Metrology, Volume 1, Issue 2 (December 2021) – 6 articles

This paper considers a future scenario in which digital reporting of measurement results is ubiquitous and digital calibration certificates (DCCs) contain information about the components of uncertainty in a measurement result. The task of linking international measurement comparisons is used as a case study to look at the benefits of digitalization. Comparison linking provides a context in which correlations are important, so the benefit of passing a digital record of contributions to uncertainty along a traceability chain can be examined. The International Committee for Weights and Measures (CIPM) uses a program of international “key comparisons” to establish the extent to which measurements of a particular quantity may be considered equivalent when made in different economies. To obtain good international coverage, the results of the comparisons may be linked together: a number of regional metrology organization (RMO) key comparisons can be linked back to an initial CIPM key comparison. Specific information about systematic effects in participants’ results must be available during linking to allow correct treatment of the correlations. However, the conventional calibration certificate formats used today do not provide this: participants must submit additional data, and the report of an initial comparison must anticipate the requirements for future linking. Special handling of additional data can be laborious and prone to error. An uncertain-number digital reporting format was considered in this case study, which caters to all the information required and would simplify the comparison analysis, reporting, and linking; the format would also enable a more informative presentation of comparison results. The uncertain-number format would be useful more generally, in measurement scenarios where correlations arise, so its incorporation into DCCs should be considered. A full dataset supported by open-source software is available. Full article

A simple method that reproducibly creates validation/reference materials for comparison of methods that measure the carbonaceous content of atmospheric particulate matter deposited on filter media at concentrations relevant to atmospheric levels has been developed and evaluated. Commonly used methods to determine the major carbonaceous components of particles collected on filters include optical attenuation for “Black” (BC) and “Brown” (BrC) carbon, thermal-optical analysis (TOA) for “Elemental” (EC) and “Organic” (OC) carbon, and total combustion for “Total” carbon (TC). The new method uses a commercial inkjet printer to deposit ink containing both organic and inorganic components onto filter substrates at programmable print densities (print levels, as specified by the printer–software combination). A variety of filter media were evaluated. The optical attenuation (ATN) of the deposited sample was determined at 880 nm and 370 nm. Reproducibility or precision (as standard deviation or in percent as coefficient of variation) in ATN for Teflon-coated glass-fiber, Teflon, and cellulose substrates was better than 5%. Reproducibility for other substrates was better than 15%. EC and OC measured on quartz-fiber filters (QFF) compared to ATN measured at 880 nm and 370 nm on either QFF or Teflon-coated glass-fiber yielded R² > 0.92 and >0.97, respectively. Four independent laboratories participated in a round robin study together with the reference laboratory. The propagated standard deviation among the five groups across all print levels was <2.2 ATN at 880 nm and <2.7 ATN at 370 nm with a coefficient of variation of <2% at ~100 ATN. Full article

Three-dimensional transfer functions (3D TFs) are generally assumed to fully describe the transfer behavior of optical topography measuring instruments such as coherence scanning interferometers in the spatial frequency domain. Therefore, 3D TFs are supposed to be independent of the surface under investigation resulting in a clear separation of surface properties and transfer characteristics. In this paper, we show that the 3D TF of an interference microscope differs depending on whether the object is specularly reflecting or consists of point scatterers. In addition to the 3D TF of a point scatterer, we will derive an analytical expression for the 3D TF corresponding to specular surfaces and demonstrate this as being most relevant in practical applications of coherence scanning interferometry (CSI). We additionally study the effects of temporal coherence and disclose that in conventional CSI temporal coherence effects dominate. However, narrowband light sources are advantageous if high spatial frequency components of weak phase objects are to be resolved, whereas, for low-frequency phase objects of higher amplitude, the temporal coherence is less affecting. Finally, we present an approach that explains the different transfer characteristics of coherence peak and phase detection in CSI signal analysis. Full article

Determining the solute mass amount in seawater using in situ measurements in seas and oceans is currently an unresolved problem. To solve it, it is necessary to develop both new methods and instruments for measurements. The authors of this article analyzed methods for the indirect measurement of salinity and density using parameters that can be measured in situ, including relative electrical conductivity, speed of sound, temperature, and hydrostatic pressure. The authors propose an electric conductivity sensor design that allows for the obtainment of data on solid suspensions along with measuring the impedance of electrodes under various the alternating current frequencies. The authors analyzed the joint measurement technique using the Conductivity-Temperature-Depth (CTD) and Sound Velocity Profiler (SVP) devices in a marine testing area. Based on the results of joint measurements, the authors present tests of water samples of various salt compositions for the presence of solid suspensions. Full article

In this paper, we consider the calibration of measuring bridges for non-conventional instrument transformers with digital output. In this context, the main challenge is represented by the necessity of synchronization between analog and digital outputs. To this end, we propose a measurement setup that allows for monitoring and quantifying the main quantities of interest. A possible laboratory implementation is presented and the main sources of uncertainty are discussed. From a metrological point of view, technical specifications and statistical analysis are employed to draw up a rigorous uncertainty budget of the calibration setup. An experimental validation is also provided through the thorough characterization of the measurement accuracy of a commercial device in use at METAS laboratories. The proposed analysis proves how the calibration of measuring bridges for non-conventional instrument transformers requires ad hoc measurement setups and identifies possible space for improvement, particularly in terms of outputs’ synchronization and flexibility of the generation process. Full article

The concept of measurement uncertainty was introduced in the 1990s by the “Guide to the expression of uncertainty in measurement”, known as GUM. The word uncertainty has a lexical meaning and reflects the lack of exact knowledge or lack of complete knowledge about the value of the measurand. Thanks to the suggestions in the GUM and following the mathematical probabilistic approaches therein proposed, an uncertainty value can be found and be associated to the measured value. In the last decades, however, other methods have been proposed in the literature, which try to encompass the definitions of the GUM, thus overcoming its limitations. Some of these methods are based on the possibility theory, such as the one known as the RFV method. The aim of this paper is to briefly recall the RFV method, starting from the very beginning and the initial motivations, and summarize in a unique paper the most relevant obtained results. Full article