Plasma, Volume 7, Issue 1 (March 2024) – 15 articles

In this study, we present the Method of Spectral Redundancy Reduction (MSRR) for analyzing OES (optical emission spectroscopy) data of dry etching processes based on the principles of spectral clustering. To achieve this, the OES data are transformed into abstract graph matrices whose associated eigenvectors directly indicate anomalies in the data set. We developed an approach that allows for the reduction in temporally resolved optical emission spectra from plasma structuring processes in such a way that individual emission lines can be algorithmically detected, which exhibit a temporal behavior different from the collective behavior of the temporally resolved overall spectrum. The proportion of emission lines that behave consistently throughout the entire process duration is not considered. Our work may find applications in which OES is used as a process-monitoring technique, especially for low-pressure plasma processing. The major benefit of the developed method is that the scale of the original data is kept, making physical interpretations possible despite data reductions. Full article

Plasma medicine is an emerging field that applies the science and engineering of physical plasma to biomedical applications. Low-temperature plasma, also known as cold plasma, is generated via the ionization of atoms in a gas, generally via exposure to strong electric fields, and consists of ions, free radicals, and molecules at varying energy states. Plasmas generated at low temperatures (approximately room temperature) have been used for applications in dermatology, oncology, and anti-microbial strategies. Despite current and ongoing clinical use, the exact mechanisms of action and the full range of effects of cold plasma treatment on cells are only just beginning to be understood. Direct and indirect effects of plasma on immune cells have the potential to be utilized for various applications such as immunomodulation, anti-infective therapies, and regulating inflammation. In this review, we combine diverse expertise in the fields of plasma chemistry, device design, and immunobiology to cover the history and current state of plasma medicine, basic plasma chemistry and their implications, the effects of cold atmospheric plasma on host cells with their potential immunological consequences, future directions, and the outlook and recommendations for plasma medicine. Full article

Runaway electron (RAE) generation in high-pressure gases is an important physical phenomenon that significantly influences discharge shapes and properties of initiated plasma. The diffuse discharges formed due to RAEs in the air and other gases at atmospheric pressure find wide applications. In the present review, theoretical and experimental results that explain the reason for RAE occurrence at high pressures are analyzed, and recommendations are given for the implementation of conditions under which the runaway electron beam (RAEB) with the highest current can be obtained at atmospheric pressure. The experimental results were obtained using subnanosecond, nanosecond, and submicrosecond generators, including those specially developed for runaway electron generation. The RAEBs were recorded using oscilloscopes and collectors with picosecond time resolution. To theoretically describe the phenomenon of continuous electron acceleration, the method of physical kinetics was used based on the Boltzmann kinetic equation that takes into account the minimum but sufficient number of elementary processes, including shock gas ionization and elastic electron scattering. The results of modeling allowed the main factors to be established that control the RAE appearance, the most important of which is electron scattering on neutral atoms and/or molecules. Theoretical modeling has allowed the influence of various parameters (including the voltage, pressure, gas type, and geometrical characteristics of the discharge gap) to be taken into account. The results of the research presented here allow RAE accelerators with desirable parameters to be developed and the possibility of obtaining diffuse discharges to be accessed under various conditions. The review consists of the Introduction, five sections, the Conclusion, and the References. Full article

This paper describes a new practical numerical model for the calculation of lateral electromagnetic (EM) loads in tokamaks during asymmetric vertical displacement events (AVDEs). The model combines key features of two recently reported trial models while avoiding their drawbacks. Their common basic feature is the superposition of two patterns of halo current: one perfectly symmetric and another perfectly anti-symmetric. This model combines the following features that have not been combined before (a) a helically distorted halo layer wrapping around core plasma, and (b) halo-to-wall interception belts slipping along plasma-facing walls. This combination almost doubles the lateral net forces. An AVDE creates significant lateral net moments. Being relatively modest at VDEs, the lateral moments become a dominant component of EM loads at AVDEs. The model carefully tracks the balance of net EM loads (zero total for the tokamak), as a necessary condition for the consequent numerical simulation of the tokamak’s dynamic response. This balance is needed as well for the development of tokamak monitoring algorithms and simulators. In order to decouple from the current uncertainties in the interpretation and simulation of AVDE physics, the model does not simulate AVDE evolution but uses it as an input assumption based on the existing interpretation and simulation of AVDE physics. This means the model is to be used in a manner of parametric study, at widely varied input assumptions on AVDE evolution and severity. Parametric results will fill a library of ready-for-use waveforms of asymmetric EM loads (distributed and total) at tokamak structures and coils, so that the physics community may point to specific variants for subsequent engineering analysis. This article presents the first practical contribution to this AVDE library. Full article

Plasma-driven science is defined as the artificial control of physical plasma-driven phenomena based on complex interactions between nonequilibrium open systems. Recently, peculiar phenomena related to physical plasma have been discovered in plasma boundary regions, either naturally or artificially. Because laboratory plasma can be produced under nominal conditions around atmospheric pressure and room temperature, phenomena related to the interaction of plasma with liquid solutions and living organisms at the plasma boundaries are emerging. Currently, the relationships between these complex interactions should be solved using science-based data-driven approaches; these approaches require a reliable and comprehensive database of dynamic changes in the chemical networks of elementary reactions. Consequently, the elucidation of the mechanisms governing plasma-driven phenomena and the discovery of the latent actions behind these plasma-driven phenomena will be realized through plasma-driven science. Full article

The performance of fusion capsules on the National Ignition Facility (NIF) is strongly affected by the physical properties of the hot deuterium–tritium (DT) fuel, such as the mass, areal density, and pressure of the hot spot at the stagnation time. All of these critical quantities depend on one measured quantity, which is the ratio of the specific peak implosion energy to the specific internal energy of the hot spot. This unique physical quantity not only can measure the incremental progress of the inertial confinement fusion capsules towards ignition but also measures the conversion of the peak implosion kinetic energy of the pusher shell into the internal energy of the hot fuel in a capsule. Analysis of existing NIF shots to date are performed. The ratio metric is compared quantitatively with the ignition criterion. Results provide new perspectives on the NIF experiments by which the performance of the burning plasma can be determined and controlled through the fine tune of the implosion parameters, which improves future designs and predictions of the ignition capsules. Full article

In this review, we detail the commonality of mathematical intuitions that underlie three numerical methods used for the quantitative description of electron swarms propagating in a gas under the effect of externally applied electric and/or magnetic fields. These methods can be linked to the integral transport equation, following a common thread much better known in the theory of neutron transport than in the theory of electron transport. First, we discuss the exact solution of the electron transport problem using Monte Carlo (MC) simulations. In reality we will go even further, showing the interpretative role that the diagrams used in quantum theory and quantum field theory can play in the development of MC. Then, we present two methods, the Monte Carlo Flux and the Propagator method, which have been developed at this moment. The first one is based on a modified MC method, while the second shows the advantage of explicitly applying the mathematical idea of propagator to the transport problem. Full article

Electron-impact ionization (EII) processes are essential for modelling high-temperature plasma in quite different research areas, from astrophysics to material science to plasma and fusion research and in several places elsewhere. In most, if not all, of these fields, partial and total EII cross sections are required, and often for a good range of electron energies, in order to determine, for instance, the level population of ions and spectral line intensities in plasma under both local and non-local thermodynamic equilibrium conditions. To obey these needs, various kinds of semi-empirical EII cross sections have been applied in practice, often simply because of the large computational demands in dealing explicitly with two free electrons within the continuum. Here, we expand Jac, the Jena Atomic Calculator, to provide such empirical EII cross sections for (most) atoms and ions across the periodic table. Five empirical models from the recent literature have been implemented to support a simple and rapid access to the partial EII cross sections for electrons from a (partly filled) shell ${(n\ell )}^q$ as well as the total ionization cross sections. We here restrict ourselves to the direct part of the EII cross section, whereas the impact excitation of electrons with subsequent autoionization and the resonant electron capture with double autoionization have been left aside in this first implementation. Rapid access to the (direct) EII cross sections will help already to better understand the role of electron-impact processes in the diagnostics of fusion plasma or the interpretation of astrophysical spectra. Full article

Biodegradable polymers (poly(butylene succinate (PBS)), poly(butylene adipate terephthalate (PBAT)) and poly(lactic acid)/poly(butylene adipate terephthalate (PLA/PBAT)) blend) were treated in radiofrequency (13.56 MHz) low-pressure (10 Pa) oxygen with argon post-crosslinking plasma to enhance wettability and adhesion properties. Surface morphology and roughness modification caused by plasma exposure were observed by scanning electron microscopy (SEM) and atomic force microscopy (AFM). Surface chemical modifications of plasma-treated samples were evaluated by Fourier Transform infrared spectroscopy (FTIR). Due to the limited durability of plasma activation, the hydrophobic recovery was evaluated by water contact angle (WCA) measurements. The ageing effect was measured over 15 days in order to assess this kind of treatment as a potential industrial scalable method to increase biodegradable polymers hydrophilic properties for food packaging applications. The effects of polymer activation on its weight loss were also determined. Differential scanning calorimetry (DSC) analysis was used to study the effect of plasma treatment on the thermal properties of the polymers, while the crystallinity was investigated by X-ray diffraction (XRD). Full article

The production of spherical powders has recently registered a boost due to the need to fabricate new printing materials for Additive Manufacturing applications, from polymers and resins to metals and ceramics. Among these materials, stainless steels powders play a leading role, since they are widely used in industry and everyday life; indeed, micron-sized spherical stainless steel powders have specific characteristics and are considered as one of the best candidates for Additive Manufacturing systems and for application in a wide range of sectors. In this paper, stainless steel 316 L powders were used to explore and identify the best process parameters of a thermal plasma process able to produce spherical powders for Additive Manufacturing applications. X-ray Diffraction, Scanning Electron Microscopy, Particle Size Distribution and Flowability analysis were performed to characterize reagents and products. Powders with a high circularity (>0.8) and improved flowability (<30 s/50 g) were successfully obtained. The collected results were compared with data available from the literature to identify the potential use of the spherical produced powders. Full article

To realize the development of a long plasma source with a uniform electron density distribution in the axial direction, the spatial distribution of plasma under a multi-cusp magnetic field was analyzed using a KEIO-MARC code. Considering a cylindrical plasma source with an axial length of 3000 mm and a cross-sectional diameter of 100 mm, in which the filament electrode was the electron source, the electron density distribution was calculated using the residual magnetic flux density, B_res, and the number of permanent magnets installed at different locations surrounding the device, N_mag, as design parameters. The results show that both B_res and N_mag improved the uniformity of the electron density distribution in the axial direction. The maximum axial electron density decreased with increasing N_mag and increased with increasing B_res. These trends can be explained by considering the nature of the multi-cusp field, where particles are mainly confined to the field-free region (FFR) near the center of the plasma column, and the loss of particles due to radial particle transport. The use of multiple filaments at intervals shorter than the plasma decay length dramatically improved axial uniformity. To further improve axial uniformity, the filament length and FFR must be properly set so that electrons are emitted inside the FFR. Full article

Water pollution with microplastics has become a significant concern. Conventional treatment methods have proven ineffective, and alternatives are being explored. Herein, we assess the degradation efficiency of polystyrene (PS) by measuring its nanosecond discharge in air in contact with water. Its discharge is characterized during processing, and a transition from streamer-like to spark-like discharge occurs due to the increased electrical conductivity of water. Experiments are conducted at different frequencies, and the highest degradation is achieved at 10 kHz; an 83% polystyrene weight loss is recorded after 5 min of processing. The optical spectra of the discharge show no evidence of C-species, and an FTIR analysis of the processed polystyrene reveals no structural modifications. An NMR analysis shows the presence of ethylbenzene in water. Finally, a mechanism of PS degradation is proposed. Full article

The space-charge effects of pulsed high-current electron beams are very important to high-power particle beam accelerators and high-power microwave devices. The related physical phenomena have been studied for decades, and a large number of informative publications can be found in numerous scientific journals over many years. This review article is aimed at systematically summarizing most of the previous findings in a logical manner. Using a normalized one-dimensional mathematical model, analytical solutions have been obtained for the space-charge-limited current of both planar diode and drifting space. In addition, in the case of a beam current higher than the space-charge-limited current, the virtual cathode behavior and beam current reflection are quantitively studied. Furthermore, the criteria of steady-state virtual cathode formation are investigated, which leads to the physical understanding of the unstable nature of the virtual cathode. This review article is expected to serve as an integrated source of related information for young researchers and students working on high-power microwaves and pulsed particle beams. Full article

Recent studies have demonstrated that the physical properties of water treated with non-thermal plasma, or plasma-activated water (PAW), significantly differ from those of distilled water. For example, contrary to expectation, the viscosity of PAW becomes lower than that of distilled water at certain temperatures. This study developed a model to explain these differences by combining the two-state model of ordinary water, which describes water as a combination of nano-crystalline clusters and amorphous, free-floating molecules, using the Debye–Huckel theory for a fluid containing ions. A model for the viscosity of PAW was then developed from the general model. It explains how PAW has a lower viscosity than distilled water as the temperature decreases and why this effect is stronger than the colligative effect for ideal solutions. Finally, the viscosity model is compared to the experimental measurements of PAW treated with gliding arc plasma, showing that the data match the predicted values quite well. The model of PAW developed here can be used to understand other physical properties beyond viscosity, such as the surface tension, contact angle, electric conductivity, heat capacity, isothermal compressibility, and density, potentially facilitating new applications of PAW. Full article

Plasma generation by cathodic arc spots plays a crucial role for coating processes that make use of the Arc-PVD technology. Usually, the arc spot motion over the cathode is steered by a magnetic field of a particular distribution and magnitude to ensure a continuous plasma generation, the avoidance of liquid droplets, and a proper utilization of cathode material by homogeneous erosion. This study presents a semi-empirical model that allows for an examination and characterization of the arc spot motion with regard to direction and speed as a function of an imposed magnetic field. This model considers the different components of random walk, retrograde, and Robson drift motion. Introduced empirical coefficients were determined by corresponding experimental investigations. The calibrated model describes the arc spot motion in good agreement to the recorded spot tracks and can therefore be applied for an evaluation of different magnetic field configurations. Full article