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Search Results (314)

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25 pages, 6292 KiB  
Article
Improving Cocoa Drying Efficiency with a Mixed Forced Convection Solar Dryer in an Equatorial Climate
by Arnaud Nzendjang Mbakouop, Claude Bertin Nzoundja Fapi, André Désire Siéwé, Hyacinthe Tchakounté and Awoh Innocentia Ankungha
Thermo 2025, 5(2), 18; https://doi.org/10.3390/thermo5020018 - 30 May 2025
Viewed by 213
Abstract
A crucial stage in the post-harvest processing of cocoa beans, drying, has a direct effect on the finished product’s quality and market value. This study investigates the efficiency, quality outcomes, and environmental implications of a mixed forced convection solar dryer designed for drying [...] Read more.
A crucial stage in the post-harvest processing of cocoa beans, drying, has a direct effect on the finished product’s quality and market value. This study investigates the efficiency, quality outcomes, and environmental implications of a mixed forced convection solar dryer designed for drying cocoa beans in Ntui, Cameroon, compared to traditional open-air drying methods. The solar dryer’s design, incorporating a solar collector, forced ventilation, and thermal storage, leverages local materials and renewable energy, offering an environmentally sustainable alternative by reducing fossil fuel reliance and post-harvest losses. Experimental trials were conducted to assess key drying parameters, including the temperature, relative humidity, water removal rate, pH, and free fatty acid (FFA) content, under the equatorial climate conditions of high solar irradiation and humidity. Results demonstrate that the solar dryer significantly reduces drying time from an average of 4.83 days in open-air drying to 2.5 days, a 50% improvement, while maintaining optimal conditions for bean quality preservation. The solar-dried beans exhibited a stable pH (5.7–5.9), a low FFA content (0.282% oleic acid equivalent, well below the EU standard of 1.75%), and superior uniformity in texture and color, meeting international quality standards. In contrast, open-air drying showed greater variability in quality due to weather dependencies and contamination risks. The study highlights the dryer’s adaptability to equatorial climates and its potential to enhance cocoa yields and quality for small-scale producers. These findings underscore the viability of solar drying as a high-performance, eco-friendly solution, paving the way for its optimization and broader adoption in cocoa-producing regions. This research contributes to the growing body of knowledge on sustainable drying technologies, addressing both economic and environmental challenges in tropical agriculture. Full article
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11 pages, 1415 KiB  
Article
The Effect of Extrinsic Staining on 3D Printed Provisional Crowns
by Abdullah Marafi, Samantha Manna, Thomas Kunkel, Mohsen Azarbal, Cortino Sukotjo, Alvin G. Wee and Stavroula Antonopoulou
Prosthesis 2025, 7(3), 47; https://doi.org/10.3390/prosthesis7030047 - 8 May 2025
Viewed by 268
Abstract
Purpose: The aim of this study was to evaluate the color stability of 3D printed resin disks using spectral reflectance data obtained at different time periods after immersion in various staining solutions. The color stability of 3D-printed temporary crowns is clinically important, as [...] Read more.
Purpose: The aim of this study was to evaluate the color stability of 3D printed resin disks using spectral reflectance data obtained at different time periods after immersion in various staining solutions. The color stability of 3D-printed temporary crowns is clinically important, as it directly affects the esthetic outcome and patient satisfaction during the provisional phase of treatment. Materials and methods: Forty identical round disk specimens measuring 10 mm in diameter and 2 mm in thickness were fabricated using CAD/CAM 3D printing resin (shade B1). Half of the specimens (n = 20) were polished using an acrylic bur and medium pumice. The remaining specimens were unpolished (n = 20). Each group of disks was then immersed in one of the following immersion solutions: artificial saliva, black tea, carrot juice, and red wine. Color difference ΔE was evaluated using the spectrophotometer, a spectral reflectance instrument, at baseline, day 1, week 1, week 2 and week 3, against a white background. Comparisons between polished and unpolished disks at each time point were conducted using Mann–Whitney tests. Differences among the staining solutions at each time point for both polished and unpolished disks were analyzed using a one-way ANOVA with Tukey’s post hoc test. Results: Color difference ΔE was measured using the CIELAB formula. The mean ΔE values of each group were calculated. The greatest difference in color was observed in the unpolished and polished disks immersed in red wine. Polished disks showed less color difference when compared to unpolished disks. Significant differences in ΔE were detected between polished and unpolished disks immersed in red wine at week 1 (p = 0.0159), week 2 (p = 0.0079) and week 3 (p = 0.0079) and in carrot juice at week 3 (p = 0.0317). Conclusions: Immersion of 3D printed disks in different staining solutions caused detectable color difference in the tested materials, which was relative to the immersion duration and the staining solution used. The color of the 3D printed resins is influenced by the surface finishing, which may result in visually perceptible color differences. The color stability of 3D printied materials should be improved to provide long-term esthetics. Full article
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15 pages, 3214 KiB  
Article
Dimensional Accuracy of Regular- and Fast-Setting Vinyl Polysiloxane Impressions Using Customized Metal and Plastic Trays—An In Vitro Study
by Moritz Waldecker, Karla Jetter, Stefan Rues, Peter Rammelsberg and Andreas Zenthöfer
Materials 2025, 18(9), 2164; https://doi.org/10.3390/ma18092164 - 7 May 2025
Viewed by 314
Abstract
The aim of this study was to compare the dimensional accuracy of vinyl polysiloxane impressions differing in terms of curing time (regular-setting (RS) or fast-setting (FS)) in combination with different tray materials (metal (M) and plastic (P)). A typodont reference model simulated a [...] Read more.
The aim of this study was to compare the dimensional accuracy of vinyl polysiloxane impressions differing in terms of curing time (regular-setting (RS) or fast-setting (FS)) in combination with different tray materials (metal (M) and plastic (P)). A typodont reference model simulated a partially edentulous maxilla. Reference points were given by center points of either precision balls welded to specific teeth or finishing-line centers of prepared teeth. These reference points enabled the detection of dimensional deviations between the digitized reference and the scans of the models achieved from the study impressions. Twenty impressions were made for each of the following four test groups: RS-M, RS-P, FS-M and FS-P. Global scan data accuracy was measured by distance and tooth axis deviations from the reference, while local accuracy was determined based on the trueness and precision of the abutment tooth surfaces. Statistical analysis was conducted using ANOVA accompanied by pairwise Tukey post hoc tests (α = 0.05). Most of the distances tended to be underestimated. Global accuracy was favorable; even for long distances, the mean absolute distance deviations were < 100 µm. Local accuracy was excellent for all test groups, with trueness ≤ 11 µm and precision ≤ 9 µm. Within the limitations of this study, all impression and tray materials were suitable to fabricate models with clinically acceptable accuracy. Full article
(This article belongs to the Special Issue Advanced Biomaterials for Dental Applications (2nd Edition))
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15 pages, 5252 KiB  
Article
Identification of the Influence of IPA Rinsing Times on Surface Roughness of SLA-Printed Parts Made of Different Materials
by Wiktor Harmatys, Adam Gąska, Piotr Gąska and Maciej Gruza
Materials 2025, 18(9), 2082; https://doi.org/10.3390/ma18092082 - 1 May 2025
Viewed by 333
Abstract
This study investigates the influence of isopropyl alcohol (IPA) washing time on the surface roughness of stereolithography (SLA)-printed parts fabricated using the Formlabs Form 3B+ printer. Three photopolymer resins provided by the manufacturer were evaluated: Gray, Tough 2000, and Rigid 10K. Samples were [...] Read more.
This study investigates the influence of isopropyl alcohol (IPA) washing time on the surface roughness of stereolithography (SLA)-printed parts fabricated using the Formlabs Form 3B+ printer. Three photopolymer resins provided by the manufacturer were evaluated: Gray, Tough 2000, and Rigid 10K. Samples were printed in standardized geometries and post-processed under controlled conditions, with IPA washing times ranging from 6 to 30 min, followed by UV post-curing. The surface roughness parameters (Ra, Rz, Rt, and RSm) were measured using a Taylor Hobson Form Talysurf i-Series profilometer under metrologically controlled conditions. The results revealed a clear correlation between increased IPA exposure time and improved surface finish, though the magnitude and monotonicity of this effect were material dependent. Rigid 10K exhibited the most consistent reduction in roughness with longer washing, while Tough 2000 showed substantial improvement with extended durations but also demonstrated temporary surface degradation at intermediate wash times. Gray resin achieved near-optimal roughness after moderate rinsing, with orientation-dependent differences observed. The findings indicate that the careful optimization of washing duration can significantly enhance the surface quality in SLA prints, potentially eliminating the need for secondary finishing processes. The implications are relevant to both industrial and medical applications where dimensional fidelity and surface smoothness are critical. Recommendations for optimal washing durations are proposed for each material, and directions for further research are outlined. Full article
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17 pages, 329 KiB  
Article
Guanidinoacetic Acid and Its Impact on the Performance, Carcass and Meat Quality of Growing and Finishing Nellore Cattle
by Letícia Carolina Bortolanza Soares, Leticia Kim Huang, Germán Darío Ramírez-Zamudio, Murilo Soler de Magistri, Joao Marcos Bovetto de Campos Valim, Vinicius Laerte Silva Herreira, Patricia Maloso Ramos, Carl Robertson Dahlen, Nara Regina Brandão Cônsolo, Saulo Luz Silva and Paulo Roberto Leme
Vet. Sci. 2025, 12(5), 425; https://doi.org/10.3390/vetsci12050425 - 30 Apr 2025
Viewed by 520
Abstract
This study evaluated the effects of guanidinoacetic acid (GAA) supplementation during the growing and finishing phases on Nellore bulls’ performance, carcass traits, and meat quality. Fifty-two Nellore bulls were randomly assigned to four treatments: control (CON, without GAA) and three GAA levels (3, [...] Read more.
This study evaluated the effects of guanidinoacetic acid (GAA) supplementation during the growing and finishing phases on Nellore bulls’ performance, carcass traits, and meat quality. Fifty-two Nellore bulls were randomly assigned to four treatments: control (CON, without GAA) and three GAA levels (3, 6, and 9 g/kg dry matter [DM] in the growing supplement; 0.3, 0.6, and 0.9 g/kg DM in the finishing diet). During the 280-day growing phase, bulls were kept in paddocks, while in the 74-day feedlot finishing phase, they were housed in collective pens. Body weight, average daily gain, and carcass ultrasound measurements were recorded in both phases. Feed intake was recorded daily during finishing, and carcass traits were evaluated post-slaughter. GAA supplementation during the growing phase did not affect performance or ultrasound carcass traits (p ≥ 0.12). In the finishing phase, increasing GAA doses linearly reduced body weight gain (p = 0.03) without affecting carcass traits assessed by ultrasound or post-slaughter (p ≥ 0.10). GAA supplementation linearly reduced cooking loss (p = 0.02) without influencing other meat quality parameters (p ≥ 0.11). It is concluded that, under the conditions of this study, GAA supplementation did not affect performance or carcass traits, except for reduced weight gain at the highest dose, but reduced water loss from cooked meat. Full article
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22 pages, 1493 KiB  
Article
Understanding the Impact of Social Stress on Serum Metabolome and Saliva Biomarkers in Growing–Finishing Pigs
by Marc Bagaria, Núria Tous, David Torrallardona, Jose Joaquín Cerón, Estefanía Pérez-Calvo, Wen Ren, Rosa Argamasilla and Emma Fàbrega
Animals 2025, 15(9), 1228; https://doi.org/10.3390/ani15091228 - 27 Apr 2025
Viewed by 443
Abstract
High levels of social stress are known to negatively impact pig welfare. The aim of this study was to evaluate the impact of social stress in growing–finishing pigs by measuring serum metabolome changes and saliva biomarkers. Seventy-two undocked pigs (thirty-six males and thirty-six [...] Read more.
High levels of social stress are known to negatively impact pig welfare. The aim of this study was to evaluate the impact of social stress in growing–finishing pigs by measuring serum metabolome changes and saliva biomarkers. Seventy-two undocked pigs (thirty-six males and thirty-six females) were housed in single-sex pens of four, with the second dominant pig in each pen selected as the focal pig. A social challenge was conducted by mixing the focal pig with three new pigs in its home pen on two consecutive days on trial days 62–64. Saliva and blood samples were collected, and the pigs’ behaviour and body lesions were evaluated pre- and post-challenge. A total of 630 serum metabolites were analysed, 292 of which could be statistically compared using Biocrates WebIDQ v5 software. Salivary haptoglobin concentrations and the number of body lesions significantly increased after the challenge (p < 0.001), whereas the average daily weight gain decreased (p < 0.05). The serum showed decreases in essential amino acids (Thr, Met, and Phe), non-essential amino acids (Glu, Asn, Asp, Pro, and Tyr), betaine, ornithine, indoxyl sulphate, taurine, and some blood di- and triacylglycerols (q < 0.05), and increases in oleic, eicosanoic, eicosadienoic, and dihomo-gamma-linolenic acids; EPA; and DHA post-challenge (q < 0.05). Overall, the results suggest the potential of metabolomics as a tool providing a more holistic view of the impact of social stress. Full article
(This article belongs to the Special Issue Saliva and Blood Markers in Animal Welfare and Health Monitoring)
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17 pages, 11140 KiB  
Article
Removing Alpha Case from Laser Powder Bed Fusion Components by Cavitation Abrasive Surface Finishing
by Rohin Petram, Conall Wisdom, Alex Montelione, Cole Nouwens, Dan Sanders, Mamidala Ramulu and Dwayne Arola
Materials 2025, 18(9), 1977; https://doi.org/10.3390/ma18091977 - 26 Apr 2025
Viewed by 328
Abstract
Laser powder bed fusion (L-PBF) has become a highly viable method for manufacturing metal structural components for a variety of industries. Despite many attractive qualities, the rough surfaces of L-PBF components often necessitates post-processing treatments to improve the surface finish. Furthermore, heat treatments [...] Read more.
Laser powder bed fusion (L-PBF) has become a highly viable method for manufacturing metal structural components for a variety of industries. Despite many attractive qualities, the rough surfaces of L-PBF components often necessitates post-processing treatments to improve the surface finish. Furthermore, heat treatments are generally necessary to control the microstructure and properties of L-PBF components, which can impart a detrimental surface oxide layer that requires removal. In this investigation, cavitation abrasive surface finishing (CASF) was adopted for the surface treatment of Ti6Al4V components produced by L-PBF and removal of the surface oxide layer. The surface texture, residual stress, and material removal were evaluated over a range of treatment conditions and as a function of the target surface orientation. Results showed that CASF reduced the average surface roughness from the as-built condition (Ra ≈ 15 µm) to below 5 µm as well as imparted a surface compressive residual stress of up to 600 MPa. The CASF treatment removed the alpha case from direct line-of-sight surfaces under a range of treatment intensity. However, deep valleys and surfaces at large oblique angles of incidence (≥60°) proved challenging to treat uniformly. Overall, results suggest that CASF could serve as a potent alternative to chemical treatments for post-processing of L-PBF components of titanium and other metals. Further investigation is recommended for improving the process effectiveness and to characterize the fatigue performance of the treated metal. Full article
(This article belongs to the Special Issue Development and Applications of Laser-Based Additive Manufacturing)
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25 pages, 14859 KiB  
Article
The Effect of Drag Finishing on Additively Manufactured Customized Dental Crowns
by Cosmin Cosma, Martin Melichar, Stelian Libu, Alexandru Popan, Glad Contiu, Cristina Teusan, Petru Berce and Nicolae Balc
Metals 2025, 15(5), 471; https://doi.org/10.3390/met15050471 - 22 Apr 2025
Viewed by 390
Abstract
Cobalt–chromium (CoCr) alloys are frequently used to produce customized dental applications such as crowns, bridges, or prostheses. These medical products have anatomical forms, and can be effectively manufactured using the laser-based powder bed fusion (PBF-LB/M) technique. A major disadvantage of this approach is [...] Read more.
Cobalt–chromium (CoCr) alloys are frequently used to produce customized dental applications such as crowns, bridges, or prostheses. These medical products have anatomical forms, and can be effectively manufactured using the laser-based powder bed fusion (PBF-LB/M) technique. A major disadvantage of this approach is the extended time required to refine the resultant surface. The purpose of this research is to reduce the surface roughness of PBF-LB/M/CoCr dental crowns by adopting drag finishing (DF) technology. To evaluate the impact of this automatic post-processing, surface roughness measurements and geometrical investigations were undertaken. The microstructure was characterized using scanning electron microscopy (SEM), and the chemical composition was verified by energy-dispersive X-ray spectroscopy (EDAX). On outside surfaces, the DF post-processing decreased the initial surface roughness by 70–90%. The dental crown’s surface roughness value after DF post-processing was comparable to that of the basic form (cylinder). The lowest roughness was obtained with DF3 post-processing (Ra~0.60 μm). The inner surfaces were limitedly finished. The 3D surface texture showed that the DF method reduced the height of peaks, uniformizing the surfaces. CMM work compared the deviations between the virtual model and the printed samples before and after DF post-processing. This analysis revealed that dimensional deviations were reduced on the outside crown walls, ranging from +0.01 to +0.05 mm. The laser parameters and the heat treatment applied increased the hardness of CoCr crowns to 520 HV, but the proper DF conditions identified reduced the surface roughness and improved the accuracy. Full article
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14 pages, 3115 KiB  
Article
Evaluation of Errors in Road Signs in a Long Roadwork Zone Using a Naturalistic Driving Study
by Anton Pashkevich and Jacek Bartusiak
Sustainability 2025, 17(8), 3755; https://doi.org/10.3390/su17083755 - 21 Apr 2025
Viewed by 379
Abstract
The paper presents an application of a new, simple approach for the naturalistic assessment of road sign quality from a driver’s perspective, using dashboard camera recordings. This method was used to evaluate signage along a 69.6 km road construction zone in Poland associated [...] Read more.
The paper presents an application of a new, simple approach for the naturalistic assessment of road sign quality from a driver’s perspective, using dashboard camera recordings. This method was used to evaluate signage along a 69.6 km road construction zone in Poland associated with the phased upgrade of a dual carriageway with unlimited access into a motorway. The analysis focused on three distinct phases of the roadwork: the beginning of roadwork, the progress of roadwork, and finishing roadwork. The correctness, visibility, and quality of the road signs were assessed on a specially developed scale. The study found that 1135 road signs were unnecessary, which was equal to 36% of all signs. The majority of all signs (48.1%) indicated prohibition: more than one third (33.6%) of them were speed limit signs, of which 52% were posted without the need. It was demonstrated that the simple method applied in this study can be considered a useful tool to identify deficiencies in signage, which could ultimately improve road safety and make road management more sustainable. Moreover, this study confirmed again that the use of appropriate video recordings makes it faster and easier to conduct an inventory of road signs. Full article
(This article belongs to the Collection Advances in Transportation Planning and Management)
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19 pages, 6080 KiB  
Review
Current Status and Future Trends for Modification Technology of Flame Retardant Nylon 66
by Bingtao Feng, Senlong Yu, Hengxue Xiang, Lili Li and Meifang Zhu
Polymers 2025, 17(8), 1074; https://doi.org/10.3390/polym17081074 - 16 Apr 2025
Viewed by 463
Abstract
Nylon 66 (PA66) has been widely used in automotive, electronics, textiles and other fields due to its excellent mechanical properties, chemical corrosion resistance and thermal stability. However, the fire hazard caused by its flammability severely limits its further application in high–end and high–risk [...] Read more.
Nylon 66 (PA66) has been widely used in automotive, electronics, textiles and other fields due to its excellent mechanical properties, chemical corrosion resistance and thermal stability. However, the fire hazard caused by its flammability severely limits its further application in high–end and high–risk fields. Therefore, improving the flame retardancy of PA66 to enhance its safety has become the focus of current research. This review aims to better understand the research status and development trends of flame retardant PA66. Firstly, the combustion process and flame retardant mechanism of PA66 were described. Secondly, the latest research progress of flame retardant PA66 was comprehensively reviewed, including blending, copolymerization and post–finishing flame retardant modification methods. Meanwhile, the research status of blending flame retardant PA66 was emphatically introduced, and the advantages and disadvantages of different additive flame retardants were analyzed. Finally, the future development direction of flame retardant PA66 is proposed, which provides an important reference for its follow-up study. Full article
(This article belongs to the Special Issue Polymer Manufacturing Processes)
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17 pages, 5344 KiB  
Article
Gestational Inulin Supplementation in Low-/High-Fat Sow Diets: Effects on Growth Performance, Lipid Metabolism, and Meat Quality of Offspring Pigs
by Pan Zhou, Yachao Wu, Jianbo Shen, Tao Duan, Long Che, Yong Zhang, Yang Zhao and Honglin Yan
Foods 2025, 14(8), 1314; https://doi.org/10.3390/foods14081314 - 10 Apr 2025
Viewed by 402
Abstract
This study investigated whether the supplementation of prebiotic inulin to gestating sows programmatically affects offspring growth performance and meat quality while exploring its epigenetic effects through histone acetylation modulation. After mating, sixty multiparous sows (Landrace × Yorkshire; parity 2–3) were assigned to a [...] Read more.
This study investigated whether the supplementation of prebiotic inulin to gestating sows programmatically affects offspring growth performance and meat quality while exploring its epigenetic effects through histone acetylation modulation. After mating, sixty multiparous sows (Landrace × Yorkshire; parity 2–3) were assigned to a 2 × 2 factorial arrangement with inulin (0% vs. 1.5%) and fat (0% or 5%) supplementation until farrowing. Post-weaning, five litters (10 piglets per litter) per treatment were selected and maintained in their original litter for fattening under standardized feeding. The results demonstrated that maternal inulin supplementation during gestation accomplished the following: (1) Increased offspring liver index by 13.4% at weaning and 6.8% at finishing (p < 0.05) while reducing the finishing-phase backfat thickness by 11.6% (p < 0.01), with a significant inulin × fat interaction attenuating fat-induced abdominal lipid accumulation at weaning (p = 0.05). (2) Decreased longissimus dorsi muscle lightness (L*) by 4.5% in finishing pigs (p = 0.02) without altering the other meat quality parameters. (3) Suppressed offspring liver lipid deposition at birth and finishing (p < 0.05), concomitant with upregulated hepatic PGC-1α and CPT1A expression (p < 0.05). (4) Elevated neonatal serum butyrate by 15.6% (p = 0.06) while inhibiting hepatic histone deacetylase (HDAC) activity and enhancing histone H3/H4 acetylation (p < 0.01). These findings suggest that maternal inulin supplementation during gestation mitigates offspring hepatic lipid deposition through butyrate-mediated epigenetic regulation, where microbial-derived butyrate from inulin fermentation inhibits HDAC activity, enhances histone acetylation levels, and upregulates fatty acid β-oxidation gene expression. This study provides novel mechanistic insights into how maternal dietary fiber nutrition programs offspring development through epigenetic reprogramming. Full article
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16 pages, 4912 KiB  
Article
Characterization of Laser-Ablated Bound Metal Deposition (laBMD)
by Alexander Watson, Masoud Rais-Rohani, John Belding, Jasper McGill and Brett D. Ellis
J. Manuf. Mater. Process. 2025, 9(4), 119; https://doi.org/10.3390/jmmp9040119 - 4 Apr 2025
Viewed by 453
Abstract
Additive manufacturing of metals is limited by a fundamental tradeoff between deposition rates and manufacturability of fine-scale features. To overcome this problem, a laser-ablated bound metal deposition (laBMD) process is demonstrated in which 3D-printed green-state bound metal deposition (BMD) parts are post-processed via [...] Read more.
Additive manufacturing of metals is limited by a fundamental tradeoff between deposition rates and manufacturability of fine-scale features. To overcome this problem, a laser-ablated bound metal deposition (laBMD) process is demonstrated in which 3D-printed green-state bound metal deposition (BMD) parts are post-processed via laser ablation prior to conventional BMD debinding and sintering. The laBMD process is experimentally characterized via a full-factorial design of experiments to determine the effect of five factors—number of laser passes (one pass, three passes), laser power (25%, 75%), scanning speed (50%, 100%), direction of laser travel (perpendicular, parallel), and laser resolution (600 dpi, 1200 dpi)—on as-sintered ablated depth, surface roughness, width, and angle between ablated and non-ablated regions. The as-sintered ablation depth/pass ranged from 3 to 122 µm/pass, the ablated surface roughness ranged from 3 to 79 µm, the angle between ablated and non-ablated regions ranged from 1° to 68°, and ablated bottom widths ranged from 729 to 1254 µm. This study provides novel insights into as-manufactured ablated geometries and surface finishes produced via laser ablation of polymer–metallic composites. The ability to inexpensively and accurately manufacture fine-scale features with tailorable geometric tolerances and surface finishes is important to a variety of applications, such as manufacturing molds for microfluidic devices. Full article
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24 pages, 7784 KiB  
Article
Enhancing the Surface Integrity of a Laser Powder Bed Fusion Inconel 718 Alloy by Tailoring the Microstructure and Microrelief Using Various Finishing Methods
by Dmytro Lesyk, Bohdan Mordyuk, Silvia Martinez, Vitaliy Dzhemelinskyi, Daniel Grochala, Andriy Kotko and Aitzol Lamikiz
Coatings 2025, 15(4), 425; https://doi.org/10.3390/coatings15040425 - 3 Apr 2025
Viewed by 493
Abstract
Heat-performance nickel-based superalloys are commonly applied in various critical industries. In this work, test samples in the form of turbine blades were manufactured by means of laser powder bed fusion (LPBF) 3D technology. This research focused on comparison of the influences of various [...] Read more.
Heat-performance nickel-based superalloys are commonly applied in various critical industries. In this work, test samples in the form of turbine blades were manufactured by means of laser powder bed fusion (LPBF) 3D technology. This research focused on comparison of the influences of various surface finishing methods. The mechanical surface post-processing of the LPBF-manufactured Inconel 718 alloy samples consisted of ultrasonic impact treatment (UIT), ultrasonic shot peening (USP), shot peening (SP), and barrel finishing (BF). The surface microrelief was evaluated using a high-precision laser profilometer, while the microstructural features were studied by light optical microscopy (LOM), scanning/transmission electron microscopy (SEM/TEM), and X-ray diffraction (XRD). Potentiodynamic polarization tests were also conducted to compare the surface finishing methods in terms of corrosion resistance improvement of the LPBF-manufactured 718 alloy samples. The effects of the surface microstructure and hardening intensity in combination with residual stresses and surface relief coupled with roughness profile shapes on the room temperature corrosion behavior of plastically deformed 718 alloy specimens manufactured by LPBF were studied. The corrosion rate (CR) of the LPBF-manufactured samples was reduced after post-processing: BF (~16 μm/year), USP (~15 μm/year), SP (~6.5 μm/year), and UIT (~5.5 μm/year). The experimental trends also agreed well with the theoretical trends of uniform corrosion of the studied alloy. Full article
(This article belongs to the Special Issue Laser Surface Engineering: Technologies and Applications)
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17 pages, 4781 KiB  
Article
Plasma Lipidomics and Proteomics Analyses Pre- and Post-5000 m Race in Yili Horses
by Jianwen Wang, Wanlu Ren, Zexu Li, Luling Li, Ran Wang, Shikun Ma, Yaqi Zeng, Jun Meng and Xinkui Yao
Animals 2025, 15(7), 994; https://doi.org/10.3390/ani15070994 - 30 Mar 2025
Viewed by 370
Abstract
The impact of exercise on human metabolism has been extensively studied, yet limited research exists on the effects of high-intensity racing on equine metabolism. The aim of this study was to screen the effect of a 5000 m race on lipids and proteins [...] Read more.
The impact of exercise on human metabolism has been extensively studied, yet limited research exists on the effects of high-intensity racing on equine metabolism. The aim of this study was to screen the effect of a 5000 m race on lipids and proteins in the plasma of Yili horses for the breeding of racehorses. Blood samples were collected from the top three finishers, and lipidomics and proteomics analyses were performed. Lipidomic analysis identified 10 differential lipids. Compared to pre-race levels, phosphatidylethanolamine (18:0/16:0) (PE (18:0/16:0)) and phosphatidylcholine (18:0/18:2) (PC (18:0/18:2)) were significantly upregulated, while triglyceride (26:4/29:4) (TG (26:4/29:4)) and phosphatidylcholine (46:14CHO) (PC (46:14CHO)) were notably downregulated. These lipids were primarily associated with the regulation of lipolysis in adipocytes and glycerolipid metabolism pathways. Proteomic analysis revealed 79 differentially expressed proteins. Post-race, proteasome subunits (alpha type_2, alpha type_5 isoform X1, alpha type_6, and beta type_2), carboxypeptidase E, and S-phase kinase-associated protein 1 showed significant downregulation. These proteins were primarily involved in the cellular catabolic process (Gene Ontology term) and pathways related to the proteasome and type I diabetes mellitus (Kyoto Encyclopedia of Genes and Genomes terms). Correlation analysis indicated a significant positive correlation between proteasome subunits (alpha type_2 and beta type_2) and PC (18:0/18:2), while a significant negative correlation was found with PC (46:14CHO). Conversely, S-phase kinase-associated protein 1, along with proteasome subunits (alpha type_5 isoform X1 and alpha type_6), exhibited a significant negative correlation with PE (18:0/16:0) and a positive correlation with TG (26:4/29:4). In conclusion, Yili horses may sustain energy balance and physiological equilibrium during racing by suppressing protein degradation and optimizing lipid metabolism. The differentially expressed substances identified could serve as key biomarkers for assessing exercise load in horses. Full article
(This article belongs to the Section Equids)
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16 pages, 5119 KiB  
Article
A Comparative Analysis of ProTaper Ultimate and Five Multifile Systems: Design, Metallurgy, and Mechanical Performance
by Jorge N. R. Martins, Emmanuel João Nogueira Leal Silva, Victor Talarico Leal Vieira, Rui Pereira da Costa, Abayomi O. Baruwa, Francisco Manuel Braz Fernandes and Marco Aurélio Versiani
Materials 2025, 18(6), 1260; https://doi.org/10.3390/ma18061260 - 13 Mar 2025
Viewed by 653
Abstract
The present research compared the design, metallurgical properties, and mechanical characteristics of the ProTaper Ultimate instruments with five multifile systems. A total of 469 new nickel–titanium rotary finishing instruments, all 25 mm in length but varying in size, taper, and metal alloy composition, [...] Read more.
The present research compared the design, metallurgical properties, and mechanical characteristics of the ProTaper Ultimate instruments with five multifile systems. A total of 469 new nickel–titanium rotary finishing instruments, all 25 mm in length but varying in size, taper, and metal alloy composition, from six different multifile systems (ProTaper Ultimate, ProTaper Next, ProFile, Mtwo, EndoSequence, and GT Series X), were inspected for irregularities and analyzed for their spiral density (spirals per millimetre), blade design, surface finishing, alloy composition, phase transformation temperatures, and mechanical performance (microhardness, torsional, and bending resistance tests). Group comparisons were performed using Kruskal–Wallis and one-way ANOVA with post hoc Tukey’s tests (α = 5%). ProFile instruments exhibited a greater number of spirals and a higher density of spirals per millimetre compared to the other systems. Microscopic analysis revealed distinct tip geometries and blade designs among tested instruments. All of them displayed parallel marks from the machining process, but the EndoSequence system had the smoothest surface finish. The alloys of all instruments consisted of an almost equiatomic ratio of nickel to titanium. At the testing temperature, the ProTaper Ultimate system exhibited a complete R-phase crystallographic arrangement, while the ProFile and Mtwo systems were fully austenitic. The ProTaper Ultimate F2, F3, and FX instruments demonstrated the highest maximum torque values (1.40, 1.45, and 3.55 N.cm, respectively) and the lowest maximum bending loads (202.7, 254.9, and 408.4 gf, respectively). EndoSequence instruments showed the highest angles of rotation, while the highest microhardness values were recorded for GT Series X (407.1 HVN) and ProTaper Next (425.0 HVN) instruments. The ProTaper Ultimate system showed a high spiral density per millimetre and a complete R-phase crystallographic arrangement at room temperature, which significantly contributed to its superior flexibility and torsional strength when compared to the other tested systems. Full article
(This article belongs to the Special Issue Development and Research of New Dental Materials)
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