Search Results (48)

The lack of an in-depth understanding of electrical conduction behaviour in anisotropic carbon fibre-reinforced laminates was reflected by the fact that there was no measurement standard. Various ad hoc experimental techniques were used, involving a range of extrinsic parameters with little or no rigorous control. Not only were widely varying values of electrical conductivity, if not incorrect values, generated, but also the effects of extrinsic parameters were attributed erroneously to those of intrinsic parameters. This predicament was compounded by different techniques used in measurements of volume and surface electrical conduction. This paper formulated the most effective experimental method, using two well-argued solid electrodes, to evaluate electrical conduction with rigorous control of all extrinsic parameters. Its main objectives were to investigate anisotropic volume and surface electrical conduction with a focus on the effects of electrode–specimen contact resistance, clamping pressure, conductive paint, contact face preparations, lay-ups, and specimen dimensions. Unique results and data trends provided the step-changing understanding of electrical conduction, such that the contributions of extrinsic factors were clearly established. The specifical findings showed that (1) the two-probe method was the only viable technique to measure both volume and surface conductivities, (2) all conductivity values were dependent on clamping torques and contact face machining, (3) the conductive paint enhancement effect was an artefact, and (4) obtaining surface conductivities by multiplying volume conductivities with laminate thickness was incorrect. Full article

Quantum well infrared photodetectors (QWIPs) are popular due to their following advantages: low cost, maturity of manufacturing, high uniformity, ease of wavelength adjustment, resistance to heat, and resistance to ionizing radiation. However, their low absorption efficiency due to their unique anisotropic absorption properties and ohmic loss of the metal grating severely limit their further adoption. We cleverly used cascaded dielectric metasurfaces to replace the traditional single-layer metal grating, which increased the absorption efficiency to near the upper limit of 100%. By analyzing the near-field profile of the electric field of the miniaturized device, we found that the upper grating, QWIP, and lower grating formed a high-efficiency FP cavity with a strong photon localization capability, allowing the microdevice to effectively achieve 99.3% absorption. In addition, QWIPs with cascade gratings can be incorporated into a polarimeter, allowing for the comprehensive detection of linear polarization information at a wavelength of 14 $\mathsf{\mu }\mathrm{m}$ through rational rotations. Our proposed double-layer grating coupling method can be considered a technology that can effectively address the low-absorption problem associated with QWIPs. Full article

Additive manufacturing (AM) of components using material extrusion (MEX) offers the potential for the integration of functions through the use of multi-material design, such as sensors, actuators, energy storage, and electrical connections. However, there is a significant gap in the availability of electrical composite properties, which is essential for informed design of electrical functional structures in the product development process. This study addresses this gap by systematically evaluating the resistivity (DC, direct current) of 14 commercially available filaments as unprocessed filament feedstock, extruded fibers, and fabricated MEX-structures. The analysis of the MEX-structures considers the influence of anisotropic electrical properties induced by the selective material deposition inherent to MEX. The results demonstrate that composites containing fillers with a high aspect ratio, such as carbon nanotubes (CNT) and graphene, significantly enhance conductivity and improve the reproducibility of MEX structures. Notably, the extrusion of filaments into MEX structures generally leads to an increase in resistivity; however, composites with CNT or graphene exhibit less reduction in conductivity and lower variability compared to those containing only carbon black (CB) or graphite. These findings underscore the importance of filler selection and composition in optimizing the electrical performance of MEX structures. Full article

Transition metal borides have emerged as pivotal players in various fields. In addition to their exceptional properties such as high hardness, a high melting point, and corrosion resistance, certain compounds exhibit remarkable characteristics including superconductivity, magnetism, electrical conductivity, and catalytic activity. Among these compounds, ZrB₁₂ has garnered significant attention due to its unique physicochemical properties. However, previous research on ZrB₁₂ has predominantly focused on its mechanical behavior while overlooking the electron-electron interactions of the superconducting state. In this paper, resistance characterization of ZrB₁₂ under high-pressure conditions was conducted to further investigate its superconductivity. Our research findings indicate that ZrB₁₂ maintains its superconductivity within a pressure range of 0 to 1.5 GPa and is classified as a type 2 superconductor. Additionally, the results confirm the anisotropic nature of ZrB₁₂’s superconductivity. As the pressure increases, the superconducting transition temperature undergoes a gradual decrease. Remarkably, ZrB₁₂ exhibits metallic behavior under pressures up to 31.4 GPa. The observed decline in superconductivity in ZrB₁₂ can be ascribed to the intensified influence of Zr’s movement on phonon dispersion, ultimately leading to a reduction in carrier concentration. Full article

Developing multifunctional flexible composites with high-performance electromagnetic interference (EMI) shielding, thermal management, and sensing capacity is urgently required but challenging for next-generation smart electronic devices. Herein, novel nacre-like aramid nanofibers (ANFs)-based composite films with an anisotropic layered microstructure were prepared via vacuum-assisted filtration and hot-pressing. The formed 3D conductive skeleton enabled fast electron and phonon transport pathways in the composite films. As a result, the composite films showed a high electrical conductivity of 71.53 S/cm and an outstanding thermal conductivity of 6.4 W/m·K when the mass ratio of ANFs to MXene/AgNWs was 10:8. The excellent electrical properties and multi-layered structure endowed the composite films with superior EMI shielding performance and remarkable Joule heating performance, with a surface temperature of 78.3 °C at a voltage of 2.5 V. Additionally, it was found that the composite films also exhibited excellent mechanical properties and outstanding flame resistance. Moreover, the composite films could be further designed as strain sensors, which show great promise in monitoring real-time signals for human motion. These satisfactory results may open up a new opportunity for EMI shielding, thermal management, and sensing applications in wearable electronic devices. Full article

Electro-conductive fabrics are key materials for designing and developing wearable smart textiles. The properties of textile materials depend on the production method, the technique which leads to high conductivity, and the structure. The aim of the research work was to determine the factors affecting the electrical conductivity of woven fabrics and elucidate the mechanism of electric current conduction through this complex, aperiodic textile material. The chemical composition of the material surface was identified using scanning electron microscopy energy dispersion X-ray spectroscopy. The van der Pauw method was employed for multidirectional resistance measurements. The coefficient was determined for the assessment of the electrical anisotropy of woven fabrics. X-ray micro-computed tomography was used for 3D woven structure geometry analysis. The anisotropy coefficient enabled the classification of electro-conductive fabrics in terms of isotropic or anisotropic materials. It was found that the increase in weft density results in an increase in sample anisotropy. The rise in thread width can lead to smaller electrical in-plane anisotropy. The threads are unevenly distributed in woven fabric, and their widths are not constant, which is reflected in the anisotropy coefficient values depending on the electrode arrangement. The smaller the fabric area covered by four electrodes, the fewer factors leading to structure aperiodicity. Full article

The alveoli, critical sites for gas exchange in the lungs, comprise alveolar epithelial cells and pulmonary capillary endothelial cells. Traditional experimental models rely on porous polyethylene terephthalate or polycarbonate membranes, which restrict direct cell-to-cell contact. To address this limitation, we developed AlveoMPU, a new foam-based mortar-like polyurethane-formed alveolar model that facilitates direct cell–cell interactions. AlveoMPU features a unique anisotropic mortar-shaped configuration with larger pores at the top and smaller pores at the bottom, allowing the alveolar epithelial cells to gradually extend toward the bottom. The underside of the film is remarkably thin, enabling seeded pulmonary microvascular endothelial cells to interact with alveolar epithelial cells. Using AlveoMPU, it is possible to construct a bilayer structure mimicking the alveoli, potentially serving as a model that accurately simulates the actual alveoli. This innovative model can be utilized as a drug-screening tool for measuring transepithelial electrical resistance, assessing substance permeability, observing cytokine secretion during inflammation, and evaluating drug efficacy and pharmacokinetics. Full article

Air-breathing proton exchange membrane fuel cells (PEMFCs) show enormous potential in small and portable applications because of their brief construction time without the need for gas supply, humidification and cooling devices. In the current work, a 3D multiphase model of single air-breathing PEMFCs is developed by considering the contact resistance between the gas diffusion layer and bipolar plate and the anisotropic thermal conduction and electric conductive in the through-plane and in-plane directions. The 3D model presents good grid independence and agreement with the experimental polarization curve. The single PEMFC with the best open area ratio of 55% achieves the maximum peak power density of 179.3 mW cm⁻². For the fuel cell stack with 10 single fuel cells, the application of the anode window flow field is beneficial to improve the stack peak power density compared to the anode serpentine flow field. The developed model is capable of providing assistance in designing high-performance air-breathing PEMFC stacks. Full article

In soft electronics, anisotropic conductive adhesive films (ACFs) are the trending interconnecting approach due to their substantial softness and superior bondability to flexible substrates. However, low bonding pressure (≤1 MPa) and fine-pitch interconnections of ACFs become challenging while being extended in advanced device developments such as wafer-level packaging and three-dimensional multi-layer integrated circuit board assembly. To overcome these difficulties, we studied two types of ACFs with distinct conductive filler sizes (ACF-1: ~20 μm and ACF-2: ~5 μm). We demonstrated a low-pressure thermo-compression bonding technique and investigated the size effect of conductive particles on ACF’s mechanical properties in a customized testing device, which consists of flexible printing circuits and Flex on Flex assemblies. A consistency of low interconnection resistance (<1 Ω) after mechanical stress (cycling bending test up to 600 cycles) verifies the assembly’s outstanding electrical reliability and mechanical stability and thus validates the great effectiveness of the ACF bonding technique. Additionally, in numerical studies using the finite element method, we developed a generic model to disclose the size effect of Au/Ni-coated polymer fillers in ACF on device reliability under mechanical stress. For the first time, we confirmed that ACFs with smaller filler particles are more prone to coating fracture, leading to deteriorated electrical interconnections, and are more likely to peel off from substrate electrode pads resulting in electrical faults. This study provides guides for ACF design and manufacturing and would facilitate the advancement of soft wearable electronic devices. Full article

This paper aims to explore the structural performance of 3D-printed and casted cement-based steel-reinforced concrete beams and one-way slabs incorporating short carbon fibre and activated carbon powder, which have been shown to enhance concrete’s flexural strength and reduce its electrical resistivity. The samples are cast and printed in 250 × 325 × 3500 mm beams and 150 × 400 × 3500 mm one-way slabs and mechanical, electrical, and piezoresistivity properties were measured. This length of beams and one-way slabs with rebars have been considered as they can magnify the flexural and cracking behaviour and make them easier to be monitored and analysed. The samples were loaded up to 80% of maximum stress. Crack propagation and strain was assessed using the 2D digital image correlation (DIC) method. The results compared samples under continuously increasing loads between 3D-printed and cast samples. The 3D-printed composites had a better piezoresistive response due to the enhanced anisotropic behaviour. DIC analysis illustrated similar results among different samples, while 3D-printed blocks had lower cracking performance due to the horizontal case fracture in lower stress. Full article

Conductive nanocomposites play a significant role in tissue engineering by providing a platform to support cell growth, tissue regeneration, and electrical stimulation. In the present study, a set of electroconductive nanocomposite hydrogels based on gelatin (G), chitosan (CH), and conductive carbon black (CB) was synthesized with the aim of developing novel biomaterials for tissue regeneration application. The incorporation of conductive carbon black (10, 15 and 20 wt.%) significantly improved electrical conductivity and enhanced mechanical properties with the increased CB content. We employed an oversimplified unidirectional freezing technique to impart anisotropic morphology with interconnected porous architecture. An investigation into whether any anisotropic morphology affects the mechanical properties of hydrogel was conducted by performing compression and cyclic compression tests in each direction parallel and perpendicular to macroporous channels. Interestingly, the nanocomposite with 10% CB produced both anisotropic morphology and mechanical properties, whereas anisotropic pore morphology diminished at higher CB concentrations (15 and 20%), imparting a denser texture. Collectively, the nanocomposite hydrogels showed great structural stability as well as good mechanical stability and reversibility. Under repeated compressive cyclic at 50% deformation, the nanocomposite hydrogels showed preconditioning, characteristic hysteresis, nonlinear elasticity, and toughness. Overall, the collective mechanical behavior resembled the mechanics of soft tissues. The electrical impedance associated with the hydrogels was studied in terms of the magnitude and phase angle in dry and wet conditions. The electrical properties of the nanocomposite hydrogels conducted in wet conditions, which is more physiologically relevant, showed a decreasing magnitude with increased CB concentrations, with a resistive-like behavior in the range 1 kHz–1 MHz and a capacitive-like behavior for frequencies <1 kHz and >1 MHz. Overall, the impedance of the nanocomposite hydrogels decreased with increased CB concentrations. Together, these nanocomposite hydrogels are compositionally, morphologically, mechanically, and electrically similar to native ECMs of many tissues. These gelatin-chitosan–carbon black nanocomposite hydrogels show great promise for use as conducting substrates for the growth of electro-responsive cells in tissue engineering. Full article

This study focuses on microscale anisotropy in rock structure and texture, exploring its influence on the macro anisotropic electromagnetic parameters of the geological media, specifically electric conductivity (σ), relative permittivity (ε), and magnetic permeability (μ). The novelty of this research lies in the advancement of geophysical monitoring methods for calculating cross properties through the estimation of effective parameters—a kind of integral macroscopic characteristic of media mostly used for composite materials with inclusions. To achieve this, we approximate real geological media with layered bianisotropic media, employing the effective media approximation (EMA) averaging technique to simplify the retrieval of the effective electromagnetic parameters (e.g., apparent resistivity–inversely proportional to electrical conductivity). Additionally, we investigate the correlation between effective electromagnetic parameters and geodynamic processes, which is supported by the experimental data obtained during monitoring studies in the Tien Shan region. The observed decrease and increase in apparent electrical resistivity values of ρ_k over time in orthogonal azimuths leads to further ρ_k deviations of up to 80%. We demonstrate that transitioning to another coordinate system is equivalent to considering gradient anisotropic media. Building upon the developed method, we derive the effective electric conductivity tensor for gradient anisotropic media by modeling the process of fracturing in a rock mass. Research findings validate the concept that continuous electromagnetic monitoring can aid in identifying natural geodynamic disasters based on variations in integral macroscopic parameters such as electrical conductivity. The geodynamic processes are closely related to seismicity and stress regimes with provided constraints. Therefore, disasters such as earthquakes are damaging and seismically hazardous. Full article

Over the past few decades, the enhancement of polymer thermal conductivity has attracted considerable attention in the scientific community due to its potential for the development of new thermal interface materials (TIM) for both electronic and electrical devices. The mechanical elongation of polymers may be considered as an appropriate tool for the improvement of heat transport through polymers without the necessary addition of nanofillers. Polyimides (PIs) in particular have some of the best thermal, dielectric, and mechanical properties, as well as radiation and chemical resistance. They can therefore be used as polymer binders in TIM without compromising their dielectric properties. In the present study, the effects of uniaxial deformation on the thermal conductivity of thermoplastic PIs were examined for the first time using atomistic computer simulations. We believe that this approach will be important for the development of thermal interface materials based on thermoplastic PIs with improved thermal conductivity properties. Current research has focused on the analysis of three thermoplastic PIs: two semicrystalline, namely BPDA-P3 and R-BAPB; and one amorphous, ULTEM^TM. To evaluate the impact of uniaxial deformation on the thermal conductivity, samples of these PIs were deformed up to 200% at a temperature of 600 K, slightly above the melting temperatures of BPDA-P3 and R-BAPB. The thermal conductivity coefficients of these PIs increased in the glassy state and above the glass transition point. Notably, some improvement in the thermal conductivity of the amorphous polyimide ULTEM^TM was achieved. Our study demonstrates that the thermal conductivity coefficient is anisotropic in different directions with respect to the deformation axis and shows a significant increase in both semicrystalline and amorphous PIs in the direction parallel to the deformation. Both types of structural ordering (self-ordering of semicrystalline PI and mechanical elongation) led to the same significant increase in thermal conductivity coefficient. Full article

We report a possible coexistence of nontrivial topology and antiferromagnetism in the newly discovered compounds EuCdBi${}_2$, with magnetic Eu layer locating above and below Bi square net. The X-ray diffraction on single crystals and powder indicats that this 112-type material crystalizes in space group of $I4/mmm$, the same as SrMnBi${}_2$ and EuMnBi${}_2$. Our combined measurements of magnetization, electrical transport and specific heat consistently reveal antiferromagnetic (AFM) transition of Eu${}^{2+}$ moments at $T_N$ = 20 K. The Eu moments are not saturated under a field of 7 T at 1.8 K. The anisotropic susceptibility suggests the Eu moments lie in the $ab$ plane, and a metamagnetic (MM) transition is observed near 1 T below $T_N$. Large positive magnetoresistance (MR) present for both $H\Vert ab$ and $H\Vert c$, which are considered to contain part contributions from Dirac bands. Hall measurements show the electron-hole compensation effect is prominent above 100 K, with a crossover of Hall resistance from negative to positive values at ∼150 K. The fitted mobility of electrons is as high as 3250 cm${}^2$ V${}^{-1}$ S${}^{-1}$ at 1.8 K. Interestingly, the rapid increase of carrier density and suppression of mobility appear at around $T_N$, indicating non-negligible interaction between Eu moments and electron/hole bands. EuCdBi${}_2$ may provide a new platform to investigate the interplay of topological bands and antiferromagnetic order. Full article

In order to meet the urgent need for high temperature piezoelectric materials with a Curie temperature over 400 °C, the Mn/Nb co-doped strategy has been proposed to improve the weak piezoelectric performance of the Aurivillius-type Na_0.5Bi_4.5Ti₄O₁₅ (NBT) high temperature piezoelectric ceramics. In this paper, the crystal structure, electrical properties, and thermal stability of the B-site Mn/Nb co-doped Na_0.5Bi_4.5Ti_4-x(Mn_1/3Nb_2/3)_xO₁₅ (NBT-100x) ceramics were systematically investigated by the conventional solid-state reaction method. The crystal structural analysis results indicate that the NBT-100x ceramics have typical bismuth oxide layer type phase structure and high anisotropic plate-like morphology. The lattice parameters and the grain sizes increase with the B-site Mn/Nb co-doped content. The electrical properties were significantly improved by Mn/Nb co-doped modifications. The maximum of the piezoelectric coefficient d₃₃ was found to be 29 pC/N for the NBT-2 ceramics, nearly twice that of the unmodified NBT ceramics. The highest values of the planar electromechanical coupling factor k_p and thickness electromechanical coupling factor k_t were also obtained for the NBT-2 ceramics, at 5.4% and 31.2%, respectively. The dielectric spectroscopy showed that the Curie temperature Tc of the Mn/Nb co-doped NBT-100x ceramics is slightly higher than that of unmodified NBT ceramics (646 °C). The DC resistivity of the NBT-2 ceramics is higher than 10⁶ Ω∙cm at 500 °C. All the results together with the good thermal stability demonstrated the Mn/Nb co-doped ceramics as an effective method to improve the NBT based piezoelectric ceramics and the potential candidates of the Mn/Nb co-doped NBT-100x ceramics for high temperature piezoelectric applications. Full article