Separation and Purification of Metals (Second Edition)

A special issue of Metals (ISSN 2075-4701). This special issue belongs to the section "Extractive Metallurgy".

Deadline for manuscript submissions: closed (31 May 2024) | Viewed by 1746

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School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China
Interests: ion flotation; precipitation flotation; floating extraction; deep separation
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Special Issue Information

Dear Colleagues,

We are pleased to announce a Special Issue of Metals (ISSN 2075-4701), entitled “Separation and Purification of Metals (Second Edition)”. In the past decades, many attempts have been made to optimize the extraction, separation, and purification of metals from abundant natural mineral or ore resources. With the rapid development of human industrialization, some metal and metal-based secondary resources can also be generated during successive material preparation, fabrication, and application processes. These types of secondary resources with high-value metals also show great recovery potential. However, clean extraction, separation, and purification of these metals, especially for rare metals with low or ultra-low concentrations, is extremely difficult. Currently, diverse processes for the separation and purification of metals from natural minerals or ores and from secondary resources are urgently needed.

This Special Issue will contain articles reporting new and progressive research results as well as reviews on fundamental aspects in the study of the separation and purification of metals and their applications. Manuscripts from both fundamental scientific researchers and authors from industrial companies involved in the field are welcome.

Prof. Dr. Guihong Han
Guest Editor

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Keywords

  • selective separation
  • solvent extraction
  • microbubble flotation
  • adsorption
  • ion exchange
  • rare metal
  • hydrometallurgy
  • pyrometallurgy
  • electrometallurgy
  • biometallurgy

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Published Papers (2 papers)

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Research

18 pages, 9191 KiB  
Article
Impact of 5-Amino-1H Tetrazole on Reducing Silver in Copper Cathodes during Electrorefining with High Silver Content Anode Plates
by Chen Chen, Chu Cheng, Mengxin Wang, Haitao Liu, Xiaoheng Li and Kexing Song
Metals 2024, 14(7), 799; https://doi.org/10.3390/met14070799 - 8 Jul 2024
Viewed by 697
Abstract
As the grade of the copper concentrate decreases and its composition becomes increasingly complex, the silver content in anode plates cast after fire refining increases, leading to a higher silver content in the copper cathode during electrorefining and a substantial loss of precious [...] Read more.
As the grade of the copper concentrate decreases and its composition becomes increasingly complex, the silver content in anode plates cast after fire refining increases, leading to a higher silver content in the copper cathode during electrorefining and a substantial loss of precious metals. This study investigates the impact of 5-amino-1H tetrazole (5-AT) on reducing silver in copper cathodes during electrorefining with high silver content anode plates. 5-AT forms an “adsorption layer” on the anode surface, reacting with Ag+ released by the anode to form a precipitate and prevent Ag+ from entering the electrolyte. This process agglomerates fine Ag-Se compounds and AgCl particles, creating larger anode slime particles that settle quickly, thus inhibiting fine silver-containing particles from adhering to the cathode. Furthermore, 5-AT adsorbs on the cathode, binding with Cu+ and promoting the Cu2+ electrodeposition process while inhibiting Ag+ electrodeposition. This facilitates uniform copper cathode grain growth and reduces inclusions in the copper cathode. The grain size of the copper cathode initially decreases and then increases as the concentration of 5-AT increases. At an optimal 5-AT concentration of 15 mg/L, the Ag content in the copper cathode decreased from 6.9 ppm to 4.7 ppm, indicating the potential efficacy of 5-AT in improving the quality of electrorefined copper. Full article
(This article belongs to the Special Issue Separation and Purification of Metals (Second Edition))
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14 pages, 2122 KiB  
Article
On the Problem of the Distillation Separation of Secondary Alloys of Magnesium with Zinc and Magnesium with Cadmium
by Valeriy Volodin, Bagdaulet Kenzhaliyev, Sergey Trebukhov, Alina Nitsenko, Xeniya Linnik and Alexey Trebukhov
Metals 2024, 14(6), 671; https://doi.org/10.3390/met14060671 - 5 Jun 2024
Cited by 1 | Viewed by 610
Abstract
An alternative to the existing method of processing secondary magnesium raw materials by remelting in a salt furnace can be distillation separation into volatile metals (Mg, Zn and Cd), low-volatile metals (Al, Mn and Zr) and rare earth elements. The separation of metals [...] Read more.
An alternative to the existing method of processing secondary magnesium raw materials by remelting in a salt furnace can be distillation separation into volatile metals (Mg, Zn and Cd), low-volatile metals (Al, Mn and Zr) and rare earth elements. The separation of metals may be tracked based on phase diagrams where the field boundaries of the vapor–liquid equilibrium are plotted. Due to the fact that Mg, Zn and Cd have comparable saturated vapor pressures, the possibility of the distillation separation of Mg–Zn and Mg–Cd systems using full state diagrams including the melt–vapor phase transition boundaries were determined in this work. The boundaries of these systems were calculated based on the partial values of saturated vapor, determined by the boiling point method, and presented in the form of temperature–concentration dependencies with the indicated boundaries. The field boundaries were calculated (L + V) at atmospheric pressure (101.33 kPa) and in vacuum (1.33 kPa and 0.7 kPa,) supposing the implementation of the process. The possibility of the separate extraction of zinc and cadmium from magnesium was considered using complete phase diagrams including the boundaries of the melt–steam phase transition. When considering the boundaries of the vapor–liquid equilibrium in the binary systems Mg–Zn and Mg–Cd, it was established that it is impossible to separate metals in one “evaporation–condensation” cycle in a vacuum of 1.33 and 0.7 kPa. The problem is caused by the small size of the fields (L + V) at the temperature, which suggests processes of the re-evaporation of the condensate from the previous distillation stage. The separation of zinc and cadmium from liquid alloys with magnesium under equilibrium conditions requires several repetitions of the condensate distillation process. In non-equilibrium conditions, the real processes will require a larger number of conversions. This implies the expediency of the joint evaporation of magnesium with zinc and cadmium and the use of condensate for additional charging to liquid magnesium, and the remainder of the distillation, where volatile metals such as Al, Mn, Zr and rare earth elements will be concentrated, should be directed to the preparation of ligatures for special magnesium-based alloys. Full article
(This article belongs to the Special Issue Separation and Purification of Metals (Second Edition))
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