Search Results (309)

The thermal, thermomechanical, and viscoelastic properties of continuous unidirectional (UD) glass fiber/high-density polyethylene (GF/HDPE) and ultra-high-molecular-weight polyethylene/high-density polyethylene (UHMWPE/HDPE) tapes are characterized in this paper in order to support their use in extreme environments. Unlike prior studies that focus on short-fiber composites or limited thermal conditions, this work examines continuous fiber architectures under five operational environments derived from Army Regulation 70-38, reflecting realistic defense-relevant extremes. Differential scanning calorimetry (DSC) was used to identify melting transitions for GF/HDPE and UHMWPE/HDPE, which guided the selection of test conditions for thermomechanical analysis (TMA) and dynamic mechanical analysis (DMA). TMA revealed anisotropic thermal expansion consistent with fiber orientation, while DMA, via strain sweep, temperature ramp, frequency sweep, and stress relaxation, quantified their temperature- and time-dependent viscoelastic behavior. The frequency-dependent storage modulus highlighted multiple resonant modes, and stress relaxation data were fitted with high accuracy (R² > 0.99) to viscoelastic models, yielding model parameters that can be used for predictive simulations of time-dependent material behavior. A comparative analysis between the two material systems showed that UHMWPE/HDPE offers enhanced unidirectional stiffness and better low-temperature performance. At the same time, GF/HDPE exhibits lower thermal expansion, better transverse stiffness, and greater stability at elevated temperatures. These differences highlight the impact of fiber type on thermal and mechanical responses, informing material selection for applications that require directional load-bearing or dimensional control under thermal cycling. By integrating thermal and viscoelastic characterization across realistic operational profiles, this study provides a foundational dataset for the application of continuous fiber thermoplastic tapes in structural components exposed to harsh thermal and mechanical conditions. Full article

A recently proposed method called “controlled swelling of monolithic films” was implemented to prepare ultra-high-molecular-weight polyethylene (UHMWPE) ultrafiltration membranes. For the first time, the effect of UHMWPE molecular weight (MW) on the structure and properties of the membranes prepared via this special case of thermally induced phase separation was studied in detail. The morphology and properties of the membranes were studied using SEM, DSC, liquid–liquid displacement porometry, and standard methods for the evaluation of mechanical properties, permeance, rejection, and abrasion resistance. High-quality membranes with a tensile strength of 5.0–17.8 MPa, a mean pore size of 25–50 nm, permeance of 17–107 L m⁻² h⁻¹ bar⁻¹, rejection of model contaminant (blue dextran) of 72–98%, and great abrasion resistance can be prepared only if the MW of the polymer in the initial monolithic film is sufficiently high. The properties of the membranes can effectively be controlled by changing the MW of the polymer and the mass fraction of the latter in the swollen film. Shrinkage is responsible for the variation in the membrane properties. The membranes prepared from a higher-MW polymer are more prone to shrinking after the removal of the solvent. Shrinkage decreases before rising again and minimizes with an increase in the polymer content in the swollen film. Full article

Patients undergo total knee arthroplasty (TKA) at younger ages with the expectation that the devices will perform well over two to three decades. During this time, the ultra-high molecular weight polyethylene (UHMWPE) bearing material properties of the implant may change due to aging induced by radiation and oxygen diffusion or other effects. Vitamin E or other antioxidants are promoted since several years to improve the oxidation resistance of UHMWPE. To compare the effectivity of these substances against established materials, a six weeks aging process was used and the chemical, mechanical and bio-tribological properties were analysed. Highly crosslinked and two weeks aged UHMWPE served as a reference for the currently established aging standards and virgin UHMWPE was aged for six weeks to separate the effects of crosslinking and vitamin E blending. Six weeks artificially aging changed the chemical, mechanical and bio-tribological properties of cross-linked UHMWPE significantly compared to only two weeks artificially aging, leading to cracks and delamination during the highly demanding activities wear test. The degradative effect of extended aging was also observed for virgin UHMWPE. These observations are in good accordance to retrieval findings. Minor changes on the chemical properties were observed for the cross-linked UHWMPE blended with vitamin E without impact on the mechanical and bio-tribological properties. Full article

Ultra-high-molecular-weight polyethylene (UHMWPE) is a pivotal material in engineering and biomedical applications due to its exceptional mechanical strength, wear resistance, and impact performance. However, its extreme melt viscosity, caused by extensive chain entanglements, severely limits processability via conventional melt-processing techniques. Recent advances in catalytic synthesis have enabled the production of disentangled UHMWPE (dis-UHMWPE), which exhibits enhanced processability while retaining superior mechanical properties. Notably, heterogeneous catalytic systems, utilizing supported fluorinated bis (phenoxy-imine) titanium (FI) catalysts, polyhedral oligomeric silsesquioxanes (POSS)-modified Z-N catalysts, and other novel catalysts, have emerged as promising solutions, combining structural control with industrial feasibility. Moreover, optimizing polymerization conditions further enhances chain disentanglement while maintaining ultra-high molecular weights. These systems utilize nanoscale supports and ligand engineering to spatially isolate active sites, tailor the chain propagation/crystallization kinetics, and suppress interchain entanglement during polymerization. Furthermore, characterization techniques such as melt rheology and differential scanning calorimetry (DSC) provide critical insights into chain entanglement, revealing distinct reorganization kinetics and bimodal melting behavior in dis-UHMWPE. This development of hybrid catalytic systems opens up new avenues for solid-state processing and industrial-scale production. This review highlights recent advances concerning interaction between catalyst design, polymerization control, and material performance, ultimately unlocking the full potential of UHMWPE for next-generation applications. Full article

Polyetheretherketone (PEEK) is a high-performance thermoplastic polymer widely recognized for its distinct mechanical strength, chemical resistance, and biocompatibility. These characteristics make it suitable for a wide range of applications, particularly in medical, aerospace, chemical, and electronics fields. Conventional processing techniques, such as 3D printing, molding, and extrusion, are widely employed for PEEK fabrication. This review critically examines recent advancements in PEEK research, with an emphasis on additive manufacturing techniques that are expanding its applications in the medical field. We provide an in-depth analysis of PEEK’s intrinsic properties, diverse processing methods, and current challenges that hinder its wider adoption. In addition to evaluating PEEK’s performance, this review compares it with alternative biomaterials—such as titanium and ultra-high molecular weight polyethylene (UHMWPE)—to explore its advantages and limitations in biomedical applications. Furthermore, this review discusses cost considerations, regulatory constraints, long-term clinical performance challenges, and failure modes that are essential for validating and ensuring the reliability of PEEK in clinical use. By synthesizing the recent literature, particularly from the last decade, this review highlights the significant potential of PEEK and underscores ongoing research efforts aimed at overcoming its limitations, paving the way for its broader implementation in advanced technological applications. Full article

This study investigates the biotribological performance of alumina–UHMWPE and alumina–PEEK hip implant couples through finite element simulation (ANSYS v24) and statistical inference (STATA v17). During gait cycle loading simulations, significant disparity in wear behaviour was observed. Alumina–UHMWPE demonstrated superior mechanical resistance, with a wear volume of 0.18481 mm³ and a wear depth of 6.93 × 10⁻⁴ mm compared to alumina–PEEK, which registered higher wear (volume: 8.4006 mm³; depth: 3.15 × 10⁻² mm). Wear distribution analysis indicated alumina–UHMWPE showed an even wear pattern in comparison to the poor, uneven alumina-PEEK high-wear patterns. Statistical comparison validated these findings, wherein alumina–UHMWPE achieved a 27.60 hip joint wear index (HCI) value, which is better than that of alumina–PEEK (35.85 HCI), particularly regarding key parameters like wear depth and volume. This computational–statistical model yields a baseline design for biomaterial choice, demonstrating the potential clinical superiority of alumina–UHMWPE in reducing implant failure risk. While this is a simulation study lacking experimental validation, the results pave the way for experimental and clinical studies for further verification and refinement. The approach enables hip arthroplasty design optimization with maximal efficiency and minimal resource-intensive testing. Full article

This study develops novel superhydrophobic UHMWPE/PTFE/PVA composites via hot-pressing sintering to achieve ultra-low friction and enhanced wear resistance. The ternary system synergistically combines UHMWPE’s mechanical stability, PTFE’s lubricity, and PVA’s dispersion/binding capability. Results show PTFE disrupts UHMWPE crystallization, reducing melting temperature by 2.77 °C and enabling energy dissipation. All composites exhibit hydrophobicity, with optimal formulations (UPP3/UPP4) reaching superhydrophobicity. Tribological testing under varied loads and frequencies reveals low friction, where UPP1 achieves a COF of 0.043 and wear rate below 1.5 × 10⁻⁵ mm³/(N·m) under low-load conditions. UHMWPE oxidative degradation forming carboxylic acids at the interface (C=O at 289 eV, C–O at 286 eV). Formation of tungsten oxides (WO₃/WO₂), carbides (WC), and transfer films on steel counterparts. A four-step tribochemical reaction pathway is established. PVA promotes uniform transfer films, while PTFE lamellar peeling and UHMWPE chain stability enable sustained lubrication. Carbon-rich stratified accumulations under high-load/speed increase COF via abrasive effects. The composites demonstrate exceptional biocompatibility and provide a scalable solution for biomedical and industrial tribological applications. Full article

Electrically conductive composites of ultra-high molecular weight polyethylene (UHMWPE) may be of interest as strain sensors for event detection in high-strain scenarios, with potential applications in ballistics or orthopedics. In this study, geometric deformations of electrically conductive composites of UHMWPE were quantified for large plastic strains via physical measurements. These measurements were compared to neat (non-composite) control materials, and to geometrical behaviors predicted under volume conservation assumptions. This study found that material geometry remained close to that predicted by volume conservation at low-to-moderate plastic strains, with differences exceeding 5% only above 100% nominal strain. Materials with higher filler loading experienced a greater increase in measured volume than neat controls, particularly at higher strains. The results suggest that this difference could be due in part to volumetric opening in the composite materials with high filler loading. Finally, necking behavior was observed and quantified in this study, presenting another effect that should be taken into account for future work characterizing the electrical behavior of these materials under large plastic deformations. The results of this study thus lay the foundation for further characterization of these electrically-conductive composites, and to determine their intrinsic electrical properties as a function of strain in particular. Full article

This study investigates the use of Ultra-High Molecular Weight Polyethylene (UHMWPE) fibers and fabric to enhance the flexural performance of Ultra-High-Performance Concrete (UHPC). A total of 45 specimens were tested to examine the effects of fiber type, fabric material, adhesive, and various combined strengthening techniques. The main findings are that incorporating UHMWPE fiber into the ultra-high-strength mortar (HSM) matrix provides superior performance compared to steel fiber, particularly in enhancing crack resistance and energy absorption. UHMWPE fiber-reinforced UHPC achieved a flexural toughness of 307 KJ/m³, over three times higher than that of steel fiber-reinforced UHPC (98 KJ/m³). The use of UHMWPE fabrics was more effective in improving the ductility and toughness of the composites than the use of glass fabrics. The bonding effect of using epoxy resin with UHMWPE fabric is better than using magnesium phosphate cement (MPC). Increasing the number of fabric layers improved the flexural properties of externally bonded fabric but had no impact on internal reinforcement techniques. The best strengthening method in this study was a combination of incorporating UHMWPE fiber internally and externally bonded fabric on a concrete surface, yielding the highest toughness of 580 KJ/m³. Full article

The polymer composite frost-resistant rubber–UHMWPE (ultra-high molecular weight polyethylene) has simultaneously damping, anti-wear and anti-friction properties. To use it in seals operating in northern climatic conditions, it is necessary to study the effect of climatic aging on mechanical, strength and tribological properties of the composite. In this study, climatic aging of rubber and UHMWPE separately was made at testing ground in Yakutsk (Russia), as well as accelerated thermal aging of the composite in laboratory conditions. Comparison of the results of climatic and laboratory aging showed that climatic aging has a negative effect on the properties of both rubber and UHMWPE. Accelerated aging, on the contrary, leads to an improvement in the anti-friction properties of the composite with a small (about 10 percent) increase in its stiffness. Thus, with prolonged use in friction units, the composite should be protected from radiation and ozone. Full article

Maintaining the consistency of linear density in ultra-high-molecular-weight polyethylene (UHMWPE) fiber has been a critical challenge in the production of UHMWPE fibers. However, there has been limited research focusing on the impact of UHMWPE resin parameters on the consistency in fiber linear density. In this study, a series of UHMWPE fibers were produced through wet spinning using UHMWPE resins with varying parameters. The effects of molecular weight, molecular weight distribution, particle size, and particle size distribution of UHMWPE resins on the consistency of linear density and the mechanical properties of UHMWPE fibers were systematically investigated. The experimental findings revealed that narrowing the molecular weight distribution and particle size distribution of ultra-high molecular weight polyethylene (UHMWPE) resin precursors significantly enhanced the consistency of resultant UHMWPE fibers, concurrently improving their tensile strength and elastic modulus. Notably, while the absolute molecular weight of the resin demonstrated no statistically significant correlation with fiber consistency, an optimal molecular weight range was identified to maximize the mechanical performance of UHMWPE fibers. Specifically, fibers synthesized from resin precursors within this molecular weight window exhibited peak values in both strength and modulus, suggesting a critical balance between molecular chain entanglement and processability. Full article

Ultra-high molecular weight polyethylene (UHMWPE) fiber-reinforced concrete (UHMWPE-FRC) is a hard–soft multiphase hybrid composite with exceptional toughness and impact resistance compared to conventional concrete. However, its cutting characteristics and processing performance have not been sufficiently investigated, potentially causing accelerated saw blade wear, higher energy consumption, and poor cutting quality, thus increasing project costs and duration. In order to intelligently evaluate the performance of diamond saw blades when cutting UHMWPE-FRC, a feature extraction method, based on feature classification and an improved Hilbert–Huang transform (HHT), is proposed, which consider Improved Complete Ensemble Empirical Mode Decomposition with Adaptive Noise (ICEEMDAN) and wavelet threshold de-noising. By conducting the cutting experiments, the cutting force was analyzed by the improved HHT, in terms of noise reduction and time-frequency. Five types of characteristics were preliminarily screened, including depth of cut (a_p), cutting speed (V_c), feed rate (V_f), concrete strength, and the type of concrete. A feature correlation analysis method for UHMWPE-FRC cutting, based on feature classification, is proposed. The five features were classified into continuous variable features and unordered categorical variable features; correlation analyses were carried out by Spearman correlation coefficient testing and Kruskal–Wallis and Dunn’s testing, respectively. It was found that the a_p and concrete strength exhibited a strong positive correlation with cutting force, making them the primary influencing factors. Meanwhile, the influence of aggregates on cutting force can be identified in the low-frequency range, while the influence of fibers can be identified in the high-frequency range. The feature classification-based correlation analysis effectively distinguishes the influence of V_c on cutting force. Full article

This study investigates the impact of small dimples on the tribological properties of CoCrMo (CCM) surfaces. Laser-ablated textures with 5 µm diameter dimples were fabricated at varying aspect ratios (0.1, 0.2, 0.3) and surface densities (5%, 15%, 25%) to evaluate their effects on friction and wear when paired with ultra-high molecular weight polyethylene (UHMWPE) counterfaces. The results showed that small dimples significantly reduced and stabilized the coefficient of friction (CoF) and wear compared to untextured CCM and larger dimples as reported in the literature. The texture configuration with a 5% surface density and 0.1 aspect ratio achieved the best combination of friction and wear performance by facilitating the formation of a stable and uniform lubricant film during sliding. These findings underscore the potential of small, precisely engineered surface textures to improve the tribological performance of CCM, offering a promising approach for reducing friction and wear in artificial hip joints. Full article

The ballistic performance of fiber-reinforced polymer composites (FRPC) is influenced by the adhesive’s mechanical properties, such as stiffness, toughness, and energy dissipation. However, the specific contributions of these properties remain unclear. This study explores how varying the hard segment (HS) content in water-based polyurethane (WPU) impacts the thermal, mechanical, and ballistic performance of FRPCs. By increasing HS content, the storage modulus and tensile strength of WPU improved, while elongation at break decreased, transitioning the adhesive from soft and ductile to rigid and brittle. Quasi-static tests, ballistic experiments, and SEM analysis were conducted on UHMWPE fiber-reinforced WPU-HS% composites. Results reveal that adhesives with high hardness and modulus hinder fiber deformation, reducing energy dissipation and causing severe delamination, which diminishes ballistic performance. Conversely, soft and ductile adhesives allow deformation alongside fibers during bullet impact, suppress delamination, and absorb more kinetic energy while transferring load. Among the tested formulations, WPU with 45% HS content exhibited the best balance of mechanical properties, achieving the most significant improvement in ballistic performance by enhancing energy absorption and minimizing damage. This study establishes a clear relationship between WPU properties and composite protective behavior, providing insights for designing high-performance ballistic materials. Full article

Ultra-high-molecular-weight polyethylene (UHMWPE) fabric is widely used in many fields due to its excellent properties such as high modulus, high strength, and impact resistance. However, its high flammability prevents its application in high-temperature environments. Therefore, it is important to develop multifunctional UHMWPE fabric to meet its different requirements in firefighting, military, and other scenarios. Here, we have prepared a durable flame-retardant superhydrophobic UHMWPE fabric by a simple coating method. A polyurethane solution mixed with decabromodiphenylethane and antimony trioxide is scraped on the surface of the fabric to form a coating, which endows the fabric with flame retardancy. The sprayed fluorinated hydrophobic agent provides superhydrophobic properties to the fabric. It is worth mentioning that plasma pretreatment greatly improves the adhesion properties of the coating by stimulating the active groups on the surface of the fabric. Tests have shown that the adhesion between the coating and the surface of the plasma-treated UHMWPE fabric has been greatly improved. The limiting oxygen index value of the coating UHMWPE fabric has increased by 90%, and it immediately extinguishes after leaving the flame, demonstrating excellent flame retardancy. The contact angle between its surface and water reaches 156°, exhibiting excellent superhydrophobicity and self-cleaning properties. This study provides a simple, convenient, and effective method for the development of multifunctional UHMWPE fabric, greatly expanding its application scenarios and providing ideas for future development. Full article