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Novel Materials, Methods and Processes for Sustainable Carbon Capture, Utilization and Storage

A special issue of Sustainability (ISSN 2071-1050). This special issue belongs to the section "Sustainable Chemical Engineering and Technology".

Deadline for manuscript submissions: closed (30 September 2023) | Viewed by 4024

Special Issue Editors


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Guest Editor
1. Department of Chemical Engineering, Dawood University of Engineering and Technology, Karachi 74800, Pakistan
2. Process Engineering Lab, Department of Chemical Engineering, Chungbuk National University, Cheongju, Korea
Interests: carbon capture and utilization; sustainable and renewable materials; thermodynamics, mass transfer and kinetics; process modelling and simulation; artificial intelligence
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Guest Editor
Research Centre for Carbon Dioxide Capture and Utilisation, School of Engineering and Technology, Sunway University, No. 5, Jalan Universiti, Bandar Sunway, Petaling Jaya 47500, Selangor, Malaysia
Interests: carbon capture technology (adsorption, absorption); advanced materials (porous carbon derived from solid waste, MOF); biomass conversion; life cycle assessment

Special Issue Information

Dear Colleagues,

Climate change caused by greenhouse gas emissions, especially anthropogenic carbon dioxide, has posed a serious threat to Earth. A lot has already changed due to climate change, especially disasters due to the rise in average global temperature up to one degree Celsius. Under the worst case scenario, also called business as usual, when no action is taken against carbon emissions, average global temperature may rise up to 5 degrees Celsius. On the carbon dioxide emissions, business as usual is no more an option for the survival of humanity on Earth. To restore and sustain planet Earth, it is inevitable that we must develop low-carbon societies with advanced technologies.

The societies with a net impact of zero or minimal carbon emissions may be achieved through countermeasures against carbon dioxide gas emissions. One of the methods for the minimization of CO2 emissions is the reduction in the use of the fossil fuels by meeting energy demands through renewable and sustainable energy resources. The use of non-carbon or renewable fuels may be an option for the developed world with less than 20% of the global population; however, the majority of the world still cannot afford such a luxury. Apart from the energy sector, transportation, manufacturing, cement, steel and almost every other industry emits carbon dioxide. Therefore, the use of renewable energy resources with zero net carbon emissions may be one of the options to reduce carbon emissions; however, it cannot be a wholistic solution for the development of a low-carbon world.

Therefore, the capture of CO2 from exhaust emissions of various industries is of the utmost importance to curtail the atmospheric concentration of CO2. Various carbon capture, utilization and storage (CCUS) technologies have been developed to mitigate CO2 emissions. However, every technology comes with pros and cons. For the moment, the major hurdle in large-scale CCUS technologies is the cost. However, to develop sustainable CCUS technologies, four major factors, such as the maturity of technology, performance, techno-economic viability and environmental friendliness, should be considered.

This Special Issue focuses on the development of novel materials, methods and processes for carbon capture, utilization and storage technologies. This Special Issue aims to provide a platform for researchers to disseminate current knowledge and latest research findings among peers and policymakers.

The scope includes, but is not limited to, the following topics:

  1. Processes: absorption, adsorption, membrane separation, oxyfuel combustion, cryogenic separation, biochemical conversion, electro- and photo-chemical reduction, bioprocesses, etc.
  2. Methods: process simulation, techno-economic analyses, life cycle assessment, numerical simulation, thermodynamic, kinetics, and mass transfer modelling, artificial intelligence, including machine learning and deep learning models, etc.
  3. Materials: biomaterials, metal organic frameworks, zeolites, graphene, Mxene, carbon nitrides, nanomaterials, polymers, ionic liquids, chemical and physical solvents, microalgae, etc.

Dr. Shaukat Ali Mazari
Dr. Farihahusnah Hussin
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Sustainability is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2400 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • carbon capture
  • conversion and storage
  • sustainable and renewable materials
  • adsorption
  • adsorption
  • membrane process
  • process modelling and simulation
  • artificial intelligence

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Published Papers (2 papers)

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Research

14 pages, 3820 KiB  
Article
Non-Aqueous Solvent Mixtures for CO2 Capture: Choline Hydroxide-Based Deep Eutectic Solvents Absorbent Performance at Various Temperatures and Pressures
by Mohd Azlan Kassim, Nor Afifah Sulaiman, Rozita Yusoff and Mohamed Kheireddine Aroua
Sustainability 2023, 15(12), 9191; https://doi.org/10.3390/su15129191 - 7 Jun 2023
Cited by 4 | Viewed by 1683
Abstract
Carbon dioxide (CO2) absorption in a non-aqueous solution is a potential technology for reducing greenhouse gas emissions. In this study, a non-aqueous solvent, sulfolane and dimethylsulfoxide (DMSO), was functionalized with a deep eutectic solvent (DES) consisting of choline hydroxide and polyamines [...] Read more.
Carbon dioxide (CO2) absorption in a non-aqueous solution is a potential technology for reducing greenhouse gas emissions. In this study, a non-aqueous solvent, sulfolane and dimethylsulfoxide (DMSO), was functionalized with a deep eutectic solvent (DES) consisting of choline hydroxide and polyamines diethylenetriamine (DETA) and triethylenetetramine (TETA). The non-aqueous absorbents’ CO2 absorption ability was investigated in a high-pressure absorption reactor with a variable absorption temperature (303.15–333.15 K) and pressure (350–1400 kPa). The results showed that 2M ChOH:TETA−DMSO solution had the highest CO2 loading capacity when compared with other screened solutions, such as 2M ChOH:TETA−Sulfolane, 2M ChOH:DETA−DMSO and 2M ChOH:DETA−Sulfolane. It was also found that the absorption capacity increased with increasing pressure and decreased with temperature. The highest CO2 absorption by 2M ChOH:TETA−DMSO was observed at a partial pressure of 1400 kPa at 303.15 K 1.2507 mol CO2/mol DES. The use of a non-aqueous solvent in the mixture showed a phase separation phenomenon after the CO2 absorption reaction due to the formation of insoluble carbamate salt, which was identified through FTIR analysis. These findings suggest that the use of a DES polyamine mixed with a non-aqueous solvent could be a promising solution for CO2 capture. Full article
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21 pages, 5979 KiB  
Article
The Effect of Physicochemical Properties and Surface Chemistry on CO2 Adsorption Capacity of Potassium Acetate-Treated Carbon Pellets
by Farihahusnah Hussin, Nur Nadira Hazani and Mohamed Kheireddine Aroua
Sustainability 2023, 15(6), 4903; https://doi.org/10.3390/su15064903 - 9 Mar 2023
Cited by 1 | Viewed by 1924
Abstract
The aim of this study is to prepare a carbon pellet using low-cost material and a green process with excellent surface properties for carbon dioxide (CO2) capture application. To enhance the surface properties of the carbon pellet, a chemical activation method [...] Read more.
The aim of this study is to prepare a carbon pellet using low-cost material and a green process with excellent surface properties for carbon dioxide (CO2) capture application. To enhance the surface properties of the carbon pellet, a chemical activation method was introduced by modifying the pellet with potassium acetate. Then, the carbon pellet was tested in a packed-bed adsorption column to evaluate their performance for breakthrough time and CO2 adsorption. The effect of the physicochemical and surface chemistry of the carbon pellet on CO2 adsorption was also studied. The SEM image showed remarkable changes in the surface morphology of the carbon pellet after modification with potassium acetate. In addition, the presence of oxygen-containing functional groups such as hydroxyl and carbonyl groups in the modified carbon pellet could effectively enhance the CO2 adsorption capacity. Thus, it is proven that the carbon pellet modified with potassium acetate is suitable for CO2 adsorption. The results revealed that the CAC-PA 2M obtained the longest breakthrough time (19.4 min), higher adsorption capacity (0.685 mmol/g), and good recyclability (the regenerated sample can be reused for more than five cycles). The comprehensive characterization study and CO2 adsorption experimental data on new carbon pellets can provide a direction for new researchers that are venturing into the CO2 capture field. Full article
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