Optics, Volume 6, Issue 1 (March 2025) – 10 articles

We present an empirical model for the cross-section of low concentration acetone gas in the range of 1671.5–1675 nm that encompasses the absorption band of the methyl stretch overtone. This model is experimentally validated with cavity ring-down spectroscopy (CRDS) measurements performed with a calibration gas and its diluted mixtures with breath samples. Particular attention is paid to accurate wavelength measurements with an interferometric wavemeter. The theoretical framework for analysis of gas mixtures with several absorbing species is presented. We show that the proposed empirical model can be used to accurately determine the concentration of acetone vapor in human breath samples. The comparison of the acetone absorption cross-section with previous results is also presented. Full article

Triplet–triplet transfer photochemical reactions are essential in many biological, chemical, and photonic applications. Here, the Pd-octaethylporphyrin sensitizer along with triplet–triplet annihilator (TTA) active 9,10-diphenylantracenes (DPA) and the related substituted variants in low concentrations were examined. A full experimental approach is presented for finding the necessary rate parameters with statistical standard deviation parameters. This was achieved by solving the pertinent non-analytical kinetic differential equation and fitting it to the experimental time-resolved photoluminescence of both slow fluorescence and sensitizer phosphorescence. The efficiency of the triplet–triplet energy transfer rate was found to be around 90% in THF but only around 75% in toluene. This appears to follow from the shorter lifetime of the sensitizer triplet in toluene. Moreover, the TTA transfer rate was on average more than 40% in THF toluene whereas a considerably lower value around 20–30% was found for toluene. This originated in an order of magnitude higher solvent quenching rate using toluene, based on the analysis of the delayed fluorescence decay traces. These are also higher than the statistically expected 1/9 TTA efficiency but in accordance with recent results in the literature, that attributed these high values to an inverse intersystem crossing process. In addition, quantum chemical calculations were carried out to reveal the pertinent excited triplet molecular orbitals of the lowest triplet excited state for a series of substituted DPAs, in comparison with the singlet ground state. Conclusively, these states distribute mainly in an anthracene ring in all compounds being in the range 1.64–1.65 eV above the ground state. The TTA efficiency was found to vary depending on the DPA annihilator substitution scheme and found to be smaller in THF. This is likely because the molecular framework over which the T1 excited molecular orbitals distribute is less sensitive for a longer lifetime of the annihilator triplet state. Full article

Standard endoscopy of vocal folds is in general limited to two-dimensional imaging. Laser-based 3D imaging offers not only absolute measurements but also the possibility of assessing all three spatial directions. However, due to human inter-individuality, a fixed grid configuration (with fixed edge length and spot size) does not necessarily provide the best coverage and resolution. We present a liquid lens optical design for a diffractive spot array generator with dynamic adjustment capabilities for both array size and spot size. The tunable nature of the liquid lenses enables precise control over the spot array generated by a diffractive optical element (DOE). The first liquid lens controls the spot divergence in the observation plane, while the second liquid lens adjusts the zoom factor. The optical configuration provides a dynamic range of 1.8 with respect to array size, significantly enhancing adaptability in imaging across various applications. Full article

A wide band range can cover more of the characteristic spectral lines of substances, and thus analyze the structure and composition of substances more accurately. In order to broaden the band range of spectral instruments, an ultra-wide-band Fourier transform infrared spectrometer is designed. The incident light of the spectrometer is constrained by a secondary imaging scheme, and switchable light sources and detectors are set to achieve an ultra-wide band coverage. A compact and highly stable double-moving mirror swing interferometer is adopted to generate optical path difference, and a controller is used to stabilize the swing of the moving mirrors. A distributed design of digital system integration and analog system integration is adopted to achieve a lightweight and low-power-consumption spectrometer. High-speed data acquisition and a transmission interface are applied to improve the real-time performance. Further, a series of experiments are performed to test the performance of the spectrometer. Finally, the experimental results show that the spectral range of the ultra-wide-band Fourier transform infrared spectrometer covers 0.770–200 μm, with an accurate wave number, a spectral resolution of 0.25 cm⁻¹, and a signal-to-noise ratio better than 50,000:1. Full article

This paper introduces a novel approach to the design of multi-element planar solar concentrators, aimed at optimizing solar energy harvesting systems. The proposed methodology is based on the integration of identical unit cells, strategically arranged to enhance solar radiation capture efficiency and achieve high angular selectivity. Mathematical modeling of the operational principles of the unit cells forms the foundation for determining production parameters and streamlining the concentrator assembly process. Particular emphasis is placed on analyzing key performance metrics, such as solar radiation concentration and optical efficiency, thereby advancing the understanding of the relationship between design parameters and energy output. The study employs MATLAB R2022b and ZemaxOpticStudio 13 software to model the solar concentrator, identifying the optimal cell configuration to achieve a geometric concentration ratio of 3.45, with angular selectivity ranging from 23° to 90°. This research contributes significantly to the field of solar concentrator technology, offering a pathway for more efficient utilization of renewable energy sources and improved adaptability to diverse operating conditions. Full article

Repeatable and reliable assessment of corneal biomechanics with spatial resolution remains a challenge. Vibrational Optical Computerized Tomography (V-OCT), based on sound-wave elastography, has made it possible to investigate the natural resonant modes of the cornea and obtain the elastic moduli non-invasively. This pilot study presents a characterization of four corneal vibrational modes from aberrometric, geometrical, and biomechanical approaches in the living human cornea of five healthy volunteers by combining a corneal sound-wave generator, dual Placido–Scheimpflug corneal imaging, and the Ocular Response Analyzer (ORA) devices. Sound-induced corneal wavefront aberration maps were reconstructed as a function of sound frequency and isolated from the natural state. While maps of low-order aberrations (LOA) revealed symmetric geometrical patterns, those corresponding to high-order aberrations (HOA) showed complex non-symmetric patterns. Corneal geometry was evaluated by reconstructing corneal elevation maps through biconical fitting, and the elastic and viscous components were calculated by applying the standard linear solid model to the ORA measurements. The results showed that sound-wave modulation can increase high-order corneal aberrations significantly. Two frequencies rendered the corneal shape more prolate (50 Hz) and oblate (150 Hz) with respect to the baseline, respectively. Finally, both the elastic and viscous properties are sensitive to sound-induced vibrational modes, which can also modulate the corneal stress-strain response. The cornea exhibits natural resonant modes influenced by its optical, structural, and biomechanical properties. Full article

The study of the refractive index of traditional lenses is one of the foundational topics in the field of optics. The refractive index of a lens determines its ability to refract and focus light, making it a key parameter in optical design and applications. For the measurement of the refractive index of blind samples of finished lenses, this paper proposes a measurement method based on the use of a focal length measuring instrument and an aspheric profilometer to measure the surface shape data of the front and back surfaces of the lens. This method combines curve fitting algorithms and curvature radius fitting algorithms, ultimately reconstructing the lens model using Zemax and back-calculating the refractive index of the lens. For the samples employed in this paper, the measurement accuracy of the focal length can achieve 1.06%, the fitting accuracy of the curvature radius can reach 0.138%, and the recovery accuracy of the refractive index can attain 6.303 × 10⁻⁴%. Full article

In this paper, a high-linear-sensitivity fiber curvature sensor based on the sphere-shaped misaligned structure (SSMS) with few-mode fiber (FMF) and single-mode fiber (SMF) was proposed and demonstrated. A spherical structure was prepared at one end of a few-mode fiber, which could effectively excite higher-order modes and generate interference in the misaligned cascade. When external environmental parameters changed, the resonance peaks formed by intermodal interference were displaced, and the shifts generated by different resonant peaks were also different. The experimental results show that the maximum curvature sensitivity was −2.220 nm/m⁻¹, and the linear fitting coefficient reached up to 0.991, which is an extremely high sensitivity among wavelength-modulated curvature sensors. Meanwhile, the strain sensitivity of the sensor was as low as 7.99 pm/μ$\overline{\mathsf{\epsilon }}$, and the temperature sensitivity was 3.958 pm/°C, which is a low temperature sensitivity and low strain sensitivity, and solves the cross-sensitivity problem. With advantages of simple manufacture, low cost, and favorable stability, the sensor is expected to be one of the best candidate instruments for measuring curvature and inclination. Full article

Time synchronization is an important technology in synchronous communication systems to ensure the accuracy of data transmission. Precise time synchronization allows the receiver to correctly interpret the signal at the correct moment. However, as communication rates increase and application scenarios diversify, pulse signal reception quality is often affected by factors such as noise interference and clock stability. In order to address these challenges, we propose a pulse signal recovery method utilizing the least squares algorithm to complete time compensation. By fitting and optimizing the received signal, we can obtain estimated values that closely approximate the actual time, thereby achieving enhanced precision in time synchronization. The results demonstrate that this method effectively reduces estimation errors, improving the system’s time synchronization accuracy to the $ns$ level. This method not only provides an effective solution for enhancing time synchronization precision but also lays the foundation for time synchronization performance in the future. Full article

Pork adulteration detection in beef is important due to health, economic, and religious concerns. This study explored the use of a Shortwave Near Infrared–Hyperspectral Imaging (SWNIR–HSI) system which captured spectral data across 894–2504 nm to detect adulteration of pork in beef. In this study, minced pork in various concentrations ranging from 0–50% (w/w) were added to pure minced beef. Spectra obtained from the SWNIR–HSI were used to develop a partial least square regression (PLSR) model. The study compared the PLSR results between full wavelengths (variables) and selected wavelengths obtained via the variable importance in projection (VIP) method. The best results from the full-wavelength PLSR model yielded a prediction accuracy (R²P) of 0.940 and a standard error of prediction (SEP) of 4.633%, while using VIP-selected wavelengths improved performance, with R²P of 0.955 and SEP of 3.811%. The study demonstrates the potency of SWNIR–HIS, particularly with selected wavelengths, as an effective and nondestructive tool for accurately predicting pork adulteration levels in beef. Full article