Search Results (18)

Conventional wastewater treatment is often insufficient in the case of mature landfill leachate. Among novel methods, internal microelectrolysis (IME) has been recently recognized as an effective method for refractory wastewater treatment. The aim of this study was the evaluation of the impact of various parameters (pH, time, types, ratios of Fe/GAC, H₂O₂ dose, the time of application and the soaking of GAC in LL) on the efficiency of the IME process applied to mature landfill leachate. As microelectrodes, waste cast-iron chips and granulated activated carbon (GAC) were used. The application of a multi-step treatment of leachates, PC > m-IME > m-IME/H₂O₂, resulted in 82.1% COD removal and a significant increase in biodegradability (BOD₅/COD rose up to 0.39). The optimal parameters were established as follows: pH 3, 120 min, ratio Fe/GAC 40/10 g/g/dm³ and ratio COD/H₂O₂ = 1/2. The results showed that the PC is a reasonable pretreatment process before IME—the improvement in total COD removal was up to 12.5%. COD removal in the IME process increased with the increase in GAC dose only up to a certain level. Also, too high doses of Fe negatively affected the efficiency of the IME process, which shows that the efficiency depends not only on the dose but also on the mass ratio of Fe/GAC. The addition of H₂O₂ significantly improved the COD removal effectiveness, especially when it was applied after 120 min of the m-IME process. The results showed also that the soaking of GAC in LL before the process did not eliminate the sorption process. Full article

The excessive discharge of nitrogen leads to water eutrophication. The partial nitritation and anammox (PN/A) process is a promising technology for biological nitrogen removal in wastewater treatment. However, applying it to mature landfill leachate (MLL) faces challenges, as the toxic substances (e.g., heavy metal) within MLL inhibit the activity of anammox bacteria. Therefore, most previous studies focused on diluted, pretreated, or chemically adjusted MLL. This study demonstrated at full scale that the two-stage PN/A process can treat raw MLL. Initially, the operational issue of sludge floatation resulted in rapid biomass loss with overflow discharging, which selectively suppresses nitrite-oxidizing bacteria (NOB), promoting the achievement of nitrite accumulation. After that, the NOB suppression was self-sustained by the high in situ free ammonia concentration, i.e., 26.2 ± 15.9 mg N/L. In the subsequent anammox tank, nitrogen removal primarily occurred via the anammox process, complemented by denitrification, achieving total nitrogen removal efficiency exceeding 72%. In addition, the nitrogen removal capacity of this system was significantly influenced by temperature with the nitrogen-loading rate above 0.4 kg N/m³/d at 38 °C and approximately 0.1 kg N/m³/d at 21 °C. The optimization of system operation, such as gradually increasing MLL content, remains necessary to enhance nitrogen removal capacity further. Full article

Sanitary landfilling is the predominant process for solid urban waste disposal, but it generates leachate that poses environmental, economic, and social concerns. Landfill leachate (LL) contains complex and refractory pollutants and toxic compounds that can vary depending on landfill maturity, age, and biochemical reactions, making its treatment challenging. Due to its unique characteristics and occurrence in remote locations, LL requires separate treatment from wastewater. Various conventional treatment processes involving biological, chemical, and physical processes have been used for LL treatment, but a single treatment process is insufficient to meet environmental standards. This review demonstrates that combined treatment processes are more effective and efficient for LL treatment compared to single processes. Among the various combinations, chemical–chemical and chemical–biological treatments are the most commonly used. Specifically, the integration of Fenton with adsorption and a membrane bioreactor (MBR) with nanofiltration (NF) processes shows promising results. The combined processes of MBR with NF, Fenton with adsorption, and PF with biological treatment show maximum removal efficiencies for COD, reaching 99 ± 1%, 99%, 98%, and 97%, respectively. Additionally, the combined Fenton with adsorption process and EC with SPF process enhance biodegradability as indicated by increased BOD₅/COD ratios, from 0.084 to 0.82 and 0.35 to 0.75, respectively. The findings emphasize the importance of developing and implementing enhanced combined treatment processes for LL, with the aim of achieving efficient and comprehensive pollutant mineralization. Such processes have the potential to address the environmental concerns associated with LL and contribute to sustainable waste management practices. Full article

Landfill leachate is regarded as a significant point source of pollutants that may pose a hazard to the environment, particularly to surface and ground waters. Leachates are highly variable and heterogeneous. Our study was focused on the characterization of landfill leachates derived from young (YDS) and matured (MDS) dumpsites in terms of the abundance of micropollutants, antimicrobial resistance genes (ARG), and microbial community structure. The concentrations of poly- and perfluoroalkyl substances (PFASs) were found to be higher in MDS compared to YDS, i.e., 13.19 and 7.16 μg/L, respectively. Among pharmaceutical compounds, ibuprofen was detected at the highest concentrations, i.e., 12.54, 12.81, and 13.13 μg/L, in the leachates derived from MDS, YDS, and ponds. The distribution of bacteria, archaea, eukaryotes, and viruses in the three leachate samples was as follows: 85.15 ÷ 88.04%, 9.13 ÷ 12.29%, 2.20 ÷ 2.68%, and 0.12 ÷ 0.15%, respectively. In total, 31 distinct families of ARGs were identified, comprising a total of 80 ARGs. Incubation of P. putida MSCL650 in sterile leachate from the pond resulted in decreasing the minimum inhibitory concentrations for six antibiotics as compared to cells incubated in nutrient broth. Hydrological processes, i.e., runoff and infiltration, can increase the dissemination of ARGs. Full article

The release of siloxane from landfill leachate has attracted wide attention. In this study, dodecamethylcyclohexasiloxane (D6) and dodecamethylpentasiloxane (L5) were chosen as the target pollutants to investigate the adsorption characteristics of cyclosiloxane and linear siloxane on municipal solid waste (MSW) under the landfill circumstance. The adsorption behavior could be well described by the Langmuir–Freundlich model, with a maximum adsorption capacity of 0.677 μg g⁻¹ and 15.864 μg g⁻¹ for L5 and D6, respectively. It seems that D6 has a stronger affinity to MSW compared with L5. The maximum adsorption was observed when the pH was 5.0 and 5.5 for D6 and L5. The optical temperature was 30 °C. The organic acid and inorganic ions in the leachate could restrict the adsorption to a low level. The results suggested that the adsorption of siloxane on MSW could be limited at the methanogenic and mature stages, which may promote the distribution of siloxane in the leachate. The results could help to understand the release behavior of siloxane from landfill leachate during the running of a landfill. Full article

The mature landfill leachate (MLL) is characterized by a large number of fulvic acids and humic acids, which is refractory organic matter and can be cleaned by ozone oxidation. However, the poor property of mass transfer prohibits the widespread use of ozone oxidation in actual leachate treatment. Meanwhile, some combined processes are adopted to treat the mature landfill leachate, which places catalytic ozonation before the membrane bioreactor (MBR) process to enhance the biodegradability of MLL. Thus, this research is conducted to investigate the practicability of applying nano-Fe₃O₄ loaded cow-dung ash (Fe₃O₄@CDA) and biological post-treatment with MBR for the effective removal of pollutants from MLL and puts forward the variation of organics in leachate between catalytic ozonation and MBR. The addition of catalytic ozonation not only improved the removal of hazardous organics but also enhanced the biodegradability of the leachate and favored the subsequent MBR process. Chemical oxygen demand (COD) removal in the catalytic ozonation step was optimized, and 53% removal was obtained at pH = 7, catalyst dosage = 1.0 g/L, and O₃ dosage = 3.0 g/L. After the MBR process, COD in effluent stabilized in the range of 57.85–65.38 mg/L, and the variation range of the ammonia nitrogen (NH₃-N) concentration was 5.98–10.24 mg/L. The catalytic ozonation-MBR integrated process showed strong feasibility in dealing with the biologically pre-treated leachate. Full article

The aim of this study was to evaluate the effectiveness of hydrodynamic cavitation (HC) as a pre-treatment method for selected organic wastes. In these HC experiments, municipal wastewater (MW) and mature landfill leachate (MLL) as well as mixtures of lignocellulosic waste (LB) suspended in these waste streams were investigated. For all HC tests, the same operational parameters were assumed: an inlet pressure of 7 bar, and 30 recirculations through the cavitation zone. A steel orifice plate with a conical concentric hole of 3/10 mm was used as the HC inductor. In almost all the materials analysed, solubilisation and decomposition of complex organic matter were observed, which were confirmed by an improved biodegradability index (BI) and soluble chemical oxygen demand (SCOD) content in the cavitated mixtures. The exception was the series with sole MW; in this case, the BI was reduced. In turn, regarding the multicomponent mixtures, more beneficial results were found for LB and MW, which were confirmed by improved BI, alkalinity and SCOD content. The results obtained indicate that HC might be applied as a pre-treatment method for selected organic wastes for further biomethane production. However, a key factor in its successful application is the selection of suitable operational conditions chosen individually for each waste type. Full article

The pollutant composition of landfill leachate is complex, and pollutant concentrations change greatly. Moreover, landfill leachates can easily penetrate into the soil and eventually pollute the ground water, which can cause environmental pollution and threaten human health. At present, landfill leachate treatment technology is still not mature. In this paper, the A/O-MBR (Anoxic–Aerobic Membrane Bioreactor) process is proposed to treat landfill leachate. To increase the hydrophilicity of the membranes and reduce the pollution of the membranes, the self-made TiO₂ nanoparticles were used to modify the ultrafiltration membranes (PVDF-2). Meanwhile, PVDF-2 composite membranes showed the best separation performance. The optimum operating parameters were determined by changing the concentration of the pollutants in the reactor and selecting the dissolved oxygen, pH, and hydraulic residence time. The results show that the optimum operating conditions of MBR are mixed liquor suspended solids (MLSS) = 3200 mg/L, DO = 1.5–2.5 mg/L in a nitrifying tank, DO = 0–0.5 mg/L in a denitrifying tank, pH = 7–8, and a hydraulic retention time (HRT) = 5 h. To reach the “Discharge Standard of Pollutants for Municipal Wastewater Treatment Plants” (GB18918-2002), the effluent of the MBR system further enters into the RO system. This work presents an environmentally friendly synthesis of TiO₂ nanoparticles and added into PVDF. The addition of self-made TiO₂ in PVDF membrane has improved the antifouling performance significantly, which has the potential for the treatment of landfill leachate. Full article

Mature landfill leachate is a complex and highly polluted effluent with a large amount of ammonia nitrogen, toxic components and low biodegradability. Its COD/N and BOD₅/COD ratios are low, which is not suitable for traditional nitrification and denitrification processes. Anaerobic ammonia oxidation (anammox) is an innovative biological denitrification process, relying on anammox bacteria to form stable biofilms or granules. It has been extensively used in nitrogen removal of mature landfill leachate due to its high efficiency, low cost and sludge yield. This paper reviewed recent advances of anammox based processes for mature landfill leachate treatment. The state of the art anammox process for mature landfill leachate is systematically described, mainly including partial nitrification–anammox, partial nitrification–anammox coupled denitrification. At the same time, the microbiological analysis of the process operation was given. Anaerobic ammonium oxidation (anammox) has the merit of saving the carbon source and aeration energy, while its practical application is mainly limited by an unstable influent condition, operational control and seasonal temperature variation. To improve process efficiency, it is suggested to develop some novel denitrification processes coupled with anammox to reduce the inhibition of anammox bacteria by mature landfill leachate, and to find cheap new carbon sources (methane, waste fruits) to improve the biological denitrification efficiency of the anammox system. Full article

Tin tetrachloride (SnCl₄) as a coagulant and rubber seed (Hevea brasiliensis) (RS), and polyacrylamide (PAM) as the coagulant aid were investigated in this work to treat matured and stabilised landfill leachate rich in COD and colour. A standard jar test was conducted at different pH values and dosages of coagulant/coagulant aid. When SnCl₄ acted as the primary coagulant, the optimum conditions occurred at pH 8 and 10,000 mg/L dosages, with 97.3% and 81% reductions of colour and COD, respectively. Both RS and PAM were not effective when used alone. When RS was used as the coagulant aid, the dosage of SnCl₄ was reduced to 8000 mg/L. The colour reduction was maintained at 97.6%, but the COD removal dropped to 43.1%. In comparison, when PAM was supplemented into 6000 mg/L SnCl₄, the reduction in colour was maintained at 97.6%, and the COD removal was almost at par when SnCl₄ was used alone. The addition of polymers as the coagulant aid helped in improving the sludge properties with a better settling rate (SSR) and larger flocs size. The decline of the SVI value indicates that less amount of sludge will be disposed of after the treatment. In addition, the rise of settling velocity (SSR) will reduce the size of the settling tank used in coagulation-flocculation treatment. Based on the results, it can be concluded that incorporation of coagulant aid into the treatment reduced the primary coagulant dosage without affecting the removal performances of pollutants. Full article

This study focused on the reduction of the treatment cost of mature landfill leachate (LL) by enhancing the coagulation pre-treatment before a UVA-LED photo-Fenton process. A more efficient advanced coagulation pretreatment was designed by combining conventional coagulation (CC) and electro-coagulation (EC). Regardless of the order in which the two coagulations were applied, the combination achieved more than 73% color removal, 80% COD removal, and 27% SUVA removal. However, the coagulation order had a great influence on both final pH and total dissolved iron, which were key parameters for the UVA-LED photo-Fenton post-treatment. CC (pH = 5; 2 g L^?1 of FeCl₃6H₂O) followed by EC (pH = 5; 10 mA cm^?2) resulted in a pH of 6.4 and 100 mg L^?1 of dissolved iron, whereas EC (pH = 4; 10 mA cm^?2) followed by CC (pH = 6; 1 g L^?1 FeCl₃6H₂O) led to a final pH of 3.4 and 210 mg L^?1 dissolved iron. This last combination was therefore considered better for the posterior photo-Fenton treatment. Results at the best cost-efficient [H₂O₂]:COD ratio of 1.063 showed a high treatment efficiency, namely the removal of 99% of the color, 89% of the COD, and 60% of the SUVA. Conductivity was reduced by 17%, and biodegradability increased to BOD₅:COD = 0.40. With this proposed treatment, a final COD of only 453 mg O₂ L^?1 was obtained at a treatment cost of EUR 3.42 kg COD^?1. Full article

The management of mature landfill leachate (MLL) represents an increasingly crucial issue to tackle. In this study, the feasibility of an integrated treatment was investigated at the laboratory scale using synthetic leachate with the objective of maximizing the recovery of potentially useful compounds present in leachate (especially ammonia nitrogen). First, in order to remove heavy metals, active filtration of the MLL was carried out using zero-valent iron (ZVI) mixed with either lapillus or granular activated carbon (GAC). The average removal rates for the ZVI/lapillus and the ZVI/GAC filter were 33%, 85%, 66%, and 58% and 56%, 91%, 67%, and 75% for COD, Cu, Ni, and Zn, respectively. Then, pre-treated MLL was added during the anaerobic digestion (AD) of cellulose with the aim of providing bacteria with macro (i.e., ammonia nitrogen) and micro (e.g., residual heavy metals) nutrients. After 38 days, the best performance in terms of cumulative methane production (5.3 NL) and methane yield (0.26 NL/gVS_added on average) was recorded in the reactor fed with the lowest dosage (17.9 mL/d) of MLL pre-treated by the ZVI/lapillus filter. The main issue that emerged during AD was the possible inhibition of the process linked to an excessive presence of humic substances; however, in future experiments, this problem can be solved through an optimization of the management of the whole process. The residual digestate from AD, rich in nitrogen and humic substances, may be safely used for agriculture purposes, closing the cycle of MLL management. Full article

The percolation of rainwater and runoff water through household waste in the dumpsite generally leads to an overabundance of leachate in Moroccan landfills, which is a source of soil, surface water and groundwater contamination. In order to ecologically solve the problem posed by the leachate in the dump site, to safeguard the environment and to contribute to sustainable development, we have carried out this study which aims to study the possibility of composting leachate with green waste and phosphate washing sludge. Various combinations with five substrates (leachate, green waste, sugar lime sludge, phosphate washing sludge and olive mill wastewater) in different proportions were used to build five windrows. A 24 h contact between the phosphate sludge or sugar lime sludge and the leachate took place prior to the addition of the green waste for the construction of the different windrows. This contact time ensured the absorption of a significant portion of the leachate and the disappearance of bad odor. A significant reduction was obtained with streptococci and mesophilic flora after 24 h of contact. The monitoring of the physicochemical parameters throughout the composting process showed that the temperature of the different windrows followed a good pace presenting all composting phases. Moisture, pH, C/N ratio and the percentage of degradation of the organic matter conformed to the quality standards of the compost. The combinations of the alkaline treatment and the composting process allowed a significant hygienization of the leachate. The results of the humification parameters and the E4/E6 ratio suggest that the composts obtained with phosphate sludge were the most stable and mature and can be used in the agricultural field or green space. Full article

Mature landfill leachates are characterized by high levels of ammoniacal nitrogen which must be reduced for discharge in the sewer system and further treatment in municipal wastewater treatment plants. The use of anammox-based processes can allow for an efficient treatment of ammonium-rich leachates. In this work, two real scale sequencing batch reactors (SBRs), designed to initially perform partial nitritation/anammox (PN/A) and simultaneous partial nitrification and denitrification (SPND) for the treatment of ammonium-rich urban landfill leachate, were modelled using BioWin 6.0 in order to enable plant-wide modelling and optimizing. The constructed models were calibrated and validated using data from long- and short-term (one cycle) SBR operation and fit well to the main physical-chemical parameters (i.e., ammonium, nitrite and nitrate concentrations) measured during short-term (one cycle) operations. Despite the different strategies in terms of dissolved oxygen (DO) concentrations and aeration and mixing patterns applied for SBR operation, the models allowed for understanding that in both reactors the PN/A process was shown as the main contributor to nitrogen removal when the availability of organic carbon was low. Indeed, in both SBRs, the activity of nitrite oxidizing bacteria was inhibited due to high levels of free ammonia, whereas anammox bacteria were active due to the simultaneous presence of ammonium and nitrite and their ability to recover from DO inhibition. Increasing the external carbon addition, a prompt decrease of the anammox biomass was observed, with SPND becoming the main nitrogen removal mechanism. Models were also applied to estimate the production rates of nitrous oxide by aerobic ammonia oxidizing bacteria and heterotrophic denitrifiers. The models were found to be a robust tool for understanding the effects of different operating conditions (i.e, temperature, cycle phases, DO concentration, external carbon addition) on the nitrogen removal performances of the two reactors, assessing the contribution of the different bacterial groups involved. Full article

(1) Background: Biological treatment of leachate in landfill sites using anaerobic ammonium oxidation (anammox) is challenging because of the intrinsic characteristics of this complex wastewater. In this work, the scale-up and subsequent full-scale implementation of the PANAMMOX^® technology (LEQUIA Research Group, Girona, Catalonia, Spain) are presented as a case study to achieve long-term nitrogen (N) removal from mature leachate mostly through a completely autotrophic pathway. (2) Methods: The treatment system consists of two sequencing batch reactors (SBRs) running in series to individually operate partial nitritation (PN) and anammox (A). Following biological treatment, physicochemical oxidation (i.e., Fenton-based process) was used to remove the remaining non-biodegradable organic matter. A cost analysis comparative was conducted in relation to the former technology used on-site for treating the leachate. (3) Results: The scale-up of the process from pilot- to full-scale was successfully achieved, finally reaching an average removal of 7.4 kg N/d. The composition of the leachate changed over time, but especially once the landfill site stopped receiving solid waste (this fact involved a marked increase in the strength of the leachate). The adjustment of the alkalinity-to-ammonium ratio before feeding PN-SBR helped to improve the N-removal efficiency. Values of conductivity above 25 mS/cm in A-SBR could negatively affect the performance of the anammox process, making it necessary to consider a dilution strategy according to the on-line monitoring of this parameter. The analysis of the operational costs showed that by implementing the PANAMMOX^® technology (LEQUIA Research Group, Girona, Catalonia, Spain) in the landfill site, savings up to 32% were achievable. (4) Conclusions: Treatment of mature landfill leachate in such a two-stage PN-A system was demonstrated as feasible and economically appealing despite the complexity of this industrial wastewater. Accurate expert supervision of the process was a key factor to reaching good performances. Full article