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Modern Material Solutions in Hydrogen Technologies

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Energy Materials".

Deadline for manuscript submissions: closed (20 December 2022) | Viewed by 4103

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Guest Editor
Department of Advanced Energy Technologies, Faculty of Infrastructure and Environment, Czestochowa University of Technology, Dabrowskiego Str. 69, 42-201 Czestochowa, Poland
Interests: materials in energy; corrosion and degradation of materials; production of protective coatings; hydrogen technologies; nanomaterials in energy and environmental engineering
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Special Issue Information

Dear Colleagues,

Currently, hydrogen is considered the fuel of the future, and for hydrogen to be widely used, infrastructure and gas distribution must be built. One of the tasks in this area is the production of green hydrogen from renewable energy sources (i.e., biomass or waste). Regardless of which direction the energy policy of Europe takes, the acquisition, transport and storage of hydrogen constitute an important aspect of building the hydrogen infrastructure of European countries. In this regard, the material aspects, e.g., durability, service life, availability and safety, rest on solving the problems of materials engineering and corrosion of materials.

I invite colleagues with research interests related to interdisciplinary issues in the field of hydrogen and materials dedicated to it to present their research, share their knowledge and expand the group of scientists supporting each other.

Let us start an adventure together that will end with the realization of the vision of using hydrogen as a conventional and environmentally friendly fuel.

Dr. Renata Włodarczyk
Guest Editor

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Keywords

  • materials protecting against hydrogen diffusion
  • hydrogen corrosion problems
  • hydrogen embrittlement
  • hydrogen storage materials
  • green/blue/gray hydrogen
  • hydrogen tank
  • fuel cell vehicle
  • materials testing procedures in hydrogen technology
  • production of new materials for hydrogen technology
  • innovative approaches for hydrogen infrastructure

Published Papers (2 papers)

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Research

16 pages, 7579 KiB  
Article
Effect of Thermal Treatment of Aluminum Core-Shell Particles on Their Oxidation Kinetics in Water for Hydrogen Production
by Olesya A. Buryakovskaya, Mikhail S. Vlaskin and Anatoly V. Grigorenko
Materials 2021, 14(21), 6493; https://doi.org/10.3390/ma14216493 - 29 Oct 2021
Cited by 8 | Viewed by 1436
Abstract
The effect of thermal treatment of aluminum core-shell particles on their oxidation kinetics in water for hydrogen production was investigated. The samples were obtained by dividing dried aluminum powder, partially oxidized by distilled water, into eight portions, which were thermally treated at temperatures [...] Read more.
The effect of thermal treatment of aluminum core-shell particles on their oxidation kinetics in water for hydrogen production was investigated. The samples were obtained by dividing dried aluminum powder, partially oxidized by distilled water, into eight portions, which were thermally treated at temperatures of 120, 200, 300, 400, 450, 500, 550 and 600 °C. Alumina shell cracking at 500–600 °C enhances hydrogen generation due to uncovering of the aluminum cores, while sharp thickening of the protective oxide film on the uncovered aluminum surfaces at 550–600 °C significantly reduces reactivity of the core-shell particles. For these reasons, after reaction with distilled water at 90 °C for two hours, the highest hydrogen yield (11.59 ± 1.20)% was obtained for the sample thermally treated at 500 °C , while the yield for aluminum core-shell powder without heat treatment was only (5.46 ± 0.13)%. Another set of experiments employed multiple consecutive cycles of alternating oxidation by water and thermal treatment at 500 °C of the same powder sample. As predicted, the hydrogen yield gradually decreased with each subsequent experiment. The series of six cycles resulted in a total hydrogen yield of 53.46%. Full article
(This article belongs to the Special Issue Modern Material Solutions in Hydrogen Technologies)
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10 pages, 3162 KiB  
Article
Electroless Plating of High-Performance Composite Pd Membranes with EDTA-Free Bath
by Jun-Yi Wang, Yen-Hsun Chi and Jin-Hua Huang
Materials 2021, 14(17), 4894; https://doi.org/10.3390/ma14174894 - 27 Aug 2021
Cited by 5 | Viewed by 1628
Abstract
High-performance composite Pd membranes were successfully fabricated using electroless plating with an EDTA-free bath. The plating started with employing the one-time addition of hydrazine. In the experiment, the hydrazine concentrations and plating bath volumes were systematically varied to optimize the plating. The optimum [...] Read more.
High-performance composite Pd membranes were successfully fabricated using electroless plating with an EDTA-free bath. The plating started with employing the one-time addition of hydrazine. In the experiment, the hydrazine concentrations and plating bath volumes were systematically varied to optimize the plating. The optimum composite Pd membrane tube showed high H2 permeance of 4.4 × 10−3 mol/m2 s Pa0.5 and high selectivity of 1.6 × 104, but poor cycling stability. Then, a method of sequential addition of the hydrazine from the high to low concentrations was employed. The resultant membrane, about 6 μm thick, still exhibited a high selectivity of 6.8 × 104 as well as a much-improved plating yield and cycling stability level; this membrane outperformed the membrane made using the unmodified plating technique with the EDTA-contained bath. This result indicates the EDTA-free bath combined with the sequential addition of hydrazine is a simple, low-cost, yet effective method for preparing thin, dense composite Pd membranes featuring high hydrogen permeation flux and high thermal durability. Full article
(This article belongs to the Special Issue Modern Material Solutions in Hydrogen Technologies)
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