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Materials, Volume 18, Issue 19

2025 October-1 - 212 articles

Cover Story: Gold nanoparticles have long fascinated researchers for their optical brilliance and versatility, yet their synthesis often demands toxic chemicals, solvents, and long reaction times. Here, we discovered a 15-minute, solvent-free route to produce “click-ready” gold nanoparticles using 2-propynylamine as both the reducing agent and surface ligand. Through reactive high-energy ball milling, gold ions are transformed into 4 nm particles that self-passivate with accessible alkyne groups (–C≡CH). This unique surface chemistry enables direct Cu(I)-catalyzed click functionalization, demonstrated through biotin–PEG4 conjugation. The result is a sustainable, single-step process that merges mechanochemistry and click chemistry to yield stable, modular nanomaterials for biosensing and advanced applications—all achieved in fifteen minutes. View this paper
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Articles (212)

  • Article
  • Open Access
911 Views
22 Pages

Achieving Large-Area Hot Embossing of Anti-Icing Functional Microstructures Based on a Multi-Arc Ion-Plating Mold

  • Xiaoliang Wang,
  • Han Luo,
  • Hongpeng Jiang,
  • Zhenjia Wang,
  • Ziyang Wang,
  • Haibao Lu,
  • Jun Xu,
  • Debin Shan,
  • Bin Guo and
  • Jie Xu

9 October 2025

Aluminum alloy surface microstructures possess functional characteristics such as hydrophilicity/hydrophobicity and anti-icing and have important applications in fields such as aerospace and power systems. In order to improve the filling quality of t...

  • Article
  • Open Access
773 Views
19 Pages

9 October 2025

TiAl alloys are ideal candidates to replace nickel-based superalloys in aero-engines due to their low density and high specific strength, yet their industrial application is hindered by narrow heat treatment windows and unbalanced mechanical performa...

  • Article
  • Open Access
805 Views
17 Pages

Fabrication and Oxidation Resistance of Metallic Ta-Reinforced High-Entropy (Ti,Zr,Hf,Nb,Ta)B2 Ceramics

  • Bowen Yuan,
  • Qilong Guo,
  • Hao Ying,
  • Liang Hua,
  • Ziqiu Shi,
  • Shengcai Yang,
  • Jing Wang and
  • Xiufang Wang

9 October 2025

High-entropy boride (HEB) ceramics combine ultra-high melting points, superior hardness, and compositional tunability, enabling service in extreme environments; however, difficult densification and limited fracture toughness still constrain their aer...

  • Article
  • Open Access
668 Views
17 Pages

Bending Behavior of Fiber Metal Laminate Plates Under Thermo-Mechanical Loads

  • Like Pan,
  • Tong Xing,
  • Yingxin Zhao,
  • Yuan Yuan and
  • Caizhi Yang

9 October 2025

An exact analytical model based on three-dimensional (3D) thermo-elasticity theory is developed to investigate the bending behavior of fiber metal laminate (FML) plates under thermo-mechanical load. The temperature-dependent properties and the orthot...

  • Review
  • Open Access
1,097 Views
29 Pages

9 October 2025

Bone fragility represents a significant global health burden, characterized by the deterioration of bone strength, increased brittleness, and heightened fracture susceptibility. Osteoporosis substantially elevates the risk of fragility fractures, the...

  • Article
  • Open Access
633 Views
14 Pages

9 October 2025

The objective of this study was to propose a correlation model of the damage class and deformation of reinforced concrete (RC) beams damaged by earthquakes with a focus on columns and walls. For this purpose, a series of full-scale RC beam specimens...

  • Article
  • Open Access
834 Views
12 Pages

Carbon Micro-Alloying Promotes Creep Flow via Enhanced Structural Heterogeneity in Fe-Based Amorphous Alloys

  • Deyu Cao,
  • Sishi Teng,
  • Jiajie Lv,
  • Xin Su,
  • Yu Tong,
  • Mingliang Xiang,
  • Lijian Song,
  • Meng Gao,
  • Yan Zhang and
  • Junqiang Wang
  • + 1 author

9 October 2025

Tuning structural heterogeneity in metallic glasses is key to improving their mechanical performance. Here we examine how carbon micro-alloying modulates the relaxation dynamics and creep of Fe-based amorphous ribbons. Increasing carbon content lower...

  • Article
  • Open Access
928 Views
22 Pages

Design of Semi-Rigid Composite Highway Pavements Using Cementitious Grouting and Porous Asphalt

  • Sevil Kofteci,
  • Mansor Nazary,
  • Ahmad Khaled Masbah and
  • Halil Ibrahim Burgan

9 October 2025

Due to the increasing volume of traffic on the world’s highways, researchers have been searching for new composite techniques and methods to develop durable and cost-effective pavement structures. The semi-rigid pavement is a composite pavement consi...

  • Article
  • Open Access
855 Views
15 Pages

8 October 2025

Hydrogen energy is viewed as a promising green energy source because of its high energy density, abundant availability, and clean combustion results. Hydrogen storage is the critical link in a hydrogen economy. Using first-principles density function...

  • Article
  • Open Access
1,310 Views
18 Pages

8 October 2025

In response to environmental pressures and the growing demand for sustainable materials, this study investigates the use of lignocellulosic fillers derived from sorghum (Sorghum bicolor L. Moench) biomass, specifically stems and leaves, as reinforcem...

  • Article
  • Open Access
894 Views
17 Pages

8 October 2025

The aim of present study is to deposit protective coatings with various surface chemical states on AZ91D Mg alloy. Hydrothermal bioactive ceramic coatings are performed with a surface modification by the chemical bonding of self-assembled monolayers...

  • Article
  • Open Access
1,142 Views
23 Pages

Synergistic Regulation of δ-MnO2 Cathode via Crystal Engineering and pH Buffering for Long-Cycle Aqueous Zinc-Ion Batteries

  • Fan Zhang,
  • Haotian Yu,
  • Qiongyue Zhang,
  • Yahao Wang,
  • Haodong Ren,
  • Huirong Liang,
  • Jinrui Li,
  • Yuanyuan Feng,
  • Bin Zhao and
  • Xiaogang Han

8 October 2025

Aqueous zinc-ion batteries (ZIBs) have emerged as a promising candidate for large-scale energy storage due to their inherent safety, low cost, and environmental friendliness. However, manganese dioxide (MnO2)-based cathodes, which are widely studied...

  • Article
  • Open Access
830 Views
27 Pages

8 October 2025

Precise forecasting of carbon content in the converter’s reblowing phase is pivotal to boosting steel production efficiency and ensuring effective control over molten steel quality. However, existing mechanistic models based on material balance...

  • Article
  • Open Access
2 Citations
929 Views
13 Pages

Analysis of Stator Material Influence on BLDC Motor Performance

  • Daniel Ziemiański,
  • Gabriela Chwalik-Pilszyk and
  • Grzegorz Dudzik

7 October 2025

Brushless DC (BLDC) motors are increasingly used in industrial applications due to their high efficiency, reliability, and low weight. However, their performance strongly depends on the electromagnetic properties of stator and rotor core materials. T...

  • Article
  • Open Access
2 Citations
692 Views
33 Pages

7 October 2025

An analysis of free vibrations for thin functionally graded plate bands is presented in this work. On the microlevel these plate bands have a tolerance-periodic microstructure in planes parallel to the mid-plane. Partial differential equations with t...

  • Article
  • Open Access
752 Views
13 Pages

Dimension Tailoring of Quasi-2D Perovskite Films Based on Atmosphere Control Toward Enhanced Amplified Spontaneous Emission

  • Zijia Wang,
  • Xuexuan Huang,
  • Zixuan Song,
  • Chiyu Guo,
  • Liang Tao,
  • Shibo Wei,
  • Ke Ren,
  • Yuze Wu,
  • Xuejiao Sun and
  • Chenghao Bi

7 October 2025

Quasi-two-dimensional (Q2D) perovskite films have garnered significant attention as novel gain media for lasers due to their tunable bandgap, narrow linewidth, and solution processability. Q2D perovskites endowed with intrinsic quantum well structure...

  • Article
  • Open Access
1 Citations
824 Views
26 Pages

7 October 2025

In order to investigate the basalt fiber influences on drying shrinkage of coal gangue ceramsite concrete, specimens with varying fiber dosages and matrix strength were prepared. The drying shrinkage (DS) was compared. To elucidate the characteristic...

  • Article
  • Open Access
1 Citations
931 Views
13 Pages

Mechanical Performance and Energy Absorption of Ti6Al4V I-WP Lattice Metamaterials Manufactured via Selective Laser Melting

  • Le Yu,
  • Xiong Xiao,
  • Xianyong Zhu,
  • Jiaan Liu,
  • Guangzhi Sun,
  • Yanheng Xu,
  • Song Yang,
  • Cheng Jiang and
  • Dongni Geng

7 October 2025

Metamaterial lattice structures based on a Triply Periodic Minimal Surface (TPMS) structure have attracted much attention due to their excellent mechanical properties and energy absorption capabilities. In this study, a novel TPMS lattice metamateria...

  • Article
  • Open Access
1 Citations
873 Views
28 Pages

7 October 2025

Waste management poses escalating threats to environmental sustainability, particularly with municipal solid waste (MSW) growth. Incineration, a widely adopted method for reducing waste volume, produces millions of tons of municipal solid waste incin...

  • Article
  • Open Access
848 Views
14 Pages

Microstructural Stability and Densification Behavior of Cantor-Type High-Entropy Alloy Processed by Spark Plasma Sintering

  • Marcin Madej,
  • Beata Leszczyńska-Madej,
  • Anna Kopeć-Surzyn,
  • Paweł Nieroda and
  • Stanislav Rusz

7 October 2025

High-entropy alloys (HEAs) of the Cantor type (CoCrFeMnNi) are widely recognized as model systems for studying the relationships between composition, microstructure, and functional performance. In this study, atomized Cantor alloy powders were consol...

  • Article
  • Open Access
798 Views
13 Pages

Wear Measurements in Cylindrical Telescopic Crowns Using an Active Piezoresistive Cantilever with an Integrated Gold Microsphere Probe

  • Tomasz Dąbrowa,
  • Dominik Badura,
  • Bartosz Pruchnik,
  • Władysław Kopczyński,
  • Ivo W. Rangelow,
  • Edward Kijak and
  • Teodor Gotszalk

7 October 2025

In this paper, we report a novel application of atomic force microscopy (AFM) for measurement of wear of prosthetic materials. In contrast to previously employed methods, we introduce AFM-based wear induction. In this way, we utilize AFM as both meas...

  • Article
  • Open Access
1,061 Views
18 Pages

Synthesis and Characterisation of Metal–Glass Composite Materials Fabricated by Liquid Phase Sintering

  • Vladimir Pavkov,
  • Gordana Bakić,
  • Vesna Maksimović and
  • Srećko Stopić

7 October 2025

In recent years, there has been a global increase in environmental awareness, which has driven the application of natural materials or the synthesis of novel, environmentally compatible materials. Composite materials hold a prominent position among m...

  • Article
  • Open Access
661 Views
12 Pages

Research on the Synthesis and Conductivity of Titanium Oxycarbide

  • Shaolong Li,
  • Fan Yang,
  • Peizhu Mao,
  • Tianzhu Mu,
  • Fuxing Zhu and
  • Shengwei Li

6 October 2025

In this study, TiCxOy was produced by sintering in an argon atmosphere using carbon–thermal reduction with TiO2 and graphite powder as the initial materials. The sintered TiCxOy was analyzed using X-ray diffraction, scanning electron microscopy...

  • Article
  • Open Access
707 Views
17 Pages

Structure and Phase Composition of the Products Derived from Vacuum–Thermal Treatment of a Tellurium-Containing Middling

  • Alina Nitsenko,
  • Xeniya Linnik,
  • Valeriy Volodin,
  • Sergey Trebukhov,
  • Bulat Sukurov,
  • Farkhad Tuleutay and
  • Tolebi Dzhienalyev

6 October 2025

In this paper, the results from a study of the products obtained by vacuum–thermal processing of industrial copper telluride in an inert atmosphere at a pressure of 66 Pa and a temperature of 1100 °C are presented. The residue obtained main...

  • Article
  • Open Access
786 Views
14 Pages

6 October 2025

The article presents a method for selecting spray coating systems for furnace walls and heat exchangers, aimed at protecting them and intensifying heat exchange processes. Calculations were made of the effect of the mutual emissivity coefficient betw...

  • Article
  • Open Access
662 Views
22 Pages

6 October 2025

This study developed the RATS (Range-Aware Two-Stage) modeling approach to establish mechanistic foundations for feed ratio optimization in fluoroelastomers. Using 19F NMR spectroscopic analysis, the approach decomposes complex composition–prop...

  • Article
  • Open Access
844 Views
18 Pages

6 October 2025

Inconel 625 is a nickel-based superalloy widely applied in aerospace and energy sectors due to its high strength and corrosion resistance. However, its poor machinability remains a significant challenge in precision manufacturing. This study investig...

  • Article
  • Open Access
801 Views
19 Pages

Microstructure and Mechanical and Corrosion Behavior of Novel High-Entropy CoCrFeNiSiVx (x = 0.25; 0.5; 0.75; 1.0) Alloys

  • Rafał Babilas,
  • Monika Spilka,
  • Katarzyna Młynarek-Żak,
  • Adrian Radoń,
  • Wojciech Łoński,
  • Krzysztof Matus and
  • Jakub Bicz

6 October 2025

In this work, a series of novel high-entropy alloys CoCrFeNiSiVx (x = 0.25; 0.5; 0.75; 1.0) with an intermetallic compound structure was proposed. The effect of vanadium addition on the structure, as well as selected mechanical and corrosion properti...

  • Article
  • Open Access
702 Views
19 Pages

6 October 2025

To address low-frequency vibration and noise issues in ship grating structures, this study proposes a novel acoustic optimization design method based on modulating flexural wave bandgap characteristics. By establishing an equivalent periodic spring-m...

  • Communication
  • Open Access
725 Views
13 Pages

5 October 2025

Redox flow batteries (RFBs) are a promising technology for large-scale energy storage due to their safety, scalability, and design flexibility. This study investigated a tiron-A (4,5-dihydroxybenzene-1,3-disulfonic acid)/tungstosilicic acid (TSA) RFB...

  • Article
  • Open Access
785 Views
13 Pages

Optical Absorption Properties of Sn- and Pd-doped ZnO: Comparative Analysis of Substitutional Metallic Impurities

  • Vicente Cisternas,
  • Pablo Díaz,
  • Ulises Guevara,
  • David Laroze and
  • Eduardo Cisternas

5 October 2025

In this article, we present density functional theory (DFT) calculations for Zn(1x)MxO, where M represents one of the following substitutional metallic impurities: Ga, Cd, Cu, Pd, Ag, In, or Sn. Our study is based on the wurtzite structure of...

  • Article
  • Open Access
867 Views
25 Pages

5 October 2025

Composite pressure vessels have attracted significant attention in recent years owing to their lightweight characteristics and superior mechanical performance. However, analyzing composite layers remains challenging due to complex filament-winding (F...

  • Article
  • Open Access
685 Views
25 Pages

5 October 2025

This study explored the feasibility of utilizing tunnel muck-derived recycled granite aggregates (RGAs) in surface-layer asphalt mixtures via hybrid with basalt aggregates. Firstly, RGAs, including coarse aggregates (RGCAs) and fine aggregates (RGFAs...

  • Article
  • Open Access
739 Views
17 Pages

5 October 2025

This study presents the modeling and analysis of a composite structure incorporating an embedded macro fiber composite (MFC) patch. MFC actuators are available in several variants, with types P1 and P2 being the most commonly used. In this paper, an...

  • Article
  • Open Access
800 Views
13 Pages

5 October 2025

Balancing stress wave attenuation with structural integrity is recognized as a critical challenge for protective materials in underground defense systems. A novel high-titanium slag (HTS) concrete featuring multiscale pores is proposed to address thi...

  • Article
  • Open Access
1,777 Views
30 Pages

Pea Pod Valorization: A Green Processing Route to Obtain Cellulosic Reinforcements for Compression Molded Polylactic Acid Biocomposites

  • Daniela Negrete-Bolagay,
  • Victor H. Guerrero,
  • Salomé Galeas,
  • Jennifer Tejedor,
  • Patricia I. Pontón and
  • Anja Dosen

4 October 2025

The valorization of agroindustrial residues represents a sustainable alternative in the production of materials attractive for sustainable technologies. In this work, cellulosic materials were isolated from treated pea pods aiming to obtain highly cr...

  • Article
  • Open Access
1 Citations
747 Views
23 Pages

4 October 2025

Expansive agents (CaO, MgO, C4A3Š) were incorporated into coal gangue-slag-fly ash based geopolymer (CSFG). The influence of expansive agents on the properties and microstructure of CSFG was investigated by macroscopic tests including setting time, c...

  • Article
  • Open Access
750 Views
18 Pages

Engineered Porosity in Microcrystalline Diamond-Reinforced PLLA Composites: Effects of Particle Concentration on Thermal and Structural Properties

  • Mateusz Ficek,
  • Franciszek Skiba,
  • Marcin Gnyba,
  • Gabriel Strugała,
  • Dominika Ferneza,
  • Tomasz Seramak,
  • Konrad Szustakiewicz and
  • Robert Bogdanowicz

4 October 2025

This research explores microcrystalline diamond particles in poly(L-lactic acid) matrices to create structured porous composites for advanced biodegradable materials. While nanodiamond–polymer composites are well-documented, microcrystalline di...

  • Article
  • Open Access
2 Citations
888 Views
26 Pages

Effect of SiO2 and MoS2 Particles as Lubricant Additives on Lubrication Performance in Sheet Metal Forming

  • Krzysztof Szwajka,
  • Tomasz Trzepieciński,
  • Marek Szewczyk and
  • Joanna Zielińska-Szwajka

4 October 2025

Modifying lubricants with hard material particles improves lubricant performance by allowing the particles to penetrate the contact area and separate the contacting surfaces. The use of solid particles as additives in fluid lubricants presents a prom...

  • Article
  • Open Access
1,025 Views
17 Pages

4 October 2025

Ensuring thermal stability is a major concern in lithium-ion battery systems. Although phase change materials (PCMs) provide a passive approach for temperature regulation, they are limited by poor heat conduction and potential leakage during phase tr...

  • Systematic Review
  • Open Access
1 Citations
2,198 Views
24 Pages

Evaluation of Factors Affecting Fluoride Release from Fluoride Varnishes: A Systematic Review

  • Maciej Dobrzyński,
  • Agnieszka Kotela,
  • Sylwia Klimas,
  • Zuzanna Majchrzak,
  • Julia Kensy,
  • Marzena Laszczyńska,
  • Mateusz Michalak,
  • Zbigniew Rybak,
  • Magdalena Fast and
  • Jacek Matys

4 October 2025

Introduction: Fluoride varnishes are widely used in caries prevention, but the rate and duration of fluoride ion release differ depending on material composition and environmental factors. Objectives: This systematic review synthesized evidence from...

  • Article
  • Open Access
1,271 Views
18 Pages

Analysis of Grain Growth Behavior of Intermetallic Compounds on Plated Pure Sn for Micropump Solder Caps

  • Hwa-Sun Park,
  • Chang-Yun Na,
  • Jong-Wook Kim,
  • Woon-Seok Jung,
  • Jae-Hyuk Park,
  • Jong-Woo Lim and
  • Youn-Goo Yang

3 October 2025

We evaluated for the morphology and growth behavior of IMC grain according to number of reflows of solder cap pure Sn microbumps. In the structure of Ni barrier/Cu layer between Cu pillar and pure Sn, solder cap pure Sn on the top layer was analyzed...

  • Article
  • Open Access
756 Views
15 Pages

3 October 2025

This study investigates the effects of Ar ion irradiation on the mechanical properties and microstructure of SA508 Grade 3 Class 1 and Class 2 reactor pressure vessel steels. Three different fluence levels of Ar ion irradiation were applied to simula...

  • Communication
  • Open Access
717 Views
9 Pages

Structure and Magnetic Properties of CNT-Reinforced Iron Composites

  • Chunxia Zhou,
  • Liang Yan,
  • Biao Yan,
  • Zhiya Han,
  • Yixiao Cao and
  • Xinyi Xu

3 October 2025

Fe-CNT composites were synthesized via mechanical ball milling, incorporating varying amounts of carbon nanotubes (CNTs) into iron powder at concentrations of 1 wt%, 2 wt%, and 3 wt%. The impact of different CNT contents on the phase structure, micro...

  • Article
  • Open Access
1 Citations
727 Views
16 Pages

3 October 2025

In this study, the decarburization behavior in basic oxygen furnace (BOF) steelmaking was investigated based on the multi-zone reaction mechanism. The contributions of the main reaction zones to decarburization were clarified, and the effects of key...

  • Article
  • Open Access
1 Citations
1,252 Views
15 Pages

3 October 2025

The proper selection of bioactive root-end material is one of the main prognostic factors for the successful healing outcome of apical microsurgery (AMS). The aim of the present in vitro study was to evaluate and compare the marginal adaptability of...

  • Article
  • Open Access
653 Views
18 Pages

3 October 2025

In this work, small amounts of Fe or Cr were added to Ni47Co3Mn36.5In13.5 alloy (x = 0) to produce five-component alloys with nominal compositions of Ni47Co3Mn35.5In13.5Fe1, Ni47Co3Mn33.5In13.5Fe3, Ni47Co3Mn35.5In13.5Cr1, and Ni47Co3Mn33.5In13.5Cr3,...

  • Article
  • Open Access
1,139 Views
23 Pages

An Experimental and FE Modeling Investigation of the Pull-Out Behavior of Anchoring Solutions in Concrete: A Comparative Study

  • Alexandru-Nicolae Bizu,
  • Dorina Nicolina Isopescu,
  • Gabriela Draghici and
  • Igor Blanari

3 October 2025

This article presents an original experimental and numerical approach to examining the pull-out behavior of fastening systems made of steel bars simultaneously embedded in both ends of concrete samples. This double-embedded configuration simulates a...

  • Article
  • Open Access
678 Views
22 Pages

3 October 2025

Rare-earth transition metal-based double perovskite ceramics E2TMO6 (where E = rare-earth metals, T = transition metals, and M = metal) have received impressive attention lately for cryogenic applications as a result of their intrinsic physical featu...

  • Article
  • Open Access
603 Views
14 Pages

3 October 2025

Sintered nano-silver paste is widely used in electronic packaging due to its excellent thermal and electrical conductivity. A phenomenological variable-order fractional constitutive model has been developed to characterize the evolution of its mechan...

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Materials - ISSN 1996-1944