Search Results (46)

Solid waste management remains a critical challenge in rapidly urbanizing regions of the Global South, where limited infrastructure and informal disposal practices compromise environmental and public health. This study addresses the issue of illegal waste dumping in Dakar, Senegal, by integrating remote sensing, geographic information systems, and citizen science into a multi-criteria framework to identify areas most susceptible to dumping. Using Landsat 8 and Sentinel-2 imagery, indicators such as land surface temperature, vegetation, soil, and water indices were combined with demographic and infrastructural data. A citizen survey involving local university students provided social perception scores and criterion weights through the Analytic Hierarchy Process. The resulting susceptibility maps revealed that high and very high dumping probabilities are concentrated around the Mbeubeuss landfill and densely populated areas of Keur Massar, while Malika showed lower susceptibility. Sensitivity analysis confirmed the model’s robustness but highlighted the influence of thermal and social perception variables. The results show that 28–35% of the study area falls under high or very high susceptibility, with hotspots concentrated near wetlands, informal settlements, and poorly serviced road networks. The weighted model demonstrates stronger spatial coherence compared to the unweighted version, offering improved interpretability for waste monitoring. These findings provide actionable insights for the Société Nationale de Gestion Intégrée des Déchets (SONAGED) and for municipal planners to prioritize interventions in high-susceptibility zones. Rather than being entirely novel, this study builds on existing remote sensing, geographic information systems and citizen science approaches by integrating them within a multi-criteria framework specifically adapted to a West African context. Full article

Numerical simulation of groundwater level dynamics plays a crucial role in the safety assessment of near-surface radioactive waste disposal facilities. Such disposal sites are typically located in regions characterized by extensive bedrock outcrops. However, accurately characterizing the permeability of fractured media is challenging, and the scarcity of groundwater level data poses significant difficulties for constructing reliable numerical models. This study focuses on a near-surface disposal site in northwestern China. By integrating field packer tests with hydraulic conductivity tensors computed from borehole televiewer data, we quantitatively evaluated the permeability of fractured rocks of different lithologies to provide accurate parameters for numerical modeling. The constructed groundwater flow model was further calibrated and validated using long-term groundwater level monitoring data and field tracer-based groundwater flow direction tests, ensuring high model reliability. Using the calibrated model, groundwater level variations were simulated under various rainfall and pumping scenarios. The results show that pumping intensity in the downstream farmland area exerts a limited influence on groundwater levels beneath the disposal site, while rainfall intensity plays a dominant role. Under the heavy rainfall scenario, the groundwater level at the disposal site rises by approximately 5.2 m after 50 years, leaving a 6 m gap above the base of the disposal unit. Under prolonged heavy rainfall conditions, implementing drainage measures may be necessary to ensure the repository’s long-term safety. Full article

Groundwater resources in Jordan are under severe stress due to rapidly increasing water demand and over-abstraction that far exceeds natural replenishment. In addition, water quality is threatened by pollution from the misuse of fertilizers and pesticides, leakage from septic tanks, and illegal waste disposal. This study focuses on the Aqeb, Corridor, and Special Economic Zone wellfields, where hydrological and hydrochemical investigations were carried out. A total of 36 groundwater samples were collected and analyzed for hydrochemical composition, stable isotopes of oxygen (δ¹⁸O) and hydrogen (δ²H), and trace elements. In addition, two exploration 2D seismic profiles crossing the study area were interpreted, providing critical insights into the activity of the subsurface Fuluk Fault zone and its relationship with the wellfields. The hydrochemical results reveal elevated total dissolved solids and nitrate concentrations, accompanied by more depleted δ¹⁸O and δ²H values in wells located in the central part of the study area. Three distinct hydrochemical groups were identified within the same aquifer, indicating heterogeneity in groundwater chemistry that reflects variations in recharge conditions, flow paths, and geochemical processes. The first group (high Na/Cl with low salinity) likely represents recently recharged waters with limited rock–water interaction. The second group (intermediate Na/Cl and moderate salinity) may be influenced by evaporation, irrigation return flow, or cation exchange. The third group (low Na/Cl with high salinity) suggests the dissolution of sulfate minerals or mixing with deeper mineralized groundwater, possibly facilitated by structural features such as the Fuluk Fault. Seismic interpretation indicates several active near-surface fault systems that are likely to serve as preferential pathways for salinity and nitrate enrichment, linked to intensive agricultural activities and wastewater leakage from nearby septic tanks. The findings emphasize the combined influence of geochemical processes, excessive groundwater abstraction, and structural features in controlling water quality in the region. Full article

The selection of suitable sites for the disposal of radioactive waste constitutes a critical component of nuclear waste management. This study presents an original methodological proposal based on the Analytic Hierarchy Process (AHP), designed to support early-stage site screening for a near-surface repository in Italy. AHP could be used to identify appropriate locations, focusing on 51 areas that have already undergone a preliminary screening phase. These areas, included in the National Map of Suitable Areas (CNAI), were selected as they fulfill all the technical requirements (geological, geomorphological, and hydraulic stability) necessary to ensure the safety performance of the engineering structures to be implemented through multiple artificial barriers, as specified in Technical Guide N. 29. The proposed methodology is applicable in cases where multiple sites listed in the CNAI have been identified as potential candidates for hosting the repository. A panel of 20 multidisciplinary experts, including engineers, environmental scientists, sociologists, and economists, evaluated two environmental, two economic, and two social criteria not included among the criteria outlined in Technical Guide N. 29. Pairwise comparisons were aggregated using the geometric mean, and consistency ratios (CRs) were calculated to ensure the coherence of expert judgements. Results show that social criteria received the highest overall weight (0.53), in particular the “degree of site acceptability”, followed by environmental (0.28) and economic (0.19) criteria. While the method does not replace detailed site investigations (which will nevertheless be carried out once the site has been chosen), it can facilitate the early identification of promising areas and guide future engagement with local communities. The approach is reproducible, adaptable to additional criteria or national requirements, and may be extended to other countries facing similar nuclear waste management challenges. Full article

The widespread use of activated carbon (AC) as an adsorbent in diverse applications generates substantial amounts of AC waste, posing environmental and disposal challenges. Therefore, effective AC regeneration is essential to enhance the sustainability of adsorption-based technologies. However, conventional regeneration methods often involve harsh chemicals or energy-intensive processes, limiting environmental and economic feasibility. In this study, the regeneration of commercial AC saturated with synthetic dyes Acid Blue 9 (AB9) and Acid Yellow 23 (AY23) is investigated using aqueous solutions of ionic liquids (ILs) as a green alternative. A set of ILs with varying cation–anion structures was synthesized and screened for regeneration performance, where [TBP][Sal] was identified as the most effective. Process parameters such as IL concentration, temperature, time, and solid-to-liquid ratio were optimized using response surface methodology, achieving regeneration efficiencies of up to 99% for AB9-AC and 80% for AY23. These efficiencies persisted over three cycles, while adsorption capacity remained unchanged for AY23 and decreased by ~40% for AB9. To improve sustainability, a preliminary study was conducted by implementing an aqueous biphasic system for IL and dye concentration from the post-regeneration solution. This integrated strategy presents a promising step toward the development of near-zero waste adsorption–regeneration cycles for AC adsorption applications. Full article

Sustainable strategies are required to mitigate elevated atmospheric CO₂ levels. Achieving that by adsorption, especially by using clay-based adsorbents, drew attention. These are even more promising when these adsorbents are obtained by low-cost modifications. This study evaluates the effect of ball milling on the carbon capture performance of Australian halloysite nanotube (HNT)-rich kaolin samples: one without iron impurities (Hal) and the other with iron impurities (HalFe). The iron was mainly nested within illite/mica minerals in HalFe. Samples were ball-milled for 30 and 60 min, and their CO₂ sorption was assessed at various pressures and temperatures. Crystallography, electronic microscopy, and surface area and charge characterization revealed reduced length and increased width of tubular structure following ball milling, leading to higher specific surface area without compromising crystallinity. CO₂ sorption of Hal increased 14% at 20 bar and 15 °C after 60 min milling, with a ~300% rise at near-atmospheric pressures. Conversely, milling negatively affected CO₂ sorption of HalFe, likely due to iron/illite-mica-related damage during milling. Crystallography, infrared, and thermographic analyses revealed physisorption as the primary sorption mechanism. Since direct disposal of CO₂-laden materials is against sustainability principles, these materials were tested for methylene blue removal from aqueous solutions, achieving ~83% (Hal) and ~91% (HalFe) removal efficiencies. This highlights HNTs-rich kaolin clays’ valorization potential for carbon capture and utilization (CCU). Full article

Copper has been proposed as a container material for the disposal of used nuclear fuel in a number of countries worldwide. The container materials will be subject to various corrosion processes in a deep geological repository, including radiation-induced corrosion (RIC) resulting from the γ-irradiation of the near-field environment. A comprehensive model is being developed to predict the extent of RIC by coupling a radiolysis model to the interfacial electrochemical reactions on the container surface. An important component of the overall model is a radiolysis model to predict the time-dependent concentration of oxidizing and reducing radiolysis products. As a first step in the model development, various radiolysis models have been validated against experimental measurements of the concentrations of dissolved and gaseous radiolysis products. Experimental data are available for pure H₂O- and Cl⁻-containing solutions, with and without a gas headspace. The results from these experiments have been compared with predictions from corresponding radiolysis models, including the effects of the partitioning of gaseous species (O₂ and H₂) at the gas–solution interface. Different reaction schemes for the Cl⁻ radiolysis models are also compared. The validated radiolysis model will then be coupled with interfacial reactions on the copper surface and additional processes related to the presence of bentonite clay in Steps 2 and 3 of the overall model, respectively. Full article

A two-dimensional longitudinal profile model was used to evaluate groundwater flow along a 48 km flowline in the Southeastern Hueco Aquifer, extending from the Diablo Plateau in Texas to the Sierra de San Ignacio in Chihuahua, Mexico. The model, incorporating geologically distributed permeability values, closely matched the predevelopment potentiometric surface. Predicted recharge rates and travel times aligned with published estimates and environmental isotopes, suggesting potential transboundary groundwater movement. The model estimated recharge rates needed to reach flow capacity, or the maximum volume a system can transmit, typically saturating the water table. Current moisture levels are insufficient, but flow capacity may have been reached during late Pleistocene pluvial periods. Required recharge rates were 297% higher than initial calibration in the U.S. and 1080% higher in Mexico, with only U.S. estimates appearing plausible for the Pleistocene–Holocene transition. These findings are relevant to regional waste disposal considerations because water tables near land surface present a risk to groundwater resources. A transient simulation modeled hydraulic head decay due to recharge abatement linked to climate change over 14,000 years. It simulated a decrease from a “flow capacity” recharge rate of 10.4 mm/year to 3.5 mm/year today. The modeling simulations ended with the hydraulic head remaining only 20 m above current levels, suggesting a minimal-to-negligible fossil hydraulic gradient in the low-permeability flow system. Full article

The deep burial disposal of nuclear waste and dry hot rock mining relates to the effects of high temperatures on the physical and mechanical properties of granite. Previous studies have shown that due to the anisotropy of mineral arrangements during granite formation, the physical and mechanical properties of granite vary greatly with different temperatures. We conducted wave velocity tests, optical mirror tests, and uniaxial and conventional triaxial compression tests on granite in three orthogonal directions before and after high-temperature treatment. The main innovative conclusions are as follows: (1) High temperatures can cause the density of thermal cracks in the cross-section of granite, which varies with different sampling directions. Temperatures below 400 °C increase the anisotropy of granite, and there are obvious advantages in the development direction. (2) Under the same temperature conditions, granite samples taken parallel to the dominant direction of cracks exhibit the best mechanical properties. (3) In uniaxial compression tests, granite samples after high-temperature treatment are mostly subjected to tensile splitting failure. When the heating temperature is higher than 400 °C, a large number of transgranular cracks are generated during the thermal damage of granite at this temperature stage. Rock samples taken perpendicular to the dominant direction of the crack can generate radial cracks near the main failure surface, while rock samples taken parallel to the dominant direction of the crack can generate more axial cracks. Full article

Transversely isotropic rocks, which are special anisotropic materials, are widely encountered in civil, mining, petroleum, geothermal, and radioactive waste-disposal engineering. Rock is frequently subject to cyclic loads resulting from natural and human-caused events. However, to date, the fracture mechanism of transversely isotropic rocks under cyclic loading remains poorly understood. To address this gap, uniaxial monotonic-loading and cyclic-loading tests were performed on slate specimens by the MTS815 system, during which acoustic emission (AE) signals inside the rock were monitored, and finally the fracture surfaces of the tested rock were scanned by scanning electron microscopy (SEM). Through these tests, the anisotropic mechanical properties, damage evolution, AE characteristics and fracture pattern of slate as a transversely isotropic rock were studied. The results show that the peak strength of specimens varies with the loading–foliation angle under monotonic and cyclic loading, following a U-shaped trend. The deformation modulus during unloading is more capable of characterizing the damage inside the specimen than that during loading. By defining the damage degree based on dissipation energy, it is found that the damage variable is influenced by the loading–foliation angle and the cyclic stress step. The AE characteristics of specimens exhibit significant anisotropy, closely correlated to the loading condition and loading–foliation angle. Regardless of cyclic stress step, the AE counts of specimens with a loading–foliation angle of 0° are mainly distributed near the peak region, whereas those of specimens with other loading–foliation angles occur primarily in the early stage of each cyclic loading. Finally, it is revealed that the fracture mechanism of slate specimens is determined by the loading–foliation angle, loading condition, and cyclic stress step. Full article

Disposal tunnels in geological repositories are ventilated continuously for over 50 years until their closure. Under these conditions, an unsaturated zone of mixed liquid and gas phases forms around the tunnels. Moreover, drying is assumed to progress from the host rock to the tunnels. To understand these drying processes, this study investigated the migration and precipitation of solutes via capillary forces during drying in packed columns using silica sand or glass beads as packed layers and X-ray CT analysis. In addition, the apparent permeability of a column packed with silica sand containing precipitation was examined using a flow experiment. The results indicate that the precipitation and accumulation of solutes were significant near the drying surfaces of the columns. The apparent mass transfer coefficient at a relatively early stage of the drying process indicates that the migration rate of solutes depends strongly on the capillary forces during the drying process. Furthermore, the apparent permeability of the columns with precipitation decreased significantly. These indicate that the precipitation and accumulation of solutes with drying in the groundwater reduce the porosity and permeability, and the advection of groundwater around the repository may be suppressed. Full article

Highly radioactive materials classified as high-level nuclear waste (HLW) of atomic power engineering should be disposed of deeply underground in special geological disposal facilities (GDFs), which can be of either shaft or borehole type. The advantages of borehole-type GDFs result from smaller volumes of mining operations, a simpler construction technology, shorter construction time and cost. This allows us to consider them as an alternative to shaft-type GDFs. The parts of the boreholes in which waste containers should be placed can be both vertical and horizontal. Computer simulation of the migration of radionuclides from a group of parallel horizontal boreholes into the biosphere made it possible to conclude that horizontal GDF boreholes have significant advantages over vertical ones. We determined a forecast of ²⁴¹Am migration by a method of mathematical modelling of ²⁴¹Am release from vitrified HLW disposed of in several horizontal drillholes. The maximum concentrations of americium in the near-surface groundwater above the repository are calculated depending on the number of boreholes, the depth of their location and the distance between them, the permeability of rocks and the time of waste storage prior to disposal. Influence of different conditions on the safety of a GDF of borehole type is estimated. Calculations show that the heat generated by HLW causes a weaker groundwater convection near horizontal boreholes compared to vertical boreholes of the same capacity. In addition to that, at an equal thickness of the rock layer separating the HLW from the surface, the geothermal temperature of the host rocks in the near field of a horizontal borehole will be lower than the average geothermal temperature near a vertical borehole. As a result, the rate of radionuclides leaching from the waste forms by groundwaters will also be lower in the case of horizontal boreholes. Full article

Point-of-care testing (POCT), also known as on-site or near-patient testing, has been exploding in the last 20 years. A favorable POCT device requires minimal sample handling (e.g., finger-prick samples, but plasma for analysis), minimal sample volume (e.g., one drop of blood), and very fast results. Shear horizontal surface acoustic wave (SH-SAW) biosensors have attracted a lot of attention as one of the effective solutions to complete whole blood measurements in less than 3 min, while providing a low-cost and small-sized device. This review provides an overview of the SH-SAW biosensor system that has been successfully commercialized for medical use. Three unique features of the system are a disposable test cartridge with an SH-SAW sensor chip, a mass-produced bio-coating, and a palm-sized reader. This paper first discusses the characteristics and performance of the SH-SAW sensor system. Subsequently, the method of cross-linking biomaterials and the analysis of SH-SAW real-time signals are investigated, and the detection range and detection limit are presented. Full article

Near-neutral pH and a low redox potential are considered favorable conditions for immobilizing radionuclides in deep repository systems within clay formations. Cigeo is the future French Industrial Center for Geological Disposal for high- and intermediate-level long-lived radioactive waste, to be built at a depth of 500 m within the Callovian–Oxfordian clay. In-depth knowledge of the mechanisms and kinetics of corrosion occurring on the surface of API 5L X65 (X65) carbon steel tubing is essential for the reversible nuclear waste management of the Cigeo site. By using all-solid and robust handmade electrodes in addition to electrochemical and gravimetric techniques, we determined the corrosion phenomenology and kinetics of X65 in contact with natural Cox pore water in equilibrium with its rock gases, flowing continuously through a multi-parameter probe device and placed at a depth of 500 m at the Bure Underground Research Laboratory, for over 180 days. Two iron oxidants were encountered, namely, depleted dioxygen (O₂) and proton H^(I), accompanied by hydrogen sulfide. Corrosion mechanisms and kinetics were well established for the two X65 electrodes, whether electrochemically perturbed or not. The corrosion thickness loss rates, determined by both electrochemical and gravimetric techniques, were between 0.016 and 0.032 mm/year. This study demonstrates, on site, the reliability of a developed methodology for continuous monitoring of the corrosion kinetics of the API 5L X65 carbon steel at the same time as the temporal variation of the key geochemical parameters of the fluid was assessed. Full article

Remote sensing can represent an important instrument for monitoring landfills and their evolution over time. In general, remote sensing can offer a global and rapid view of the Earth’s surface. Thanks to a wide variety of heterogeneous sensors, it can provide high-level information, making it a useful technology for many applications. The main purpose of this paper is to provide a review of relevant methods based on remote sensing for landfill identification and monitoring. The methods found in the literature make use of measurements acquired from both multi-spectral and radar sensors and exploit vegetation indexes, land surface temperature, and backscatter information, either separately or in combination. Moreover, additional information can be provided by atmospheric sounders able to detect gas emissions (e.g., methane) and hyperspectral sensors. In order to provide a comprehensive overview of the full potential of Earth observation data for landfill monitoring, this article also provides applications of the main procedures presented to selected test sites. These applications highlight the potentialities of satellite-borne sensors for improving the detection and delimitation of landfills and enhancing the evaluation of waste disposal effects on environmental health. The results revealed that a single-sensor-based analysis can provide significant information on the landfill evolution. However, a data fusion approach that incorporates data acquired from heterogeneous sensors, including visible/near infrared, thermal infrared, and synthetic aperture radar (SAR), can result in a more effective instrument to fully support the monitoring of landfills and their effect on the surrounding area. In particular, the results show that a synergistic use of multispectral indexes, land surface temperature, and the backscatter coefficient retrieved from SAR sensors can improve the sensitivity to changes in the spatial geometry of the considered site. Full article