Journal Description
Ceramics
Ceramics
is an international, peer-reviewed, open access journal of ceramics science and engineering, published quarterly online by MDPI.
- Open Access— free for readers, with article processing charges (APC) paid by authors or their institutions.
- High Visibility: indexed within Scopus, ESCI (Web of Science), and other databases.
- Journal Rank: JCR - Q2 (Materials Science, Ceramics) / CiteScore - Q2 (Materials Science (miscellaneous))
- Rapid Publication: manuscripts are peer-reviewed and a first decision is provided to authors approximately 19.6 days after submission; acceptance to publication is undertaken in 3.7 days (median values for papers published in this journal in the first half of 2025).
- Recognition of Reviewers: reviewers who provide timely, thorough peer-review reports receive vouchers entitling them to a discount on the APC of their next publication in any MDPI journal, in appreciation of the work done.
Impact Factor:
2.0 (2024);
5-Year Impact Factor:
2.3 (2024)
Latest Articles
Barium Strontium Titanate: Comparison of Material Properties Obtained via Solid-State and Sol–Gel Synthesis
Ceramics 2025, 8(4), 126; https://doi.org/10.3390/ceramics8040126 - 4 Oct 2025
Abstract
Barium strontium titanates (Ba1−xSrxTiO3, BST) with varying barium-to-strontium ratios were synthesized by the solid-state route (SSR) as well as by the sol–gel process (SGP). In the case of the SSR, the strontium amount x was varied from
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Barium strontium titanates (Ba1−xSrxTiO3, BST) with varying barium-to-strontium ratios were synthesized by the solid-state route (SSR) as well as by the sol–gel process (SGP). In the case of the SSR, the strontium amount x was varied from 0.0 to 0.25 in 0.05 steps, due to the enhanced synthetic effort, and in the case of the SGP, x was set only to 0.05, 0.15, and 0.25. The resulting properties after synthesis, calcination, and sintering, like particle size distribution, specific surface area, particle morphology, and crystalline phase were characterized. The expected tetragonal phase, free from any remarkable impurity, was found in all cases, and irrespective of the selected synthesis method. Pressed pellets were used for the measurement of the temperature and frequency-dependent relative permittivity enabling the estimation of the Curie temperatures of all synthesized BSTs. Irrespective of the selected synthesis method, the obtained Curie temperature drops with increasing strontium content to almost identical values, e.g., in the case of x = 0.15, a Curie temperature range 95–105 °C was measured. Thin BST films could be deposited on different substrate materials applying electrophoretic deposition in a good and reliable quality according to the Hamaker equation. The properties of the BSTs obtained by the simpler solid-state route are almost identical to the ones yielded by the more complex sol–gel process. In future, this result allows for a possible wider usage of BST perovskites for ferroelectric and piezoelectric devices due to the easy synthetic access by the solid-state route.
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(This article belongs to the Special Issue Advances in Electronic Ceramics, 2nd Edition)
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Impact of Thermal Cycling on the Vickers Microhardness of Dental CAD/CAM Materials: Greater Retention in Polymer-Infiltrated Ceramic Networks (PICNs) Compared to Nano-Filled Resin Composites
by
Jorge I. Fajardo, César A. Paltán, Marco León, Annie Y. Matute, Ana Armas-Vega, Rommel H. Puratambi, Bolívar A. Delgado-Gaete, Silvio Requena and Alejandro Benalcazar
Ceramics 2025, 8(4), 125; https://doi.org/10.3390/ceramics8040125 - 4 Oct 2025
Abstract
We synthesized the current evidence from the literature and conducted a 2 × 3 factorial experiment to quantify the impact of thermocycling on the Vickers microhardness (HV) of dental CAD/CAM materials: VITA ENAMIC (VE, polymer-infiltrated ceramic network) and CERASMART (CS, nanofilled resin-matrix). Sixty
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We synthesized the current evidence from the literature and conducted a 2 × 3 factorial experiment to quantify the impact of thermocycling on the Vickers microhardness (HV) of dental CAD/CAM materials: VITA ENAMIC (VE, polymer-infiltrated ceramic network) and CERASMART (CS, nanofilled resin-matrix). Sixty polished specimens (n = 10 per Material × Cycles cell; 12 × 2 × 2 mm) were thermocycled at 5–55 °C (0, 10,000, 20,000 cycles; 30 s dwell, ≈10 s transfer) and tested as HV0.3/10 (300 gf, 10 s; five indentations/specimen with standard spacing). Assumptions regarding the model residuals were met (Shapiro–Wilk W ≈ 0.98, p ≈ 0.36; Levene F(5,54) ≈ 1.12, p ≈ 0.36), so a two-way ANOVA (Type II) with Tukey’s HSD post hoc (α = 0.05) was applied. VE maintained consistently higher HV than CS at all cycle levels and showed a smaller drop from baseline: VE (mean ± SD): 200.2 ± 10.8 (0), 192.4 ± 13.9 (10,000), and 196.7 ± 9.3 (20,000); CS: 60.8 ± 6.1 (0), 53.4 ± 4.7 (10,000), and 62.1 ± 3.8 (20,000). ANOVA revealed significant main effects from the material (η2p = 0.972) and cycles (η2p = 0.316), plus a Material × Cycles interaction (η2p = 0.201). Results: Thermocycling produced material-dependent changes in microhardness. Relative to baseline, VE varied by −3.9% (10,000) and −1.7% (20,000), while CS varied by −12.2% (10,000) and +2.1% (20,000); from 10,000→20,000 cycles, microhardness recovered by +2.2% (VE) and +16.3% (CS). Pairwise comparisons were consistent with these trends (CS decreased at 10,000 vs. 0 and recovered at 20,000; VE only showed a modest change). Conclusions: Thermocycling effects were material-dependent, with smaller losses and better retention in VE (PICN) than in CS. These results align with the literature (resin-matrix/hybrids are more sensitive to thermal aging; polished finishes mitigate losses). While HV is only one facet of performance, the superior retention observed in PICN under thermal challenge suggests the improved preservation of superficial integrity; standardized reporting of aging parameters and integration with wear, fatigue, and adhesion outcomes are recommended to inform indications and longevity.
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(This article belongs to the Special Issue Advances in Ceramics, 3rd Edition)
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Enhanced Transdermal Delivery via Electrospun PMMA Fiber Mats Incorporating Ibuprofen-Intercalated Layered Double Hydroxides
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Van Thi Thanh Tran, Shusei Yamashita, Hideaki Sano, Osamu Nakagoe, Shuji Tanabe and Kai Kamada
Ceramics 2025, 8(4), 124; https://doi.org/10.3390/ceramics8040124 - 4 Oct 2025
Abstract
This study reports the development of electrospun poly(methyl methacrylate) (PMMA) fiber mats incorporating ibuprofen (IBU)-intercalated layered double hydroxides (LDH) for enhanced transdermal drug delivery systems (TDDS). IBU, in its anionic form, was successfully intercalated into LDH, which possesses anion exchange capabilities, and subsequently
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This study reports the development of electrospun poly(methyl methacrylate) (PMMA) fiber mats incorporating ibuprofen (IBU)-intercalated layered double hydroxides (LDH) for enhanced transdermal drug delivery systems (TDDS). IBU, in its anionic form, was successfully intercalated into LDH, which possesses anion exchange capabilities, and subsequently embedded into PMMA fibers via electrospinning. In vitro drug release experiments demonstrated that UPMMA–LDH–IBU fibers exhibited significantly higher IBU release than PMMA–IBU controls. This enhancement was attributed to the improved hydrophilicity and water absorption imparted by the LDH, as confirmed by contact angle and water uptake measurements. Furthermore, artificial skin permeation tests revealed that the UPMMA–LDH–IBU fibers maintained comparable release rates to those observed during buffer immersion, indicating that the rate-limiting step was the diffusion of IBU within the fiber matrix rather than the interface with the skin or buffer. These findings highlight the critical role of LDH in modulating drug release behavior and suggest that UPMMA–LDH–IBU electrospun fiber mats offer a promising and efficient platform for advanced TDDS applications.
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(This article belongs to the Special Issue Ceramics Containing Active Molecules for Biomedical Applications)
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Time-Dependent Piranha Solution Treatment as an Alternative to Sandblasting for Improving Zirconia–Resin Cement Bond Strength
by
Apichai Maneenacarith, Nantawan Krajangta, Thanasak Rakmanee and Awiruth Klaisiri
Ceramics 2025, 8(4), 123; https://doi.org/10.3390/ceramics8040123 - 2 Oct 2025
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This study investigated the effect of piranha solution etching duration on the shear bond strength of zirconia ceramics bonded to resin cement, comparing it to conventional sandblasting treatment. Fifty fully sintered zirconia specimens (6.0 mm diameter, 4.0 mm thickness) were prepared and randomly
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This study investigated the effect of piranha solution etching duration on the shear bond strength of zirconia ceramics bonded to resin cement, comparing it to conventional sandblasting treatment. Fifty fully sintered zirconia specimens (6.0 mm diameter, 4.0 mm thickness) were prepared and randomly divided into five groups (n = 10): sandblasting control and piranha solution treatment for 1, 2, 3, and 4 min. Piranha solution was prepared by mixing 98% H2SO4 and 35% H2O2 in a 3:1 ratio. All specimens were bonded to resin composite cylinders using dual-cure resin cement. Shear bond strength testing was performed using a universal testing machine at a 0.5 mm/min crosshead speed. Failure modes were analyzed using a stereomicroscope and classified as adhesive, cohesive, or mixed failures. One-way ANOVA revealed significant differences between groups (p < 0.05). Tukey’s post hoc test showed that 1-min piranha treatment produced significantly lower bond strength (7.64 ± 2.02 MPa) compared to all other groups. The 2-min (15.17 ± 2.79 MPa), 3-min (14.99 ± 3.27 MPa), and 4-min (18.34 ± 3.15 MPa) piranha treatments showed no significant differences compared to sandblasting (15.41 ± 2.61 MPa). Failure mode analysis revealed 100% adhesive failures for the 1-min group, while all other groups showed 80% adhesive and 20% mixed failures. Piranha solution treatment duration significantly affected zirconia bonding performance. While 1-min treatment proved inadequate, 2–4 min treatments achieved bond strengths comparable to sandblasting. The findings suggest that piranha solution treatment for 2–4 min represents a viable alternative to sandblasting for zirconia surface preparation, with the 2-min protocol being the most efficient choice for clinical application.
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The Effect of Low-Grade Hydrothermal Aging on the Shade Stability of Monolithic CAD/CAM Dental Ceramic Restorations
by
Mohammad Zaki Daoud, Layla A. Abu-Naba’a and Rami Al Fodeh
Ceramics 2025, 8(4), 122; https://doi.org/10.3390/ceramics8040122 - 28 Sep 2025
Abstract
Translucency and color stability are key factors for the long-term success of dental ceramics. The aim was to compare the translucency parameter (TP) and color stability (ΔE) of CAD/CAM ceramics, including a lithium disilicate (E; IPS e.max CAD), a zirconia-reinforced lithium-silicate (S; VitaSuprinity),
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Translucency and color stability are key factors for the long-term success of dental ceramics. The aim was to compare the translucency parameter (TP) and color stability (ΔE) of CAD/CAM ceramics, including a lithium disilicate (E; IPS e.max CAD), a zirconia-reinforced lithium-silicate (S; VitaSuprinity), and a zirconia-based ceramic (Z; Ceramill Zolid HT+), before and after low-grade hydrothermal aging (134 °C and 2 bars for 20 h). Ninety disks (n = 30/group, A2, 1.2 ± 0.02 mm) were fabricated and their L*, a*, and b* values were recorded against black and white backgrounds to calculate TP, contrast ratio (CR), and opacity (OP). ANOVA, Bonferroni post hoc, and paired t-tests (α = 0.05) showed that after aging, the Z group showed ↓L and ↑a values; the E group showed ↓L with ↑ a and b; and the S group showed only ↑a. All ceramics exhibited ΔE values below the clinical acceptability threshold of 3.7. E presented the highest TP, whereas Z demonstrated the highest CR and masking ability. Aging significantly increased CR and OP but did not alter TP. Within the limitations of this study, all tested ceramics maintained clinically acceptable shade stability and translucency, with E showing superior initial translucency and Z offering improved masking potential.
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(This article belongs to the Special Issue Preparation and Application of Transparent Ceramics)
Open AccessArticle
An Investigation of the Microstructure and Wear Resistance of Laser Clad 316 Stainless Steel/TiC Coatings Containing Different LaB6 Contents
by
Dongdong Zhang, Haozhe Li, Yu Liu, Jingyu Jiang and Yali Gao
Ceramics 2025, 8(4), 121; https://doi.org/10.3390/ceramics8040121 - 26 Sep 2025
Abstract
In this paper, 316 stainless steel/TiC coatings with different LaB6 contents (0%, 2%, 4%, 6%) were prepared on the surface of 45 steel by laser cladding technology. The effects of the LaB6 content on the phase composition, microstructure, microhardness, and wear
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In this paper, 316 stainless steel/TiC coatings with different LaB6 contents (0%, 2%, 4%, 6%) were prepared on the surface of 45 steel by laser cladding technology. The effects of the LaB6 content on the phase composition, microstructure, microhardness, and wear resistance of the coatings were studied. The results show that without the LaB6 addition, the coating is composed of Austenite and TiC phases, with defects such as pores and cracks, and the microstructure is mainly equiaxed grains. With the addition of LaB6, Fe-Cr phases are formed in the coating, and the microstructure transforms into columnar grains and dendritic grains. The grains are first refined and then coarsened, among which the coating with 4% LaB6 (C4) has the smallest grain size. The experimental results indicate that the microhardness of the coatings first increases and then decreases with the increase in the LaB6 content, and the C4 coating has the highest microhardness (594HV0.2). The wear rate shows the same variation trend. The C4 coating has the lowest wear rate and the best wear resistance. This is attributed to the synergistic effect of the fine grain strengthening and TiC particle dispersion strengthening.
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(This article belongs to the Special Issue Advances in Ceramics, 3rd Edition)
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Changes in Morphology Caused by Mass Transfer Phenomenon
by
Toshihiro Ishikawa
Ceramics 2025, 8(4), 120; https://doi.org/10.3390/ceramics8040120 - 24 Sep 2025
Abstract
The mass transfer phenomenon of contained impurities causes differences in the morphologies, densification processes, and heat resistance of ceramics. Of these, in this paper, differences in the heat resistance of ceramic fibers are discussed. Third-generation SiC polycrystalline fibers demonstrated excellent heat resistance. However,
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The mass transfer phenomenon of contained impurities causes differences in the morphologies, densification processes, and heat resistance of ceramics. Of these, in this paper, differences in the heat resistance of ceramic fibers are discussed. Third-generation SiC polycrystalline fibers demonstrated excellent heat resistance. However, at temperatures above 1800 °C, sintered fiber (Tyranno SA) and non-sintered fiber (Hi-Nicalon Type S) showed remarkable differences in heat resistance. At temperatures above 1800 °C, the non-sintered fiber underwent structural changes, including the formation of a surface carbon layer and abnormal SiC grain growth, whereas the sintered fiber maintained its stable polycrystalline structure. Until now, these differences and a detailed description of them have not been discussed. Here, we first explain the dramatic differences in heat resistance that occurred at high temperatures in relation to the mass transfer of excess carbon. Our findings should be widely used for the development of much more stable structures and for the long-term use of materials at higher temperatures in applications such as airplane engines and turbines.
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(This article belongs to the Special Issue Advances in Ceramics, 3rd Edition)
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Open AccessReview
Binary Oxide Ceramics (TiO2, ZnO, Al2O3, SiO2, CeO2, Fe2O3, and WO3) for Solar Cell Applications: A Comparative and Bibliometric Analysis
by
Yana Suchikova, Serhii Nazarovets, Marina Konuhova and Anatoli I. Popov
Ceramics 2025, 8(4), 119; https://doi.org/10.3390/ceramics8040119 - 23 Sep 2025
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Binary oxide ceramics have emerged as key materials in solar energy research due to their versatility, chemical stability, and tunable electronic properties. This study presents a comparative analysis of seven prominent oxides (TiO2, ZnO, Al2O3, SiO2
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Binary oxide ceramics have emerged as key materials in solar energy research due to their versatility, chemical stability, and tunable electronic properties. This study presents a comparative analysis of seven prominent oxides (TiO2, ZnO, Al2O3, SiO2, CeO2, Fe2O3, and WO3), focusing on their functional roles in silicon, perovskite, dye-sensitized, and thin-film solar cells. A bibliometric analysis covering over 50,000 publications highlights TiO2 and ZnO as the most widely studied materials, serving as electron transport layers, antireflective coatings, and buffer layers. Al2O3 and SiO2 demonstrate highly specialized applications in surface passivation and interface engineering, while CeO2 offers UV-blocking capability and Fe2O3 shows potential as an absorber material in photoelectrochemical systems. WO3 is noted for its multifunctionality and suitability for scalable, high-rate processing. Together, these findings suggest that binary oxide ceramics are poised to transition from supporting roles to essential components of stable, efficient, and environmentally safer next-generation solar cells.
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Research Progress on the Sintering Techniques of Zirconia in Prosthetic Dentistry
by
Chuyue Yang and Xiaoqiang Liu
Ceramics 2025, 8(3), 118; https://doi.org/10.3390/ceramics8030118 - 22 Sep 2025
Abstract
Zirconia is widely used in prosthodontics due to its excellent biocompatibility, mechanical properties, and esthetic characteristics. This article reviews the fundamentals of sintering zirconia for prosthodontic applications. Various sintering techniques, including conventional, spark plasma, high-speed, and microwave sintering, are discussed regarding their influence
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Zirconia is widely used in prosthodontics due to its excellent biocompatibility, mechanical properties, and esthetic characteristics. This article reviews the fundamentals of sintering zirconia for prosthodontic applications. Various sintering techniques, including conventional, spark plasma, high-speed, and microwave sintering, are discussed regarding their influence on translucency, strength, and microstructure. This review aims to provide a comprehensive reference for the sintering methods of zirconia currently used or may be used for dental prosthodontics.
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(This article belongs to the Special Issue Advances in Ceramics, 3rd Edition)
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First-Principles Calculation of Mechanical Properties and Thermal Conductivity of C-Doped AlN
by
Hongfei Shao, Ying Wang, Jiahe Song, Liwen Lei, Xia Liu, Xuejun Hou and Jinyong Zhang
Ceramics 2025, 8(3), 117; https://doi.org/10.3390/ceramics8030117 - 19 Sep 2025
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Due to its good thermal conductivity and small thermal expansion coefficient, aluminum nitride (AlN) is an excellent material for thermal shock resistance. Recently, carbon (C) doping has emerged as a potential strategy for tailoring the properties of AlN, but its effects on the
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Due to its good thermal conductivity and small thermal expansion coefficient, aluminum nitride (AlN) is an excellent material for thermal shock resistance. Recently, carbon (C) doping has emerged as a potential strategy for tailoring the properties of AlN, but its effects on the mechanical properties and thermal conductivity of AlN remain unclear. In the present study, the mechanical properties and thermal conductivity of C-doped AlN (C@AlN) with various C-doping densities were investigated using first-principles calculations based on density functional theory. The results suggest that C doping often leads to an increase in the c lattice constant. When the C-doping concentration reaches 12.5%, the structural symmetry of 4C@AlN is fully broken. In addition, as the C-doping density increases, the strength and stiffness of C@AlN generally decrease while the ductility increases. Moreover, the thermal conductivity of C@AlN generally decreases as the C-doping density increases, mainly because of the structural distortion. Meanwhile, as the C-doping density reaches 12.5%, the thermal conductivity of 4C@AlN anomalously increases, due to the symmetry breakage.
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Analysis of the Environmental Compatibility of the Use of Porcelain Stoneware Tiles Manufactured with Waste Incineration Bottom Ash
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Luigi Acampora, Giulia Costa, Iason Verginelli, Francesco Lombardi, Claudia Mensi and Simone Malvezzi
Ceramics 2025, 8(3), 116; https://doi.org/10.3390/ceramics8030116 - 19 Sep 2025
Abstract
In line with circular economy principles and the reduction of primary material exploitation, waste-to-energy (WtE) by-products such as bottom ash (BA) are increasingly being used as raw materials in cement and ceramics manufacturing. However, it is critical to verify that the final product
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In line with circular economy principles and the reduction of primary material exploitation, waste-to-energy (WtE) by-products such as bottom ash (BA) are increasingly being used as raw materials in cement and ceramics manufacturing. However, it is critical to verify that the final product presents not only adequate technical properties but also that it does not pose negative impacts to the environment and human health during its use. This study investigates the environmental compatibility of the use of ceramic porcelain stoneware tiles manufactured with BA as partial replacement of traditional raw materials, with a particular focus on the leaching behavior of the tiles during their use, and also after crushing to simulate their characteristics at their end of life. To evaluate the latter aspect, compliance leaching tests were performed on crushed samples and compared with Italian End-of-Waste (EoW) thresholds for the use of construction and demolition waste as recycled aggregates. Whereas, to assess the environmental compatibility of the tiles during the utilization phase, a methodology based on the application of monolithic leaching tests to intact tiles, and the evaluation of the results through multi-scenario human health risk assessment and the analysis of the main mechanisms governing leaching at different stages, was employed. The results of the study indicate that the analyzed BA-based tiles showed no significant increase in the release of potential contaminants compared to traditional formulations and fully complied with End-of-Waste criteria. The results of the monolith tests used as input for site-specific risk assessment, simulating worst-case scenarios involving the potential contamination of the groundwater, indicated negligible risks to human health for both types of tiles, even considering very conservative assumptions. As for differences in the release mechanisms, tiles containing BA exhibited a shift toward depletion-controlled leaching and some differences in early element release compared to the ones with a traditional formulation.
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(This article belongs to the Special Issue Ceramics in the Circular Economy for a Sustainable World)
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Quantitative Assessment of Ceramic Suspension Stability Using a LUMiSizer Analytical Centrifuge
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Patrik Sokola, Tina Skalar, Pavel Šiler, Jan Blahut, Michal Kalina, Peter Veteška and Petr Ptáček
Ceramics 2025, 8(3), 115; https://doi.org/10.3390/ceramics8030115 - 18 Sep 2025
Abstract
The stability of ceramic suspensions is a key factor in the preparation and shaping of ceramic bodies. The presented work offers an experimental determination of ceramics suspensions stability using the LUMiSizer analytical centrifuge, focusing on kinetic behaviour using transmission profiles and instability indexes.
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The stability of ceramic suspensions is a key factor in the preparation and shaping of ceramic bodies. The presented work offers an experimental determination of ceramics suspensions stability using the LUMiSizer analytical centrifuge, focusing on kinetic behaviour using transmission profiles and instability indexes. Multiple ceramic systems comprising corundum, metakaolin, and zirconia suspensions were experimentally examined under varying solid contents, dispersant dosages, and additive concentrations. Results showed that highly loaded corundum suspensions with dispersant (Dolapix CE64) achieved excellent stability, with an instability index below 0.05. Compared to classical sedimentation tests, which are time-consuming and not highly sensitive, LUMiSizer offers a suitable alternative by guaranteeing correct kinetic data and instability indexes indicating suspension behaviour using centrifugal force. Comparisons of the LUMiSizer results and data obtained using the modified Stokes law confirmed increased terminal velocities in experiments with metakaolin suspensions, indicating the sensitivity of the centrifuge to the effect of dispersion medium shape. The influence of porogen (waste coffee grounds) on the stability of corundum suspensions was also investigated, followed by slip casting to create and characterize a ceramic body, confirming the possibility of shaping based on stability results. Furthermore, instability indices are suggested as a rapid, quantitative method for comparing system stability and as an auxiliary criterion to the rheological measurements. Optimal dispersant concentration for zirconia-based photocurable suspensions was identified as 8.5 wt.%, which minimized viscosity and, at the same time, assured maximal kinetic stability. Integrating the LUMiSizer analytical centrifuge with standard methods, including sedimentation tests and rheological measurements, highlights its value as a powerful tool for characterizing and optimizing ceramic suspensions.
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(This article belongs to the Special Issue Advances in Ceramics, 3rd Edition)
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Compositional Effects on Mechanical Performance of Zirconia–Magnesia–Alumina Ceramics
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Rafael Shakirzyanov, Sofiya Maznykh, Yuriy Garanin and Malik Kaliyekperov
Ceramics 2025, 8(3), 114; https://doi.org/10.3390/ceramics8030114 - 17 Sep 2025
Abstract
The study of the relationship between the composition and mechanical properties of structural ceramics based on zirconium, magnesium and aluminum oxides is an important scientific and technological task. In this study, ceramics of the composition x·ZrO2-(90−x)·MgO-10·Al2O3 (x
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The study of the relationship between the composition and mechanical properties of structural ceramics based on zirconium, magnesium and aluminum oxides is an important scientific and technological task. In this study, ceramics of the composition x·ZrO2-(90−x)·MgO-10·Al2O3 (x = 10–80 wt.%) were obtained using standard ceramic technology. XRD, SEM, Vickers hardness and biaxial flexural strength measurements were performed to determine the effect of concentration x on the phase composition, microstructure and mechanical characteristics of the sintered samples. The results show that with an increase in the starting concentration x in experimental samples, the fraction of the stabilized ZrO2 phase grows, and the grain size decreases. These two factors determine the values of microhardness and biaxial bending strength. Experimental investigation on the ternary oxide ceramics shows that for ceramics sintered at 1500 °C, the microhardness values varied within the range of 815–1300 HV1 and the biaxial bending strength of 110–250 MPa.
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(This article belongs to the Special Issue Mechanical Behavior and Reliability of Engineering Ceramics)
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ZIF-8 as a Drug Delivery System (DDS) for Hesperidin: Synthesis, Characterization, and In Vitro Release Profile
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Pedro Sá, Nathália Souza, Pedrita Sampaio, James Silva and Larissa Rolim
Ceramics 2025, 8(3), 113; https://doi.org/10.3390/ceramics8030113 - 11 Sep 2025
Abstract
Metal–organic frameworks (MOFs) are promising materials for drug delivery due to their structural tunability and high surface area. This work reports on the synthesis of ZIF-8 for the in situ encapsulation of hesperidin, a flavonoid with poor water solubility used in the treatment
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Metal–organic frameworks (MOFs) are promising materials for drug delivery due to their structural tunability and high surface area. This work reports on the synthesis of ZIF-8 for the in situ encapsulation of hesperidin, a flavonoid with poor water solubility used in the treatment of circulatory system disorders, as a gastric-targeted drug delivery system (DDS). A 23 full factorial design was used to optimize drug loading, investigating the effects of DMSO concentration, 2-MIm/Zn2+ molar ratio, and final solution volume (water content). The materials were characterized by ATR-FT-IR, TG, XRD, and SEM analyses, confirming successful ZIF-8 synthesis and partial hesperidin encapsulation. Drug release kinetics were evaluated at pH 1.0 and 6.86. The system showed a faster and more pronounced release at pH 1.0, driven by MOF degradation, demonstrating its potential as a gastric-targeted DDS. This study confirms the feasibility of ZIF-8 to improve hesperidin solubility and bioavailability, highlighting a novel strategy for its therapeutic application.
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(This article belongs to the Special Issue Ceramics Containing Active Molecules for Biomedical Applications)
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Luminescence of (YxGd3−x)(AlyGa5−y)O12:Ce and (LuxGd3−x)(AlyGa5−y)O12:Ce Radiation-Synthesized Ceramics
by
Aida Tulegenova, Victor Lisitsyn, Gulnur Nogaibekova, Renata Nemkayeva and Aiymkul Markhabayeva
Ceramics 2025, 8(3), 112; https://doi.org/10.3390/ceramics8030112 - 5 Sep 2025
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(YxGd3−x)(AlyGa5−y)O12:Ce and (LuxGd3−x)(AlyGa5−y)O12:Ce ceramics were synthesized for the first time by direct exposure of a powerful electron flux to a mixture of the
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(YxGd3−x)(AlyGa5−y)O12:Ce and (LuxGd3−x)(AlyGa5−y)O12:Ce ceramics were synthesized for the first time by direct exposure of a powerful electron flux to a mixture of the corresponding oxide components. Five-component ceramics were obtained from oxide powders of Y2O3, Lu2O3, Gd2O3, Al2O3, Ga2O3, and Ce2O3 in less than 1 s, without the use of any additional reagents or process stimulants. The average productivity of the synthesis process was approximately 5 g/s. The reaction yield, defined as the mass ratio of the synthesized ceramic to the initial mixture, ranged from 94% to 99%. The synthesized ceramics exhibit photoluminescence when excited by radiation in the 340–450 nm spectral range. The position of the luminescence bands depends on the specific composition, with the emission maxima located within the 525–560 nm range. It is suggested that under high radiation power density, the element exchange rate between the particles of the initial materials is governed by the formation of an ion–electron plasma.
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Effect of Fe2O3 on Compressive Strength and Microstructure of Porous Acicular Mullite
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Mia Omerašević, Miomir Krsmanović, Nada Adamović, Chang-An Wang and Dušan Bučevac
Ceramics 2025, 8(3), 111; https://doi.org/10.3390/ceramics8030111 - 5 Sep 2025
Abstract
Porous acicular mullite was fabricated at 1300 °C starting from Al2O3 and mixture of SiO2 and MoO3 obtained by previous oxidation of waste MoSi2. It was found that the presence of MoO3 favors formation of
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Porous acicular mullite was fabricated at 1300 °C starting from Al2O3 and mixture of SiO2 and MoO3 obtained by previous oxidation of waste MoSi2. It was found that the presence of MoO3 favors formation of acicular (prism-like) mullite grains with sharp edges. The effect of addition of Fe2O3 (4–12 wt.%) on phase composition, compressive strength, thermal conductivity and microstructure was studied. The addition of Fe2O3 improved the compressive strength from approximately 25 MPa in pure mullite to about 76 MPa in samples containing 12 wt.% Fe2O3, while the open porosity decreased from 55.4% to 51.8%. The presence of Fe2O3 caused a decrease in mullite formation temperature owing to the formation of liquid phase and accelerated diffusion. The solubility of iron oxide in mullite lattice was between 8 and 12 wt.% Fe2O3. The incorporated iron ions also promoted the rounding of sharp edges in prismatic mullite grains, leading to a reduced specific surface area of 0.55 m2/g in the sample with 12 wt.% Fe2O3. The thermal conductivity of mullite increased with addition of 12 wt.% Fe2O3 reaching value of 1.17 W/m·K.
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(This article belongs to the Special Issue Ceramic Materials for Industrial Decarbonization)
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Room Temperature Surfactant-Free Synthesis of Cobalt-Doped CaMoO4 Nanoparticles: Structural and Microstructural Insights
by
Said Abidi and Mohamed Benchikhi
Ceramics 2025, 8(3), 110; https://doi.org/10.3390/ceramics8030110 - 31 Aug 2025
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This study reports the successful synthesis of pure cobalt-substituted calcium molybdate powders (Co-doped CaMoO4) through a co-precipitation method conducted at room temperature, without the use of surfactants or hazardous organic solvents. The formation of solid solutions with x values ranging from
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This study reports the successful synthesis of pure cobalt-substituted calcium molybdate powders (Co-doped CaMoO4) through a co-precipitation method conducted at room temperature, without the use of surfactants or hazardous organic solvents. The formation of solid solutions with x values ranging from 0.00 to 0.08 was confirmed by X-ray diffraction, Rietveld refinement, and Raman spectroscopy analyses. Elemental analysis using energy-dispersive X-ray spectroscopy showed a strong correlation between the experimental and nominal stoichiometries. The synthesized molybdate powders consist of micrometer-sized particles exhibiting diverse morphologies, including microspheres, flower-like architectures, and dumbbell-shaped particles. These agglomerates are composed of primary particles smaller than 43 nm. The specific surface area increased from 3.59 m2/g for the undoped CaMoO4 to 10.74 m2/g for the 6% Co-doped CaMoO4. These nanostructured powders represent promising host materials for 4f ions, making them potential candidates for solid-state lighting applications.
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Life Cycle Assessment of Industrial Glass Cullet Recycling Process Based on Alkaline Activation
by
Elena Battiston, Francesco Carollo, Giulia Tameni, Enrico Bernardo and Anna Mazzi
Ceramics 2025, 8(3), 109; https://doi.org/10.3390/ceramics8030109 - 29 Aug 2025
Abstract
To mitigate the issue of accumulating glass waste, an advanced process has been developed for the production of glass foams via alkaline activation, employing industrial glass cullet as the primary raw material. This method contributes to circular economy strategies by enabling high-value upcycling
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To mitigate the issue of accumulating glass waste, an advanced process has been developed for the production of glass foams via alkaline activation, employing industrial glass cullet as the primary raw material. This method contributes to circular economy strategies by enabling high-value upcycling of secondary raw materials. The aim of the study is to conduct an environmental assessment of this recycling process using the Life Cycle Assessment (LCA). The analysis is performed with SimaPro software, adopting the ReCiPe impact assessment method, which allows for the quantification of 18 impact categories. Four distinct foaming processes were compared to determine the most environmentally preferable option and a sensitivity analysis was conducted to assess how variations in energy sources influence the environmental performance. The findings indicate that the scenario involving hardening at 40 °C for seven days results in the highest environmental burdens. Specifically, in the Human Carcinogenic Toxicity category, the normalized impacts for this process are approximately an order of magnitude greater. Electricity consumption is identified as the primary contributor to the overall impact. The sensitivity analysis underscores that utilizing photovoltaic panels reduces impacts. Future developments will focus on expanding the system boundaries to provide a more comprehensive understanding and supporting informed decision-making.
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(This article belongs to the Special Issue Ceramics in the Circular Economy for a Sustainable World)
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Alkali Activation of Glass for Sustainable Upcycling: An Overview
by
Giulia Tameni and Enrico Bernardo
Ceramics 2025, 8(3), 108; https://doi.org/10.3390/ceramics8030108 - 27 Aug 2025
Abstract
The recycling of glass presently poses several challenges, predominantly to the heterogeneous chemical compositions of various glass types, along with the waste glass particle size distribution, both of which critically influence the efficiency and feasibility of recycling operations. Numerous studies have elucidated the
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The recycling of glass presently poses several challenges, predominantly to the heterogeneous chemical compositions of various glass types, along with the waste glass particle size distribution, both of which critically influence the efficiency and feasibility of recycling operations. Numerous studies have elucidated the potential of converting non-recyclable glass waste into valuable materials thanks to the up-cycling strategies, including stoneware, glass wool fibres, glass foams, glass-ceramics, and geopolymers. Among the promising alternatives for improving waste valorisation of glass, alkali-activated materials (AAMs) emerge as a solution. Waste glasses can be employed both as aggregates and as precursors, with a focus on its application as the sole raw material for synthesis. This overview systematically explores the optimisation of precursor selection from a sustainability standpoint, specifically addressing the mild alkali activation process (<3 mol/L) of waste glasses. The molecular mechanisms governing the hardening process associated with this emerging class of materials are elucidated. Formulating sustainable approaches for the valorisation of glass waste is becoming increasingly critical in response to the rising quantities of non-recyclable glass and growing priority on circular economy principles. In addition, the paper highlights the innovative prospects of alkali-activated materials derived from waste glass, emphasising their emerging roles beyond conventional structural applications. Environmentally relevant applications for alkali-activated materials are reported, including the adsorption of dyes and heavy metals, immobilisation of nuclear waste, and an innovative technique for hardening as microwave-assisted processing.
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Ceramics—The Forgotten but Essential Ingredients for a Circular Economy on the Moon
by
Alex Ellery
Ceramics 2025, 8(3), 107; https://doi.org/10.3390/ceramics8030107 - 22 Aug 2025
Abstract
Settlement on the Moon will require full exploitation of its resources if such settlements are to be permanent. Such in situ resource utilisation (ISRU) has primarily been focused on accessing water ice at the lunar poles and the use of raw lunar regolith
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Settlement on the Moon will require full exploitation of its resources if such settlements are to be permanent. Such in situ resource utilisation (ISRU) has primarily been focused on accessing water ice at the lunar poles and the use of raw lunar regolith as a compressive building material. Some work has also examined the extraction of metals, but there has been little consideration of the many useful ceramics that can be extracted from the Moon and how they may be fabricated. We introduce a strategy for full lunar industrialisation based on a circular lunar industrial ecology and examine the contribution of ceramics. We review ceramic fabrication methods but focus primarily on 3D printing approaches. The popular direct ink writing method is less suitable for the Moon and other methods require polymers which are scarce on the Moon. This turns out to be crucial, suggesting that full industrialisation of the Moon cannot be completed until the problem of ceramic fabrication is resolved, most likely in conjunction with polymer synthesis from potential carbon sources.
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