Hydrogen, Volume 6, Issue 2 (June 2025) – 5 articles

This study explores hydrogen’s potential as a sustainable energy source for Brunei, given the nation’s reliance on fossil fuels and associated environmental concerns. Specifically, it evaluates two hydrogen production technologies; steam methane reforming (SMR) and alkaline water electrolysis (AWE), through a techno-economic framework that assesses life cycle cost (LCC), efficiency, scalability, and environmental impact. SMR, the most widely used technique, is cost-effective but carbon-intensive, producing considerable carbon dioxide emissions unless combined with carbon capture to yield “blue hydrogen”. On the other hand, AWE, particularly when powered by renewable energy, offers a cleaner alternative despite challenges in efficiency and cost. The assessment revealed that AWE has a significantly higher LCC than SMR, making AWE the more economically viable hydrogen production method in the long term. A sensitivity analysis was also conducted to determine the main cost factors affecting the LCC, providing insights into the long term viability of each technology from an operational and financial standpoint. AWE’s economic viability is mostly driven by the high electricity and feedstock costs, while SMR relies heavily on feedstock costs. However, Environmental Impact Analysis (EIA) indicates that AWE produces significantly higher carbon dioxide emissions than SMR, which emits approximately 9100 metric tons of carbon dioxide annually. Nevertheless, findings suggest that AWE remains the more sustainable option due to its higher LCC costs and compatibility with renewable energy, especially in regions with access to low-cost renewable electricity. Full article

Efficient hydrogen storage is critical for advancing hydrogen-based technologies. This study investigates the effects of pressure and surface area on hydrogen storage in three carbon-based materials: graphite, graphene oxide, and reduced graphene oxide. Hydrogen adsorption–desorption experiments under pressures ranging from 1 to 9 bar revealed nonlinear storage capacity responses, with optimal performance at around 5 bar. The specific surface area plays a pivotal role, with reduced graphene oxide and exhibiting a surface area of 70.31 m²/g, outperforming graphene oxide (33.75 m²/g) and graphite (7.27 m²/g). Reduced graphene oxide achieved the highest hydrogen storage capacity, with 768 sccm and a 3 wt.% increase over the other materials. In assessing proton-exchange fuel cell performance, this study found that increased hydrogen storage correlates with enhanced power density, with reduced graphene oxide reaching a maximum of 0.082 W/cm², compared to 0.071 W/cm² for graphite and 0.017 W/cm² for graphene oxide. However, desorption rates impose temporal constraints on fuel cell operation. These findings enhance our understanding of pressure–surface interactions and underscore the balance between hydrogen storage capacity, surface area, and practical performance in carbon-based materials, offering valuable insights for hydrogen storage and fuel cell applications. Full article

Green hydrogen production is emerging as a crucial component in global decarbonization efforts. This review focuses on the role of computational approaches and artificial intelligence (AI) in optimizing green hydrogen technologies. Key approaches to improving electrolyzer efficiency and scalability include computational fluid dynamics (CFD), thermodynamic modeling, and machine learning (ML). As an instance, CFD has achieved over 95% accuracy in estimating flow distribution and polarization curves, but AI-driven optimization can lower operational expenses by up to 24%. Proton exchange membrane electrolyzers achieve efficiencies of 65–82% at 70–90 °C, but solid oxide electrolyzers reach up to 90% efficiency at temperatures ranging from 650 to 1000 °C. According to studies, combining renewable energy with hydrogen production reduces emissions and improves grid reliability, with curtailment rates of less than 1% for biomass-driven systems. This integration of computational approaches and renewable energy ensures a long-term transition to green hydrogen while also addressing energy security and environmental concerns. Full article

The operational performance of proton exchange membrane fuel cells (PEMFC) is highly influenced by temperature, making effective thermal management essential. However, the multivariate coupling between pumps and radiators presents significant control challenges. To address this issue, a dual DDPG-PID control strategy is proposed, integrating temperature and flow rate variations to enhance system stability and response. Simulation results demonstrate that the proposed method significantly reduces temperature control errors and improves response time compared to conventional PID-based strategies. Specifically, the D-DDPG PID achieves a temperature error reduction of up to 75.4% and shortens the average tuning time by up to 25.6% compared to PSO-PID. Furthermore, the strategy optimizes cooling system performance, demonstrating its effectiveness in PEMFC thermal management. Full article

The challenge of achieving net-zero CO₂ emissions will require a significant scaling up of the production of several raw materials that are critical for decarbonizing the global economy. In contrast, metal extraction processes utilize carbon as a reducing agent, which is oxidized to CO₂, resulting in considerable emissions and having a negative impact on climate change. In order to abate their emissions, extractive industries will have to go through a profound transformation, including switching to alternative climate-neutral energy and feedstock sources. This paper presents the authors’ perspectives for consideration in relation to the H₂ potential for direct reduction of oxide and sulfide ores. For each case scenario, the reduction of CO₂ emissions is analyzed, and a breakthrough route for H₂S decomposition is presented, which is a by-product of the direct reduction of sulfide ores with H₂. Electrified indirect-fired metallurgical kiln advantages are also presented, a solution that can substitute fossil fuel-based heating technologies, which is one of the main backbones of industrial processes currently applied to the extractive industries. Full article