis of oxides, covering aspects such as novel microwave-assisted synthesis procedures for all classes of oxides, the study of unusual particle morphologies obtained by microwave-assisted synthesis, and general considerations concerning the high efficiency of microwave-assisted synthesis, for example, by elaborating on the coupling mechanisms between microwaves and oxide materials. In the case of known oxide phases, which are synthesized by microwave-assisted techniques for the first time, it would be advantageous if the synthesized products are characterized in terms of phase purity, crystal structure, and the respective functionality that is relevant in such oxides.

Prof. Rainer Schmidt
Dr. Jesús Prado-Gonjal
Guest Editor

Manuscript Submission Information

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Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Applied Sciences is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2400 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • microwave synthesis
  • oxides
  • green chemistry

Published Papers (1 paper)

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Research

13 pages, 4840 KiB  
Article
Synthesis of CuO for Microwave-Assisted Pyrolysis of Biomass
by Eri J. Paz-García, Silvia P. Paredes-Carrera, Sergio O. Flores-Valle, Isis S. Rodríguez-Clavel, Jesús C. Sánchez-Ochoa and Rosa M. Pérez-Gutiérrez
Appl. Sci. 2019, 9(24), 5525; https://doi.org/10.3390/app9245525 - 16 Dec 2019
Cited by 5 | Viewed by 2595
Abstract
In this study, CuO was synthesized as a microwave absorber in the pyrolysis of a biomass model (sugarcane bagasse). CuO was synthesized for 5 min of irradiation using the following techniques: microwave (MW), ultrasound (US), combined mode (MW-US), and conduction heating (CH) as [...] Read more.
In this study, CuO was synthesized as a microwave absorber in the pyrolysis of a biomass model (sugarcane bagasse). CuO was synthesized for 5 min of irradiation using the following techniques: microwave (MW), ultrasound (US), combined mode (MW-US), and conduction heating (CH) as a reference material. The use of these treatments promotes changes in the morphology, as MW and US generate leaves and monolithic faceted morphologies, respectively. Changes were also generated in some textural characteristics such as crystal size, surface area, and volume-pore size. They were produced as a consequence of changes in the conditions during the crystallization stage produced by the different irradiation types. The microwave-assisted pyrolysis was performed aiming for the maximum liquid fraction (bio-oil) in the products. The reaction time, the size of the biomass, and the CuO synthesis method were also analyzed. The following particle size (ps) intervals were studied: ps < 0.5 mm, 0.5 mm < ps < 1.7 mm, 1.7 mm < ps < 3.5 mm. The best conditions at 1160 Watts in the microwave were: 4 min of reaction, particle size lower than 0.5 mm, and CuO synthesized by US. The use of CuO in the pyrolysis almost triples the amount of the obtained liquid fraction, when compared with the pyrolysis without the use of a microwave absorbent. The CuO was reduced to Cu2O and Cu after the pyrolysis. In this work, a reduction in the reaction times from hours to minutes was achieved during the synthesis of CuO and the pyrolysis biomass. The liquid fraction (bio-oil) can be raw material to obtain value-added chemical products or biofuels. Full article
(This article belongs to the Special Issue Microwave Synthesis of Oxide Materials)
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