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Search Results (1,093)

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Keywords = solar thermal applications

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28 pages, 1518 KiB  
Review
Hybrid Energy Harvesting Applications of ZnO Nanorods for Future Implantable and Wearable Devices
by Kathalingam Adaikalam and Hyun-Seok Kim
Micromachines 2025, 16(6), 605; https://doi.org/10.3390/mi16060605 - 22 May 2025
Viewed by 129
Abstract
The currently used electrical energy devices for portable applications are in limited life and need of frequent recharging, it is a big bottleneck for wireless and transportation systems. The scientific community is motivated to find innovative and efficient devices to convert environmental energy [...] Read more.
The currently used electrical energy devices for portable applications are in limited life and need of frequent recharging, it is a big bottleneck for wireless and transportation systems. The scientific community is motivated to find innovative and efficient devices to convert environmental energy into useful forms. Nanogenerator can mitigate this issue by harvesting ambient energy of different forms into useful electrical energy. Particularly flexible nanogenerators can efficiently convert ambient mechanical energy into electrical energy which can be fruitfully used for self-powered sensors and electronic appliances. Zinc oxide is an interesting photosensitive and piezoelectric material that is expected to play a vital role in the synergetic harvesting of environmental thermal, sound, mechanical, and solar energies. As ZnO can be synthesized using easy methods and materials at low cost, the conversion efficiencies of solar and other energy forms can increase considerably. ZnO is a versatile material with interesting semiconducting, optical, and piezoelectric properties; it can be used advantageously to harvest more than one type of ambient energy. The coupled semiconducting and piezoelectric properties of ZnO are attractive for fabricating nanogenerators capable of harvesting both ambient optical and mechanical energies simultaneously. These nanolevel conversion devices are much required to power remote and implantable devices without the need for additional power sources. The present review briefly discusses the principles and mechanisms of different energy harvesting abilities of ZnO nanorods and their composites by consolidating available literature. In addition, the developments taking place in nanogenerators of different kinds—such as photovoltaic, piezoelectric, pyroelectric, and triboelectrics for self-powered technology—and their progress in hybrid energy harvesting application is reviewed. Full article
15 pages, 2591 KiB  
Article
Empirical Modeling of Seasonal Cooling Performance Based on Test Devices Using Zinc Oxide/Low-Density Polyethylene Passive Cooling Membranes
by Yinjia Zhang, Jun Natsuki, Chengwu Weng, Vuong Dinh Trung, Yiwen Wang, Lina Cui and Toshiaki Natsuki
Polymers 2025, 17(10), 1420; https://doi.org/10.3390/polym17101420 - 21 May 2025
Viewed by 93
Abstract
Outdoor structures, such as vehicles, buildings, and outdoor equipment, are prone to overheat due to prolonged exposure to solar irradiation, which could affect their service life or user experience. To address this urgent issue, we developed a climate-adaptive thermal management solution using zinc [...] Read more.
Outdoor structures, such as vehicles, buildings, and outdoor equipment, are prone to overheat due to prolonged exposure to solar irradiation, which could affect their service life or user experience. To address this urgent issue, we developed a climate-adaptive thermal management solution using zinc oxide (ZnO)/low-density polyethylene (LDPE) hybrid membranes. The cooling performance of the membrane was examined across different seasons, achieving maximum temperature reductions (T) of 12.55 °C in summer, 8.02 °C in autumn, and 2.90 °C in winter. Our results demonstrated that the material’s cooling efficiency varied with seasonal solar irradiance, showing quicker responsiveness in summer and reduced in winter, effectively preventing overcooling. Moreover, the enclosed specific volume (SV) was identified as another critical parameter affecting cooling performance. We established an empirical correlation between T and SV to quantify passive cooling performance across different seasons. This standardized method for assessing the cooling effect enables comparison between different materials, which is essential for determining climate-adaptive thermal management. Notably, the ZnO/LDPE membranes exhibited stable and balanced performance year-round, highlighting their potential for substantial energy savings in outdoor applications. This research provided valuable insights for designing climate-adaptive passive cooling materials that optimize thermal management across seasonal variations while contributing to sustainable energy conservation. Full article
(This article belongs to the Section Polymer Membranes and Films)
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17 pages, 881 KiB  
Article
Research on Stochastic Dual Model Predictive Control and Application to Solar Thermal Collector Field
by Xiaoyan Zhang, Diandian Wang, Chaobo Chen, Xiaohua Song and Suping Zhao
Electronics 2025, 14(10), 2048; https://doi.org/10.3390/electronics14102048 - 18 May 2025
Viewed by 142
Abstract
Uncertainty is inevitable in real-world systems. If uncertainty is not effectively addressed, it may degrade the performance of model predictive control (MPC). This paper proposes a stochastic dual model predictive control (SDMPC) method for linear systems with parameter uncertainty and measurement noise. The [...] Read more.
Uncertainty is inevitable in real-world systems. If uncertainty is not effectively addressed, it may degrade the performance of model predictive control (MPC). This paper proposes a stochastic dual model predictive control (SDMPC) method for linear systems with parameter uncertainty and measurement noise. The method not only actively explores uncertainty while optimizing control but also introduces probabilistic output constraints to expand the set of feasible solutions. Specifically, Kalman filtering is employed to construct a real-time parameter estimator. The future output errors are incorporated into the nominal cost function as exploration signals to balance exploration and exploitation. Simulation results in the field of solar collectors show that SDMPC can effectively track the temperature by varying the inlet flow under changing environmental and opportunity constraints. The cumulative performance index of SDMPC is 125.3, compared to 316.4 obtained by conventional MPC, validating its effectiveness. Full article
(This article belongs to the Section Systems & Control Engineering)
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15 pages, 4699 KiB  
Article
Carbon Dot-Modulated Phase-Change Composites for Wide Temperature Range and High-Density Heat Storage and Release
by Jingya Liang, Ning Li, Jie Wu, Qing Chang, Jinlong Yang and Shengliang Hu
Energies 2025, 18(10), 2597; https://doi.org/10.3390/en18102597 - 16 May 2025
Viewed by 142
Abstract
Organic phase-change materials (PCMs) offer great promise in addressing challenges in thermal energy storage and heat management, but their applications are greatly limited by low energy density and a rigid phase transition temperature. Herein, by introducing carbon dots (CDs) with abundant oxygen-related groups, [...] Read more.
Organic phase-change materials (PCMs) offer great promise in addressing challenges in thermal energy storage and heat management, but their applications are greatly limited by low energy density and a rigid phase transition temperature. Herein, by introducing carbon dots (CDs) with abundant oxygen-related groups, we develop a novel kind of erythritol (ET)-based composite PCMs (CD-ETs) featuring an enhanced latent heat storage capacity and a reduced degree of supercooling compared to pure ETs. The optimally formulated CD-ETs increase the latent heat storage capacity from 377.3 to 410.2 J·g−1 and the heat release capacity from 209.0 to 240.2 J·g−1 compared to the pristine ETs. Moreover, the subcooled degree of CD-ETs is more than 30 °C lower than that of pristine ETs. By successively encapsulating CD-ETs and CD-containing polyethylene glycol (PEG) with a low melting point in a reduced graphene oxide-modified melamine sponge, the resultant shape-stabilized system not only prevents leakage of molten PCMs but also allows for a wide response temperature window and promotes the heat transfer ability of melted PEG in close contact with solid CD-ETs. Stepped melting and crystallization guarantee phase changes in high-melting-point ETs via solar heating, Joule heating or a combination thereof. Specifically, the melting enthalpy of this system is as high as 306.5 J·g−1, and its cold crystallization enthalpy reaches 196.5 J·g−1, surpassing numerous organic PCMs. This work provides a facile and efficient strategy for the design of ideal thermal energy storage materials to meet the needs of application scenarios in a cost-effective manner. Full article
(This article belongs to the Section J1: Heat and Mass Transfer)
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42 pages, 2459 KiB  
Review
Climate-Responsive Design of Photovoltaic Façades in Hot Climates: Materials, Technologies, and Implementation Strategies
by Xiaohui Wu, Yanfeng Wang, Shile Deng and Ping Su
Buildings 2025, 15(10), 1648; https://doi.org/10.3390/buildings15101648 - 14 May 2025
Viewed by 429
Abstract
With the intensification of global climate change, buildings in hot climate zones face increasing challenges related to high energy consumption and thermal comfort. Building integrated photovoltaic (BIPV) façades, which combine power generation and energy saving potential, require further optimization in their climate-adaptive design. [...] Read more.
With the intensification of global climate change, buildings in hot climate zones face increasing challenges related to high energy consumption and thermal comfort. Building integrated photovoltaic (BIPV) façades, which combine power generation and energy saving potential, require further optimization in their climate-adaptive design. Most existing studies primarily focus on the photoelectric conversion efficiency of PV modules, yet there is a lack of systematic analysis of the coupled effects of temperature, humidity, and solar radiation intensity on PV performance. Moreover, the current literature rarely addresses the regional material degradation patterns, integrated cooling solutions, or intelligent control systems suitable for hot and humid climates. There is also a lack of practical, climate specific design guidelines that connect theoretical technologies with real world applications. This paper systematically reviews BIPV façade design strategies following a climate zoning framework, summarizing research progress from 2019 to 2025 in the areas of material innovation, thermal management, light regulation strategies, and parametric design. A climate responsive strategy is proposed to address the distinct challenges of humid hot and dry hot climates. Finally, this study discusses the barriers and challenges of BIPV system applications in hot climates and highlights future research directions. Unlike previous reviews, this paper offers a multi-dimensional synthesis that integrates climatic classification, material suitability, passive and active cooling strategies, and intelligent optimization technologies. It further provides regionally differentiated recommendations for façade design and outlines a unified framework to guide future research and practical deployment of BIPV systems in hot climates. Full article
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24 pages, 5625 KiB  
Review
A Review of High-Temperature Resistant Silica Aerogels: Structural Evolution and Thermal Stability Optimization
by Zhenyu Zhu, Wanlin Zhang, Hongyan Huang, Wenjing Li, Hao Ling and Hao Zhang
Gels 2025, 11(5), 357; https://doi.org/10.3390/gels11050357 - 13 May 2025
Viewed by 327
Abstract
Silica aerogels exhibit exceptionally low thermal conductivity and a low apparent density, as they are unique porous nanomaterials. They are extensively used in thermal insulation in terms of aerospace and building construction, adsorption processes for environmental applications, concentrating solar power systems, and so [...] Read more.
Silica aerogels exhibit exceptionally low thermal conductivity and a low apparent density, as they are unique porous nanomaterials. They are extensively used in thermal insulation in terms of aerospace and building construction, adsorption processes for environmental applications, concentrating solar power systems, and so on. However, the degradation of the silica aerogel’s nanoporous structure at high temperatures seriously restricts their practical applications. Through a comprehensive review of the high-temperature structural evolution and sintering mechanisms of silica aerogels, this paper introduces two strategies to enhance their thermal stability, including heteroatom doping and surface heterogeneous structure construction. In particular, atomic layer deposition (ALD) of ultra-thin coatings on silica aerogel holds significant potential for enhancing thermal stability, while preserving its ultra-low thermal conductivity. Full article
(This article belongs to the Special Issue Advanced Aerogels: From Design to Application)
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22 pages, 26736 KiB  
Article
High-Temperature Corrosion of Different Steels in Liquid Sn-Bi-Zn Heat Transfer Alloy
by Qingmeng Wang, Xiuli Wang, Xiaomin Cheng, Qianju Cheng and Yi Yang
Materials 2025, 18(9), 2149; https://doi.org/10.3390/ma18092149 - 7 May 2025
Viewed by 134
Abstract
In the fields of nuclear engineering and solar thermal utilization, low melting point alloys with excellent thermal conductivity and heat transfer performance have attracted extensive research as a new generation of heat transfer fluids, leading to many fundamental and important application issues. This [...] Read more.
In the fields of nuclear engineering and solar thermal utilization, low melting point alloys with excellent thermal conductivity and heat transfer performance have attracted extensive research as a new generation of heat transfer fluids, leading to many fundamental and important application issues. This study investigates the high-temperature corrosion behavior of Sn-50Bi-2Zn (wt.%) heat transfer alloy against 304 stainless steel (304), 310S heat-resistant steel (310S), and 20 carbon steel (20C) at 600 °C. Theoretical analysis, based on Fick’s diffusion law, and experimental measurements reveal significant differences in corrosion severity. After 473 h, 20 carbon steel exhibited the lowest corrosion layer thickness (0.07 mm), while 310S suffered the most severe corrosion (1.50 mm), exceeding 304SS (0.83 mm) by 81%. Diffusion coefficients derived from Sn penetration depths further quantified these trends: D310S = 2.51 × 10−7 mm2/s (6.8 × higher than 304: 3.7 × 10−8 mm2/s) and D20C = 2.87 × 10−10 mm2/s (128 × lower than 304SS). XRF analysis confirmed the dissolution of steel components into the molten alloy, with Fe, Cr, and Ni content increasing to 0.382 wt.%, 0.417 wt.%, and 0.694 wt.%, respectively, after 480 h. These results underscore the critical role of Ni content in accelerating Sn/Zn diffusion and pore formation, providing actionable insights for material selection in high-temperature heat transfer systems. Full article
(This article belongs to the Section Metals and Alloys)
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25 pages, 14247 KiB  
Article
Energy Efficiency and Environmental Sustainability in Rural Buildings: A Life Cycle Assessment of Photovoltaic Integration in Poultry Tunnels—A Case Study in Central Italy
by Stefano Bigiotti, Carlo Costantino, Alessio Patriarca, Giulia Mancini, Giorgio Provolo, Fabio Recanatesi, Maria Nicolina Ripa and Alvaro Marucci
Appl. Sci. 2025, 15(9), 5094; https://doi.org/10.3390/app15095094 - 3 May 2025
Viewed by 305
Abstract
Livestock buildings in rural areas are increasingly recognized for their environmental impact, yet few studies provide applied, scenario-based evaluations to guide retrofit interventions. While the existing literature acknowledges the environmental burden of livestock facilities, it often lacks operationally grounded analyses applicable to real-world [...] Read more.
Livestock buildings in rural areas are increasingly recognized for their environmental impact, yet few studies provide applied, scenario-based evaluations to guide retrofit interventions. While the existing literature acknowledges the environmental burden of livestock facilities, it often lacks operationally grounded analyses applicable to real-world agricultural contexts. This paper proposes an original integration of experimental climatic monitoring and life cycle assessment (LCA) to evaluate retrofit scenarios for energy efficiency in real poultry farming contexts. Based on an accurate climatic monitoring campaign conducted on-site during the spring and summer periods, relevant data were collected on air temperature, humidity, wind speed, and solar radiation affecting two poultry tunnels in central Italy, highlighting the need for thermal mitigation. The comparison between the observed operational scenario and the hypothesized improved scenario, involving energy supply from photovoltaic sources, evaluated using the PVGIS tool, demonstrated a significant reduction in environmental impact, with a 33.4% decrease in global warming potential and a 26.1% reduction in energy consumption. This study combines experimental on-site climatic data collection with comparative environmental evaluation using LCA methodology. The LCA approach, which guided the entire study, highlighted how the energy efficiency gained through solar panels adequately offsets their production and maintenance costs over the long term. These findings offer a replicable model for energy retrofits in rural livestock facilities, contributing to both environmental goals and rural resilience. Full article
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19 pages, 7711 KiB  
Article
Exploring Options for the Application of Azobenzene for Molecular Solar Thermal Energy Storage: Integration with Parabolic Trough Solar Systems
by Li Zhang, Changcheng Guo, Yazhu Zhang, Haofeng Wang, Wenjing Liu, Jing Jin, Shaopeng Guo and Erdem Cuce
Energies 2025, 18(9), 2298; https://doi.org/10.3390/en18092298 - 30 Apr 2025
Viewed by 304
Abstract
Molecular solar thermal (MOST) energy systems can be utilized for the absorption, storage, and release of energy from the ultraviolet (UV) band of the solar spectrum. In this study, we designed a molecular solar thermal energy storage and release device based on the [...] Read more.
Molecular solar thermal (MOST) energy systems can be utilized for the absorption, storage, and release of energy from the ultraviolet (UV) band of the solar spectrum. In this study, we designed a molecular solar thermal energy storage and release device based on the photoisomerization reaction of azobenzene. The device was integrated with a parabolic trough solar system, broadening the absorption range of the solar spectrum. By utilizing a coated secondary reflector, the system achieved efficient reflection of ultraviolet (UV) light in the 290–490 nm range, while solid-state azobenzene enabled the conversion of photon energy into chemical energy for storage and release. Experimental results under winter outdoor conditions demonstrated that: the secondary reflector significantly enhanced UV light concentration; the molecular solar thermal energy device exhibited remarkable thermal efficiency. Under an average solar irradiance of 302.23 W·m−2, the device demonstrated excellent thermal performance, with the azobenzene reaching a peak temperature of 42.07 °C. The maximum heat release capacity was measured at 10.89 kJ·kg−1·m−1, while achieving a remarkable heat release power of 29.31 W·kg−1·m−1. Full article
(This article belongs to the Section A2: Solar Energy and Photovoltaic Systems)
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25 pages, 26783 KiB  
Article
Performance Enhancement of a Solar Air Heater Equipped with a Tree-like Fractal Cylindrical Pin for Drying Applications: Tests Under Real Climatic Conditions
by Chotiwut Prasopsuk, Kittiwoot Sutthivirode and Tongchana Thongtip
Energies 2025, 18(9), 2230; https://doi.org/10.3390/en18092230 - 27 Apr 2025
Viewed by 334
Abstract
This paper reports the improved thermal and drying performance of a solar air heater powered by real solar irradiance and equipped with a tree-like fractal-based cylindrical pin (SAH-TFCP) as a turbulator for drying applications. The main purpose of this work is to demonstrate [...] Read more.
This paper reports the improved thermal and drying performance of a solar air heater powered by real solar irradiance and equipped with a tree-like fractal-based cylindrical pin (SAH-TFCP) as a turbulator for drying applications. The main purpose of this work is to demonstrate the SAH-TFCP’s improvement potential based on its thermal and drying performance as compared with a conventional solar air heater based on a flat-plate absorber (SAH-FP). The test was implemented based on solar time from 8:30 to 17:30 under Thailand’s climatic conditions at a latitude angle of 14° and a longitude angle of 100°. Turmeric slices were used to evaluate the SAH’s drying performance. The thermal efficiency, moisture content wet basis (MCwb), drying rate (DR), and drying efficiency were measured as parameters of interest to assess the improvement potential of the SAH-TFCP over the SAH-FP. The results indicate that the SAH-TFCP provides better thermal and drying performance than the SAH-FP. A higher flow rate yields a higher thermal efficiency and a greater improvement potential. The improvement potential is around 44–85%. The drying efficiency of the SAH-TFCP is always higher than that of the SAH-FP and has an improvement potential of 32–44%, depending on the airflow rate. Full article
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23 pages, 6747 KiB  
Article
A Comparative Analysis of Advanced Glazing Technologies for Energy-Efficient Buildings in Jeddah City, Saudi Arabia
by Mohammed M. Gomaa, Amr Sayed Hassan Abdallah, Mohammed A. Aloshan and Ayman Ragab
Buildings 2025, 15(9), 1477; https://doi.org/10.3390/buildings15091477 - 26 Apr 2025
Viewed by 347
Abstract
This study employs Design Builder software to evaluate advanced glazing technologies for enhancing the thermal performance of residential buildings in Jeddah, Saudi Arabia. Recognizing the energy inefficiencies caused by adopting Western architectural styles unsuited to local climatic conditions, and given that buildings consume [...] Read more.
This study employs Design Builder software to evaluate advanced glazing technologies for enhancing the thermal performance of residential buildings in Jeddah, Saudi Arabia. Recognizing the energy inefficiencies caused by adopting Western architectural styles unsuited to local climatic conditions, and given that buildings consume 44% of national energy, we conducted a systematic parametric analysis to isolate the effects of key glazing parameters. The study examines six polycarbonate (PC) configurations and three critical comparative cases: (1) a selective double-glazed unit representing a new baseline glazing; (2) a low-U configuration to isolate thermal insulation effects; and (3) a low-SHGC configuration to evaluate solar heat gain mitigation independently. These controlled comparisons address a critical research gap by decoupling the traditionally confounded impacts of U-value and SHGC in hot climates. The simulations reveal that the 36 mm aerogel glazing (U = 0.9 W/m2·K, SHGC = 0.3) reduces cooling demand by 48.6% annually compared to single-pane glazing while maintaining indoor temperatures at 30.09 °C versus 38.43 °C at baseline. Notably, the findings demonstrate that 87% of these savings derive from SHGC reduction, with only 3.02 percentage points attributable to U-value improvements. The selective DGU benchmark delivers 85% of aerogel’s benefits at 40% lower cost, establishing it as a practical solution for most applications. These findings provide evidence-based guidance for Saudi Vision 2030’s sustainability goals, emphasizing that while aerogel glazing excels in extreme solar exposures, strategic SHGC optimization in conventional glazing can achieve the most energy savings in hot climates. Full article
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37 pages, 12224 KiB  
Review
Research Progress of Photothermal Superhydrophobic Surfaces for Anti-Icing/Deicing
by Hui Gao, Tianjun Yin, Jieyin Ma, Yuqin Zhou, Ke Li and Jiayi Bao
Molecules 2025, 30(9), 1865; https://doi.org/10.3390/molecules30091865 - 22 Apr 2025
Viewed by 689
Abstract
Photothermal superhydrophobic surfaces with micro/nano-structured morphologies have emerged as promising candidates for anti-icing and deicing applications due to their exceptional water repellency and efficient solar-to-thermal conversion. These surfaces synergistically integrate the passive icephobicity of superhydrophobic coatings with the active heating capability of photothermal [...] Read more.
Photothermal superhydrophobic surfaces with micro/nano-structured morphologies have emerged as promising candidates for anti-icing and deicing applications due to their exceptional water repellency and efficient solar-to-thermal conversion. These surfaces synergistically integrate the passive icephobicity of superhydrophobic coatings with the active heating capability of photothermal materials, offering energy-efficient and environmentally friendly solutions for sectors such as aviation, wind energy, and transportation. Hence, they have received widespread attention in recent years. This review provides a comprehensive overview of recent advances in photothermal superhydrophobic coatings, focusing on their anti-icing/deicing mechanisms, surface wettability, and photothermal conversion performance for anti-icing/deicing applications. Special emphasis is placed on material categories, including metals and their compounds, carbon-based materials, and polymers, analyzing their structural features and application effectiveness. Furthermore, the application of anti-icing/deicing in various fields is described. Finally, perspectives on future development are presented, including pursuing fluorine-free, cost-effective, and multifunctional coatings to meet the growing demand for innovative, sustainable anti-icing/deicing technologies. Full article
(This article belongs to the Special Issue Micro/Nano-Materials for Anti-Icing and/or De-Icing Applications)
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27 pages, 8658 KiB  
Article
Enhancing Agricultural Sustainability Through Intelligent Irrigation Using PVT Energy Applications: Implementing Hybrid Machine and Deep Learning Models
by Youness El Mghouchi and Mihaela Tinca Udristioiu
Agriculture 2025, 15(8), 906; https://doi.org/10.3390/agriculture15080906 - 21 Apr 2025
Viewed by 285
Abstract
This research focuses on developing an intelligent irrigation solution for agricultural systems utilising solar photovoltaic-thermal (PVT) energy applications. This solution integrates PVT applications, prediction, modelling and forecasting as well as plants’ physiological characteristics. The primary objective is to enhance water management and irrigation [...] Read more.
This research focuses on developing an intelligent irrigation solution for agricultural systems utilising solar photovoltaic-thermal (PVT) energy applications. This solution integrates PVT applications, prediction, modelling and forecasting as well as plants’ physiological characteristics. The primary objective is to enhance water management and irrigation efficiency through innovative digital techniques tailored to different climate zones. In the initial phase, the performance of PVT solutions was evaluated using ANSYS Fluent software R19.2, revealing that scaled PVT systems offer optimal efficiency for PV systems, thereby optimising electrical production. Subsequently, a comprehensive approach combining integral feature selection (IFS) with machine learning (ML) and deep learning (DL) models was applied for reference evapotranspiration (ETo) prediction and water needs forecasting. Through this process, 301 optimal combinations of predictors and best-performing linear models for ETo prediction were identified. Achieving R2 values exceeding 0.97, alongside minimal indicators of dispersion, the results indicate the effectiveness and accuracy of the elaborated models in predicting the ETo. In addition, by employing a hybrid deep learning approach, 28 best models were developed for forecasting the next periods of ETo. Finally, an interface application was developed to house the identified models for predicting and forecasting the optimal water quantity required for specific plant or crop irrigation. This application serves as a user-friendly platform where users can input relevant predictors and obtain accurate predictions and forecasts based on the established models. Full article
(This article belongs to the Section Digital Agriculture)
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19 pages, 14314 KiB  
Article
Sustainable Breakthrough in Manganese Oxide Thermochemical Energy Storage: Advancing Efficient Solar Utilization and Clean Energy Development
by Zhizhen Wang, Mengjiao Zhao and Denghui Wang
Sustainability 2025, 17(8), 3752; https://doi.org/10.3390/su17083752 - 21 Apr 2025
Viewed by 344
Abstract
Solar power generation systems, recognized for their high energy quality and environmental benefits, require efficient energy storage to ensure stable grid integration and reduce reliance on fossil fuels. Thermochemical energy storage (TCS) using metal oxides, such as the Mn2O3/Mn [...] Read more.
Solar power generation systems, recognized for their high energy quality and environmental benefits, require efficient energy storage to ensure stable grid integration and reduce reliance on fossil fuels. Thermochemical energy storage (TCS) using metal oxides, such as the Mn2O3/Mn3O4 redox system, offers advantages like high energy density, wide temperature range, and stability, making it ideal for solar power applications. This study investigates Mn3O4 and Mn2O3 as initial reactants, analyzing reaction temperature range, rate, conversion efficiency, and cyclic performance via synchronous thermal analysis. Microstructural characterization was performed using XRD, SEM, BET, XPS, nanoparticle size, and zeta potential measurements. The results show that Mn3O4 reversibly converts to Mn2O3 with over 100% conversion efficiency over five cycles with 3.3% weight loss, indicating stable performance. Mn3O4 oxidation follows Arrhenius’ Law below 700 °C but deviates at higher temperatures. The oxidation mechanism function is G(α) = α and f(α) = 1, with an activation energy of 20.47 kJ/mol and a pre-exponential factor of 0.268/s. Mn2O3 synthesized via ammonia precipitation exhibits reversible redox behavior with 3.3% weight loss but samples from low-concentration precursors show poor cyclic performance. The reduction reaction of Mn2O3 has an activation energy of 249.87 kJ/mol. By investigating the Mn2O3/Mn3O4 redox system for TCS, this study advances its practical integration into solar thermal power systems and offers critical guidance for developing scalable, low-carbon energy storage technologies. These findings can support Sustainable Development Goals (SDGs) by advancing renewable energy storage technologies, reducing carbon emissions, and promoting the integration of solar power into sustainable energy grids. Full article
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33 pages, 5789 KiB  
Review
Concentrated Solar Thermal Power Technology and Its Thermal Applications
by Chunchao Wu, Yonghong Zhao, Wulin Li, Jianjun Fan, Haixiang Xu, Zhongqian Ling, Dingkun Yuan and Xianyang Zeng
Energies 2025, 18(8), 2120; https://doi.org/10.3390/en18082120 - 20 Apr 2025
Viewed by 449
Abstract
The industrial sector accounts for approximately 65% of global energy consumption, with projections indicating a steady annual increase of 1.2% in energy demand. In the context of growing concerns about climate change and the need for sustainable energy solutions, solar thermal energy has [...] Read more.
The industrial sector accounts for approximately 65% of global energy consumption, with projections indicating a steady annual increase of 1.2% in energy demand. In the context of growing concerns about climate change and the need for sustainable energy solutions, solar thermal energy has emerged as a promising technology for reducing reliance on fossil fuels. With its ability to provide high-efficiency heat for industrial processes at temperatures ranging from 150 °C to over 500 °C, solar thermal power generation offers significant potential for decarbonizing energy-intensive industries. This review provides a comprehensive analysis of various solar thermal technologies, including parabolic troughs, solar towers, and linear Fresnel reflectors, comparing their effectiveness across different industrial applications such as process heating, desalination, and combined heat and power (CHP) systems. For instance, parabolic trough systems have demonstrated optimal performance in high-temperature applications, achieving efficiency levels up to 80% for steam generation, while solar towers are particularly suitable for large-scale, high-temperature operations, reaching temperatures above 1000 °C. The paper also evaluates the economic feasibility of these technologies, showing that solar thermal systems can achieve a levelized cost of energy (LCOE) of USD 60–100 per MWh, making them competitive with conventional energy sources in many regions. However, challenges such as high initial investment, intermittency of solar resource, and integration into existing industrial infrastructure remain significant barriers. This review not only discusses the technical principles and economic aspects of solar thermal power generation but also outlines specific recommendations for enhancing the scalability and industrial applicability of these technologies in the near future. Full article
(This article belongs to the Special Issue Renewable Energy Power Generation and Power Demand Side Management)
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