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Keywords = reduced matrix element

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18 pages, 2385 KiB  
Article
Buckling Solution of Fixed–Free Anisotropic Laminated Composite Columns Under Axial Loading
by Rund Al-Masri, Hayder A. Rasheed and Bacim Alali
Fibers 2025, 13(4), 35; https://doi.org/10.3390/fib13040035 - 27 Mar 2025
Viewed by 125
Abstract
A generalized buckling solution for anisotropic laminated composite fixed–free columns under axial compression is developed using the critical stability matrix. The axial, coupling, and flexural equivalent stiffness coefficients of the anisotropic layup are determined from the generalized constitutive relationship through the static condensation [...] Read more.
A generalized buckling solution for anisotropic laminated composite fixed–free columns under axial compression is developed using the critical stability matrix. The axial, coupling, and flexural equivalent stiffness coefficients of the anisotropic layup are determined from the generalized constitutive relationship through the static condensation of the composite stiffness matrix. The derived formula reduces down to the Euler buckling equation for isotropic and some special laminated composites. The analytical results are verified against finite element solutions for a wide range of anisotropic laminated layups yielding high accuracy. A parametric study is conducted to examine the effects of ply orientations, element thickness, finite element type, column size, and material properties. Comparisons with numerical results reveal a very high accuracy across the entire parametric profile and a linear correlation between the percentage error and a non-dimensional condensed parameter is extracted and plotted. Full article
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23 pages, 326 KiB  
Article
Superregular Matrices over Finite Fields
by Paulo Almeida, Miguel Beltrá and Diego Napp
Mathematics 2025, 13(7), 1091; https://doi.org/10.3390/math13071091 - 26 Mar 2025
Viewed by 75
Abstract
A trivially zero minor of a matrix is a minor having all its terms in the Leibniz formula equal to zero. A matrix is superregular if all of its minors that are not trivially zero are nonzero. In the area of Coding Theory, [...] Read more.
A trivially zero minor of a matrix is a minor having all its terms in the Leibniz formula equal to zero. A matrix is superregular if all of its minors that are not trivially zero are nonzero. In the area of Coding Theory, superregular matrices over finite fields are connected with codes with optimum error correcting capabilities. There are two types of superregular matrices that yield two different types of codes. One has in all of its entries a nonzero element, and these are called full superregular matrices. The second interesting class of superregular matrices is formed by lower triangular Toeplitz matrices. In contrast to full superregular matrices, all general constructions of these matrices require very large field sizes. In this work, we investigate the construction of lower triangular Toeplitz superregular matrices over small finite prime fields. Instead of computing all possible minors, we study the structure of finite fields in order to reduce the possible nonzero minors. This allows us to restrict the huge number of possibilities that one needs to check and come up with novel constructions of superregular matrices over relatively small fields. Finally, we present concrete examples of lower triangular Toeplitz superregular matrices of sizes up to 10. Full article
13 pages, 3770 KiB  
Article
Ductility Control via Nano-Precipitation at Grain Boundaries in Ti-Zr-Hf-Nb-Ta Multi-Principal Element Alloys
by Jiaying Li, Huibin Ke, Benpeng Wang, Liang Wang and Yunfei Xue
Materials 2025, 18(7), 1463; https://doi.org/10.3390/ma18071463 - 25 Mar 2025
Viewed by 174
Abstract
The formation of nano-sized Hf2Fe precipitates at grain boundaries through Fe micro-alloying enhances the strength of Ti-Zr-Hf-Nb-Ta multi-principal element alloys (MPEAs), but this improvement comes at the cost of reduced ductility. Aging at 500 °C for just 30 min resulted in [...] Read more.
The formation of nano-sized Hf2Fe precipitates at grain boundaries through Fe micro-alloying enhances the strength of Ti-Zr-Hf-Nb-Ta multi-principal element alloys (MPEAs), but this improvement comes at the cost of reduced ductility. Aging at 500 °C for just 30 min resulted in a marked reduction in elongation, from 17.5% to 7.5%. This decline is attributed to lattice mismatch between the precipitates and the matrix, as well as increased stacking stress at the grain boundaries. By adjusting the Fe composition and heat treatment parameters, the quantity of Hf2Fe at the grain boundaries of (TiZrHfNbTa)100−xFex alloy was effectively controlled, achieving a balanced combination of strength of 1037 MPa and elongation of 14%. Furthermore, this method enabled ductility modulation over a wide range, with elongation varying from 2.65% to 19% while maintaining alloy strength between 955 and 1081 MPa, providing valuable insights for tailoring these alloys to diverse application requirements. The precipitation thermodynamics of the (TiZrHfNbTa)100−xFex alloy was also investigated using the CALPHAD method, with thermodynamic calculations validated against experimental results, laying a foundation for more in-depth kinetic study of nano-size precipitates in these alloys. Additionally, the relationships between thermodynamics, precipitates evolution, and mechanical properties were discussed. Full article
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16 pages, 8657 KiB  
Article
Effect of Ce-Y Composite Addition on the Inclusion Evolution in T91 Heat-Resistant Steel
by Jun Liu, Gen Li, Chengbin Shi, Zhengxin Tang, Lei Jia, Yu Zhao, Shijun Wang and Xikou He
Materials 2025, 18(7), 1459; https://doi.org/10.3390/ma18071459 - 25 Mar 2025
Viewed by 169
Abstract
This study investigates the influence of rare earth elements Ce and Y on the evolution of inclusions in T91 steel by melting experimental steels with varying Ce-Y contents in a vacuum induction melting furnace. The results show that the inclusions in the steel [...] Read more.
This study investigates the influence of rare earth elements Ce and Y on the evolution of inclusions in T91 steel by melting experimental steels with varying Ce-Y contents in a vacuum induction melting furnace. The results show that the inclusions in the steel without rare earth are mainly composed of Mg-Al-O oxides, (Nb, V, Ti)(C, N) carbonitrides, and composite inclusions formed by carbonitrides coated oxides, and all of them have obvious edges and corners. Upon the addition of different concentrations of Ce and Y, the oxygen content in the steel significantly decreased, and the inclusions were modified into spherical rare earth oxides, sulfides, and oxy-sulfides. Additionally, no large-sized primary carbonitrides were observed. The average size of the inclusions was reduced from 2.8 μm in the non-rare-earth-added steel to 1.7 μm and 1.9 μm with rare earth addition. Thermodynamic analysis indicates that the possible inclusions precipitated in the steel with varying Ce contents include Ce2O3, Ce2O2S, Y2O3, Y2S3, and CeS. With the increase in Ce content, the rare earth inclusions Y2S3, Y2O3, and CeS can be transformed into Ce2O2S and Ce2O3. There are two kinds of reactions in the process of high-temperature homogenization: one is the internal transformation reaction of inclusions, which makes Y easier to aggregate in the inner layer, and the other is the reaction of Y2S3→CeS and Y2O3 + Y2S3→Ce2O2S due to the diffusion of Ce in the matrix to the inclusions. Combined with the mismatch analysis, it can be seen that Al2O3 has the best effect on the heterogeneous nucleation of carbonitrides during the solidification of molten steel. Among the rare earth inclusions, only Ce2O3 may become the nucleation core of carbonitrides, and the rest are more difficult to form heterogeneous nucleation. Therefore, by Ce-Y composite addition, increasing the Y/Ce ratio can reduce the formation of Ce2O3, which can avoid the precipitation of primary carbonitride and ultimately improve the dispersion strengthening effect. This study is of great significance for understanding the mechanism of rare earth elements in steel and provides theoretical guidance for the composition design and industrial trial production of rare earth steel. Full article
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16 pages, 4187 KiB  
Article
A Proposal for Rapid Assessment of Long-Distance Oil and Gas Pipelines After Earthquakes
by Hongyuan Jing, Liang Huang, Hua Liu, Weijun Jiang, Qinglu Deng and Ruiqing Niu
Appl. Sci. 2025, 15(7), 3595; https://doi.org/10.3390/app15073595 - 25 Mar 2025
Viewed by 168
Abstract
A substantial proportion of long-distance oil and gas pipelines in China traverse active faults and high-risk areas characterised by intricate topographic and geological environments. These pipelines are susceptible to a range of safety concerns, exacerbated by the increasing frequency of strong earthquakes in [...] Read more.
A substantial proportion of long-distance oil and gas pipelines in China traverse active faults and high-risk areas characterised by intricate topographic and geological environments. These pipelines are susceptible to a range of safety concerns, exacerbated by the increasing frequency of strong earthquakes in recent years. To address this issue, a comprehensive risk investigation framework has been proposed for long-distance oil and gas pipelines following seismic events. This initiative aims to ensure the safety of pipeline transportation. In this paper, the elements of pipeline safety evaluation under the influence of coseismic hazards are first organized, followed by a construction of post-earthquake pipeline safety rapid assessment theoretical framework based on the seismic geological disaster risk evaluation system. Each method in the system is then introduced one by one. Unlike existing studies that predominantly focus on localized fault activity or static risk assessment, our framework introduces three key innovations: (1) a hierarchical integration of multi-source monitoring data (SCADA, UAV-AI, and numerous monitoring devices) into a unified GIS platform, overcoming the fragmentation of existing systems; (2) a dynamic four-step evaluation process (susceptibility → hazard → risk → safety) that incorporates both pre-earthquake geological conditions and post-earthquake real-time triggers (e.g., PGA, rainfall); (3) a novel risk matrix mechanism for pipeline safety, which dynamically updates risk levels based on field monitoring data rather than relying solely on probabilistic models. This study provides a novel theoretical framework for assessing the safety of pipelines after earthquakes, which can provide a timely basis for pipeline management decisions and reduce the potential damage to pipelines caused by earthquakes. It is important to note that this framework is still in a preliminary stage and needs to be continuously deepened and optimised. Full article
(This article belongs to the Section Earth Sciences)
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19 pages, 6379 KiB  
Article
Enhanced Flame Retardancy of Unsaturated Polyester Resin via Simultaneously Using a Novel DOPO-Based Organic Flame Retardant and Modified Silicon Carbide
by Piye Wu, Jingjie Hu, Chanyu Liu, Ping He, Feng You, Hao Yang and Man Xu
Coatings 2025, 15(4), 376; https://doi.org/10.3390/coatings15040376 - 23 Mar 2025
Viewed by 95
Abstract
Unsaturated polyester (UP) resin is widely utilized in the construction and automotive industries. The flammable nature of UP must be constrained when its products are manufactured. A novel organic flame retardant has been synthesized from 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and triallyl isocyanate (TAIC). This DOPO-TAIC [...] Read more.
Unsaturated polyester (UP) resin is widely utilized in the construction and automotive industries. The flammable nature of UP must be constrained when its products are manufactured. A novel organic flame retardant has been synthesized from 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and triallyl isocyanate (TAIC). This DOPO-TAIC additive has been used to reduce the flammability of a matrix. Additionally, this flame retardant was then combined with dopamine-modified silicon carbide (M-SiC) to further diminish the flammability of UP. The limiting oxygen index (LOI) value combustion of a UP/DOPO-TAIC/M-SiC blend was 30.8% when the filler contents of DOPO-TAIC and M-SiC was 15 wt.% and 30 wt.%, respectively. These materials exhibited a UL 94 V-0 rating for combustion. Compared to the values for combustion of the neat UP, the peak heat release rate (Pk-HRR) and total heat release rate (THR) for this blend were reduced by 51% and 35%, respectively. The mode of action for flame retardant of UP blends containing DOPO-TAIC and M-SiC has been composed. The presence of a flame retardant containing P-Si elements can significantly reduce flammability compared to that of unmodified resin. Full article
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24 pages, 5260 KiB  
Article
Research on Parameter Influence of Offshore Wind Turbines Based on Measured Data Analysis
by Renfei Kuang, Jinhai Zhao, Tuo Zhang and Chengyang Li
J. Mar. Sci. Eng. 2025, 13(4), 629; https://doi.org/10.3390/jmse13040629 - 21 Mar 2025
Viewed by 125
Abstract
Offshore wind turbines are prone to structural damage over time due to environmental factors, which increases operational costs and the risk of accidents. Early detection of structural damage through monitoring systems can help reduce maintenance costs. However, under complex external conditions and varying [...] Read more.
Offshore wind turbines are prone to structural damage over time due to environmental factors, which increases operational costs and the risk of accidents. Early detection of structural damage through monitoring systems can help reduce maintenance costs. However, under complex external conditions and varying structural parameters, existing methods struggle to accurately and quickly detect damage. Understanding the factors that influence structural health is critical for effective long-term monitoring, as these factors directly affect the accuracy and timeliness of damage identification. This study comprehensively analyzed 5 MW offshore wind turbine measurement data, including constructing a digital twin model, establishing a surrogate model, and performing a sensitivity analysis. For monopile-based turbines, sensors in x and y directions were installed at four heights on the pile foundation and tower. Via Bayesian optimization, the finite element model’s structural parameters were updated to align its modal parameters with sensor data analysis results. The update efficiencies of different objective functions and the impacts of neural network hyperparameters on the surrogate model were examined. The sensitivity of the turbine’s structural parameters to modal parameters was studied. The results showed that the modal flexibility matrix is more effective in iteration. A 128-neuron, double-hidden-layer neural network balanced computational efficiency and accuracy well in the surrogate model for modal analysis. Flange damage and soil degradation near the pile mainly impacted the turbine’s health. Full article
(This article belongs to the Section Coastal Engineering)
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21 pages, 1068 KiB  
Article
A Novel Vulnerability Evaluation Model of a Public Service Building Based on Structural Equation Modeling and Matter-Element Extension
by Hao Peng, Jin Zhang, Xinyu Wang and Chenyang Peng
Buildings 2025, 15(6), 948; https://doi.org/10.3390/buildings15060948 - 17 Mar 2025
Viewed by 174
Abstract
Vulnerability assessments of public service buildings (PSBs) are critical to life cycle management. An accurate evaluation can substantially improve the quality of public services and reduce the government’s financial burden. We proposed a WBS-VBS framework to build a vulnerability decomposition matrix for PSBs. [...] Read more.
Vulnerability assessments of public service buildings (PSBs) are critical to life cycle management. An accurate evaluation can substantially improve the quality of public services and reduce the government’s financial burden. We proposed a WBS-VBS framework to build a vulnerability decomposition matrix for PSBs. A Chinese vocational education center relocation case study validated the method. Structural equation modeling (SEM) was used to normalize the path coefficients and obtain the index weights. The matter-element extension method was utilized to calculate correlation functions and determine the vulnerability levels of different indicators. The case study results demonstrate the effectiveness of the model. Full article
(This article belongs to the Special Issue Advances in Life Cycle Management of Buildings)
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24 pages, 15226 KiB  
Article
Effect of Yarn-Level Fibre Hybridisation on Thermomechanical Behaviour of 3D Woven Orthogonal Flax/E-Glass Composite Laminae
by Nenglong Yang, Zhenmin Zou, Constantinos Soutis, Prasad Potluri and Kali Babu Katnam
J. Compos. Sci. 2025, 9(3), 135; https://doi.org/10.3390/jcs9030135 - 13 Mar 2025
Viewed by 297
Abstract
This study investigates the novel role of yarn-level fibre hybridisation in tailoring thermomechanical properties and thermal residual stress (TRS) fields in the resin at both micro- and meso-scales of 3D orthogonal-woven flax/E-glass hybrid composites. Unlike previous studies, which primarily focus on macro-scale composite [...] Read more.
This study investigates the novel role of yarn-level fibre hybridisation in tailoring thermomechanical properties and thermal residual stress (TRS) fields in the resin at both micro- and meso-scales of 3D orthogonal-woven flax/E-glass hybrid composites. Unlike previous studies, which primarily focus on macro-scale composite behaviour, this work integrates a two-scale homogenisation scheme. It combines microscale representative volume element (RVE) models and mesoscale repeating unit cell (RUC) models to capture the effects of hybridisation from the fibre to lamina scale. The analysis specifically examines the cooling phase from a curing temperature of 100 °C down to 20 °C, where TRS develops due to thermal expansion mismatches. Microstructures are generated employing a random sequential expansion algorithm for RVE models, while weave architecture is generated using the open-source software TexGen 3.13.1 for RUC models. Results demonstrate that yarn-level hybridisation provides a powerful strategy to balance mechanical performance, thermal stability, and residual stress control, revealing its potential for optimising composite design. Stress analysis indicates that under in-plane tensile loading, stress levels in matrix-rich regions remain below 1 MPa, while binder yarns exhibit significant stress concentration, reaching up to 8.71 MPa under shear loading. The study quantifies how varying fibre hybridisation ratios influence stiffness, thermal expansion, and stress concentrations—bridging the gap between microstructural design and macroscopic composite performance. These findings highlight the potential of yarn-level fibre hybridisation in tailoring thermomechanical properties of yarns and laminae. The study also demonstrates its effectiveness in reducing TRS in composite laminae post-manufacturing. Additionally, hybridisation allows for adjusting density requirements, making it suitable for applications where weight and thermal properties are critical. Full article
(This article belongs to the Section Fiber Composites)
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24 pages, 5803 KiB  
Article
Design, Modeling, and Optimization of a Nearly Constant Displacement Reducer with Completely Distributed Compliance
by Yanchao Tong, Beibei Hou, Shuaishuai Lu, Pengbo Liu, Zhi Yang and Peng Yan
Appl. Sci. 2025, 15(6), 2886; https://doi.org/10.3390/app15062886 - 7 Mar 2025
Viewed by 195
Abstract
This article proposes a displacement reducer based on distributed compliant mechanisms to improve the motion resolution of actuators commonly used in precision operation systems that require high-precision control and positioning, such as micro-grippers, biological manipulation, and micro-alignment mechanisms. Distributed compliance significantly diminishes its [...] Read more.
This article proposes a displacement reducer based on distributed compliant mechanisms to improve the motion resolution of actuators commonly used in precision operation systems that require high-precision control and positioning, such as micro-grippers, biological manipulation, and micro-alignment mechanisms. Distributed compliance significantly diminishes its effective moving lumped mass, endowing the structure with advantages such as reduced stress concentration and an expansive range of motion. Additionally, the design incorporates an over-constraint structure through a dual-layer displacement reducer, ensuring that the reducer achieves a nearly constant reduction ratio. According to the compliance matrix method, the analytical model of the reducer is established to predict the input–output behaviors, which are verified by finite element simulations. On the basis of sensitivity analysis to structure parameters, including node positions and beam parameters, the Particle Swarm Optimization (PSO) algorithm is used to optimize the displacement reduction performance. Through finite element analysis and experimental results on the prototype, the proposed displacement reducer demonstrates a large reduction ratio of 11.03, an energy transfer efficiency of 39.6%, and a nearly constant reduction ratio with an input displacement range of 0 to 2000 µm. Full article
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27 pages, 21307 KiB  
Article
A POD-Based Reduced-Dimension Method for Solution Coefficient Vectors in the Crank–Nicolson Mixed Finite Element Method for the Fourth-Order Parabolic Equation
by Xiaohui Chang and Hong Li
Fractal Fract. 2025, 9(3), 137; https://doi.org/10.3390/fractalfract9030137 - 21 Feb 2025
Viewed by 321
Abstract
This research proposes a method for reducing the dimension of the coefficient vector for Crank–Nicolson mixed finite element (CNMFE) solutions to solve the fourth-order variable coefficient parabolic equation. Initially, the CNMFE schemes and corresponding matrix schemes for the equation are established, followed by [...] Read more.
This research proposes a method for reducing the dimension of the coefficient vector for Crank–Nicolson mixed finite element (CNMFE) solutions to solve the fourth-order variable coefficient parabolic equation. Initially, the CNMFE schemes and corresponding matrix schemes for the equation are established, followed by a thorough discussion of the uniqueness, stability, and error estimates for the CNMFE solutions. Next, a matrix-form reduced-dimension CNMFE (RDCNMFE) method is developed utilizing proper orthogonal decomposition (POD) technology, with an in-depth discussion of the uniqueness, stability, and error estimates of the RDCNMFE solutions. The reduced-dimension method employs identical basis functions, unlike standard CNMFE methods. It significantly reduces the number of unknowns in the computations, thereby effectively decreasing computational time, while there is no loss of accuracy. Finally, numerical experiments are performed for both fourth-order and time-fractional fourth-order parabolic equations. The proposed method demonstrates its effectiveness not only for the fourth-order parabolic equations but also for time-fractional fourth-order parabolic equations, which further validate the universal applicability of the POD-based RDCNMFE method. Under a spatial discretization grid 40×40, the traditional CNMFE method requires 2×412 degrees of freedom at each time step, while the RDCNMFE method reduces the degrees of freedom to 2×6 through POD technology. The numerical results show that the RDCNMFE method is nearly 10 times faster than the traditional method. This clearly demonstrates the significant advantage of the RDCNMFE method in saving computational resources. Full article
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24 pages, 11564 KiB  
Article
Effects of Granulated Cork with Bark on the Microstructure and Resistance to Extreme Environmental Conditions of Concrete for Non-Structural Precast Elements
by María Concepción Pacheco Menor, María José Arévalo Caballero, Antonio Macías García and Pedro Serna Ros
Materials 2025, 18(5), 933; https://doi.org/10.3390/ma18050933 - 21 Feb 2025
Viewed by 382
Abstract
The building sector is responsible for major environmental impacts. Utilising bio-based raw materials, such as bio-aggregates, in concrete production could address to this environmental challenge. While the physical and mechanical properties of various bio-based concretes have been explored, research on their microstructure and [...] Read more.
The building sector is responsible for major environmental impacts. Utilising bio-based raw materials, such as bio-aggregates, in concrete production could address to this environmental challenge. While the physical and mechanical properties of various bio-based concretes have been explored, research on their microstructure and resistance to extreme conditions is limited. Cork is a light, renewable and biodegradable material. Cork industries produce a considerable number of solid wastes, among them is granulated cork with bark (GCB) that is not adequate to produce agglomerated cork. To reduce this waste volume, it is possible to use GCB as a bio-based aggregate in the production of concrete for applications in non-structural precast elements that are lighter and/or have thermal properties. The influence of GCB on the microstructure and resistance to extreme conditions of concrete for non-structural use is presented here. Concrete mixes with GCB are compared with a concrete mix made with natural aggregates (RC). Replacements of 20% and 30% of natural aggregate (2–5 mm) by GCB were considered. The microstructure shows the good integration of the GCB in the cement matrix. Freeze–thaw and wet–dry cycle tests do not affect the variation in mass and compressive strength of concrete mixes with GCB in comparison to RC mixes, although they do affect its visual appearance and microstructure somewhat. Concrete mixes with GCB present a greater variation in mass and compressive strength, 30% for RC mix and 43–49% for concrete mixes with GCB, under high temperatures. Concrete mixes with GCB did not show spontaneous combustion. Full article
(This article belongs to the Special Issue Advance in Sustainable Construction Materials, Second Volume)
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15 pages, 6494 KiB  
Article
Microstructure, Mechanical Properties, and Corrosion Behavior in Al-5.6Zn-2.5Mg-1.6Cu-0.2Cr Alloy with Minor Yttrium Addition
by Ting Yao, Daihong Xiao, Yingjie Yan and Wensheng Liu
Materials 2025, 18(4), 875; https://doi.org/10.3390/ma18040875 - 17 Feb 2025
Viewed by 338
Abstract
This study systematically investigated the effects of the addition of the rare earth element yttrium (Y) on the microstructural evolution, mechanical properties, and corrosion behavior of as-extruded Al-5.6Zn-2.5Mg-1.6Cu-0.20Cr (wt.%) alloy through comprehensive characterization techniques, including X-ray diffraction (XRD), tensile testing, corrosion analysis, and [...] Read more.
This study systematically investigated the effects of the addition of the rare earth element yttrium (Y) on the microstructural evolution, mechanical properties, and corrosion behavior of as-extruded Al-5.6Zn-2.5Mg-1.6Cu-0.20Cr (wt.%) alloy through comprehensive characterization techniques, including X-ray diffraction (XRD), tensile testing, corrosion analysis, and electron microscopy. Microstructural characterization demonstrated that the incorporation of yttrium resulted in significant refinement of secondary phase particles within the as-extruded alloy matrix. Moreover, quantitative analysis revealed a substantial increase in low-angle grain boundary (LAGB) density, dislocation density, and the formation of subgrain structures. Notably, the volume fraction of η′ strengthening precipitates showed a marked increase, accompanied by a corresponding reduction in the width of precipitate-free zones (PFZs) along grain boundaries. Following the T74 aging treatment, the alloy with 0.1 wt.% yttrium addition exhibited a remarkable improvement in intergranular corrosion resistance, with the maximum corrosion depth reduced to 107.8 μm. However, it should be noted that the exfoliation corrosion resistance exhibited an inverse correlation with increasing yttrium content, suggesting a concentration-dependent behavior in corrosion performance. Full article
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16 pages, 2149 KiB  
Article
Rapid Adsorption of Ammonium on Coffee Husk and Chicken Manure-Derived Biochars: Mechanisms Unveiled by Chemical Speciation, Physical, and Spectroscopic Approaches
by Everton Geraldo de Morais, Carlos Alberto Silva, Suduan Gao, Leônidas Carrijo Azevedo Melo, Pedro Antônio Namorato Benevenute, Bruno Cocco Lago, Jéssica Cristina Teodoro and Luiz Roberto Guimarães Guilherme
Sustainability 2025, 17(4), 1616; https://doi.org/10.3390/su17041616 - 15 Feb 2025
Cited by 1 | Viewed by 555
Abstract
Biochars have emerged as a sustainable technology for converting waste into high-value, stable carbon products. Depending on its properties, biochar can retain various elements, including nitrogen (N) as ammonium (N-NH4+). This study aimed to evaluate the rapid retention of N-NH [...] Read more.
Biochars have emerged as a sustainable technology for converting waste into high-value, stable carbon products. Depending on its properties, biochar can retain various elements, including nitrogen (N) as ammonium (N-NH4+). This study aimed to evaluate the rapid retention of N-NH4+ in biochars produced from coffee husk (CH) and chicken manure (CM) at different pyrolysis temperatures (PTs) (300 °C, 400 °C, and 900 °C) and investigate the mechanisms involved. A rapid N-NH4+ adsorption experiment was conducted, in which an NH4Cl solution was passed through the biochars. The following analyses were performed: cation exchange capacity (CEC), surface area, pore volume and size, total N content, N retention, infrared analysis (ATR-FTIR), and leachate solution analysis, followed by chemical speciation using Visual MINTEQ software. The results indicated that different mechanisms were involved in rapid N-NH4+ retention. In CH-derived biochars produced at 300 °C, N-NH4+ retention occurred primarily through electrostatic interactions with negative charges (CEC), as confirmed by ATR-FTIR analysis. In CM-derived biochars produced at 400 °C, N-NH4+ retention was mainly through the formation of struvite (NH4MgPO4·6H2O), as confirmed by chemical speciation of leachate solution in Visual MINTEQ. In CH-derived biochars produced at 900 °C, N-NH4+ ions were trapped in the pores of the charred matrix due to the increased biochar surface area, pore volume, and decreased pore size. The biochars studied proved effective in retaining N-NH4+ through different mechanisms, suggesting that biochars can enhance rapid N retention and reduce N leaching, potentially serving as a source of N for crops. Full article
(This article belongs to the Special Issue Sustainable Thermochemical Conversion of Organic Solid Waste)
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14 pages, 10104 KiB  
Article
A Compact and Wideband Beam-Scanning Antenna Array Based on SICL Butler Matrix
by Zhu Hua, Chuang Gao, Jiejun Peng, Shuting Fan and Zhengfang Qian
Electronics 2025, 14(4), 757; https://doi.org/10.3390/electronics14040757 - 15 Feb 2025
Viewed by 325
Abstract
A compact and wideband beamforming antenna array based on a substrate-integrated coaxial line (SICL) Butler matrix at 60 GHz is proposed in this paper. The cavity-backed patch antenna loading double-ridged horn antenna is designed to enhance a gain of 5.4 dB and a [...] Read more.
A compact and wideband beamforming antenna array based on a substrate-integrated coaxial line (SICL) Butler matrix at 60 GHz is proposed in this paper. The cavity-backed patch antenna loading double-ridged horn antenna is designed to enhance a gain of 5.4 dB and a bandwidth of 2.7 GHz. Different phase centers of double-ridged horn elements are formed into a non-uniform array to reduce sidelobes by −7.9 dB. By introducing the defected ground structure (DGS) for a broadband coupler, a rotationally symmetric SICL Butler matrix is designed with a 55–70 GHz bandwidth and compact dimensions of 63 × 65 × 0.512 mm3. To validate the design, a prototype was fabricated and measured. The experimental results show a wideband −10 dB impedance bandwidth of 23.3% (55.4–70 GHz) with measured gains ranging from 15 to 16.1 dBi at 62 GHz. The one-dimensional beam scanning covers ±32°. The simulation and measurement results are in good agreement. Full article
(This article belongs to the Special Issue Antennas and Microwave/Millimeter-Wave Applications)
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