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Hydrophilic and Hydrophobic Natural Polymer Materials

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Analysis and Characterization".

Deadline for manuscript submissions: closed (31 October 2023) | Viewed by 19457

Special Issue Editors


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Guest Editor
Designer Energy, 2, Bergman Street, Rehovot 7670504, Israel
Interests: plant biomass, composition, structure, chemistry and use; nanotechnology of natural polymers; nanoparticles; nanofibrils; chemistry, technology; nanotechnology of cellulose and other polysaccharides; polymer chemistry; structure and properties of macromolecular compounds; biochemicals; bioenergy
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Guest Editor
Israeli Association of Inventors, 3a Shimkinst, Haifa, Israel
Interests: nanotechnology; material science; conducting polymers; adhesion; polymer rheology; polymer composites; nanocellulose

Special Issue Information

Dear Colleagues,

Natural polymers involve a wide group of high-molecular compounds having different molecular and supramolecular structures, which can be isolated from land plants (lignin, cellulose, hemicelluloses, and other polysaccharides), land animals (wool, keratin, proteins, etc.), algae & sea animals (agar, proteins, chitin, chitosan, etc.), organisms (proteins, RNA, DNA), and other natural sources. These natural polymers are widespread on Earth and have great scientific and practical significance. Important features of natural polymers are their reproducibility and biodegradability in nature. Thanks to their reproducibility, natural polymers are an inexhaustible source of raw materials. On the other hand, after use, diverse products made from natural polymers decompose in nature under the action of microorganisms and do not pollute the environment.

Despite the difference in structure and origin, most natural polymers contain polar groups (hydroxyl, carboxyl, ether, ester, amino groups, etc.), which impart them increased hydrophilicity. Due to their hydrophilicity, natural polymers find application in the technologies of sorbents, absorbents, thickeners, excipients, carriers, fillers, and biocompatible materials for their wide use in medicine, cosmetics, pharmaceutics, hygiene, biology, chemistry, material engineering, environmental protection, and other areas.

An additional important property of natural polymers is the possibility of their chemical modification by replacing hydrophilic groups with hydrophobic ones. The methods of physicochemical methods include the coating of hydrophilic natural polymers with hydrophobic melts or latexes. Due to these modification methods, hydrophilic natural polymers turn to hydrophobic waterproof and vaporproof materials, which can be used, for example, for the production of hydrophobic fillers and reinforcements compatible with hydrophobic binders and with hydrophobic compositions of coatings, paints, adhesives, and other hydrophobic materials.

This special issue is devoted to the novel studies and applications of natural hydrophilic polymers, and promising methods of their modification to create hydrophobic polymers and materials, to study structure and properties, as well as to the use of modified polymers or materials. Both original research articles and reviews are encouraged.

Dr. Michael Ioelovich
Prof. Dr. Oleg L. Figovsky
Guest Editors

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Keywords

  • hydrophilic
  • hydrophobic
  • plant polymers
  • animal polymers
  • biopolymers
  • natural polymers from sea animals and algae
  • methods of hydrophobization and superhydrophbization
  • methods of investigation of hydrophobic/superhydrophobic natural polymers and materials
  • structure
  • properties
  • applications

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Published Papers (4 papers)

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Research

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13 pages, 3394 KiB  
Article
New Copolymers of Vinylphosphonic Acid with Hydrophilic Monomers and Their Eu3+ Complexes
by Olga Nazarova, Elena Chesnokova, Tatyana Nekrasova, Yulia Zolotova, Anatoliy Dobrodumov, Elena Vlasova, Andrei Fischer, Marina Bezrukova and Eugeniy Panarin
Polymers 2022, 14(3), 590; https://doi.org/10.3390/polym14030590 - 31 Jan 2022
Cited by 3 | Viewed by 3102
Abstract
Free radical copolymerization is used for the synthesis of novel water-soluble copolymers of vinylphosphonic acid with 2-deoxy-2-methacrylamido-D-glucose or 4-acryloylmorpholine, with varied compositions and molecular masses, as well as for the synthesis of copolymers of vinylphosphonic acid with acrylamide. The obtained copolymers contain 6–97 [...] Read more.
Free radical copolymerization is used for the synthesis of novel water-soluble copolymers of vinylphosphonic acid with 2-deoxy-2-methacrylamido-D-glucose or 4-acryloylmorpholine, with varied compositions and molecular masses, as well as for the synthesis of copolymers of vinylphosphonic acid with acrylamide. The obtained copolymers contain 6–97 mol.% of vinylphosphonic acid units, and their molecular masses vary from 5 × 103 to 310 × 103. The monomer reactivity ratios of vinylphosphonic acid and 2-deoxy-2-methacrylamido-D-glucose in copolymerization are determined for the first time, and their values are 0.04 and 9.02, correspondingly. It is demonstrated that the synthesized copolymers form luminescent mixed-ligand complexes with Eu3+, thenoyltrifluoroacetone, and phenanthroline. The influence of the comonomer’s nature on the intensity of the luminescence of complex solutions is revealed. Full article
(This article belongs to the Special Issue Hydrophilic and Hydrophobic Natural Polymer Materials)
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11 pages, 1641 KiB  
Article
Adjustment of Hydrophobic Properties of Cellulose Materials
by Michael Ioelovich
Polymers 2021, 13(8), 1241; https://doi.org/10.3390/polym13081241 - 12 Apr 2021
Cited by 23 | Viewed by 5199
Abstract
In this study, physicochemical and chemical methods of cellulose modification were used to increase the hydrophobicity of this natural semicrystalline biopolymer. It has been shown that acid hydrolysis of the initial cellulose increases its crystallinity, which improves hydrophobicity, but only to a small [...] Read more.
In this study, physicochemical and chemical methods of cellulose modification were used to increase the hydrophobicity of this natural semicrystalline biopolymer. It has been shown that acid hydrolysis of the initial cellulose increases its crystallinity, which improves hydrophobicity, but only to a small extent. A more significant hydrophobization effect was observed after chemical modification by esterification, when polar hydroxyl groups of cellulose were replaced by non-polar substituents. The esterification process was accompanied by the disruption of the crystalline structure of cellulose and its transformation into the mesomorphous structure of cellulose esters. It was found that the replacement of cellulose hydroxyls with ester groups leads to a significant increase in the hydrophobicity of the resulting polymer. Moreover, the increase of the number of non-polar groups in the ester substituent contributes to rise in hydrophobicity of cellulose derivative. Depending on the type of ester group, the hydrophobicity increased in the following order: acetate < propionate < butyrate. Therefore, tributyrate cellulose (TBC) demonstrated the most hydrophobicity among all studied samples. In addition, the mixed ester, triacetobutyrate cellulose (TAB), also showed a sufficiently high hydrophobicity. The promising performance properties of hydrophobic cellulose esters, TBC and TAB, were also demonstrated. Full article
(This article belongs to the Special Issue Hydrophilic and Hydrophobic Natural Polymer Materials)
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Review

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21 pages, 3017 KiB  
Review
Preparation, Characterization and Application of Amorphized Cellulose—A Review
by Michael Ioelovich
Polymers 2021, 13(24), 4313; https://doi.org/10.3390/polym13244313 - 9 Dec 2021
Cited by 27 | Viewed by 3772
Abstract
This review describes the methods of cellulose amorphization, such as dry grinding, mercerization, treatment with liquid ammonia, swelling in solvents, regeneration from solutions, etc. In addition, the main characteristics and applications of amorphized celluloses are discussed. An optimal method for preparing completely amorphous [...] Read more.
This review describes the methods of cellulose amorphization, such as dry grinding, mercerization, treatment with liquid ammonia, swelling in solvents, regeneration from solutions, etc. In addition, the main characteristics and applications of amorphized celluloses are discussed. An optimal method for preparing completely amorphous cellulose (CAC) via the treatment of original cellulose material with a cold NaOH/Urea-solvent at the solvent to cellulose ratio R ≥ 5 is proposed. Structural studies show that amorphous cellulose contains mesomorphous clusters with a size of 1.85 nm and specific gravity of 1.49 g/cm3. Furthermore, each such cluster consists of about five glucopyranose layers with an average interlayer spacing of 0.45 nm. Amorphous cellulose is characterized by increased hydrophilicity, reactivity, and enzymatic digestibility. Due to its amorphous structure, the CAC can be used as a promising substrate for enzymatic hydrolysis to produce glucose, which can be applied in biotechnology for growing various microorganisms. In addition, the application of CAC in agriculture is described. A waste-free method for producing amorphous nanocellulose is considered, and the main applications of nanosized amorphous cellulose are discussed. Full article
(This article belongs to the Special Issue Hydrophilic and Hydrophobic Natural Polymer Materials)
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34 pages, 14084 KiB  
Review
Recent Advances on Cellulose Nanocrystals and Their Derivatives
by Shuting Peng, Qiguan Luo, Guofu Zhou and Xuezhu Xu
Polymers 2021, 13(19), 3247; https://doi.org/10.3390/polym13193247 - 24 Sep 2021
Cited by 23 | Viewed by 4031
Abstract
Nanocellulose, typically cellulose nanocrystals (CNCs), has excellent properties and is widely used. In particular, CNC has a small dimension, high chemical reactivity, and high sustainability, which makes it an excellent candidate as a starting material to be converted into nanocellulose derivatives. Chemical modification [...] Read more.
Nanocellulose, typically cellulose nanocrystals (CNCs), has excellent properties and is widely used. In particular, CNC has a small dimension, high chemical reactivity, and high sustainability, which makes it an excellent candidate as a starting material to be converted into nanocellulose derivatives. Chemical modification is essential for obtaining the desired products; the modifications create different functional attachment levels and generate novel microstructures. Recent advances on nanocellulose derivatives have not yet been reviewed and evaluated for the last five years. Nanocellulose derivative materials are being used in a wide variety of high-quality functional applications. To meet these requirements, it is essential for researchers to fully understand CNCs and derivative materials, precisely their characteristics, synthesis methods, and chemical modification approaches. This paper discusses CNC and its derivatives concerning the structural characteristics, performance, and synthesis methods, comparing the pros and cons of these chemical modification approaches reported in recent years. This review also discusses the critical physicochemical properties of CNC derivative products, including solubility, wetting performance, and associated impacts on properties. Lastly, this paper also comments on the bottlenecks of nanocellulose derivatives in various applications and briefly discusses their future research direction. Full article
(This article belongs to the Special Issue Hydrophilic and Hydrophobic Natural Polymer Materials)
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