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Feature Papers in Applied Chemistry: 3rd Edition

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Applied Chemistry".

Deadline for manuscript submissions: 31 July 2024 | Viewed by 1255

Special Issue Editor


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Guest Editor
Low-Carbon Technology & Chemical Reaction Engineering Lab, College of Chemical Engineering, Sichuan University, Chengdu 610065, China
Interests: nano environmental materials; adsorption; CO2 capture; supercapacitor; supwetting surfaces for oil/water separation
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Special Issue Information

Dear Colleagues,

It is our pleasure to announce a Special Issue entitled “Feature Papers in Applied Chemistry: 3rd Edition”. This is a collection of important high-quality papers (original research articles or comprehensive review papers) published in an open access format by Editorial Board Members or prominent scholars invited by the Editorial Office and the Guest Editors. This Special Issue aims to discuss new knowledge or cutting-edge developments in the applied chemistry research field through selected works, in the hopes of making a great contribution to the community. We aim for this Special Issue to be the best forum for disseminating research findings and sharing innovative ideas in the field.

Prof. Dr. Shaojun Yuan
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Molecules is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • applied chemistry
  • new molecules/materials
  • analytical methods and techniques
  • electrochemistry and catalysis
  • new materials and medicines

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Published Papers (3 papers)

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Research

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14 pages, 2507 KiB  
Article
Carbon Dots Anchoring Single-Atom Pt on C3N4 Boosting Photocatalytic Hydrogen Evolution
by Jing Wang, Jiayu Song, Xin Kang, Dongxu Wang, Chungui Tian, Qin Zhang, Hui Zhao and Jiancong Liu
Molecules 2024, 29(8), 1890; https://doi.org/10.3390/molecules29081890 - 21 Apr 2024
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Abstract
Carbon nitride (C3N4) has gained considerable attention and has been regarded as an ideal candidate for photocatalytic hydrogen evolution. However, its photocatalytic efficiency is still unsatisfactory due to the rapid recombination rate of photo-generated carriers and restricted surface area [...] Read more.
Carbon nitride (C3N4) has gained considerable attention and has been regarded as an ideal candidate for photocatalytic hydrogen evolution. However, its photocatalytic efficiency is still unsatisfactory due to the rapid recombination rate of photo-generated carriers and restricted surface area with few active sites. Herein, we successfully synthesized a single-atom Pt cocatalyst-loaded photocatalyst by utilizing the anchoring effect of carbon dots (CDs) on C3N4. The introduction of CDs onto the porous C3N4 matrix can greatly enhance the specific surface area of C3N4 to provide more surface-active sites, increase light absorption capabilities, as well as improve the charge separation efficiency. Notably, the functional groups of CDs can efficiently anchor the single-atom Pt, thus improving the atomic utilization efficiency of Pt cocatalysts. A strong interaction is formed via the connection of Pt-N bonds, which enhances the efficiency of photogenerated electron separation. This unique structure remarkably improves its H2 evolution performance under visible light irradiation with a rate of 15.09 mmol h−1 g−1. This work provides a new approach to constructing efficient photocatalysts by using CDs for sustainable hydrogen generation, offering a practical approach to utilizing solar energy for clean fuel production. Full article
(This article belongs to the Special Issue Feature Papers in Applied Chemistry: 3rd Edition)
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21 pages, 6181 KiB  
Article
Emulsion Liquid Membranes Based on Os–NP/n–Decanol or n–Dodecanol Nanodispersions for p–Nitrophenol Reduction
by Andreia Pîrțac, Aurelia Cristina Nechifor, Szidonia-Katalin Tanczos, Ovidiu Cristian Oprea, Alexandra Raluca Grosu, Cristian Matei, Vlad-Alexandru Grosu, Bogdan Ștefan Vasile, Paul Constantin Albu and Gheorghe Nechifor
Molecules 2024, 29(8), 1842; https://doi.org/10.3390/molecules29081842 - 18 Apr 2024
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Abstract
Membrane materials with osmium nanoparticles have been recently reported for bulk membranes and supported composite membrane systems. In the present paper, a catalytic material based on osmium dispersed in n–decanol (nD) or n–dodecanol (nDD) is presented, which also works as an emulsion membrane. [...] Read more.
Membrane materials with osmium nanoparticles have been recently reported for bulk membranes and supported composite membrane systems. In the present paper, a catalytic material based on osmium dispersed in n–decanol (nD) or n–dodecanol (nDD) is presented, which also works as an emulsion membrane. The hydrogenation of p–nitrophenol (PNP) is carried out in a reaction and separation column in which an emulsion in the acid-receiving phase is dispersed in an osmium nanodispersion in n–alcohols. The variables of the PNP conversion process and p–aminophenol (PAP) transport are as follows: the nature of the membrane alcohol, the flow regime, the pH difference between the source and receiving phases and the number of operating cycles. The conversion results are in all cases better for nD than nDD. The counter-current flow regime is superior to the co-current flow. Increasing the pH difference between the source and receiving phases amplifies the process. The number of operating cycles is limited to five, after which the regeneration of the membrane dispersion is required. The apparent catalytic rate constant (kapp) of the new catalytic material based on the emulsion membrane with the nanodispersion of osmium nanoparticles (0.1 × 10−3 s−1 for n–dodecanol and 0.9 × 10−3 s−1 for n–decanol) is lower by an order of magnitude compared to those based on adsorption on catalysts from the platinum metal group. The advantage of the tested membrane catalytic material is that it extracts p–aminophenol in the acid-receiving phase. Full article
(This article belongs to the Special Issue Feature Papers in Applied Chemistry: 3rd Edition)
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Review

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30 pages, 8167 KiB  
Review
Recent Advances in the Nickel-Catalyzed Alkylation of C-H Bonds
by Franc Požgan, Uroš Grošelj, Jurij Svete, Bogdan Štefane and Hamad H. Al Mamari
Molecules 2024, 29(9), 1917; https://doi.org/10.3390/molecules29091917 - 23 Apr 2024
Viewed by 251
Abstract
Functionalization of C-H bonds has emerged as a powerful strategy for converting inert, nonfunctional C-H bonds into their reactive counterparts. A wide range of C-H bond functionalization reactions has become possible by the catalysis of metals, typically from the second row of transition [...] Read more.
Functionalization of C-H bonds has emerged as a powerful strategy for converting inert, nonfunctional C-H bonds into their reactive counterparts. A wide range of C-H bond functionalization reactions has become possible by the catalysis of metals, typically from the second row of transition metals. First-row transition metals can also catalyze C-H functionalization, and they have the merits of greater earth-abundance, lower cost and better environmental friendliness in comparison to their second-row counterparts. C-H bond alkylation is a particularly important C-H functionalization reaction due to its chemical significance and its applications in natural product synthesis. This review covers Ni-catalyzed C-H bond alkylation reactions using alkyl halides and olefins as alkyl sources. Full article
(This article belongs to the Special Issue Feature Papers in Applied Chemistry: 3rd Edition)
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