Diamond-Based Microsystems

A special issue of Micromachines (ISSN 2072-666X). This special issue belongs to the section "D:Materials and Processing".

Deadline for manuscript submissions: closed (31 July 2020) | Viewed by 3690

Special Issue Editor


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Guest Editor
CEA, LIST, Diamond Sensors Laboratory, 91191 Gif Sur Yvette, France
Interests: chemical sensors; gas sensors; medical implantable devices; diamond microsystems; diamond materials; MEMS/NEMS

Special Issue Information

Dear Colleagues,

Diamond features a wide range of outstanding physical and chemical properties that offer many promises for new and extreme applications, ranging from power electronics and bipolar high-frequency devices to quantum sensing, heat spreaders, chemical/biochemical sensing, microdosimetry, and in-vivo neural interfacing, to name a few. Diamond-based MEMS/NEMS devices can benefit, for instance, from the material’s exceptional mechanical properties, including a Young’s modulus approaching 1100 GPa. Such devices will find applications in chemical/biochemical sensors, RF switches, microresonators for harsh environments, and so on. Recent technologies have also been developed to produce nitrogen-vacancies (NV) centers in the close vicinity of the diamond surfaces, with long spin coherence time constants. Here, the application of NV centers for magnetometry gains increasing momentum for the future generation of navigation devices, magnetic resonance imaging, local current sensing, and many more. Furthermore, hybrid diamond-/GaN-based MMICs have been demonstrated, taking advantage of the highest known thermal conductivity of diamond (1600–2000 W·m−1·K−1) to achieve, for example, ultra-high data rate communication devices, even though challenges like those associated with the thermal barrier resistance between GaN and high thermally conducting diamond substrates remain. Furthermore, when doped with boron, diamond makes a remarkable electrode material, with a low intrinsic capacitive current and wide potential window in aqueous media, offering many opportunities for high-performance analytical sensing. The biocompatibility of diamond, along with its high stability, is also extremly attractive for implantable stimulating electrodes. Recent examples include retinal implants. Diamond-based electron emitters for the generation of solvated electrons in buffer solutions are also currently being developed, typically for CO2 reduction. Thus, with this Special Issue, we welcome research papers in these areas where recent progress in diamond processing techniques, including surface smooting, patterning, etching, deposition on exotic materials, and so on, enables the development of “diamond-based microsystems” that address some of the important challenges of our societies in the medical, security, energy, and technology domains.

Dr. Emmanuel Scorsone
Guest Editor

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Keywords

  • Diamond microsystems
  • MEMS/NEMS
  • Microsystems for magnetometry and single photon-generation
  • Bio/chemical sensors
  • Electronic components
  • Implantable devices
  • Bio-interfaces
  • Electrophysiology
  • Electrochemical sensors
  • Microdosimeters

Published Papers (1 paper)

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Review

21 pages, 4597 KiB  
Review
Diamond Deposition on Iron and Steel Substrates: A Review
by Xiaoju Li, Lianlong He, Yuanshi Li and Qiaoqin Yang
Micromachines 2020, 11(8), 719; https://doi.org/10.3390/mi11080719 - 24 Jul 2020
Cited by 18 | Viewed by 3433
Abstract
This article presents an overview of the research in chemical vapor deposition (CVD) diamond films on steel substrates. Since the steels are the most commonly used and cost-effective structural materials in modern industry, CVD coating diamond films on steel substrates are extremely important, [...] Read more.
This article presents an overview of the research in chemical vapor deposition (CVD) diamond films on steel substrates. Since the steels are the most commonly used and cost-effective structural materials in modern industry, CVD coating diamond films on steel substrates are extremely important, combining the unique surface properties of diamond with the superior toughness and strength of the core steel substrates, and will open up many new applications in the industry. However, CVD diamond deposition on steel substrates continues to be a persistent problem. We go through the most relevant results of the last two and a half decades, including recent advances in our group. This review discusses the essential reason of the thick catalytic graphite interlayer formed on steel substrates before diamond deposition. The high carbon diffusion in iron would induce severe internal carburization, and then voluminous graphite precipitated from the substrate. In order to hinder the catalytic graphite formation, various methods have been applied for the adherent diamond film deposition, such as pre-imposed various interlayers or multi-interlayers, special controls of the deposition process, the approaches of substrate alloying and so on. We found that adherent diamond films can be directly deposited on Al alloying steel substrates, and then the role of Al alloying element was examined. That is a thin dense amorphous alumina sublayer in situ formed on the alloying substrate, which played a critical role in preventing the formation of graphite phase and consequently enhancing diamond growth and adhesion. The mechanism of Al alloying suggests that the way used to improve hot corrosion resistance is also applicable. Then, some of the hot corrosion resistance methods, such as aluminizing, siliconizing, and so on, which have been used by some researchers examining CVD diamond films on steel substrates, are reviewed. Another way is to prepare diamond-like carbon (DLC) films on steel substrates at low temperature, and then the precipitated graphite from the internal carburization can be effectively avoided. In addition, based on some new findings, the understanding of the diamond nucleation and metastable growth is discussed. Full article
(This article belongs to the Special Issue Diamond-Based Microsystems)
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