Current Trends in Homogeneous and Heterogeneous Catalysts for Water Electrolysis

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Electrocatalysis".

Deadline for manuscript submissions: closed (20 October 2021) | Viewed by 3818

Special Issue Editors

School of Chemistry, National University of Ireland Galway, University Road, H91 CF50 Galway, Ireland
Interests: water splitting; artificial photosynthesis; photochemistry; photoactive materials; nanomaterials
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Co-Guest Editor
Institute of Chemical Research of Catalonia (ICIQ),the Barcelona Institute of Science and Technology Av.Països atalans 16, Tarragona, Spain
Interests: chemistry; materials science; energy

Special Issue Information

Dear Colleagues,

The production of green hydrogen through water electrolysis powered by renewable energy sources constitutes one of the most promising solutions to tackle climate change. With recent advances in solar and wind energy, the price of electricity is drastically decreasing, even achieving zero cost when the electrical grid cannot cope with electricity production. In order to lower the costs of water electrolysis, research into novel electrocatalysts based on earth-abundant elements is fundamental. These need to be applied to both the oxygen-evolving reaction (OER) and the hydrogen-evolving reaction (HER). Targeted electrocatalysts need to be active and stable over different pH ranges, depending on the type of electrolyzer to be incorporated in. Moreover, they should be able to maintain their activity in the presence of foreign ions or molecules, so that the purification requirements for long-term operation are minimized.

This Special Issue aims to cover recent research and developments in the synthesis of highly-stable and active electrocatalysts for water splitting, both for OER and HER. For the advancement in the field, we encourage authors to contribute to this issue with electrocatalysts based on both molecular and materials systems, since detailed understanding of the mechanisms of the reaction is crucial for the design and preparation of novel electrocatalysts. In addition, details of advanced characterization of electrocatalysts, computational studies, incorporation in flow electrochemical cells and potential scale-up of electrolyzers are important subjects in this issue.

Dr. Pau Farras
Prof. Dr. Jose Ramon Galan-Mascaros
Guest Editors

Manuscript Submission Information

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Keywords

  • electrocatalysis
  • water splitting
  • hydrogen evolution
  • oxygen evolution
  • renewable energy
  • electrolysers
  • energy storage

Published Papers (1 paper)

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Research

12 pages, 2721 KiB  
Article
Facile Synthesis of Iron-Titanate Nanocomposite as a Sustainable Material for Selective Amination of Substitued Nitro-Arenes
by Manzar Sohail, Nimra Tahir, Anosha Rubab, Matthias Beller and Muhammad Sharif
Catalysts 2020, 10(8), 871; https://doi.org/10.3390/catal10080871 - 03 Aug 2020
Cited by 5 | Viewed by 3186
Abstract
The fabrication of durable and low-cost nanostructured materials remains important in chemical, biologic and medicinal applications. Particularly, iron-based nanomaterials are of central importance due to the ‘noble’ features of iron such as its high abundance, low cost and non-toxicity. Herein we report a [...] Read more.
The fabrication of durable and low-cost nanostructured materials remains important in chemical, biologic and medicinal applications. Particularly, iron-based nanomaterials are of central importance due to the ‘noble’ features of iron such as its high abundance, low cost and non-toxicity. Herein we report a simple sol–gel method for the synthesis of novel iron–titanium nanocomposite-based material (Fe9TiO15@TiO2). In order to prepare this material, we made a polymeric gel using ferrocene, titanium isopropoxide and THF precursors. The calcination of this gel in air at 500 °C produced Fe-Ti bimetallic nanoparticles-based composite and nano-TiO2 as support. Noteworthy, our methodology provides an excellent control over composition, size and shape of the resulting nanoparticles. The resulted Fe-based material provides a sustainable catalyst for selective synthesis of anilines, which are key intermediates for the synthesis of several chemicals, dyes and materials, via reduction of structurally diverse and functionalized nitroarenes. Full article
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