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Magnetochemistry, Volume 7, Issue 1

2021 January - 16 articles

Cover Story: The hydrothermal reaction of lanthanide(III) nitrates and pyrimidine-4,6-dicarboxylic acid gives rise to five different families of isostructural coordination polymers (CPs). These compounds contain oxalate anions, generated as a byproduct, or nitrate anions when the synthesis is carried out in the absence of solvent, both of which participate as co-ligands. The analysis of the alternating current measurements shows field-induced SMM behavior in the Dy-based counterparts, among which higher energy barriers are achieved for those compounds containing the polyhedron that best approaches to an ideal shape. Moreover, these CPs present intense and quite long-lived photoluminescence in solid state at room temperature with characteristic emissions of the corresponding lanthanide, among which one of the Eu-based CPs shows an absolute quantum yield of 25.0%. View this paper.
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Articles (16)

  • Feature Paper
  • Article
  • Open Access
8 Citations
4,287 Views
20 Pages

We numerically investigate the dynamics of a pair of circular Janus microparticles immersed in a Newtonian fluid under a simple shear flow and a uniform magnetic field by direct numerical simulation. Using the COMSOL software, we applied the finite e...

  • Feature Paper
  • Review
  • Open Access
28 Citations
10,463 Views
12 Pages

Quantitative NMR as a Versatile Tool for the Reference Material Preparation

  • Kihwan Choi,
  • Sangki Myoung,
  • Yejin Seo and
  • Sangdoo Ahn

The assessment of primary calibrator purity is critical for establishing traceability to the International System of Units (SI). Recently, quantitative nuclear magnetic resonance (qNMR) has been used as a purity determination method for reference mat...

  • Article
  • Open Access
8 Citations
4,265 Views
10 Pages

Microstructure Evolution of Ag/TiO2 Thin Film

  • Dewi Suriyani Che Halin,
  • Kamrosni Abdul Razak,
  • Mohd Arif Anuar Mohd Salleh,
  • Mohd Izrul Izwan Ramli,
  • Mohd Mustafa Al Bakri Abdullah,
  • Ayu Wazira Azhari,
  • Kazuhiro Nogita,
  • Hideyuki Yasuda,
  • Marcin Nabiałek and
  • Jerzy J. Wysłocki

Ag/TiO2 thin films were prepared using the sol-gel spin coating method. The microstructural growth behaviors of the prepared Ag/TiO2 thin films were elucidated using real-time synchrotron radiation imaging, its structure was determined using grazing...

  • Article
  • Open Access
28 Citations
7,002 Views
18 Pages

LaFe13xSix compounds exhibit a giant magnetocaloric effect and they are considered as a good magnetocaloric working substance for an environmentally friendly cooling technique. Nevertheless as the Curie temperature TC is around 200 K, it is ne...

  • Article
  • Open Access
2 Citations
4,336 Views
15 Pages

Enrichment of Rabbit Primitive Hematopoietic Cells via MACS Depletion of CD45+ Bone Marrow Cells

  • Jaromír Vašíček,
  • Andrej Baláži,
  • Miroslav Bauer,
  • Andrea Svoradová,
  • Mária Tirpáková,
  • Ľubomír Ondruška,
  • Vladimír Parkányi,
  • Alexander V. Makarevich and
  • Peter Chrenek

Hematopoietic stem and progenitor cells (HSC/HPCs) of human or few animal species have been studied for over 30 years. However, there is no information about rabbit HSC/HPCs, although they might be a valuable animal model for studying human hematopoi...

  • Article
  • Open Access
7 Citations
3,312 Views
12 Pages

New Mononuclear Mn(III) Complexes with Hydroxyl-Substituted Hexadentate Schiff Base Ligands

  • Peng-Yu Xu,
  • Yu-Ting Wang,
  • Zong-Mei Yu,
  • Yong-Hua Li and
  • Shi Wang

This paper reports the syntheses, crystal structures and magnetic properties of Mn(III) hexadentate Schiff base complexes [Mn(4-OH-sal-N-1,5,8,12)]NO3(1) and [Mn(4-OH-sal-N-1,5,8,12)]ClO4(2), where (4-OH-sal-N-1,5,8,12)2− (4,4′-((1E,13E)-...

  • Article
  • Open Access
8 Citations
4,287 Views
12 Pages

A Novel Computational Method to Identify/Analyze Hysteresis Loops of Hard Magnetic Materials

  • Alessandro Giuseppe D’Aloia,
  • Antonio Di Francesco and
  • Valerio De Santis

In this study, a novel computational method capable of reproducing hysteresis loops of hard magnetic materials is proposed. It is conceptually based on the classical Preisach model but has a completely different approach in the modeling of the hyster...

  • Article
  • Open Access
45 Citations
5,575 Views
14 Pages

Evaluation of the Effect of Silica Fume on Amorphous Fly Ash Geopolymers Exposed to Elevated Temperature

  • Ong Huey Li,
  • Liew Yun-Ming,
  • Heah Cheng-Yong,
  • Ridho Bayuaji,
  • Mohd Mustafa Al Bakri Abdullah,
  • Foo Kai Loong,
  • Tan Soo Jin,
  • Ng Hui Teng,
  • Marcin Nabiałek and
  • Ng Yong Sing
  • + 1 author

The properties of amorphous geopolymer with silica fume addition after heat treatment was rarely reported in the geopolymer field. Geopolymer was prepared by mixing fly ash and alkali activator. The silica fume was added in 2% and 4% by weight. The g...

  • Feature Paper
  • Article
  • Open Access
12 Citations
4,903 Views
20 Pages

Single-Ion Magnet and Photoluminescence Properties of Lanthanide(III) Coordination Polymers Based on Pyrimidine-4,6-Dicarboxylate

  • Oier Pajuelo-Corral,
  • Jose Angel García,
  • Oscar Castillo,
  • Antonio Luque,
  • Antonio Rodríguez-Diéguez and
  • Javier Cepeda

Herein, we report the magnetic and photoluminescence characterization of coordination polymers (CP) built from the combination of lanthanide(III) ions, pyrimidine-4,6-dicarboxylate (pmdc) ligand and a co-ligand with formula {[Dy(μ-pmdc)(μ-ox)0....

  • Feature Paper
  • Article
  • Open Access
12 Citations
3,771 Views
19 Pages

In this paper, the behavior of a ferromagnetic material is considered in the framework of microstructural modeling. The equations describing the behavior of such material in the magnetic field, are constructed based on minimization of total magnetic...

  • Feature Paper
  • Article
  • Open Access
22 Citations
4,354 Views
13 Pages

Fabrication of Dy2O3 Transparent Ceramics by Vacuum Sintering Using Precipitated Powders

  • Dianjun Hu,
  • Xin Liu,
  • Ziyu Liu,
  • Xiaoying Li,
  • Feng Tian,
  • Danyang Zhu,
  • Zhaoxiang Yang,
  • Lexiang Wu and
  • Jiang Li

As a kind of promising material for a Faraday isolator used in the visible and near infrared range, Dy2O3 transparent ceramics were prepared by vacuum sintering from the nano-powders synthesized by the liquid precipitation method using ammonium hydro...

  • Review
  • Open Access
1 Citations
3,105 Views
6 Pages

Xerostomia is a common adverse effect of radiation therapy at the head and neck area. Radiation-induced xerostomia can be severe and detrimental for the quality of life. Clinicians and radiologists have focused on the prevention of xerostomia as feas...

  • Feature Paper
  • Article
  • Open Access
2 Citations
3,865 Views
10 Pages

The combination of an androstane-3,17-diol nucleus and a 2β-N-alkylamidopiperazino sidechain is important for the anticancer activity of a new family of steroid derivatives. As the structure-activity relationship studies have so far been limited...

  • Article
  • Open Access
1 Citations
3,394 Views
7 Pages

Periodical transformation of ferroin to ferriin is accompanied by changes in magnetic properties of liquids during Belousov–Zhabotinsky (BZ) reaction malonic acid, sodium bromide, sodium bromate, ferroin, and sulfuric acid. Instead of the earli...

  • Article
  • Open Access
3,311 Views
17 Pages

This paper describes two cases of interaction between a quantized electromagnetic field and two different XY spin molecules; one with spins ½, and the other with spins 1. Both interact with a quantized electromagnetic field, with one of the sp...

  • Review
  • Open Access
14 Citations
4,510 Views
29 Pages

Single-molecule magnets involving monometallic 4f complexes have been investigated extensively in last two decades to understand the factors that govern the slow magnetization relaxation behavior in these complexes and to establish a magneto-structur...

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Magnetochemistry - ISSN 2312-7481