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Keywords = Longmaxi shale formation

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15 pages, 2733 KiB  
Article
The Range and Evolution Model of the Xiang-E Submarine Uplifts at the Ordovician–Silurian Transition: Evidence from Black Shale Graptolites
by Zhi Zhou, Hui Zhou, Zhenxue Jiang, Shizhen Li, Shujing Bao and Guihong Xu
J. Mar. Sci. Eng. 2025, 13(4), 739; https://doi.org/10.3390/jmse13040739 (registering DOI) - 8 Apr 2025
Viewed by 39
Abstract
Accurately delineating the range of the Xiang-E submarine uplifts is the key to the exploration and development of Silurian shale gas in the Western Hunan–Hubei region. Based on the graptolite stratigraphic division of Well JD1 in Jianshi area, Hubei Province, and combined with [...] Read more.
Accurately delineating the range of the Xiang-E submarine uplifts is the key to the exploration and development of Silurian shale gas in the Western Hunan–Hubei region. Based on the graptolite stratigraphic division of Well JD1 in Jianshi area, Hubei Province, and combined with the GBDB online database (Geobiodiversity Database), the study compared the shale graptolite sequences of the Wufeng Formation and Longmaxi Formation from 23 profile points and 11 wells which cross the Ordovician–Silurian boundary. The range of the Xiang-E submarine uplift was delineated, and its evolution model and formation mechanism at the Ordovician–Silurian transition were discussed. The graptolite stratigraphic correlation results of drillings and profiles confirmed the development of submarine uplifts in the Western Hunan–Hubei region at the Ordovician–Silurian transition–Xiang-E submarine uplift. Under the joint control of the Guangxi movement and the global sea-level variation caused by the condensation and melting of polar glaciers, the overall evolution of the Xiang-E submarine uplift is characterized by continuous uplift from the Katian Age to the early Rhuddanian Age, with the influence gradually expanding, and then gradually shrinking back in the middle and late Rhuddanian Age. The initial form of the Xiang-E submarine uplift may have originated from the Guangxi movement, and the global sea-level variation caused by polar glacier condensation and melting is the main controlling factor for the changes in its influence range. Within the submarine uplifts range, the Wufeng–Longmaxi Formations generally lack at least two graptolite zone organic-rich shales in the WF2-LM4, and the shale gas reservoir has a poor hydrocarbon generation material foundation, posing a high risk for shale gas exploration. The Silurian in Xianfeng, Lichuan, Yichang of Hubei and Wushan of Chongqing has good potential for shale gas exploration and development. Full article
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17 pages, 5000 KiB  
Article
Effects of Fracturing Fluids on Properties of Shale Reservoir: A Case Study of the Longmaxi Formation in the Sichuan Basin
by Yishan Cheng, Zhiping Li and Longfei Xu
Minerals 2025, 15(4), 392; https://doi.org/10.3390/min15040392 - 8 Apr 2025
Viewed by 61
Abstract
Hydraulic fracturing is widely used for developing shale reservoirs with low porosity and permeability. Large volumes of fracturing fluids are injected into reservoirs, yet the impact of these fluids on shale is not entirely understood. This study investigates the effects of commonly used [...] Read more.
Hydraulic fracturing is widely used for developing shale reservoirs with low porosity and permeability. Large volumes of fracturing fluids are injected into reservoirs, yet the impact of these fluids on shale is not entirely understood. This study investigates the effects of commonly used fracturing fluids on the fundamental properties of shale during the shut-in period using experimental methods. Shale samples are collected from the Longmaxi Formation in the Sichuan Basin. Two types of fracturing fluids (guar gel and slickwater) are prepared for tests. The effects of these fluids on shale’s mineral composition, pore distribution, and fracture structure are analyzed using a range of techniques, including X-ray diffraction, nuclear magnetic resonance, nitrogen adsorption-desorption, and X-ray computed tomography scanning. The results show that the shale is composed of quartz, siderite, and clay minerals. The reservoir’s pore structure is relatively uniform, with a higher proportion of small pores and a predominance of wedge-shaped pore types. The porosity ranges from 1.8% to 4.33%, with an average pore diameter varying between 10.8 nm and 24.8 nm. More fracturing fluid enters the reservoir as shut-in time increases. Initially, fluid invasion occurs rapidly, but the volume of infiltrated fluid stabilizes after 15 days. The fracturing fluids cause chemical reactions and hydration of clay minerals. Both fracturing fluids lead to a decrease in the proportion of clay minerals and an increase in the proportion of quartz. After soaking in guar gel, the shale’s surface area and pore volume decrease while the average pore diameter increases. The breakdown of guar gel leads to a residue that blocks pore spaces, resulting in lower surface porosity. In contrast, slickwater increases surface area and pore volume while reducing the average pore diameter. Slickwater also promotes the development of fractures, with larger pores forming around them. The results suggest that slickwater is more effective than guar gel in improving shale’s pore structure. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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29 pages, 12050 KiB  
Article
Quantitative Classification of Shale Lithofacies and Gas Enrichment in Deep-Marine Shale of the Late Ordovician Wufeng Formation and Early Silurian Longyi1 Submember, Sichuan Basin, China
by Liyu Fang, Fanghao Xu, Guosheng Xu, Jiaxin Liu, Haoran Liang and Xin Gong
Energies 2025, 18(7), 1835; https://doi.org/10.3390/en18071835 (registering DOI) - 4 Apr 2025
Viewed by 81
Abstract
The classification of shale lithofacies, pore structure characteristics, and controlling factors of gas enrichment in deep-marine shale are critical for deep shale gas exploration and development. This study investigates the Late Ordovician Wufeng Formation (448–444 Ma) and Early Silurian Longyi1 submember (444–440 [...] Read more.
The classification of shale lithofacies, pore structure characteristics, and controlling factors of gas enrichment in deep-marine shale are critical for deep shale gas exploration and development. This study investigates the Late Ordovician Wufeng Formation (448–444 Ma) and Early Silurian Longyi1 submember (444–440 Ma) in the western Chongqing area, southern Sichuan Basin, China. Using experimental data from deep-marine shale samples, including total organic carbon (TOC) content analysis, X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), low-pressure N2 and CO2 adsorption, gas content measurement, and three-quartile statistical analysis, a lithofacies classification scheme for deep-marine shale was established. The differences between various global marine shale formations were compared, and the main controlling factors of gas enrichment and advantageous lithofacies for deep shale were identified. The results show that six main lithofacies were identified: organic-rich siliceous shale (S1), organic-rich mixed shale (M1), medium-organic siliceous shale (S2), medium-organic mixed shale (M2), organic-lean siliceous shale (S3), and organic-lean mixed shale (M3). Deep-marine shale gas mainly occurs in micropores, and the development degree of micropores determines the gas content. Micropore development is jointly controlled by the TOC content, felsic mineral content, and clay mineral content. TOC content directly controls the development degree of micropores, whereas the felsic and clay mineral contents control the preservation and destruction of micropores during deep burial. The large-scale productivity of siliceous organisms during the Late Ordovician Wufeng period to the Early Silurian Longmaxi period had an important influence on the formation of S1. By comparing the pore structure parameters and gas contents of different lithofacies, it is concluded that S1 should be the first choice for deep-marine shale gas exploration, followed by S2. Full article
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25 pages, 8170 KiB  
Article
Linking Volcanism, Hydrothermal Venting, and Ordovician/Silurian Marine Organic-Rich Sediments in the Eastern Sichuan Basin, Southwest China
by Shaojie Li, Zhou Zhu, Qilin Xiao, Suyang Cai and Huan Li
J. Mar. Sci. Eng. 2025, 13(3), 483; https://doi.org/10.3390/jmse13030483 - 28 Feb 2025
Viewed by 445
Abstract
The Ordovician/Silurian boundary (Wufeng/Longmaxi formations) in the Shizhu region, eastern Sichuan Basin, China hosts organic-rich black shales which are frequently interbedded with bentonite and hydrothermal minerals (e.g., pyrite). This study investigated the mineralogical, total organic carbon (TOC), total sulfur (TS), and major and [...] Read more.
The Ordovician/Silurian boundary (Wufeng/Longmaxi formations) in the Shizhu region, eastern Sichuan Basin, China hosts organic-rich black shales which are frequently interbedded with bentonite and hydrothermal minerals (e.g., pyrite). This study investigated the mineralogical, total organic carbon (TOC), total sulfur (TS), and major and trace element compositions of organic-rich samples. Non-visible volcanic input is identified to influence organic matter accumulation, as shown by the correlations between TOC and proxies, including Zr and Hf contents and the Cr/Al2O3, V/Al2O3, Ni/Al2O3, and SiO2/Al2O3 ratios. Redox indicators (V/Cr, v/v + Ni, degree of pyritization (DOP), U/Th, and Mo contents) display positive correlations with TOC values, suggesting that an oxygen-depleted environment is necessary for organic matter (OM) preservation. The TOC values exhibit better regression coefficients (R2) against redox indicators, including DOP (0.43), U/Th (0.70), and Mo contents (0.62), than V/Cr (0.16) and v/v + Ni (0.21). This may because some V, Cr, and Ni is hosted in non-volcanic ashes within shales but not inherited from contemporaneous water columns. The greater scatter in TOC-DOP and TOC-Mo relative to TOC-U/Th relations may result from hydrothermal venting in shales, evidenced by the coexistence of framboid and euhedral pyrite and the previous finding of hydrothermally altered dolomites in the studied sections. There is no systematic relation between TOC and Ni/Co ratios, and this means that portions of Ni are contributed by non-visible volcanic ashes and Ni and Co are redistributed during the precipitation of hydrothermal pyrites due to their strong chalcophile affinities. Such a feature may further suggest that most pyrites are precipitated during hydrothermal venting. The DOP displays broad correlations with non-visible volcanic indicators, supporting that hydrothermal venting may be triggered by volcanic activities. The outcomes of this study highlight that caution is necessary when evaluating the sedimentary facies features of volcanism-affected organic-rich black shales with the used metallic proxies. Full article
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22 pages, 9608 KiB  
Article
Research and Application of Geomechanics Using 3D Model of Deep Shale Gas in Luzhou Block, Sichuan Basin, Southwest China
by Ye Chen, Wenzhe Li, Xudong Wang, Yuan Wang, Li Fu, Pengcheng Wu and Zhiqiang Wang
Geosciences 2025, 15(2), 65; https://doi.org/10.3390/geosciences15020065 - 13 Feb 2025
Viewed by 446
Abstract
The deep shale gas resources of the Sichuan Basin are abundant and constitute an important component of China’s natural gas production. Complicated by fault zones and other geostructures, the in situ stress state of the deep shale gas reservoirs in the Luzhou block [...] Read more.
The deep shale gas resources of the Sichuan Basin are abundant and constitute an important component of China’s natural gas production. Complicated by fault zones and other geostructures, the in situ stress state of the deep shale gas reservoirs in the Luzhou block remains poorly understood. This study integrated multiple datasets, including acoustic logging, diagnostic fracture injection testing (DFIT), imaging logging, and laboratory stress measurements, for calibration and constraint. A high-precision geomechanical model of the Luzhou block was constructed using the finite element method. This model characterizes the geomechanical properties of the reservoir and explores its applications in optimizing shale gas horizontal well placement, drilling processes, and fracture design. The study findings indicate that the Longmaxi Formation reservoir demonstrates abnormally high pore pressure, with gradients ranging from 16.7 to 21.7 kPa/m. The predominant stress regime is strike-slip, with an overburden stress gradient of 25.5 kPa/m and a minimum horizontal principal stress gradient ranging from 18.8 to 24.5 kPa/m. Based on a three-dimensional geomechanical model, a quantitative delineation of areas conducive to density reduction and pressure control drilling was conducted, and field experiments were implemented in well Y65-X. Utilizing an optimized drilling fluid density of 1.85 g/cm3, the deviated horizontal section was completed in a single trip, resulting in a 67% reduction in the drilling cycle compared to adjacent wells. Similarly, the Y2-X well demonstrated a test daily output of 506,900 cubic meters following an optimization of segmentation clustering and fracturing parameters. Studies indicate that 3D geomechanical modeling, informed by multi-source data constraints, can markedly enhance model precision, and such geomechanical models and their results can effectively augment drilling operational efficiency, elevate single-well production, and are advantageous for development. Full article
(This article belongs to the Section Geomechanics)
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21 pages, 5790 KiB  
Article
Sealing Effects on Organic Pore Development in Marine Shale Gas: New Insights from Macro- to Micro-Scale Analyses
by Qiumei Zhou, Hao Xu, Wen Zhou, Xin Zhao, Ruiyin Liu and Ke Jiang
Energies 2025, 18(1), 193; https://doi.org/10.3390/en18010193 - 5 Jan 2025
Viewed by 610
Abstract
The physics of how organic pores change under high thermal evolution conditions in overmature marine shale gas formations remains unclear. In this study, systematic analyses at the macro- to micro-scales were performed to reveal the effects of the sealing capacity on organic pore [...] Read more.
The physics of how organic pores change under high thermal evolution conditions in overmature marine shale gas formations remains unclear. In this study, systematic analyses at the macro- to micro-scales were performed to reveal the effects of the sealing capacity on organic pore development. Pyrolysis experiments were conducted in semi-closed and open systems which provided solid evidence demonstrating the importance of the sealing capacity. Low-maturity marine shale samples from the Dalong Formation were used in the pyrolysis experiments, which were conducted at 350 °C, 400 °C, 450 °C, 500 °C, 550 °C, and 600 °C. The pore characteristics and geochemical parameters of the samples were examined after each thermal simulation stage. The results showed that the TOC of the semi-closed system decreased gradually, while the TOC of the open system decreased sharply at 350 °C and exhibited almost no change thereafter. The maximum porosity, specific surface area, and pore volume of the semi-closed system (10.35%, 2.99 m2/g, and 0.0153 cm3/g) were larger than those of the open system (3.87%, 1.97 m2/g, and 0.0059 cm3/g). In addition, when the temperature was 600 °C, the pore diameter distribution in the open system was 0.001–0.1 μm, while the pore diameter distribution in the semi-closed system was 0.001–10 μm. The pore volumes of the macropores and mesopores in the semi-closed system remained larger than those in the open system. The pore volumes of the micropores in the semi-closed and open systems were similar. The pyrolysis results indicated that (1) the pressure difference caused by the sealing capacity controls organic pore development; (2) organic pores developed in the semi-closed system, and the differences between the two systems mainly occurred in the overmature stage; and (3) the differences were caused by changes in the macropore and mesopore volumes, not the micropore volume. It was concluded that the sealing capacity is the key factor for gas pore generation in the overmature stage of marine shale gas reservoirs when the organic matter (OM) type, volume, and thermal evolution degree are all similar. The macropores and mesopores are easily affected by the sealing conditions, but the micropores are not. Finally, the pyrolysis simulation results were validated with the Longmaxi shale and Qiongzhusi shale properties. The Longmaxi shale is similar to semi-closed system, and the Qiongzhusi shale is similar to open system. Two thermal evolution patterns of organic pore development were proposed based on the pyrolysis results. This study provides new insights into the evolution patterns of organic pores in marine shale gas reservoirs. Full article
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19 pages, 14658 KiB  
Article
The Heterogeneity Characterization of Lacustrine Shale Pores in the Daanzhai Member of the Ziliujing Formation in the Yuanba Area, Sichuan Basin
by Haiyan Hu, Daxing Wang, Wangpeng Li, Gengen Zhu and Xiaoyu Chen
Minerals 2025, 15(1), 11; https://doi.org/10.3390/min15010011 - 26 Dec 2024
Viewed by 428
Abstract
To investigate the heterogeneous characteristics of the shale pore size distribution (PSD) of the Daanzhai Member in the Ziliujing Formation in the Sichuan Basin and its influencing factors, an analysis of its shale components, pore structure, and morphology was conducted. The analysis methods [...] Read more.
To investigate the heterogeneous characteristics of the shale pore size distribution (PSD) of the Daanzhai Member in the Ziliujing Formation in the Sichuan Basin and its influencing factors, an analysis of its shale components, pore structure, and morphology was conducted. The analysis methods included the determination of total organic carbon (TOC), field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), LP-CO2GA, and LT-N2GA. The heterogeneity of the PSD was further analyzed via multifractal theory. The results indicate that the PSDs of both micropores and mesopores in shale exhibit multifractal features. The heterogeneity of mesopores is higher than that of micropores, but the pore connectivity is lower in mesopores than in micropores. Additionally, the degree of dispersion is higher in mesopores than in micropores. The PSD of micropores is influenced mainly by pores in the range of 0.30~0.70 nm in diameter. The distribution of mesopores is significantly affected by pores within the range of 2~10 nm in diameter. The pore connectivity and heterogeneity of mesopores are influenced primarily by the specific surface area (SSA) of the shale. In the case of micropores, both the SSA and pore volume (PV) contribute to the pore connectivity and heterogeneity. The effects of the rock components on the pore heterogeneity and connectivity vary significantly, with mineral components being the primary factors influencing pore heterogeneity. Compared with those of the mature Bakken Formation and the overmature Wufeng–Longmaxi Formation, the shale of the high-maturity Daanzhai Member has higher small-scale pore heterogeneity but weaker mesopore heterogeneity. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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18 pages, 4434 KiB  
Article
Fractal Characteristics of Pore Structure of Longmaxi Shales with Different Burial Depths in Southern Sichuan and Its Geological Significance
by Manping Yang, Yanyan Pan, Hongye Feng, Qiang Yan, Yanjun Lu, Wanxin Wang, Yu Qi and Hongjian Zhu
Fractal Fract. 2025, 9(1), 2; https://doi.org/10.3390/fractalfract9010002 - 24 Dec 2024
Viewed by 731
Abstract
Burial depth can significantly impact the pore structure characteristics of shale. The Lower Silurian Longmaxi Shale in the Weiyuan block of the Sichuan Basin is a marine formation that we studied for deep shale gas exploration. We used two groups of Longmaxi samples, [...] Read more.
Burial depth can significantly impact the pore structure characteristics of shale. The Lower Silurian Longmaxi Shale in the Weiyuan block of the Sichuan Basin is a marine formation that we studied for deep shale gas exploration. We used two groups of Longmaxi samples, outcrop shale and middle-deep shale, to investigate the pore structure fractal features at varying burial depths using a combination of mineralogy, organic geochemistry, scanning electron microscopy (SEM), and low-temperature gas (CO2, N2) adsorption. The V-S fractal model was used to determine the fractal dimension (Dc) of micropores, and the FHH fractal model was used to determine the fractal dimension (DN) of mesopores. The findings indicate that the pore morphology of organic matter becomes irregular and more broken as the burial depth increases, as does the content and maturity of organic matter. The pore size of organic matter gradually decreases, the SSA (BET, DR) and PV (BJH, DA) of shale pores increase, the pore structure becomes more complex, and the average shale pore size decreases. According to this study, the organic matter content and its maturity show an increasing trend as burial depth increases. Meanwhile, the organic matter’s pore morphology tends to be irregular, and fracture rates rise, which causes the organic matter’s pore size to gradually decrease. In addition, the SSA (comprising the values assessed by BET and DR techniques) and PV (evaluated by BJH and DA methods) of shale pores grew, suggesting that the pore structure became more complex. Correspondingly, the average pore size of the shale decreased. The fractal dimensions of the micropores (DC), mesoporous surface (DN1), and mesoporous structure (DN2) of outcrop shale are 2.6728~2.7245, 2.5612~2.5838, and 2.7911~2.8042, respectively. The mean values are 2.6987, 2.5725, and 2.7977, respectively. The DC, DN1, and DN2 of middle-deep shale are 2.6221~2.7510, 2.6085~2.6390, and 2.8140~2.8357, respectively, and the mean values are 2.7050, 2.6243, and 2.8277, respectively. As the fractal dimension grows, the shale’s pore structure becomes more intricate, and the heterogeneity increases as the buried depth increases. The fractal dimension has a positive association with the pore structure parameters (SSA, PV), TOC, and Ro and a negative association with the mineral component (quartz, feldspar, clay mineral) contents. Minerals like quartz, feldspar, and clay will slow down the expansion of pores, but when SSA and PV increase, the pore heterogeneity will be greater and the pore structure more complex. Full article
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18 pages, 9297 KiB  
Article
Characteristics of Lamination in Deep Marine Shale and Its Influence on Mechanical Properties: A Case Study on the Wufeng-Longmaxi Formation in Sichuan Basin
by Jingqiang Tan, Baojian Shen, Huricha Wu, Yaohua Wang, Xinyao Ma, Xiao Ma and Wenhui Liu
Minerals 2024, 14(12), 1249; https://doi.org/10.3390/min14121249 - 9 Dec 2024
Viewed by 763
Abstract
The extensive development of lamination structures in shale significantly influences its mechanical properties. However, a systematic analysis of how laminae affect the macroscopic mechanical behavior of rocks remains absent. In this study, field emission scanning electron microscopy (FE-SEM), thin section observation, X-ray diffraction [...] Read more.
The extensive development of lamination structures in shale significantly influences its mechanical properties. However, a systematic analysis of how laminae affect the macroscopic mechanical behavior of rocks remains absent. In this study, field emission scanning electron microscopy (FE-SEM), thin section observation, X-ray diffraction (XRD), triaxial compression and Brazilian tests were carried out on the deep marine shale of the Wufeng-Longmaxi Formation in Sichuan Basin. The results reveal four distinct laminasets: grading thin silt–thick mud (GSM1), grading medium thick silt–mud (GSM2), grading thick silt–thin mud (GSM3) and alternating thick silt–thin mud (ASM). GSM3 and ASM laminasets exhibit the weakest mechanical properties and the simplest fracture patterns, while GSM2 demonstrates moderate mechanical properties and more complex fracture patterns. GSM1 shows the highest mechanical strength and the most intricate fracture patterns. Mechanical properties are positively correlated with siliceous mineral content and negatively correlated with clay mineral content and scale of laminae development (average density and thickness), revealing that lamination plays a key role in fracture behavior, with more intensively developed laminasets leading to the concentrated distribution of brittle silty minerals, facilitating microcrack propagation. Moreover, microstructure has an important effect on both mechanical properties and fracture pattern. In grain-supported structures, closely packed silty brittle mineral grains reduce the energy required for crack extension. In matrix-supported structures, widespread silty brittle mineral grains increase energy requirements for crack extension, leading to more irregular and complex fracture networks. This study enhances the understanding of the effects of lamination on the rock mechanical behavior of shales, optimizing hydraulic fracturing design in shale reservoirs. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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31 pages, 23830 KiB  
Article
Characteristics and Paleoenvironment of the Niutitang Shale Reservoir in the Zhenba Area
by Tao Tian, Wei Chang, Pei Zhang, Jiahui Yang, Li Zhang and Tianzi Wang
Processes 2024, 12(11), 2595; https://doi.org/10.3390/pr12112595 - 18 Nov 2024
Viewed by 865
Abstract
The lack of in-depth analysis on the reservoir characteristics and the paleoenvironmental conditions of the Niutitang Formation in the study area has led to an unclear understanding of its geological background. In this study, core samples from well SZY1 were selected, and X-ray [...] Read more.
The lack of in-depth analysis on the reservoir characteristics and the paleoenvironmental conditions of the Niutitang Formation in the study area has led to an unclear understanding of its geological background. In this study, core samples from well SZY1 were selected, and X-ray diffraction (XRD), scanning electron microscopy (SEM), and quantitative elemental analysis were employed to systematically investigate the reservoir properties and paleoenvironment of the shales. The results indicate that the Niutitang Formation shales form a low-porosity, low-permeability reservoir. By utilizing indicators such as the chemical index of alteration (CIA) and elemental ratios, the study delves into the paleoclimate and paleoproductivity of the region. The (La/Yb)n ratio is approximately 1, indicating a rapid deposition rate that is beneficial for the accumulation and preservation of organic matter. The chondrite-normalized and North American Shale Composite (NASC)-normalized rare earth element (REE) distribution patterns of the shales show consistent trends with minimal variation, reflecting the presence of mixed sources for the sediments in the study area. Analysis reveals that the Niutitang Formation shales are enriched in light rare-earth elements (LREEs) with a negative europium anomaly, and the primary source rocks are sedimentary and granitic, located far from areas of seafloor hydrothermal activity. The NiEF and CuEF values suggest high paleoproductivity, and the shales were deposited in an anoxic-reducing environment. The depositional environments of the Marcellus and Utica shales in the United States, the Wufeng-Longmaxi black shales in the Changning area of the Sichuan Basin, and the shales in the study area are similar, characterized by anoxic reducing conditions and well-developed fractures. The thermal evolution degree of the study area is relatively moderate, currently in the peak gas generation stage, with the reservoir quality rated as medium to high, indicating good potential for hydrocarbon accumulation and promising exploration prospects. Full article
(This article belongs to the Special Issue Shale Gas and Coalbed Methane Exploration and Practice)
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20 pages, 8601 KiB  
Article
Mechanisms of Reservoir Space Preservation in Ultra-Deep Shales: Insights from the Ordovician–Silurian Wufeng–Longmaxi Formation, Eastern Sichuan Basin
by Pengwan Wang, Xiaolong He, Ya’na Chen, Chuan Xu, Quanbin Cao, Kai Yang and Bing Zhang
Minerals 2024, 14(10), 1046; https://doi.org/10.3390/min14101046 - 18 Oct 2024
Viewed by 992
Abstract
This study aims to explore the reservoir characteristics and formation mechanisms of ultra-deep shale gas in the Ordovician–Silurian Wufeng–Longmaxi Formation in the Sichuan Basin in order to provide theoretical support and practical guidance for the exploration and development of ultra-deep shale gas. With [...] Read more.
This study aims to explore the reservoir characteristics and formation mechanisms of ultra-deep shale gas in the Ordovician–Silurian Wufeng–Longmaxi Formation in the Sichuan Basin in order to provide theoretical support and practical guidance for the exploration and development of ultra-deep shale gas. With recent breakthroughs in ultra-deep shale gas exploration, understanding its organic matter development, mineral composition, and reservoir space characteristics has become particularly important. The background of this research lies in the significant potential of ultra-deep shale gas, which remains inadequately understood, necessitating an in-depth analysis of its pore structure and reservoir quality. Through a systematic study of the ultra-deep shale in well FS1 of Sichuan Basin, that the following was found: (i) The ultra-deep shale in the Wufeng–Longmaxi Formation is mainly composed of quartz and clay minerals, exhibiting high total organic carbon (TOC) and high porosity characteristics, indicating it is in an overmature thermal evolution stage. (ii) Organic pores and microcracks in the ultra-deep shale are more developed compared to middle-shallow and deep shale, forming a complex pore structure that is conducive to gas storage. (iii) In the diagenesis process, the dissolution and recrystallization of the biogenic skeleton promote the cementation between autogenetic quartz particles, forming a rigid skeleton that effectively inhibits the impact of mechanical compaction. (iv) The overpressure environment created by the hydrocarbon generation process, along with gas production from hydrocarbon cracking, can effectively offset the mechanical compaction of overburden pressure on micropores, and this overpressure environment also promotes the further development of microfractures, which is beneficial for the development and preservation of ultra-deep shale pores. In summary, this study not only reveals the reservoir characteristics and formation mechanisms of ultra-deep shale but also provides essential references for the exploration and development of ultra-deep shale gas in the Sichuan Basin and similar regions, emphasizing the ongoing significance of research in this field. Full article
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24 pages, 13038 KiB  
Article
Deciphering Nano-Resolution Petrological Characteristics of the Siliceous Shale at the Bottom of the Longmaxi Formation in the Zigong Area, Sichuan Basin, China: Deep-Water Microbialites
by Xiaofeng Zhou, Wei Guo, Xizhe Li, Pingping Liang, Junmin Yu and Chenglin Zhang
Minerals 2024, 14(10), 1020; https://doi.org/10.3390/min14101020 - 10 Oct 2024
Cited by 1 | Viewed by 609
Abstract
Three nano-resolution petrological microtextures were discovered in the siliceous shale at the bottom of the Longmaxi Formation in the Zigong area, Sichuan Basin. Based on observations of the occurrences of the minerals, organic matter, and organic matter pores in the different microtextures and [...] Read more.
Three nano-resolution petrological microtextures were discovered in the siliceous shale at the bottom of the Longmaxi Formation in the Zigong area, Sichuan Basin. Based on observations of the occurrences of the minerals, organic matter, and organic matter pores in the different microtextures and analysis of their relationships by means of nano-resolution petrological image datasets obtained using the Modular Automated Processing System (MAPS 3.18), the formation mechanism of the siliceous shale was studied. The results show that the strong modification of clay-rich sediments by a deep-water traction current was the basis for the formation of the siliceous shale. The clay-rich sediments were converted into flocculent sediments rich in oxygen and nutrients via agitation and transport by the deep-water traction current, providing space and a material basis for microbes to flourish. Under the continuous activity of the deep-water traction current, the clay-rich sediments were transformed into microbial mats, in which in situ terrigenous detrital quartz and feldspar, endogenous detrital calcite, authigenic dolomite, and dolomite ringed by ferrodolomite were scattered. During the burial stage, the microbial mats were lithified into the siliceous shale composed of three petrological microtextures. Microtexture I was mainly transformed by microbes. Microtexture II was formed via lithification of the residual clay-rich sediments. Microtexture III was composed of migratory organic matter filling hydrocarbon-generating pressurized fractures. Due to the universality of deep-water traction flow and the diversity of microbes in deep-water sediments, we firmly believe that more and more deep-water microbialites will be discovered worldwide through systematic characterization of nano-resolution petrology with the booming development of the shale gas industry. Full article
(This article belongs to the Section Mineral Deposits)
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27 pages, 9970 KiB  
Article
Factors Controlling Differences in Morphology and Fractal Characteristics of Organic Pores of Longmaxi Shale in Southern Sichuan Basin, China
by Yuanlin Wang, Denglin Han, Wei Lin, Yunqian Jia, Jizhen Zhang, Chenchen Wang and Binyu Ma
Fractal Fract. 2024, 8(10), 555; https://doi.org/10.3390/fractalfract8100555 - 25 Sep 2024
Cited by 2 | Viewed by 1402
Abstract
Shale gas is a prospective cleaner energy resource and the exploration and development of shale gas has made breakthroughs in many countries. Structure deformation is one of the main controlling factors of shale gas accumulation and enrichment in complex tectonic areas in southern [...] Read more.
Shale gas is a prospective cleaner energy resource and the exploration and development of shale gas has made breakthroughs in many countries. Structure deformation is one of the main controlling factors of shale gas accumulation and enrichment in complex tectonic areas in southern China. In order to estimate the shale gas capacity of structurally deformed shale reservoirs, it is necessary to understand the systematic evolution of organic pores in the process of structural deformation. In particular, as the main storage space of high-over-mature marine shale reservoirs, the organic matter pore system directly affects the occurrence and migration of shale gas; however, there is a lack of systematic research on the fractal characteristics and deformation mechanism of organic pores under the background of different tectonic stresses. Therefore, to clarify the above issues, modular automated processing system (MAPS) scanning, low-pressure gas adsorption, quantitative evaluation of minerals by scanning (QEMSCAN), and focused ion beam scanning electron microscopy (FIB-SEM) were performed and interpreted with fractal and morphology analyses to investigate the deformation mechanisms and structure of organic pores from different tectonic units in Silurian Longmaxi shale. Results showed that in stress concentration areas such as around veins or high-angle fractures, the organic pore length-width ratio and the fractal dimension are higher, indicating that the pore is more obviously modified by stress. Under different tectonic backgrounds, the shale reservoir in Weiyuan suffered severe denudation and stronger tectonic compression during burial, which means that the organic pores are dominated by long strip pores and slit-shaped pores with high fractal dimension, while the pressure coefficient in Luzhou is high and the structural compression is weak, resulting in suborbicular pores and ink bottle pores with low fractal dimension. The porosity and permeability of different forms of organic pores are also obviously different; the connectivity of honeycomb pores with the smallest fractal dimension is the worst, that of suborbicular organic pores is medium, and that of long strip organic pores with the highest fractal dimension is the best. This study provides more mechanism discussion and case analysis for the microscopic heterogeneity of organic pores in shale reservoirs and also provides a new analysis perspective for the mechanism of shale gas productivity differences in different stress–strain environments. Full article
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30 pages, 19679 KiB  
Article
Paleoenvironmental Transition during the Rhuddanian–Aeronian and Its Implications for Lithofacies Evolution and Shale Gas Exploration: Insights from the Changning Area, Southern Sichuan Basin, South-West China
by Hangyi Zhu
Minerals 2024, 14(9), 949; https://doi.org/10.3390/min14090949 - 18 Sep 2024
Viewed by 818
Abstract
During the Rhuddanian–Aeronian interglacial period, global geological events such as glacial melting, synsedimentary volcanic activity, biological resurgence, and large-scale marine transgressions caused frequent fluctuations in paleoproductivity, climate changes, and sea level variations. These paleoenvironmental transitions directly influenced the development characteristics of shale lithofacies. [...] Read more.
During the Rhuddanian–Aeronian interglacial period, global geological events such as glacial melting, synsedimentary volcanic activity, biological resurgence, and large-scale marine transgressions caused frequent fluctuations in paleoproductivity, climate changes, and sea level variations. These paleoenvironmental transitions directly influenced the development characteristics of shale lithofacies. This study investigates the Longmaxi Formation shale in the Changning area in the Southern Sichuan basin, focusing on 28 core samples from Well N1. Using scanning electron microscopy, QEMSCAN, TOC, XRD, and major and trace element analyses, we reconstructed the paleoenvironmental transitions of this period and explored their control over shale lithofacies types and mineral compositions. Four shale lithofacies were identified: carbonate rich lithofacies (CRF), biogenic quartz-rich lithofacies (BQRF), detrital clay-rich lithofacies (CRDF), and detrital quartz-rich lithofacies (DQRF). During the Rhuddanian period, rising global temperatures caused glacial melting and rapid marine transgressions. The low oxygen levels in bottom waters, combined with upwelling and abundant volcanic material, led to high paleoproductivity. This period primarily developed BQRF and CRF. Rich nutrients and abundant siliceous organisms, along with anoxic to anaerobic conditions, provided the material basis and preservation conditions for high biogenic quartz and organic matter content. High paleoproductivity and anoxic conditions also facilitated the precipitation of synsedimentary calcite and supplied Mg2+ and SO42− for the formation of iron-poor dolomite via sulfate reduction. From the Late Rhuddanian to the Mid-Aeronian, the Guangxi orogeny caused sea levels to fall, increasing water oxidation and reducing upwelling and volcanic activity, which lowered paleoproductivity. Rapid sedimentation rates, stepwise global temperature increases, and the intermittent intensification of weathering affected terrigenous clastic input, resulting in the alternating deposition of CRF, CRDF, and DQRF. Two favorable shale gas reservoirs were identified from the Rhuddanian–Aeronian period: Type I (BQRF) in the L1–L3 Layers, characterized by high TOC and brittleness, and Type II (DQRF) in the L4 Layer, with significant detrital quartz content. The Type I-favorable reservoir supports ongoing gas production, and the Type II-favorable reservoir offers potential as a future exploration target. Full article
(This article belongs to the Special Issue Environment and Geochemistry of Sediments, 2nd Edition)
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17 pages, 4395 KiB  
Article
Genesis of Low-Resistivity Shale Reservoirs and Its Influence on Gas-Bearing Property: A Case Study of the Longmaxi Formation in Southern Sichuan Basin
by Xi Hu, Anfu Zhou, Yading Li, Hongzong Jiang, Yonghong Fu, Yuqiang Jiang and Yifan Gu
Appl. Sci. 2024, 14(17), 7515; https://doi.org/10.3390/app14177515 - 25 Aug 2024
Viewed by 921
Abstract
To mitigate the exploration and development risks, it is necessary to have a deeper understanding of the formation mechanism and gas-bearing control factors of low-resistance shale reservoirs. This study focuses on typical shale gas wells (including low-resistivity wells) in Luzhou area, and identification [...] Read more.
To mitigate the exploration and development risks, it is necessary to have a deeper understanding of the formation mechanism and gas-bearing control factors of low-resistance shale reservoirs. This study focuses on typical shale gas wells (including low-resistivity wells) in Luzhou area, and identification criteria for low-resistance shale reservoirs are redefined as resistivity less than 10 Ω·m and continuous formation thickness greater than 6 m. At the macro scale, low-resistivity shale reservoirs are characterized by high clay mineral content and high water saturation with low gas content. At the micro scale, the main pore size is less than 10 nm, with a small total pore volume but a large specific surface area. Shale reservoirs close to the Class II fault have high water saturation and strong compaction, which hinders the mutual transformation between minerals, resulting in low-resistivity shale with high clay mineral content, small pore volume, and pore size, which promotes the enhancement of reservoir conductivity. The gas content of low-resistivity shale reservoirs is lower, because the distance from the Class II fault is closer, resulting in high water saturation and strong diagenesis, which is not conducive to pore development and shale gas accumulation. When the water saturation exceeds 40%, the pore volume of shale reservoirs rapidly decreases to as low as 0.0074 cm3/g. In order to reduce the risk of exploration and development of the area, the well location deployment needs to be more than 2.8 km away from the Class II fault. Full article
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