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Membranes, Volume 8, Issue 3

2018 September - 51 articles

Cover Story: In this paper, we present a facile fabrication of enhanced direct contact membrane distillation membrane via immobilization of the hydrophillic graphene oxide (GO) on the permeate side of a commercial polypropylene supported polytetrafluoroethylene (PTFE) membrane. The hydrophilicity of the permeate side of a membrane was modified by immobilizing GO to facilitate the rapid condensation and removal of the permeated water vapors. Both flux and mass transfer coefficients improved significantly with the GO immobilization. View the paper here.
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Articles (51)

  • Article
  • Open Access
30 Citations
6,360 Views
22 Pages

19 September 2018

The use of the Nernst–Planck and Poisson (NPP) equations allows computation of the space charge density near solution/electrode or solution/ion-exchange membrane interface. This is important in modelling ion transfer, especially when taking int...

  • Article
  • Open Access
10 Citations
7,500 Views
15 Pages

19 September 2018

Controlling surface–protein interaction during wastewater treatment is the key motivation for developing functionally modified membranes. A new biocatalytic thermo-responsive poly vinylidene fluoride (PVDF)/nylon-6,6/poly(N-isopropylacrylamide)...

  • Review
  • Open Access
72 Citations
15,394 Views
27 Pages

Short Review on Porous Metal Membranes—Fabrication, Commercial Products, and Applications

  • Bo Zhu,
  • Mikel Duke,
  • Ludovic F. Dumée,
  • Andrea Merenda,
  • Elise Des Ligneris,
  • Lingxue Kong,
  • Peter D. Hodgson and
  • Stephen Gray

18 September 2018

Porous metal membranes have recently received increasing attention, and significant progress has been made in their preparation and characterisation. This progress has stimulated research in their applications in a number of key industries including...

  • Review
  • Open Access
21 Citations
7,617 Views
20 Pages

Thermodynamic Aspects in Non-Ideal Metal Membranes for Hydrogen Purification

  • Stefano Bellini,
  • Yu Sun,
  • Fausto Gallucci and
  • Alessio Caravella

16 September 2018

In this paper, an overview on thermodynamic aspects related to hydrogen-metal systems in non-ideal conditions is provided, aiming at systematically merging and analyzing information achieved from several different studies present in the open literatu...

  • Article
  • Open Access
9 Citations
6,234 Views
17 Pages

Grain Boundary Segregation in Pd-Cu-Ag Alloys for High Permeability Hydrogen Separation Membranes

  • Ole Martin Løvvik,
  • Dongdong Zhao,
  • Yanjun Li,
  • Rune Bredesen and
  • Thijs Peters

12 September 2018

Dense metal membranes that are based on palladium (Pd) are promising for hydrogen separation and production due to their high selectivity and permeability. Optimization of alloy composition has normally focused on bulk properties, but there is growin...

  • Article
  • Open Access
38 Citations
7,343 Views
16 Pages

8 September 2018

Enhancement of membrane permeability at no detriment of its other performances, e.g., selectivity, is a goal-directed objective in membrane fabrication. A novel antioxidant DES-lignin (lignin extracted from birch wood by using a deep eutectic solvent...

  • Brief Report
  • Open Access
16 Citations
6,899 Views
13 Pages

7 September 2018

Phosphorene is a two-dimensional material exfoliated from bulk phosphorus and it possesses a band gap. Specifically, relevant to the field of membrane science, the band gap of phosphorene provides it with potential photocatalytic properties, which co...

  • Article
  • Open Access
62 Citations
7,382 Views
13 Pages

6 September 2018

Graphene oxide (GO) has been widely reported and used for treatment of heavy metals from different waste streams. Although their use as additives for membranes has greatly enhanced membrane properties, there is still a bottleneck in obtaining membran...

  • Article
  • Open Access
33 Citations
9,588 Views
16 Pages

6 September 2018

A predictive model correlating the parameters in the mass transfer-based model Spiegler–Kedem to the pure water permeability is presented in this research, which helps to select porous polyamide membranes for enhanced oil recovery (EOR) applica...

  • Article
  • Open Access
6 Citations
6,218 Views
17 Pages

Exploring the Gas-Permeation Properties of Proton-Conducting Membranes Based on Protic Imidazolium Ionic Liquids: Application in Natural Gas Processing

  • Parashuram Kallem,
  • Christophe Charmette,
  • Martin Drobek,
  • Anne Julbe,
  • Reyes Mallada and
  • Maria Pilar Pina

5 September 2018

This experimental study explores the potential of supported ionic liquid membranes (SILMs) based on protic imidazolium ionic liquids (ILs) and randomly nanoporous polybenzimidazole (PBI) supports for CH4/N2 separation. In particular, three classes of...

  • Article
  • Open Access
34 Citations
9,137 Views
19 Pages

5 September 2018

Poly(1-trimethylsilyl-1-propyne) (PTMSP) is a high free volume polymer with exceptionally high gas permeation rate but the serious aging problem and low selectivity have limited its application as CO2 separation membrane material. Incorporating inorg...

  • Article
  • Open Access
1 Citations
4,953 Views
10 Pages

On-Line NIR to Regulate Pervaporation Process: Application for Dehydration

  • Thomas La Rocca,
  • Emilie Carretier,
  • Thomas Clair,
  • Martial Etienne and
  • Philippe Moulin

4 September 2018

The regeneration of volatile organic solvents via dehydration tests, from 90 wt %, was evaluated by pervaporation using an on-line near-infrared (NIR) spectrometer. Experiments were performed using a bis(triethoxysilyl)methane (BTESM)-based ceramic H...

  • Article
  • Open Access
24 Citations
11,628 Views
15 Pages

A Novel Time Lag Method for the Analysis of Mixed Gas Diffusion in Polymeric Membranes by On-Line Mass Spectrometry: Pressure Dependence of Transport Parameters

  • Marcello Monteleone,
  • Elisa Esposito,
  • Alessio Fuoco,
  • Marek Lanč,
  • Kryštof Pilnáček,
  • Karel Friess,
  • Caterina Grazia Bezzu,
  • Mariolino Carta,
  • Neil Bruce McKeown and
  • Johannes Carolus Jansen

3 September 2018

This paper presents a novel method for transient and steady state mixed gas permeation measurements, using a quadrupole residual gas analyser for the on-line determination of the permeate composition. The on-line analysis provides sufficiently quick...

  • Article
  • Open Access
98 Citations
10,410 Views
17 Pages

1 September 2018

The present investigation reports as it is possible to prepared polyvinylidene fluoride (PVDF) membranes for microfiltration (MF) and ultrafiltration (UF) applications, by using triethyl phosphate (TEP) as non–toxic solvent in accordance with t...

  • Article
  • Open Access
15 Citations
5,149 Views
16 Pages

1 September 2018

Submerged forward osmosis (FO) is of high interest for bioreactors, such as osmotic membrane bioreactor, microalgae photobioreactor, food or bioproduct concentration where pumping through pressurized modules is a limitation due to viscosity or breaka...

  • Article
  • Open Access
53 Citations
8,218 Views
15 Pages

Modification of Nanofiber Support Layer for Thin Film Composite Forward Osmosis Membranes via Layer-by-Layer Polyelectrolyte Deposition

  • Ralph Rolly Gonzales,
  • Myoung Jun Park,
  • Leonard Tijing,
  • Dong Suk Han,
  • Sherub Phuntsho and
  • Ho Kyong Shon

Electrospun nanofiber-supported thin film composite membranes are among the most promising membranes for seawater desalination via forward osmosis. In this study, a high-performance electrospun polyvinylidenefluoride (PVDF) nanofiber-supported thin f...

  • Article
  • Open Access
36 Citations
6,500 Views
15 Pages

Composite gel polymer electrolytes (GPEs) based on organo-modified montmorillonite clays have been prepared and investigated. The organo-clay was prepared by intercalation of CTAB molecules in the interlamellar space of sodium smectite clay (SWy) thr...

  • Review
  • Open Access
47 Citations
17,814 Views
23 Pages

Thin film composite (TFC) membrane, which consists of polyamide (PA) active film rests on porous support layer, has been the major type of reverse osmosis (RO) membrane since its development by Cadotte in the 1970s, and has been remarkably used to pr...

  • Article
  • Open Access
52 Citations
9,804 Views
16 Pages

Chemical Crosslinking of 6FDA-ODA and 6FDA-ODA:DABA for Improved CO2/CH4 Separation

  • Mohd Zamidi Ahmad,
  • Henri Pelletier,
  • Violeta Martin-Gil,
  • Roberto Castro-Muñoz and
  • Vlastimil Fila

Chemical grafting or crosslinking of polyimide chains are known to be feasible approaches to increase polymer gas-pair selectivity and specific gas permeance. Different co-polyimides; 6FDA-ODA and 6FDA-ODA:DABA were synthesized using a two-step conde...

  • Review
  • Open Access
36 Citations
8,110 Views
22 Pages

Progress in Methanol Steam Reforming Modelling via Membrane Reactors Technology

  • Adolfo Iulianelli,
  • Kamran Ghasemzadeh and
  • Angelo Basile

Hydrogen has attracted growing attention for various uses, and, particularly, for polymer electrolyte membrane fuel cells (PEMFCs) supply. However, PEMFCs need high grade hydrogen, which is difficult in storing and transportation. To solve these issu...

  • Article
  • Open Access
57 Citations
7,787 Views
10 Pages

In this study, TiO2 nanoparticles were inserted into the polyamide layer of traditional thin film composite membrane. The nanoparticles were dispersed in a trimesoyl chloride-hexane solution before interfacial polymerization with m-phenylenediamine-a...

  • Article
  • Open Access
23 Citations
7,320 Views
18 Pages

Next to the pore size distribution, surface charge is considered to be one main factor in the separation performance of ultrafiltration (UF) membranes. By applying an external surface potential onto an electro-conductive UF membrane, electrostatic in...

  • Article
  • Open Access
41 Citations
7,330 Views
12 Pages

In this paper, a facile fabrication of enhanced direct contact membrane distillation membrane via immobilization of the hydrophilic graphene oxide (GO) on the permeate side (GOIM-P) of a commercial polypropylene supported polytetrafluoroethylene (PTF...

  • Review
  • Open Access
232 Citations
14,473 Views
24 Pages

A Review on Properties of Natural and Synthetic Based Electrospun Fibrous Materials for Bone Tissue Engineering

  • Deval Prasad Bhattarai,
  • Ludwig Erik Aguilar,
  • Chan Hee Park and
  • Cheol Sang Kim

Bone tissue engineering is an interdisciplinary field where the principles of engineering are applied on bone-related biochemical reactions. Scaffolds, cells, growth factors, and their interrelation in microenvironment are the major concerns in bone...

  • Article
  • Open Access
24 Citations
4,329 Views
8 Pages

An Efficient Polymer Inclusion Membrane-Based Device for Cd Monitoring in Seawater

  • Ibrahim Ait Khaldoun,
  • Lynda Mitiche,
  • Amar Sahmoune and
  • Clàudia Fontàs

A novel and simple device that includes a polymer inclusion membrane (PIM) has been prepared and tested for the first time to detect low concentration levels of cadmium in seawater. The ionic liquid trihexyl (tetradecyl) phosphonium chloride (THTDPCl...

  • Review
  • Open Access
33 Citations
8,041 Views
27 Pages

Current and Emerging Techniques for High-Pressure Membrane Integrity Testing

  • Eddy R. Ostarcevic,
  • Joseph Jacangelo,
  • Stephen R. Gray and
  • Marlene J. Cran

Ideally, pressure driven membrane processes used in wastewater treatment such as reverse osmosis and nanofiltration should provide a complete physical barrier to the passage of pathogens such as enteric viruses. In reality, manufacturing imperfection...

  • Article
  • Open Access
38 Citations
7,753 Views
10 Pages

Electrospun Silver Coated Polyacrylonitrile Membranes for Water Filtration Applications

  • Shalv Amit Parekh,
  • Rebecca Nicole David,
  • Kranthi K. R. Bannuru,
  • Lakshminarasimhan Krishnaswamy and
  • Avinash Baji

The scarcity of drinking water and the contamination of water sources in underdeveloped countries are serious problems that require immediate low-tech and low-cost solutions. In this study, we fabricated polyacrylonitrile (PAN) porous membranes coate...

  • Article
  • Open Access
5 Citations
6,387 Views
8 Pages

Controlled polymerizations are often used to synthesize polymers with low dispersity, which involves expensive initiators, constrained atmospheres, and multi-step purifying processes, especially with water soluble monomers. These drawbacks make the s...

  • Article
  • Open Access
37 Citations
12,025 Views
22 Pages

In this work we present a method to manufacture flat sheet membranes with a thin isoporous block copolymer (BCP) layer (thickness <3 µm) by profile roller coating (breadth: 30 cm) on top of a porous support membrane. Highly diluted BCP-solut...

  • Review
  • Open Access
99 Citations
11,260 Views
38 Pages

Plasma Modification and Synthesis of Membrane Materials—A Mechanistic Review

  • Jingshi Wang,
  • Xiao Chen,
  • Rackel Reis,
  • Zhiqiang Chen,
  • Nick Milne,
  • Bjorn Winther-Jensen,
  • Lingxue Kong and
  • Ludovic F. Dumée

Although commercial membranes are well established materials for water desalination and wastewater treatment, modification on commercial membranes is still necessary to deliver high-performance with enhanced flux and/or selectivity and fouling resist...

  • Article
  • Open Access
6 Citations
4,255 Views
8 Pages

Extraction Kinetics of As(V) by Aliquat-336 Using Asymmetric PVDF Hollow-Fiber Membrane Contactors

  • Said Bey,
  • Hassina Semghouni,
  • Alessandra Criscuoli,
  • Mohamed Benamor,
  • Enrico Drioli and
  • Alberto Figoli

This work focuses on the study of the mass transfer of arsenic(V) through asymmetric polyvinylidene fluoride hollow-fiber membrane contactors using Aliquat-336 as an extractant. In the first part of this work, the fibers were prepared and characteriz...

  • Article
  • Open Access
21 Citations
9,565 Views
16 Pages

Hollow Fiber Membranes of Blends of Polyethersulfone and Sulfonated Polymers

  • Nazia Noor,
  • Joachim Koll,
  • Nico Scharnagl,
  • Clarissa Abetz and
  • Volker Abetz

Hollow fiber membranes (HFM) are fabricated from blend solutions of a polyethersulfone (PESU) with a sulfonated PESU (sPESU) or a sulfonated polyphenylenesulfone (sPPSU). The influence of different additives in the dope solution and different bore fl...

  • Article
  • Open Access
33 Citations
7,603 Views
11 Pages

High Performance Polymer/Ionic Liquid Thermoplastic Solid Electrolyte Prepared by Solvent Free Processing for Solid State Lithium Metal Batteries

  • Francisco González,
  • Pilar Tiemblo,
  • Nuria García,
  • Oihane Garcia-Calvo,
  • Elisabetta Fedeli,
  • Andriy Kvasha and
  • Idoia Urdampilleta

A polymer/ionic liquid thermoplastic solid electrolyte based on poly(ethylene oxide) (PEO), modified sepiolite (TPGS-S), lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), and 1-Butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PYR14T...

  • Article
  • Open Access
7 Citations
4,092 Views
12 Pages

Factors Affecting Mass Transport Properties of Poly(ε-caprolactone) Membranes for Tissue Engineering Bioreactors

  • Nazely Diban,
  • Beatriz Gómez-Ruiz,
  • María Lázaro-Díez,
  • Jose Ramos-Vivas,
  • Inmaculada Ortiz and
  • Ane Urtiaga

High porosity and mass transport properties of microfiltration polymeric membranes benefit nutrients supply to cells when used as scaffolds in interstitial perfusion bioreactors for tissue engineering. High nutrients transport is assumed when pore si...

  • Article
  • Open Access
20 Citations
4,422 Views
10 Pages

This paper presents a case study describing a full-scale membrane bioreactor (MBR) for the pretreatment of landfill leachates. The treatment train includes an aerated equalization tank, a denitrification tank, an oxidation/nitrification tank, and two...

  • Review
  • Open Access
91 Citations
12,183 Views
48 Pages

Application of conventional polymeric membranes in CO2 separation processes are limited by the existing trade-off between permeability and selectivity represented by the renowned upper bound. Addition of porous nanofillers in polymeric membranes is a...

  • Article
  • Open Access
21 Citations
4,696 Views
9 Pages

TiO2 is usually used as a sintering aid to lower the sintering temperature of porous alumina membrane support. Two ways of the addition of TiO2 are chosen: in-situ precipitation and in-situ hydrolysis. The results show that the distribution status of...

  • Review
  • Open Access
109 Citations
16,412 Views
33 Pages

Forward osmosis (FO) is a membrane technology that uses the osmotic pressure difference to treat two fluids at a time giving the opportunity for an energy-efficient water and wastewater treatment. Various applications are possible; one of them is the...

  • Article
  • Open Access
21 Citations
7,451 Views
15 Pages

Air Backwash Efficiency on Organic Fouling of UF Membranes Applied to Shellfish Hatchery Effluents

  • Clémence Cordier,
  • Christophe Stavrakakis,
  • Patrick Sauvade,
  • Franz Coelho and
  • Philippe Moulin

Among all the techniques studied to overcome fouling generated in dead-end filtration, the injection of air during backwashes proved to be the most effective. Indeed, shear stress engendered by the two-phase flow enhanced particle removal on membrane...

  • Article
  • Open Access
70 Citations
9,909 Views
11 Pages

Concentration Polarization in Ultrafiltration/Nanofiltration for the Recovery of Polyphenols from Winery Wastewaters

  • Alexandre Giacobbo,
  • Andréa Moura Bernardes,
  • Maria João Filipe Rosa and
  • Maria Norberta De Pinho

Concentration polarization is intrinsically associated with the selective character of membranes and often means flux decline and which causes a subsequent decrease of ultrafiltration and nanofiltration performance. More important is the fact that it...

  • Review
  • Open Access
170 Citations
15,569 Views
36 Pages

Recent Advances in Poly(vinylidene fluoride) and Its Copolymers for Lithium-Ion Battery Separators

  • João C. Barbosa,
  • José P. Dias,
  • Senentxu Lanceros-Méndez and
  • Carlos M. Costa

The separator membrane is an essential component of lithium-ion batteries, separating the anode and cathode, and controlling the number and mobility of the lithium ions. Among the polymer matrices most commonly investigated for battery separators are...

  • Review
  • Open Access
34 Citations
7,810 Views
16 Pages

Biomimetic membranes are attracting increased attention due to the huge potential of using biological functional components and processes as an inspirational basis for technology development. Indeed, this has led to several new membrane designs and a...

  • Article
  • Open Access
20 Citations
5,745 Views
11 Pages

Single Gas Permeance Performance of High Silica SSZ-13 Zeolite Membranes

  • Li Liang,
  • Meihua Zhu,
  • Le Chen,
  • Caijun Zhong,
  • Yiming Yang,
  • Ting Wu,
  • Heli Wang,
  • Izumi Kumakiri,
  • Xiangshu Chen and
  • Hidetoshi Kita

Continuous and high silica SSZ-13 zeolite membranes were prepared on porous mullite supports from high SiO2/Al2O3 ratio or aluminum-free precursor synthesis gel. Single gas permeance (CO2 and CH4) of the high silica SSZ-13 zeolite membrane was decrea...

  • Article
  • Open Access
9 Citations
5,023 Views
17 Pages

Performance of PES/LSMM-OGCN Photocatalytic Membrane for Phenol Removal: Effect of OGCN Loading

  • Noor Elyzawerni Salim,
  • Nor Azureen Mohamad Nor,
  • Juhana Jaafar,
  • Ahmad Fauzi Ismail,
  • Takeshi Matsuura,
  • Mohammed Rasool Qtaishat,
  • Mohd Hafiz Dzarfan Othman,
  • Mukhlis Abdul Rahman,
  • Farhana Aziz and
  • Norhaniza Yusof

In designing a photocatalytic oxidation system, the immobilized photocatalyst technique becomes highly profitable due to its promising capability in treating organic pollutants such as phenols in wastewater. In this study, hydrophiLic surface modifyi...

  • Article
  • Open Access
22 Citations
6,665 Views
15 Pages

The pervaporation separation of organic compounds from acetone-butanol-ethanol (ABE) fermentation model solutions was studied using activated carbon (AC) nanoparticle-poly (dimethylsiloxane) (PDMS) mixed matrix membranes (MMM). The effects of the ope...

  • Article
  • Open Access
25 Citations
6,340 Views
14 Pages

Ionic Liquid-Based Electrolyte Membranes for Medium-High Temperature Lithium Polymer Batteries

  • Guk-Tae Kim,
  • Stefano Passerini,
  • Maria Carewska and
  • Giovanni Battista Appetecchi

Li+-conducting polyethylene oxide-based membranes incorporating N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide are used as electrolyte separators for all-solid-state lithium polymer batteries operating at medium-high temperatures. T...

  • Article
  • Open Access
27 Citations
9,333 Views
13 Pages

Osmotic power extracted from the mixing of freshwater with seawater is a renewable energy resource that has gained increasing attention during recent years. The estimated energy can significantly contribute to the production of power worldwide. Howev...

  • Article
  • Open Access
5 Citations
5,671 Views
12 Pages

In this research, we investigated the influence of feedwater ionic strength on diffusion of divalent ions through a hollow-fiber nanofiltration membrane. The results indicated that solute flux of magnesium was increased as a result of elevating the i...

  • Article
  • Open Access
8 Citations
4,485 Views
10 Pages

Texas Sour Orange Juice Used in Scaffolds for Tissue Engineering

  • Mandana Akia,
  • Nataly Salinas,
  • Cristobal Rodriguez,
  • Robert Gilkerson,
  • Luis Materon and
  • Karen Lozano

Fine fibers of polyhydroxybutyrate (PHB), a biopolymer, were developed via a centrifugal spinning technique. The developed fibers have an average diameter of 1.8 µm. Texas sour orange juice (SOJ) was applied as a natural antibacterial agent and...

  • Article
  • Open Access
54 Citations
8,542 Views
15 Pages

In this paper, we present the characteristics and performance of polymer electrolyte membranes (PEMs) based on poly(vinylidene fluoride) (PVDF). The membranes were prepared via a phase-inversion method (non-solvent-induced phase separation (NIPS)). A...

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Membranes - ISSN 2077-0375