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A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Construction and Building Materials".

Deadline for manuscript submissions: closed (15 September 2020) | Viewed by 51254

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Prof. Dr. Mariaenrica Frigione

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Guest Editor

Innovation Engineering Department, University of Salento, 73100 Lecce, Italy
Interests: cold-cured adhesives and matrices for FRP employed in constructions; polymeric nanostructured adhesives and coatings; hydrophobic coatings for stone conservation and wood protection; durability of polymers, adhesives and coatings; eco-efficient materials for construction and cultural heritage
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Dr. José Aguiar

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Guest Editor

Centre for Territory, Environment and Construction (CTAC), University of Minho, 4800-058 Guimarães, Portugal
Interests: sustainable construction; energy efficiency of buildings; phase change materials; composite materials; material durability; construction and demolition wastes; foundry industry wastes; polymers in concrete
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Most of the typical materials employed in today’s construction industry present limitations, especially with regard to their durability—in either common or severe environmental conditions—and their impact on the environment. In response to these issues, academic and industrial efforts around the world have been devoted to developing new smart materials that can provide efficient alternatives, improve energy efficiency in buildings, or upgrade, repair, and protect existing infrastructures. Different and wide technological innovations are, therefore, quickly fostering advancements in the field of construction materials. A new generation of materials (e.g., bricks, cement, coatings, concrete, FRP, glass, masonry, mortars, nanomaterials, PCM, polymers, steel, wood, etc.) is, in fact, gaining a prominent position in modern building technology, because such materials are able to overcome various limitations and flaws of the conventional materials employed in construction, without neglecting the smart applications of pioneering materials in ancient constructions and historic buildings.

Even though the adoption of innovative materials in the field of construction has been demonstrated to be a successful strategy to achieve enhanced performance or even new and unexpected characteristics, several issues are still not completely resolved. On top of those issues, the cost/performance ratio of the novel solutions is important, because such materials must be demonstrated to be convenient without compromising quality. Other concerns are related to their sustainability: whether they are eco-friendly options, exploiting recycled materials or byproducts from other productions—the most desirable solution. Finally, the use of materials or systems that are unconventional in this field creates the need to update or develop new specifications and standards.

This Special Issue aims to provide a platform for discussing open issues, challenges, and achievements related to innovative materials proposed for use in the construction industry.

Prof. Mariaenrica Frigione
Prof. José Barroso de Aguiar
Guest Editors

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Keywords

Auto-repairing features
Durability
Energy-efficiency
Increase in human comfort
Nanotechnology
New standards
Recycling
Reduction of natural resources
Renewability
Self-cleaning characteristics
Sustainability

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Published Papers (12 papers)

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Editorial

Jump to: Research, Review

4 pages, 178 KiB

Open AccessEditorial

Innovative Materials for Construction

by Mariaenrica Frigione and José Luís Barroso de Aguiar

Materials 2020, 13(23), 5448; https://doi.org/10.3390/ma13235448 - 2 Dec 2020

Cited by 4 | Viewed by 2869

Abstract

Academic and industrial efforts around the world are continuously engaged to develop new smart materials that can provide efficient alternatives to conventional construction materials and improve the energy-efficiency in buildings or are able to upgrade, repair, and protect existing infrastructures [...] Full article

(This article belongs to the Special Issue Innovative Materials for Construction)

Research

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20 pages, 4645 KiB

Open AccessArticle

Study of the Incorporation of Ladle Furnace Slag in the Manufacture of Cold In-Place Recycling with Bitumen Emulsion

by Juan María Terrones-Saeta, Francisco Javier Iglesias-Godino, Francisco Antonio Corpas-Iglesias and Carmen Martínez-García

Materials 2020, 13(21), 4765; https://doi.org/10.3390/ma13214765 - 26 Oct 2020

Cited by 14 | Viewed by 2958

Abstract

Cold in-place recycling with bitumen emulsion is a good environmental option for road conservation. The technique produces lower CO₂ emissions because the product is manufactured and spread in the same location as the previous infrastructure, and its mixing with bitumen emulsion occurs at room temperature. Adding materials with cementitious characteristics gives the final mixture greater resistance and durability, and incorporating an industrial by-product such as ladle furnace slag (of which cementitious characteristics have been corroborated by various authors) enables the creation of sustainable, resistant pavement. This paper describes the incorporation of ladle furnace slag in reclaimed asphalt pavements (RAP) to execute in-place asphalt pavement recycling with bitumen emulsion. Various test groups of samples with increasing percentages of emulsion were created to study both the density of the mixtures obtained, and their dry and post-immersion compressive strength. To determine these characteristics, the physical and chemical properties of the ladle furnace slag and the reclaimed asphalt pavements were analyzed, as well as compatibility with the bitumen emulsion. The aforementioned tests define an optimal combination of RAP (90%), ladle furnace slag (10%), water (2.6%), and emulsion (3.3%), which demonstrated maximum values for compressive strength of the dry and post-immersion bituminous mixture. These tests therefore demonstrate the suitability of ladle furnace slag for cold in-place recycling with bitumen emulsion. Full article

(This article belongs to the Special Issue Innovative Materials for Construction)

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20 pages, 9598 KiB

Open AccessArticle

The Influence of the Addition of Plant-Based Natural Fibers (Jute) on Biocemented Sand Using MICP Method

by Md Al Imran, Sivakumar Gowthaman, Kazunori Nakashima and Satoru Kawasaki

Materials 2020, 13(18), 4198; https://doi.org/10.3390/ma13184198 - 21 Sep 2020

Cited by 48 | Viewed by 4946

Abstract

The microbial-induced carbonate precipitation (MICP) method has gained intense attention in recent years as a safe and sustainable alternative for soil improvement and for use in construction materials. In this study, the effects of the addition of plant-based natural jute fibers to MICP-treated sand and the corresponding microstructures were measured to investigate their subsequent impacts on the MICP-treated biocemented sand. The fibers used were at 0%, 0.5%, 1.5%, 3%, 5%, 10%, and 20% by weight of the sand, while the fiber lengths were 5, 15, and 25 mm. The microbial interactions with the fibers, the CaCO₃ precipitation trend, and the biocemented specimen (microstructure) were also evaluated based on the unconfined compressive strength (UCS) values, scanning electron microscopy (SEM), and fluorescence microscopy. The results of this study showed that the added jute fibers improved the engineering properties (ductility, toughness, and brittleness behavior) of the biocemented sand using MICP method. Furthermore, the fiber content more significantly affected the engineering properties of the MICP-treated sand than the fiber length. In this study, the optimal fiber content was 3%, whereas the optimal fiber length was s 15 mm. The SEM results indicated that the fiber facilitated the MICP process by bridging the pores in the calcareous sand, reduced the brittleness of the treated samples, and increased the mechanical properties of the biocemented sand. The results of this study could significantly contribute to further improvement of fiber-reinforced biocemented sand in geotechnical engineering field applications. Full article

(This article belongs to the Special Issue Innovative Materials for Construction)

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19 pages, 4439 KiB

Open AccessArticle

Lime-Based Mortar Reinforced by Randomly Oriented Short Fibers for the Retrofitting of the Historical Masonry Structure

by Michele Angiolilli, Amedeo Gregori and Marco Vailati

Materials 2020, 13(16), 3462; https://doi.org/10.3390/ma13163462 - 6 Aug 2020

Cited by 32 | Viewed by 3103

Abstract

Recent seismic events prompted research to develop innovative materials for strengthening and repair of both modern and historic masonry constructions (buildings, bridges, towers) and structural components (walls, arches and vaults, pillars, and columns). Strengthening solutions based on composite materials, such as the Fiber Reinforced Polymers (FRP) or the Fiber Reinforced Cementitious Matrix (FRCM), have been increasingly considered in the last two decades. Despite reinforcement made of short-fibers being a topic that has been studied for several years from different researchers, it is not yet fully considered for the restoration of the masonry construction. This work aims to experimentally investigate the enhancement of the mechanical properties of lime-based mortar reinforced by introducing short glass fibers in the mortar matrix with several contents and aspect ratios. Beams with dimensions of 160 mm × 40 mm × 40 mm with a central notch were tested in three-point bending configuration aiming to evaluate both the flexural strength and energy fracture of the composite material. Then, the end pieces of the broken beams were tested in Brazilian and compressive tests. All the tests were performed by a hydraulic displacement-controlled testing machine. Results highlight that the new composite material ensures excellent ductility capacity and it can be considered a promising alternative to the classic fiber-reinforcing systems. Full article

(This article belongs to the Special Issue Innovative Materials for Construction)

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11 pages, 2584 KiB

Open AccessArticle

Effects of a New Type of Shrinkage-Reducing Agent on Concrete Properties

by Mari Masanaga, Tsuyoshi Hirata, Hirokatsu Kawakami, Yuka Morinaga, Toyoharu Nawa and Yogarajah Elakneswaran

Materials 2020, 13(13), 3018; https://doi.org/10.3390/ma13133018 - 6 Jul 2020

Cited by 9 | Viewed by 2775

Abstract

Shrinkage-reducing agents have been developed to mitigate shrinkage and to control cracks in concrete. This study aims to evaluate the impact of a newly developed shrinkage-reducing agent (N-SRA) on concrete properties and to compare its properties with a conventional shrinkage-reducing agent (C-SRA). The hydration rate, compressive strength, splitting tensile strength, shrinkage, occurrence of cracking, and freezing and thawing were investigated. N-SRA showed higher surface tension than C-SRA and reduced shrinkage to the same degree as C-SRA with half the dosage of C-SRA. The addition of N-SRA or C-SRA did not influence the early compressive strength but slightly reduced splitting tensile strength at seven days. Concrete with N-SRA showed higher compressive strength at 28 days than those of concrete with C-SRA or without SRA. Furthermore, concrete with N-SRA extended the period for the occurrence of shrinkage cracking under restrained conditions. It was found that N-SRA provided excellent freezing and thawing resistance because of the formation of good air voids, while C-SRA demonstrated inefficient behaviour in such an environment. Full article

(This article belongs to the Special Issue Innovative Materials for Construction)

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15 pages, 3096 KiB

Open AccessArticle

Strontium Retention of Calcium Zirconium Aluminate Cement Paste Studied by NMR, XRD and SEM-EDS

by Dominika Madej

Materials 2020, 13(10), 2366; https://doi.org/10.3390/ma13102366 - 21 May 2020

Cited by 4 | Viewed by 3198

Abstract

This work concerns the hydration mechanism of calcium zirconium aluminate as a ternary compound appearing in the CaO-Al₂O₃-ZrO₂ diagram besides the calcium aluminates commonly used as the main constitutes of calcium aluminate cements (CACs). Moreover, a state-of-the-art approach towards significant changes in hydraulic properties was implemented for the first time in this work, where the effect of structural modification on the hydration behavior of calcium zirconium aluminate was proved by XRD, ²⁷Al MAS NMR and SEM-EDS. The substitution of Sr²⁺ for Ca²⁺ in the Ca₇ZrAl₆O₁₈ lattice decreases the reactivity of Sr-substituted Ca₇ZrAl₆O₁₈ in the presence of water. Since the original cement grains remain unhydrated up to 3 h (Ca₇ZrAl₆O₁₈) or 72 h (Sr_1.25Ca_5.75ZrAl₆O₁₈) of curing period in the hardened cement paste structures, strontium can be considered as an inhibition agent for cement hydration. The complete conversion from anhydrous ²⁷Al^IV to hydrated ²⁷Al^VI species was achieved during the first 24 h (Ca₇ZrAl₆O₁₈) or 7 d(Sr_1.25Ca_5.75ZrAl₆O₁₈) of hydration. Simultaneously, the chemical shift in the range of octahedral aluminum from ca. 4 ppm to ca. 6 ppm was attributed to the transformation of the hexagonal calcium aluminate hydrates and Sr-rich (Sr,C)₃AH₆ hydrate into the cubic phase Ca-rich (Sr,C)₃AH₆ or pure C₃AH₆ in the hardened Sr-doped cement paste at the age of 7 d. The same ²⁷Al NMR chemical shift was detected at the age of 24 h for the reference hardened undoped Ca₇ZrAl₆O₁₈ cement paste. Full article

(This article belongs to the Special Issue Innovative Materials for Construction)

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15 pages, 4238 KiB

Open AccessArticle

Thermal Performance of Mortars Based on Different Binders and Containing a Novel Sustainable Phase Change Material (PCM)

by Antonella Sarcinella, José Luìs Barroso De Aguiar, Mariateresa Lettieri, Sandra Cunha and Mariaenrica Frigione

Materials 2020, 13(9), 2055; https://doi.org/10.3390/ma13092055 - 28 Apr 2020

Cited by 25 | Viewed by 3397

Abstract

Increasing concerns about climate change and global warming bring about technical steps for the development of several energy-efficient technologies. Since the building sector is one of the largest energy users for cooling and heating necessities, the incorporation of a proper energy-efficient material into the building envelopes could be an interesting solution for saving energy. Phase change material (PCM)-based thermal energy storage (TES) seems suitable to provide efficient energy redistribution. This is possible because the PCM is able to store and release its latent heat during the phase change processes that occurs according to the environmental temperature. The purpose of this paper was the characterization of the thermal properties of a composite PCM (i.e., Lecce stone/poly-ethylene glycol, previously developed) incorporated into mortar compositions based on different binders (i.e., hydraulic lime and cement). The study was carried out using an experimental set up through which it was possible to simulate the different seasons of the years. It was observed that the addition of PCM in mortars leads to a decrease of the maximum temperatures and increase of the minimum temperatures. Furthermore, the results shown a reduction of the heating and cooling needs, thus confirming the capability of this material to save energy. Full article

(This article belongs to the Special Issue Innovative Materials for Construction)

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22 pages, 15229 KiB

Open AccessArticle

Analytic Hierarchy Process-Based Construction Material Selection for Performance Improvement of Building Construction: The Case of a Concrete System Form

by Dongmin Lee, Dongyoun Lee, Myungdo Lee, Minju Kim and Taehoon Kim

Materials 2020, 13(7), 1738; https://doi.org/10.3390/ma13071738 - 8 Apr 2020

Cited by 22 | Viewed by 4490

Abstract

Selecting the best materials that ensure maximum performance is crucial in the construction engineering design of any construction project. However, this is challenging and usually not properly considered because of the lack of systematic and scientific evaluation methods for the performance of materials. This paper proposes a new approach of selecting material to satisfy the performance goal of material designers in building constructions based on the analytic hierarchy process method. To validate the suggested model, a case study was conducted for a concrete system form, the performance of which is susceptible to its materials and has a strong effect on overall project productivity. The newly developed form comprising polymers and alloys showed that the proposed material selection model provided a better combination of materials, and the solution was technically more advanced and ensured better performance. This paper contributes to the body of knowledge by expanding the understanding of how construction material properties affect project performance and provides a guideline for material engineers to select the best-performing building materials while considering a performance goal. Full article

(This article belongs to the Special Issue Innovative Materials for Construction)

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15 pages, 8034 KiB

Open AccessArticle

Flexural Behavior of a Precast Concrete Deck Connected with Headed GFRP Rebars and UHPC

by Won Jong Chin, Young Hwan Park, Jeong-Rae Cho, Jin-Young Lee and Young-Soo Yoon

Materials 2020, 13(3), 604; https://doi.org/10.3390/ma13030604 - 29 Jan 2020

Cited by 12 | Viewed by 4143

Abstract

Steel bent reinforcing bars (rebars) are widely used to provide adequate anchorage. Bent fiber-reinforced polymer (FRP) rebars are rarely used because of the difficulty faced during the bending process of the FRP rebars at the construction site. Additionally, the bending process may cause a significant decrease in the structural performance of the FRP rebars. Therefore, to overcome these drawbacks, a headed glass fiber-reinforced polymer (GFRP) rebar was developed in this study. The pull-out tests of the headed GFRP rebars with diameters of 16 and 19 mm were conducted to evaluate their bond properties in various cementitious materials. Moreover, structural flexural tests were conducted on seven precast concrete decks connected with the headed GFRP rebars and various cementitious fillers to estimate the flexural behavior of the connected decks. The results demonstrate that the concrete decks connected with the headed GFRP rebar and ultra-high-performance concrete (UHPC) exhibited improved flexural performance. Full article

(This article belongs to the Special Issue Innovative Materials for Construction)

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14 pages, 1323 KiB

Open AccessArticle

Applications of Sustainable Polymer-Based Phase Change Materials in Mortars Composed by Different Binders

by Mariaenrica Frigione, Mariateresa Lettieri, Antonella Sarcinella and José Luìs Barroso de Aguiar

Materials 2019, 12(21), 3502; https://doi.org/10.3390/ma12213502 - 25 Oct 2019

Cited by 20 | Viewed by 3058

Abstract

Eco-sustainable, low toxic and low flammable poly-ethylene glycol (PEG) was forced into flakes of the porous Lecce stone (LS), collected as stone cutting wastes, employing a very simple cheap method, to produce a “form-stable” phase change material (PCM). The experimental PCM was included in mortars based on different binders (hydraulic lime, gypsum and cement) in two compositions. The main thermal and mechanical characteristics of the produced mortars were evaluated in order to assess the effects due to the incorporation of the PEG-based PCM. The mortars containing the PEG-based PCM were found to be suitable as thermal energy storage systems, still displaying the characteristics melting and crystallization peaks of PEG polymer, even if the related enthalpies measured on the mortars were appreciably reduced respect to pure PEG. The general reduction in mechanical properties (in flexural and compressive mode) measured on all the mortars, brought about by the presence of PEG-based PCM, was overcome by producing mortars possessing a greater amount of binder. The proposed LS/PEG composite can be considered, therefore, as a promising PCM system for the different mortars analyzed, provided that an optimal composition is identified for each binder. Full article

(This article belongs to the Special Issue Innovative Materials for Construction)

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13 pages, 4978 KiB

Open AccessArticle

Experimental and Numerical Analysis of a Composite Thin-Walled Cylindrical Structures with Different Variants of Stiffeners, Subjected to Torsion

by Tomasz Kopecki, Przemysław Mazurek and Tomasz Lis

Materials 2019, 12(19), 3230; https://doi.org/10.3390/ma12193230 - 2 Oct 2019

Cited by 27 | Viewed by 3664

Abstract

The aim of the study was to determine the impact of the use of isogrid stiffeners on the stress and displacement distribution of a thin-walled cylindrical shell made of layered composites subjected to torsion. It also strives to define criteria for assessing the results of non-linear numerical analysis of models of the examined structures by comparing them with the results of the model experiment. The study contains the results of experimental research using models made of glass–epoxy composites and the results of numerical analyses in non-linear terms. The experiment was carried out using a special test stand. The research involved two types of considered structures. The results of the research allowed to create the concept of an adequate numerical model in terms of the finite element method, allowing to determine the distribution of stress and strain in the components of the studied structures. Simultaneously, the obtained conformity between the results of non-linear numerical analyses and the experiment allows to consider the results of analyses of the modified model in order to determine the properties of different stiffening variants as reliable. The presented research allows to determine the nature of the deformation of composite thin-walled structures in which local loss of stability of the covering is acceptable in the area of post-critical loads. Full article

(This article belongs to the Special Issue Innovative Materials for Construction)

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Review

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28 pages, 964 KiB

Open AccessReview

Insights into the Current Trends in the Utilization of Bacteria for Microbially Induced Calcium Carbonate Precipitation

by Sing Chuong Chuo, Sarajul Fikri Mohamed, Siti Hamidah Mohd Setapar, Akil Ahmad, Mohammad Jawaid, Waseem A. Wani, Asim Ali Yaqoob and Mohamad Nasir Mohamad Ibrahim

Materials 2020, 13(21), 4993; https://doi.org/10.3390/ma13214993 - 5 Nov 2020

Cited by 130 | Viewed by 10039

Abstract

Nowadays, microbially induced calcium carbonate precipitation (MICP) has received great attention for its potential in construction and geotechnical applications. This technique has been used in biocementation of sand, consolidation of soil, production of self-healing concrete or mortar, and removal of heavy metal ions from water. The products of MICP often have enhanced strength, durability, and self-healing ability. Utilization of the MICP technique can also increase sustainability, especially in the construction industry where a huge portion of the materials used is not sustainable. The presence of bacteria is essential for MICP to occur. Bacteria promote the conversion of suitable compounds into carbonate ions, change the microenvironment to favor precipitation of calcium carbonate, and act as precipitation sites for calcium carbonate crystals. Many bacteria have been discovered and tested for MICP potential. This paper reviews the bacteria used for MICP in some of the most recent studies. Bacteria that can cause MICP include ureolytic bacteria, non-ureolytic bacteria, cyanobacteria, nitrate reducing bacteria, and sulfate reducing bacteria. The most studied bacterium for MICP over the years is Sporosarcina pasteurii. Other bacteria from Bacillus species are also frequently investigated. Several factors that affect MICP performance are bacterial strain, bacterial concentration, nutrient concentration, calcium source concentration, addition of other substances, and methods to distribute bacteria. Several suggestions for future studies such as CO₂ sequestration through MICP, cost reduction by using plant or animal wastes as media, and genetic modification of bacteria to enhance MICP have been put forward. Full article

(This article belongs to the Special Issue Innovative Materials for Construction)

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