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Performance Enhancement and Sustainable Application of Cellulose

A special issue of Sustainability (ISSN 2071-1050). This special issue belongs to the section "Sustainable Materials".

Deadline for manuscript submissions: closed (15 April 2023) | Viewed by 4664

Special Issue Editors


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Guest Editor
Faculty of Technology and Metallurgy, University of Belgrade, 11000 Belgrade, Serbia
Interests: fiber science, functionalization of cellulose fibers; cellulose dissolution and regeneration; surface chemistry; bioactive fibers; medical textiles

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Guest Editor
Department of Textile Technology, Innovation Center of the Faculty of Technology and Metallurgy in Belgrade, 11000 Belgrade, Serbia
Interests: cellulose-based adsorbents; wastewater treatment; waste valorization as adsorbents; adsorption of heavy metal ions and organic dyes onto lignocellulosic and cellulose-based waste; circular economy concept for textile waste
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Special Issue Information

Dear Colleagues,

In the recent decade, due to the continuous growth of the population and economic development of human society linked with increasing demands in fuels, raw chemicals, and materials, demand for abundant and sustainable feedstocks is continuously increasing as well. Since plants can produce more than 1.5 × 1012 tons of cellulose every year, cellulose has gained worldwide attention from both industry and academia. Among traditional applications in the textile and paper industry, cellulose is used as starting materials in packaging materials, promising bio-based fillers, versatile light-weight construction materials, sorbents in water treatment, UV radiation shielding, wound dressing and self-cleaning textiles, selective nanostructured membranes and thin films, high-performance composites, electronics, fuel cells, cell-based sensors, vascular grafts, drug delivery, bio-inspired mechanically adaptive materials, etc. The advantages of cellulose in such applications include, besides a relative abundance and the availability from renewable resources, low density, high mechanical properties, good reactivity of hydroxyl groups and easy adjustment/tailoring of surface/bulk properties, non-toxicity, biocompatibility, recyclability, and biodegradability. However, cellulose-based materials have several disadvantages related to their poor barrier to water vapor and oxygen, low compatibility with hydrophobic materials, and flammability. Nevertheless, these disadvantages can be minimized by combining cellulose with different biopolymers and inorganic particles or by its chemical modifications.

The present Special Issue is dedicated to the performance enhancement of cellulose and cellulose-based materials, whose usage will improve sustainability by reducing waste and toxic emissions, leading to a greener and cleaner environment. Special emphasis can be put on the functionalization, characterization, and structure-properties relationship to achieve appropriate physical forms and properties for targeted applications and functionalities. Studies concerning the sustainable use of biomass targeting the idea of converting the linear path of materials (extraction, use, disposal in landfill) to a circular material flow that reuses materials as much as possible, are also welcomed.

It is our pleasure to invite academics and experts from the industry to submit a manuscript for this Special issue. We aim to present original articles, short communications, and reviews on topics related to performance enhancement and sustainable application of cellulose.

Prof. Dr. Mirjana Kostic
Dr. Aleksandra Ivanovska
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Sustainability is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2400 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • cellulose natural fibers
  • regenerated cellulose fibers and films
  • cellulose nanocrystals, nano- and microfibrillated cellulose
  • cellulose functionalization
  • cellulose-derived materials
  • agro-industrial byproduct and waste as a source of cellulose and nanocellulose
  • green composites/ nanocomposites/materials
  • advanced carbon materials
  • cellulose-based sorbents for different organic and inorganic pollutants
  • revalorization of cellulose-based sorbents with adsorbed pollutants
  • active and intelligent food packaging
  • materials for biomedical applications
  • sustainable cellulose-based material processing
  • recycling and recovery
  • materials circularity, circular economy

Published Papers (2 papers)

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Research

14 pages, 4358 KiB  
Article
Plasma Treatment as a Sustainable Method for Enhancing the Wettability of Jute Fabrics
by Aleksandra Ivanovska, Marija Milošević, Bratislav Obradović, Zorica Svirčev and Mirjana Kostić
Sustainability 2023, 15(3), 2125; https://doi.org/10.3390/su15032125 - 23 Jan 2023
Cited by 8 | Viewed by 1959
Abstract
In this paper, raw jute fabric was subjected to atmospheric pressure dielectric barrier discharge (at 150 or 300 Hz) to enhance its wettability, i.e., capillarity and wetting time. Attenuated Total Reflectance-Fourier Transform Infrared (ATR-FTIR) spectroscopy and Field Emission Scanning Electron Microscopy (FE-SEM) were [...] Read more.
In this paper, raw jute fabric was subjected to atmospheric pressure dielectric barrier discharge (at 150 or 300 Hz) to enhance its wettability, i.e., capillarity and wetting time. Attenuated Total Reflectance-Fourier Transform Infrared (ATR-FTIR) spectroscopy and Field Emission Scanning Electron Microscopy (FE-SEM) were used to assess the changes in the fabrics’ surface chemistry and morphology induced by plasma treatments. The obtained results revealed that both plasma treatments enhanced the wettability of jute fabrics, which could be ascribed to the changes in the fibers’ surface chemistry (the removal of non-cellulosic components, exposure of the cellulose molecules, and oxidation) and morphology (increased roughness due to etching of the surface layers and partial fibrillation). Capillary rise heights increased by approximately 1.8 and 1.9 times, and wetting times were 35 and 34 times shorter 24 h after the plasma treatment at 150 and 300 Hz, respectively. Special attention was given to the aging effect of plasma treatment indicated no significant changes in the fabrics’ capillarity and wetting time after 28 and 7 days, respectively, proving the durability of the effects of plasma treatment. Plasma-treated raw jute fabrics could be used as water-binding geo-prebiotic polysaccharide supports to provide the necessary water for the initial growth of cyanobacterial biocrusts. The lack of moisture is the main constraint in biocrust development after cyanobacterial inoculation. The combination of such water-supportive fabrics and cyanobacterial strains could be used for the rehabilitation of various degraded lands, sediments, and substrates, as well as for air and water pollution control. Full article
(This article belongs to the Special Issue Performance Enhancement and Sustainable Application of Cellulose)
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19 pages, 4697 KiB  
Article
Mechanical and Shape Memory Properties of 3D-Printed Cellulose Nanocrystal (CNC)-Reinforced Polylactic Acid Bionanocomposites for Potential 4D Applications
by Victor Chike Agbakoba, Percy Hlangothi, Jerome Andrew and Maya Jacob John
Sustainability 2022, 14(19), 12759; https://doi.org/10.3390/su141912759 - 7 Oct 2022
Cited by 10 | Viewed by 2036
Abstract
There is a growing need for diversified material feedstock for 3D printing technologies such as fused deposition modelling (FDM) techniques. This has resulted in an increased drive in the research and development of eco-friendly biopolymer-based composites with wide applications. At present, bionanocomposites of [...] Read more.
There is a growing need for diversified material feedstock for 3D printing technologies such as fused deposition modelling (FDM) techniques. This has resulted in an increased drive in the research and development of eco-friendly biopolymer-based composites with wide applications. At present, bionanocomposites of polylactic acid (PLA), biopolymer, and cellulose nanocrystals (CNCs) offer promising technical qualities suitable for FDM 3D printing applications due to their biodegradability and wide-ranging applications. In this work, the applicability of the PLA/CNCs bionanocomposites in 4D applications was investigated by studying its shape-recovery behaviour. Tensile and dynamic mechanical analysis (DMA) was used to elucidate the mechanical and flexural properties of the 3D-printed specimens. The results revealed improvement in the deflection temperature under load (DTUL), creep deformation, and recovery of the PLA/CNCs bionanocomposites. Tensile and static 3-point bending analyses of the bionanocomposites revealed improved tensile strength and modulus of the 3D printed parts. The potential 4D application of the PLA/CNCs bionanocomposites was also investigated by successfully printing PLA/CNC bionanocomposites directly onto a nylon fabric. The PLA/CNCs-fabric prototype included a foldable cube and grid-patterned designs. Additionally, the heat-induced shape memory behaviour of these prototypes was demonstrated. Full article
(This article belongs to the Special Issue Performance Enhancement and Sustainable Application of Cellulose)
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