Search Results (293)

In this study, Californian-style black table olives were enriched with fresh and lyophilized “Carao” (Cassia grandis L.) to enhance their mineral composition, antioxidant activity, phenolic compound content, and to evaluate their potential for reducing acrylamide levels. Mineral concentrations were quantified using inductively coupled plasma optical emission spectrometry (ICP-OES). The addition of both fresh and lyophilized “Carao” significantly increased the iron concentration in the olives. Additionally, levels of calcium, magnesium, and potassium were elevated in both “Carao” treatments. Among the treatments, the addition of fresh “Carao” resulted in the highest increase in antioxidant activity, followed by the lyophilized “Carao”, with increases of 62.3% and 68.3%, respectively. The effect of fresh and lyophilized “Carao” on acrylamide reduction in oxidized olives is also discussed. Full article

The monitoring of contaminants in imitation jewelry has become important nowadays due to the high amount of products sold worldwide. Due to the complexity of the sample matrix (composed mainly of metals in high concentration), sample analysis can be very challenging. One interesting alternative for this purpose is the use of photochemical vapor generation coupled to inductively coupled plasma optical emission spectrometry (PVG-ICP-OES) due to the ability of separating the analytes from the sample solution prior to analysis; additionally, it is considered an eco-friendly approach if compared to other vapor generation techniques. Thus, this work presents the development and application of a PVG-ICP-OES system for the determination of Hg and Pb in imitation jewelry after sample dissolution in hydrochloric acid. The PVG system was built with two UV lamps (254 nm), a quartz capillary reactor, and a glass gas-liquid separator. Acetic acid concentration and UV exposure time were optimized using a central composite design, as well as the carrier gas flow rate and the radiofrequency (RF) power for the ICP-OES. The optimum conditions were achieved at 30% v/v acetic acid, 60 s reaction time, 0.035 L min⁻¹ carrier gas flow rate, and 1310 W for RF power. The influence of the sample matrix and chemical modifiers were studied, where it was found that the presence of the sample matrix may cause suppression of the analytical signal. The accuracy of the method was evaluated by recovery tests, which ranged from 88 to 102%. The detection limits ranged from 1 to 3 mg g⁻¹, allowing the monitoring of Hg and Pb in imitation jewelry. Full article

Rock dust (RD) is a by-product of the precious metal mining industry. Some mining operations produce close to 2,000,000 Mg of RD/year, posing disposal issues. This study evaluated the physicochemical and microbial properties of RD from gold mining and its potential use in RD-based growing media. Ten media formulations were tested: Promix (Control), 100% (RD), 100% topsoil (TS), 50% RD + 50% topsoil (RDT), 25% RD + 75% topsoil (RT), 50% RD + 50% Promix (RP), 50% RD + 25% biochar + 25% Promix (RBP), 50% RD + 25% compost + 25% Promix (RCP), 50% RD + 50% biochar (RB), and Huplaso (negative control). RD particle size ranged from 0.1 to 2 mm with a bulk density of 1.5 g cm⁻³, while RD-based media ranged from 0.8 to 1.1 g cm⁻³ showing increased porosity. Nutrient content was analyzed using Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES), and the active microbial community assessed using PLFA biomarkers via GC-MS/FID, n = 4 and p = 0.05. Microbial analysis identified five classes (protozoa, eukaryotes, Gram-positive (G+), Gram-negative (G−), and fungi (F)), with a significant increase in G−, G+, and F in RD-based amendment RBP (28%) compared to control P (9%). G+, G−, and F showed a strong negative correlation (r = −0.98) with pH, while calcium correlated positively (r = 0.85) with eukaryotes and a strong positive correlation (r = 0.95) of cation exchange capacity with G+. This study suggests blending RD with organic amendments improves physicochemical quality and microbial activity, supporting its use in crop production over disposal. Full article

Increasing pollution of aquatic ecosystems due to anthropogenic activities underscores the urgent need for effective water quality monitoring. This study evaluates the use of fish scales from chub (Squalius cephalus) and nase (Chondrostoma nasus) as non-invasive bioindicators of trace and macroelement pollution in the Maros/Mureș River. We conducted qualitative and quantitative elemental analyses using X-ray fluorescence (XRF) and inductively coupled plasma optical emission spectrometry (ICP-OES). Scanning electron microscopy (SEM) revealed distinct scale structures among the species studied. Concentrations of Ca, K, Mg, Na, P, S, Al, Ba, Cu, Cr, Fe, Mn, Sr, and Zn were measured by ICP-OES. Our findings indicate significant variability in elemental accumulation in fish scales, supporting their potential use as bioindicators of environmental pollution, with variability depending on the ecological characteristics of the species. This methodology offers promising applications for modern interdisciplinary monitoring programs. Full article

The objective of this study was to evaluate the variation in the mineral concentrations of the inflorescences of Yucca filifera (izote), Agave salmiana (maguey), Diphysa americana (cuachepil), and Chamaedorea tepejilote (tepejilote) in samples collected from different communities in Oaxaca, Mexico. For each sample, the concentrations of macro- and microelements were determined via inductively coupled plasma–optical emission spectrometry (ICP-OES). For each species, significant differences (p < 0.05) in mineral contents were detected on the basis of geographic sampling origin, both among and within locations, for all the minerals evaluated except for Na in all the cases, Cu in izote and tepejilote, and Si in maguey. The macro- and microelement patterns range from highest to lowest concentrations were as follows: K > Ca ≥ P > Mg > S > Na and Si > Fe ≥ Zn > Mn > Cu > Mo. High values were recorded in tepejilote, whereas low values were observed in cuachepil, maguey pulquero, and izote. The average values between species ranged from 199.1 to 3650.3, 243.6 to 3383.7, 354.8 to 941.7, 164.5 to 1281, 76.2 to 1142.9, 1.3 to 44.7, 4.27 to 201, 2.41 to 13.67, 3.08 to 9.23, 0.81 to 13.65, and 0.52 to 3.09 mg 100 g⁻¹ dw in K, Ca, P, Mg, S, Na, Si, Fe, Zn, Mn, and Cu, respectively, indicating a nutritional source in the regions where they are distributed. Full article

Background and Objectives: Maintaining an appropriate hydration status is crucial for promoting health. Children, who are in the process of growth and development, are at a higher risk of insufficient water intake and dehydration. This study aimed to compare water intake among children with different levels of dietary sodium intake, and explore the relationship between hydration status, and dietary sodium intake and water intake. Methods: In this cross-sectional survey, 155 students in grades 4–6 from a primary school in Binyang County, Nanning, Guangxi, were recruited. Water intake from fluid was assessed using a validated 7-Day 24 h Fluid Intake Survey Questionnaire (days 1–7). Food intake was recorded and weighed using the duplicate diet method on days 5, 6, and 7. The water content in food was determined using the direct drying method, and dietary sodium intake was measured using inductively coupled plasma-optical emission spectrometry (ICP-OES). Urine osmolality was measured at two time points (morning and before afternoon classes) on days 5, 6, and 7 to assess hydration status. Results: A total of 155 participants (87 boys and 68 girls) completed the study, with a completion rate of 100%. The average dietary sodium intake, total water intake (TWI), water intake from fluid, and water intake from food were 1647 mg, 2039 mL, 956 mL, and 1175 mL, respectively. Among the participants, 19.4% exceeded the recommended sodium intake (2000 mg/day), 41.9% did not meet the adequate daily water intake from fluid, and 63.2% did not meet the adequate daily total water intake. When participants were divided into quartiles based on dietary sodium intake, significant differences were observed in water intake from fluid (p = 0.031) and food (p < 0.001). The water intake from fluid among participants in the HS1 (982 mL) and HS2 groups (997 mL) was higher than that among participants in LS2 (759 mL). Water intake from food increased progressively with increasing sodium intake (851 mL, 1075 mL, 1224 mL, and 1550 mL). Urine osmolality was associated with meeting the daily adequate water intake from fluid (p = 0.006), but not with exceeding the sodium intake standard (p = 0.787). There was no interaction between meeting the daily adequate water intake from fluid and exceeding the sodium intake standard (p = 0.413). Conclusions: Insufficient water intake was common among children. Children with a higher dietary sodium intake had a higher water intake from fluid and food. Urine osmolality was closely related to daily water intake from fluid, but not to sodium intake. Full article

The dichotomy of striking a balance between sustainable food crop production for the skyrocketing human population and ensuring agricultural practices that mitigate environmental degradation has prompted much research into sustainable crop production methods. The application of amendments has become an integral part of arable soil management in restoring declining soil fertility for sustainable and high-quality crop production. This study was conducted on lettuce and carrot cultivated on soil treated with three different amendments: cow dung, sewage sludge, and nitrogen–phosphorus–potassium (NPK) mineral fertilizer. The vegetables were harvested at maturity at 60 and 110 days for lettuce and carrot, respectively, dried in a hot air oven, crushed, and then digested to obtain an aliquot sample. The level of macronutrients was quantified from the aliquots using inductively coupled plasma optical emission spectrometry (ICP-OES), Avio 550 Max, PerkinElmer, USA. It was observed that both soil treatment and types of vegetables significantly impacted the level of mineral contents in the vegetables. The highest values of 58.00 ± 8.36 mg/kg and 72.97 ± 12.53 mg/kg were recorded for Na and P in carrots from soil treated with sewage sludge, respectively. The highest values of 247.97 ± 17.07 mg/kg and 104.72 ± 4.12 mg/kg were recorded for Ca and Mg in lettuce from sewage sludge-treated soil, respectively. Similarly, the highest value of 546.75 ± 76.44 mg/kg for K was also recorded in lettuce, but from cow dung-treated soil. The overall pattern of mineral accumulation by vegetables shows that carrots accumulate more Na than lettuce, and lettuce accumulates more Mg, Ca, and K than carrots, while there was no significant difference in the level of P in both lettuce and carrots. The findings reveal that lettuce and carrots from soil treated with organic manure cow dung and sewage sludge accumulated higher mineral contents of most of the investigated minerals. It was also observed that lettuce accumulated higher contents of most of the minerals investigated. This study therefore concludes that organic manures are better alternatives to mineral fertilizers for vegetable production, which supports the effort to strike a balance between sustainable and ecofriendly agriculture. Full article

Citriculture has worldwide importance, and monitoring the nutritional status of plants through leaf analysis is essential. Recently, proximal sensing has supported this process, although there is a lack of studies conducted specifically for citrus. The objective of this study was to evaluate the application of portable X-ray fluorescence spectrometry (pXRF) combined with machine learning algorithms to predict the nutrient content (B, Ca, Cu, Fe, K, Mg, Mn, P, S, and Zn) of citrus leaves, using inductively coupled plasma optical emission spectrometry (ICP-OES) results as a reference. Additionally, the study aimed to differentiate 15 citrus scion/rootstock combinations via pXRF results and investigate the effect of the sample condition (fresh or dried leaves) on the accuracy of pXRF predictions. The samples were analyzed with pXRF both fresh and after drying and grinding. Subsequently, the samples underwent acid digestion and analysis via ICP-OES. Predictions using dried leaves yielded better results (R² from 0.71 to 0.96) than those using fresh leaves (R² from 0.35 to 0.87) for all analyzed elements. Predictions of scion/rootstock combinations were also more accurate with dry leaves (Overall accuracy = 0.64, kappa index = 0.62). The pXRF accurately predicted nutrient contents in citrus leaves and differentiated leaves from 15 scion/rootstock combinations. This can significantly reduce costs and time in the nutritional assessment of citrus crops. Full article

During the grinding process, magnesite (MgCO₃) and calcareous gangue minerals, such as dolomite (MgCa(CO₃)₂), are prone to surface dissolution. The dissolved metal ions adsorb onto the mineral surfaces, causing the surface properties of both minerals to converge, which complicates flotation separation. This study investigates the use of ethylene glycol tetra-acetic acid (EGTA) to optimize the grinding–flotation system for the recovery of magnesite. The mechanisms underlying EGTA’s effects on the minerals were examined through various characterization techniques, including contact angle measurements, zeta potential analysis, Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and inductively coupled plasma optical emission spectrometry (ICP-OES). Single-mineral flotation tests revealed that EGTA addition during grinding enhanced the separation between magnesite and dolomite in flotation. An artificial mixed-ore flotation yielded a concentrate with 46.47% MgO grade and 92.21% MgO recovery. Mechanistic studies indicated that EGTA selectively adsorbed onto Ca sites on the surface of dolomite, increasing its hydrophilicity. Additionally, EGTA effectively chelated Ca²⁺ in the slurry, improving the chemical environment. Therefore, EGTA demonstrated significant potential for improving the flotation of magnesite. Full article

Mytilus chilensis is considered an important food source for the Chilean population and represents a considerable fraction of its aquacultural production, mainly in southern Chile’s coastal regions. This study aimed to assess the concentrations of total arsenic (tAs), lead (Pb), and cadmium (Cd), their bioaccessibility, and associated health risks in M. chilensis from the Valdivia River Estuary (VRE) in the Los Ríos Region and the Reloncaví Fjord (RF) in the Los Lagos Region. The metal concentrations were quantified using Inductively Coupled Plasma–Optical Emission Spectrometry (ICP-OES). The concentrations of tAs, Cd, and Pb were 6682 ± 2018, 1592 ± 742, and 1208 ± 639 ng/g d.w., respectively. Variations in the metal concentrations were observed across areas, months, and sampling points but remained below national and international limits. No correlation was found between the metal concentrations and environmental parameters. The bioaccessibility percentages were tAs (68 ± 10%), Cd (45 ± 21%), and Pb (15 ± 4%). The tAs, Pb and Cd levels in M. chilensis from southern Chile do not represent a risk to human health. Full article

This study investigates the content of some metals and metalloids in the flowers of three Aesculus cultivars (AHP, Aesculus hippocastanum pure species, with white flowers; AHH, Aesculus hippocastanum hybrid species, with pink flowers; and AXC, Aesculus × carnea, with red flowers) over a four-year period (2016–2019) using inductively coupled plasma optical emission spectrometry (ICP OES) and principal component analysis (PCA). The research focuses on assessing macro- and micro-elemental compositions, identifying variations in mineral uptake, and exploring potential correlations with soil composition. Results highlight significant differences in elemental profiles among the three species, despite similar total ash content. Potassium and phosphorus emerged as dominant macroelements, with AXC showing lower magnesium levels compared to AHP and AHH. Particularly intriguing was the detection of antimony in all cultivars, raising questions about its role and bioaccumulation pathways in floral tissues. Iron and aluminum concentrations varied significantly across species, indicating species-specific metal transport mechanisms. Nickel content showed temporal fluctuations, potentially influenced by climatic conditions and soil properties. PCA revealed distinct clustering patterns, linking elemental concentrations to specific species and years. This comprehensive analysis enhances understanding of metal absorption and distribution in ornamental plants, providing insights into their metabolic processes and potential implications for environmental monitoring and phytoremediation strategies. Full article

Background/Objectives: Degenerative lumbo-sacral spinal stenosis is characterized by spinal canal narrowing, often linked to ligamentum flavum hypertrophy. This study evaluated the elemental composition of ligamentum flavum tissue in DLSS patients compared to healthy controls. Methods: This study involved 180 patients diagnosed with degenerative lumbo-sacral spinal stenosis and 102 healthy controls. Ligamentum flavum samples were analyzed for concentrations of magnesium (Mg), calcium (Ca), phosphorus (P), zinc (Zn), copper (Cu), iron (Fe), sodium (Na), potassium (K), manganese (Mn), and lead (Pb) using inductively coupled plasma optical emission spectrometry (ICP-OES). Statistical analyses were conducted using Student’s t-test, ANOVA, and Pearson’s correlation, with a significance threshold of p < 0.05. Results: The study group exhibited significantly elevated levels of Mg (p < 0.001), Ca (p = 0.014), and P (p = 0.006), along with reduced concentrations of Zn (p = 0.021) and Cu (p = 0.038) compared to controls. No statistically significant differences were observed for Na, K, Mn, or Fe (p > 0.05). Elemental imbalances were more pronounced in individuals with higher body mass index (BMI) and varied by gender. Pain intensity demonstrated a significant correlation with Zn (p = 0.012) and Na (p = 0.045), but no consistent associations with Mg, Ca, or P. Conclusions: Altered Mg, Ca, P, and Zn levels in ligamentum flavum suggest their involvement in degenerative lumbo-sacral spinal stenosis pathophysiology. These elements may serve as potential biomarkers and therapeutic targets for mitigating spinal canal narrowing. Full article

Tellurium, recognized as one of the technology-critical elements, should be considered as a xenobiotic. Its application, i.a. in the growing photovoltaic industry, raises concerns about Te(IV) and Te(VI) release to the environment. As both forms differ in mobility and toxicity, Te speciation should be included in water monitoring, but problems with speciation changes occurring during sampling, transport, and sample storage require the use of on-site separation of Te forms. A simple procedure based on solid phase extraction (SPE) with the anionic exchange mechanism (SAX, involving commercially available columns), followed by their quantification with elemental techniques, has a high potential for implementation in routine analysis. The proposed SPE-ICP-MS (inductively coupled plasma mass spectrometry) method allows direct analysis of Te(VI) and Te(IV), with Te(IV) determined after elution from the column. The detection limits obtained for the 5.0 mL sample are 0.02 ng mL⁻¹ and 0.05 ng mL⁻¹ for Te(VI) and Te(IV), respectively. Hydride generation inductively coupled plasma optical emission spectrometry (HG-ICP-OES) was used to control possible changes in tellurium speciation occurring during species isolation using SPE. The simple and fast water pretreatment proposed here offers the possibility of separating Te(IV) and Te(VI) at the sampling site, and the elution of Te(IV) does not have to be conducted on-site. Application to the river water and seawater matrix proved the feasibility of incorporating Te speciation analysis into routine water analysis. Full article

Multivariate and statistical tool advancements help to assess potential pollution threats, their geochemical distribution, and the competition between natural and anthropogenic influences, particularly on sediment contamination with potentially toxic metals (PTMs). For this, riverine sediments from 25 locations along urban banksides of the River Ravi, Pakistan, were collected and analyzed to explore the distribution, pollution, ecological, and toxicity risk indices of PTMs like Al, As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sb, Sn, Sr, V, and Zn using Inductively Coupled Plasma–Optical Emission Spectrometry (ICP-OES) technique. Additionally, techniques such as X-ray Diffraction (XRD) and Scanning Electron Microscopy–Energy Dispersive X-ray Spectroscopy (SEM-EDS) were employed to investigate the mineralogical and morphological aspects. The results indicated that mean concentrations (mg kg⁻¹) of Cd (2.37), Cr (128), Hg (16.6), Pb (26.6), and Sb (2.44) were significantly higher than reference values given for upper continental crust (UCC) and world soil average (WSA), posing potential threats. Furthermore, the geochemical pollution indices showed that sediments were moderately polluted with Cd (I_geo = 2.37, EF = 12.1, and CF = 7.89) and extremely polluted with Hg (I_geo = 4.54, EF = 63.2, and CF = 41.41). Ecological and toxicity risks were calculated to be extremely high, using respective models, predominantly due to Hg (Er_i = 1656 and ITRI = 91.6). SEM-EDS illustrated the small extent of anthropogenic particles having predominant concentrations of Zn, Fe, Pb, and Sr. Multivariate statistical analyses revealed significant associations between the concentrations of PTMs and the sampling locations, highlighting the anthropogenic contributions linked to local land-use characteristics. The present study concludes that River Ravi sediments exhibit moderate levels of Cd and extreme pollution by Hg, both of which contribute highly to extreme ecological and toxicity risks, influenced by both natural and anthropogenic contributions. Full article

This study, based on our previous research, aims to quantitatively determine the enhanced protection of austenitic stainless steels against pitting corrosion in NaCl solution by self-assembled molecular (SAM) layers, in their original form and after γ-irradiation. This study focuses on four stainless steels of varying compositions, covered by self-assembled undecenyl phosphonic acid layers. The metal dissolution in corrosion experiments was measured by a special, highly sensitive analytical technique using the inductively coupled plasma–optical emission spectrometry (ICP-OES). The comparison of the dissolved metal ion concentrations measured in the presence of different metals with and without nanocoatings allowed the evaluation of the anticorrosion effectiveness of nanofilms as well as the importance of the alloying elements. The ICP-OES results demonstrated that the quality of layers have a significant impact on anticorrosion efficacy. The γ-irradiated self-assembled layers were the most effective in controlling the dissolution of stainless steels. The mechanisms of the inhibition in the presence of these nanolayers were elucidated by infrared spectroscopy. First of all, it revealed the differences in the adsorption of the undecenyl phosphonic acid self-assembled layer, both with and without γ-irradiation. The other important observation that confirmed the increased anticorrosion efficiency after γ-irradiation proved the formation of a more compact, polymer-like layer over the metal surface. The increased anticorrosion efficacy, defined as the enhancement in Pitting Resistance Equivalent Numbers (PRENs) in the presence of self-assembled layers (either pre- or post-γ-irradiation), can be documented. Full article