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Magnetochemistry, Volume 6, Issue 2

2020 June - 12 articles

Cover Story: The single-molecule magnet (SMM) performances of phenanthroline dione (L)-based mononuclear complexes can be modulated by changing the β-diketonate ancillary ligand associated with the dysprosium center. Surprisingly, both experimental measurements and wavefunction theory calculations highlighted better SMM behavior for the [Dy(hfac)3(L)] compound than for [Dy(tta)3(L)], which might be due to the difference in dipolar interactions through σ–π interactions. View this paper
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Articles (12)

  • Review
  • Open Access
17 Citations
4,731 Views
27 Pages

A review of the tripodal Schiff base (SB) complexes of tris(2-aminoethyl)amine, Nap(CH2CH 2NH2)3 (tren), and a few closely related tripodal amines with Cr(II), Mn(III) (d4), Mn(II), Fe(III) (d5), Fe(II) (d6), and Co(II) (d7) is provided. Attention is...

  • Article
  • Open Access
1 Citations
3,687 Views
16 Pages

Organic Spintronics: A Theoretical Investigation of a Graphene-Porphyrin Based Nanodevice

  • Elisabetta del Castillo,
  • Fausto Cargnoni,
  • Raffaella Soave and
  • Mario Italo Trioni

Spintronics is one of the most exciting applications of graphene-based devices. In this work Density Functional Theory is used to study a nanojunction consisting of two semi-infinite graphene electrodes contacted with an iron-porphyrin (FeP) molecule...

  • Feature Paper
  • Article
  • Open Access
17 Citations
5,080 Views
17 Pages

Spin Cross-Over (SCO) Anionic Fe(II) Complexes Based on the Tripodal Ligand Tris(2-pyridyl)ethoxymethane

  • Emmelyne Cuza,
  • Samia Benmansour,
  • Nathalie Cosquer,
  • Françoise Conan,
  • Sébastien Pillet,
  • Carlos J. Gómez-García and
  • Smail Triki

Reactions of Fe(II) with the tripodal chelating ligand 1,1,1-tris(2-pyridyl)ethoxymethane (py3C-OEt) and (NCE) co-ligands (E = S, Se, BH3) give a series of mononuclear complexes formulated as [Fe(py3C-OEt)2][Fe(py3C-OEt)(NCE)3]2·2CH3CN,...

  • Feature Paper
  • Review
  • Open Access
21 Citations
6,842 Views
22 Pages

Magnetic nanoparticles have been largely applied to increase the efficacy of antibiotics due to passive accumulation provided by enhancing permeability and retention, which is essential for the treatment of lung infections. Recurring lung infections...

  • Article
  • Open Access
1 Citations
2,778 Views
12 Pages

The article describes the interaction of nanocomposites based on the FemOn–SiO2 system with an electromagnetic field (radiation) in an ultra-wide frequency range 0–1021 Hz. The development of the technique based on the sol–gel metho...

  • Article
  • Open Access
46 Citations
5,760 Views
16 Pages

Saturation of Specific Absorption Rate for Soft and Hard Spinel Ferrite Nanoparticles Synthesized by Polyol Process

  • Cristian Iacovita,
  • Gabriela Fabiola Stiufiuc,
  • Roxana Dudric,
  • Nicoleta Vedeanu,
  • Romulus Tetean,
  • Rares Ionut Stiufiuc and
  • Constantin Mihai Lucaciu

Spinel ferrite nanoparticles represent a class of magnetic nanoparticles (MNPs) with enormous potential in magnetic hyperthermia. In this study, we investigated the magnetic and heating properties of spinel soft NiFe2O4, MnFe2O4, and hard CoFe2O4 MNP...

  • Article
  • Open Access
18 Citations
7,787 Views
14 Pages

High Yield Synthesis and Application of Magnetite Nanoparticles (Fe3O4)

  • Charles Wroblewski,
  • Tunde Volford,
  • Blake Martos,
  • Jurek Samoluk and
  • Perry Martos

Magnetite nanoparticles (Fe3O4), average particle size of 12.9 nm, were synthesized de novo from ferrous and ferric iron salt solutions (total iron salt concentration of 3.8 mM) using steady-state headspace NH3(g), 3.3% v/v, at room temperature and p...

  • Article
  • Open Access
8 Citations
5,113 Views
16 Pages

Paintings are complex multi-layered systems made of organic and inorganic materials. Several factors can affect the degradation of paintings, such as environmental conditions, past restoration works and, finally, the type of painting technique and th...

  • Article
  • Open Access
7 Citations
3,808 Views
11 Pages

Field-Induced Single-Ion Magnet Phenomenon in Hexabromo- and Hexaiodorhenate(IV) Complexes

  • Carlos Rojas-Dotti,
  • Adrián Sanchis-Perucho,
  • Marta Orts-Arroyo,
  • Nicolás Moliner,
  • Ricardo González,
  • Francesc Lloret and
  • José Martínez-Lillo

Two mononuclear ReIV complexes of general formula (PPh4)2[ReX6] [PPh4+ = tetraphenylphosphonium cation, X = Br (1) and I (2)] have been prepared and structurally and magnetically characterised. Both compounds crystallise in the triclinic system with...

  • Review
  • Open Access
2 Citations
3,061 Views
11 Pages

Magnetic resonance spectroscopy of biomolecules has recently gained attention for clinical diagnosis. Its combination with saliva collection and analysis can promote early disease detection and monitoring, by identifying biomarkers of specific underl...

  • Article
  • Open Access
11 Citations
4,408 Views
14 Pages

Dysprosium Single-Molecule Magnets Involving 1,10-Phenantroline-5,6-dione Ligand

  • Olivier Galangau,
  • Jessica Flores Gonzalez,
  • Vincent Montigaud,
  • Vincent Dorcet,
  • Boris le Guennic,
  • Olivier Cador and
  • Fabrice Pointillart

The two mononuclear complexes of the formula [Dy(tta)3(L)] (1) and [Dy(hfac)3(L)] (2) (where tta- = 2-thenoytrifluoroacetylacetonate and hfac- = 1,1,1,5,5,5-hexafluoroacetylacetonate) were obtained from the coordination reaction of the Dy(tta)3&middo...

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Magnetochemistry - ISSN 2312-7481