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Mid-Infrared and THz Spectroscopy: Innovative Tools and Applications

A special issue of Applied Sciences (ISSN 2076-3417). This special issue belongs to the section "Applied Physics General".

Deadline for manuscript submissions: closed (15 September 2021) | Viewed by 8325

Special Issue Editors


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Guest Editor
Agenzia Spaziale Italiana, Contrada Terlecchia snc, I-75100 Matera, MT, Italy
Interests: near-/mid-infrared laser sources; frequency metrology; whispering gallery mode resonators; comb spectroscopy; mid-infrared quantum cascade lasers; photoacoustic spectroscopy; quantum technologies
Special Issues, Collections and Topics in MDPI journals

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Guest Editor
Istituto Nazionale di Ottica CNR, Via Nello Carrara 1, I-50019 Sesto Fiorentino FI, Italy
Interests: high sensitivity and precision THz spectroscopy; high-finesse THz resonant cavities; synthesis of terahertz frequencies by optical frequency mixing; THz quantum cascade lasers; THz frequency metrology; dual comb spectroscopy

Special Issue Information

Dear Colleagues,

One of the most challenging struggles in photonics in recent decades has been the realization of high-performance infrared spectrometers, in particular in the mid-infrared (mid-IR) and THz ranges of the electromagnetic spectrum. In fact, these regions are crucial for gas-phase laser spectroscopy: in the mid-IR the linestrength of absorption lines is generally larger with respect to the near-infrared, while Doppler linewidths linearly decrease with increasing wavelength. This becomes even more important in the THz range, where molecular spectroscopy has proven an amazing scientific potential.

In these two spectral domains, many chemical species have very strong characteristic vibrational, rotational, and ro-vibrational transitions, which why they are commonly addressed as molecular fingerprint regions. The laser spectroscopy of molecular gas samples is playing a significant role both in attractive fundamental research (i.e., time variation of fundamental constants, the search for hypothetical long-range fifth forces between hadrons, detection of parity violation, test of quantum electro-dynamics models) and in real-world applications, spanning from environmental monitoring to health care, from food adulteration testing to homeland security.

The present Special Issue is dedicated to state-of-the-art laser spectrometers in the mid-IR and THz range, including smart techniques and new theoretical and experimental approaches for gas-phase molecular spectroscopy. Particular interest will be given to innovative tools for spectroscopy in such spectral regions, including but not limited to emerging photonic technologies, novel and improved sources, non-linear crystals, supercontinuum sources, waveguides, resonators, hollow core fibers, novel and improved detectors, high-performance resonant cavities, electro-optic devices, and metamaterials. Finally, a focal point will be the latest advances in mid-IR and THz frequency metrology, by using consolidated or emerging frequency comb synthesizers (i.e., microresonators, quantum cascade lasers, or quadratic combs).

Dr. Mario Siciliani de Cumis
Dr. Luigi Consolino
Guest Editors

Manuscript Submission Information

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Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Applied Sciences is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2400 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • mid-IR and THz spectroscopic techniques
  • mid-IR and THz sources
  • mid-IR and THz detectors
  • frequency combs
  • hollow core fibers
  • non-linear crystals
  • mid-IR and THz waveguides
  • mid-IR and THz devices
  • microresonators
  • dual comb spectroscopy

Published Papers (3 papers)

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Research

12 pages, 3459 KiB  
Article
Direct Observation of Terahertz Frequency Comb Generation in Difference-Frequency Quantum Cascade Lasers
by Luigi Consolino, Malik Nafa, Michele De Regis, Francesco Cappelli, Saverio Bartalini, Akio Ito, Masahiro Hitaka, Tatsuo Dougakiuchi, Tadataka Edamura, Paolo De Natale and Kazuue Fujita
Appl. Sci. 2021, 11(4), 1416; https://doi.org/10.3390/app11041416 - 4 Feb 2021
Cited by 17 | Viewed by 2631
Abstract
Terahertz quantum cascade laser sources based on intra-cavity difference frequency generation from mid-IR devices are an important asset for applications in rotational molecular spectroscopy and sensing, being the only electrically pumped device able to operate in the 0.6–6 THz range without the need [...] Read more.
Terahertz quantum cascade laser sources based on intra-cavity difference frequency generation from mid-IR devices are an important asset for applications in rotational molecular spectroscopy and sensing, being the only electrically pumped device able to operate in the 0.6–6 THz range without the need of bulky and expensive liquid helium cooling. Here we present comb operation obtained by intra-cavity mixing of a distributed feedback laser at λ = 6.5 μm and a Fabry–Pérot device at around λ = 6.9 μm. The resulting ultra-broadband THz emission extends from 1.8 to 3.3 THz, with a total output power of 8 μW at 78 K. The THz emission has been characterized by multi-heterodyne detection with a primary frequency standard referenced THz comb, obtained by optical rectification of near infrared pulses. The down-converted beatnotes, simultaneously acquired, confirm an equally spaced THz emission down to 1 MHz accuracy. In the future, this setup can be used for Fourier transform based evaluation of the phase relation among the emitted THz modes, paving the way to room-temperature, compact, and field-deployable metrological grade THz frequency combs. Full article
(This article belongs to the Special Issue Mid-Infrared and THz Spectroscopy: Innovative Tools and Applications)
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14 pages, 5939 KiB  
Article
Silicon-Based Multilayer Waveguides for Integrated Photonic Devices from the Near to Mid Infrared
by Iñaki López García, Mario Siciliani de Cumis, Davide Mazzotti, Iacopo Galli, Pablo Cancio Pastor and Paolo De Natale
Appl. Sci. 2021, 11(3), 1227; https://doi.org/10.3390/app11031227 - 29 Jan 2021
Viewed by 2378
Abstract
Advancements in spectroscopy, quantum optics, communication, and sensing require new classes of integrated photonic devices to host a wide range of non-linear optical processes involving wavelengths from the visible to the infrared. In this framework, waveguide (WG) structures designed with innovative geometry and [...] Read more.
Advancements in spectroscopy, quantum optics, communication, and sensing require new classes of integrated photonic devices to host a wide range of non-linear optical processes involving wavelengths from the visible to the infrared. In this framework, waveguide (WG) structures designed with innovative geometry and materials can play a key role. We report both finite element modeling and experimental characterization of silicon nitride multilayer WGs from the visible to the mid-infrared spectral regions. The simulations evaluated optical behavior and mechanical stress as a function of number of WG layers and photonic structure dimensions. WGs were optimized for waveguiding at 1550 nm and 2640 nm. Experimental characterization focused on optical behavior and coupling losses from 532 nm to 2640 nm. Measured losses in WGs indicate a quasi-perfect waveguiding behavior in the IR range (with losses below 6 dB), with a relevant increase (up to 20 dB) in the visible range. Full article
(This article belongs to the Special Issue Mid-Infrared and THz Spectroscopy: Innovative Tools and Applications)
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9 pages, 1185 KiB  
Article
A Mid-Infrared Narrowband Absorber Based on a Subwavelength Fine-Structured Silicon–Gold Metagrating
by Xin He, Jinliang Jie, Junbo Yang, Yunxin Han and Sen Zhang
Appl. Sci. 2019, 9(23), 5022; https://doi.org/10.3390/app9235022 - 21 Nov 2019
Cited by 8 | Viewed by 2371
Abstract
A subwavelength fine-structured silicon–gold metagrating was designed for realizing mid-infrared (mid-IR) narrowband absorbers. The metagrating consisted of a silicon grating on the stack of a gold film and a quartz substrate. The silicon grating consisted of two periodically arranged silicon strips in each [...] Read more.
A subwavelength fine-structured silicon–gold metagrating was designed for realizing mid-infrared (mid-IR) narrowband absorbers. The metagrating consisted of a silicon grating on the stack of a gold film and a quartz substrate. The silicon grating consisted of two periodically arranged silicon strips in each unit cell. The numerical results reveal that perfect absorption of the traverse-magnetic (TM) polarized light at a wavelength of 4.071 μm can be achieved, with an absorption rate of ~99.2% and an absorption full-width at half-maximum (FWHM) bandwidth of ~31 nm. Thus, the proposed structure is useful for the spectral control of mid-IR signals. When used as a refractive index sensor, the structure has a measuring range of 1.0–2.0 with a quasi linear response, with a figure of merit (FOM) of ~103. Full article
(This article belongs to the Special Issue Mid-Infrared and THz Spectroscopy: Innovative Tools and Applications)
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