Monitoring and Assessment of Mercury Pollution

A special issue of Toxics (ISSN 2305-6304). This special issue belongs to the section "Ecotoxicology".

Deadline for manuscript submissions: closed (22 November 2024) | Viewed by 3339

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Guest Editor
Department of Earth Sciences, University of Florence, 50121 Florence, Italy
Interests: heavy metal pollution; arsenic; mercury; ore deposits; stream sediment quality; water chemistry
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Guest Editor
Department of Earth Sciences, University of Florence, 50121 Florence, Italy
Interests: mercury; environmental biology; atmospheric pollution

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Guest Editor
Department of Earth Sciences, University of Florence, 50121 Florence, Italy
Interests: mercury; water pollution; hydrology; geomorphology; soil pollution

Special Issue Information

Dear Colleagues,

After more than forty years since the first outbreak of mercury (Hg) poisoning, the issue still raises worldwide debate. Despite the increasing efforts to reduce Hg pollution, human activity still produces a massive amount of Hg: only in 2018, anthropogenic emission exceeded 2 million kg of Hg, representing 30% of the total Hg entering the atmosphere yearly.

Mercury is one of the most naturally occurring toxic substances in the Earth’s crust and it exists in the environment in several forms, each of them with specific characteristics, properties, and environmental effects. The assessment of mercury pollution involves evaluating various sources, including industrial emissions, artisanal mining, and natural processes, which release both elemental and organic forms of mercury into the environment. Effective monitoring strategies involve ground-based measurements and remote sensing technologies to track atmospheric, aquatic, and soil mercury levels. Monitoring Hg pollution is fundamental to understanding its dispersion, transformation, and bioaccumulation throughout terrestrial and aquatic ecosystems. The occurrence of mercury in the environment poses risks to human populations, particularly through the consumption of contaminated fish and water, with neurological and developmental health impacts. The clinical effects of human exposure are numerous and differ based on the Hg forms. This scenario is indeed rapidly transforming due to the effects of climate change, contributing to drastic changes in the environmental conditions affecting Hg dispersion in the environment. Therefore, it is necessary to continuously update of our general knowledge on Hg geochemistry.

The detection and the quantification of the different Hg species is thus of primary importance to predict the fate of this pollutant and its potential effects on the environment and humans.

In this Special Issue, we kindly invite you to contribute papers dealing with the issue of Hg pollution, its monitoring and quantification. The wide range of this topic could include both research and review papers for possible publication in this issue.

Dr. Pilario Costagliola
Dr. Francesco Ciani
Dr. Alessia Nannoni
Guest Editors

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Keywords

  • mercury
  • risk assessment
  • environmental contamination
  • mercury speciation and quantification
  • environmental monitoring
  • assessment methods

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Published Papers (2 papers)

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Research

14 pages, 21149 KiB  
Article
The Legacy of Hg Contamination in a Past Mining Area (Tuscany, Italy): Hg Speciation and Health Risk Assessment
by Simone Arrighi, Fabrizio Franceschini, Riccardo Petrini, Silvia Fornasaro and Lisa Ghezzi
Toxics 2024, 12(6), 436; https://doi.org/10.3390/toxics12060436 - 16 Jun 2024
Viewed by 1706
Abstract
The mercury cell manufacturing process, which has been extensively used in chlor-alkali plants to produce chlorine and caustic soda by electrolysis, represents a major source of Hg environmental pollution. At Saline di Volterra (Tuscany, Italy), solution mining by pumping water into halite deposits [...] Read more.
The mercury cell manufacturing process, which has been extensively used in chlor-alkali plants to produce chlorine and caustic soda by electrolysis, represents a major source of Hg environmental pollution. At Saline di Volterra (Tuscany, Italy), solution mining by pumping water into halite deposits was applied to produce brines for a mercury-cell chlor-alkali plant. The Hg-contaminated, exhausted brines were pumped back at depth into the rock salt field in order to renew the available resources. Activities ceased in 1994, following the leakage dispersion of highly contaminated Hg(0)-bearing brines into the environment. The mercury content in the soil, measured during a survey conducted in 2000, reached 334 mg/kg, highlighting diffuse contamination in the floodplain. By 2009, the Hg concentration had generally decreased and was mostly confined to the topsoil layer. In order to evaluate the present Hg soil pollution, a geochemical survey was carried out in 2023, almost thirty years after the contamination event. The obtained data indicated the occurrence of legacy Hg, which reached 25.5 mg/kg in some soil samples. Speciation analysis for the most contaminated soil revealed that Hg(0) represented about 17.3% of the total Hg and that water-soluble and organic Hg fractions were negligible. These results suggest that the originally released metallic mercury has volatilized and likely oxidized, becoming practically immobile in the soil. A risk assessment, performed by applying Hg speciation analysis, indicated that the mercury in the soil does not carry a risk of non-cancerous effects for different exposure routes in case of subsequent use of the site and that the formerly contaminated area can now be converted into a leisure area. Full article
(This article belongs to the Special Issue Monitoring and Assessment of Mercury Pollution)
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11 pages, 1187 KiB  
Article
Mercury Dynamics in the Sea of Azov: Insights from a Mass Balance Model
by Christoph Gade, Rebecca von Hellfeld, Lenka Mbadugha and Graeme Paton
Toxics 2024, 12(6), 417; https://doi.org/10.3390/toxics12060417 - 7 Jun 2024
Viewed by 1057
Abstract
The Sea of Azov, an inland shelf sea bounding Ukraine and Russia, experiences the effects of ongoing and legacy pollution. One of the main contaminants of concern is the heavy metal mercury (Hg), which is emitted from the regional coal industry, former Hg [...] Read more.
The Sea of Azov, an inland shelf sea bounding Ukraine and Russia, experiences the effects of ongoing and legacy pollution. One of the main contaminants of concern is the heavy metal mercury (Hg), which is emitted from the regional coal industry, former Hg refineries, and the historic use of mercury-containing pesticides. The aquatic biome acts both as a major sink and source in this cycle, thus meriting an examination of its environmental fate. This study collated existing Hg data for the SoA and the adjacent region to estimate current Hg influxes and cycling in the ecosystem. The mercury-specific model “Hg Environmental Ratios Multimedia Ecosystem Sources” (HERMES), originally developed for Canadian freshwater lakes, was used to estimate anthropogenic emissions to the sea and regional atmospheric Hg concentrations. The computed water and sediment concentrations (6.8 ng/L and 55.7 ng/g dw, respectively) approximate the reported literature values. The ongoing military conflict will increase environmental pollution in the region, thus further intensifying the existing (legacy) anthropogenic pressures. The results of this study provide a first insight into the environmental Hg cycle of the Sea of Azov ecosystem and underline the need for further emission control and remediation efforts to safeguard environmental quality. Full article
(This article belongs to the Special Issue Monitoring and Assessment of Mercury Pollution)
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