Catalytic Reforming and Hydrogen Production: From the Past to the Future

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Industrial Catalysis".

Deadline for manuscript submissions: 31 August 2024 | Viewed by 1191

Special Issue Editors


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Guest Editor
School of Environmental Engineering, Technical University of Crete, GR-73100 Chania, Greece
Interests: methane production; catalyst; synthesis gas; hydrogen production; steam reforming; WGS reaction
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Guest Editor
Department of Chemical and Biological Engineering, University at Buffalo, The State University of New York, Buffalo, NY 14260, USA
Interests: heterogeneous catalysis; nanoparticle synthesis; surface science; catalysts; environmental processes

Special Issue Information

Dear Colleagues,

The Special Issue is dedicated to the exploration of catalytic reforming and hydrogen production, delving into a journey starting in the past of these processes and ending in their future applications. The catalytic reforming of light hydrocarbons stands out as a prominent technique for generating valuable products like synthesis gas. Syngas, a crucial intermediary substance in the creation of hydrogen, ammonia, methanol, and synthetic hydrocarbon fuels, holds significant potential for fostering a cleaner, more sustainable energy environment. Furthermore, through advancements in catalyst development, reactor designs, and process optimization strategies, hydrogen has emerged as a pivotal player in the global energy shift towards a more efficient and sustainable hydrogen economy.

This Special Issue aims to showcase the most recent research findings in heterogeneous catalysis concerning catalytic reforming and hydrogen production, assuming a future where clean energy takes center stage. We invite submissions in the form of original research papers or reviews that reflect the state of the art of this research area. Topics of interest include, but are not limited to, the following:

  • Methane conversion.
  • Dry reforming.
  • CO2 methanation.
  • Hydrogen production processes.
  • Water–gas shift (WGS) reaction.
  • Production of syngas.
  • Fischer–Tropsch synthesis.
  • Fuel cells.

Dr. Georgios Bampos
Dr. Paraskevi Panagiotopoulou
Dr. Eleni A. Kyriakidou
Guest Editors

Manuscript Submission Information

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Keywords

  • syngas
  • hydrogen production
  • steam reforming
  • CO2 methanation
  • water gas shift (WGS) reaction
  • fuels
  • clean energy
  • hydrocarbons to fuels
  • fuel cells

Published Papers (1 paper)

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Research

19 pages, 5418 KiB  
Article
Ni-Ag Catalysts for Hydrogen Production through Dry Reforming of Methane: Characterization and Performance Evaluation
by Hayat Henni, Rafik Benrabaa, Pascal Roussel and Axel Löfberg
Catalysts 2024, 14(7), 400; https://doi.org/10.3390/catal14070400 - 25 Jun 2024
Viewed by 798
Abstract
To investigate the influence of Ag and the loading of Ni species, Ni-Ag type catalysts were synthesized with varying Ni/Ag ratios (1, 1.5 and 2) using the coprecipitation method. The catalysts were extensively characterized using various techniques such as TG-DSC-SM, XRD, ICP, BET, [...] Read more.
To investigate the influence of Ag and the loading of Ni species, Ni-Ag type catalysts were synthesized with varying Ni/Ag ratios (1, 1.5 and 2) using the coprecipitation method. The catalysts were extensively characterized using various techniques such as TG-DSC-SM, XRD, ICP, BET, SEM-EDX and TPR and subsequently tested in the CH4/CO2 reaction without any pretreatment. Regardless of the ratio employed, a phase mixture containing NiO and Ag was observed after calcination under air between 600 °C and 1200 °C. SEM analysis confirmed the presence of a close interface between Ag and NiO. The specific surface area was found to be significantly higher for the catalyst with lower Ni content (R = 1). TPR analysis demonstrated that the inclusion of Ag facilitated the reduction of Ni at lower temperatures. XRD analyses of the spent catalyst confirmed catalyst reduction during the reaction. Among the samples, a catalyst with Ni/Ag = 1 exhibited superior catalytic activity without any pretreatment under a reduction atmosphere, in which case the conversions of methane and CO2 at 650 °C amounted to 38 and 45 mol%, respectively, with H2/CO = 0.7 and 71 mol% of H2. The presence of Ag species enhances the stability of the Ni catalyst and improves catalytic performance in the dry reforming of methane. Full article
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