Environmental Remediation via Metal-Oxides-Mediated Heterogeneous Photocatalysis

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Photocatalysis".

Deadline for manuscript submissions: closed (30 December 2023) | Viewed by 8802

Special Issue Editors


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Guest Editor
Leibniz Institute for Catalysis (LIKAT), Rostock, Germany
Interests: photocatalysis; artificial photosynthesis; solar fuels; the synthesis of advanced nanomaterials
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Guest Editor
Institute of Nanoscience and Nanotechnology, National Centre of Scientific Research Demokritos, Athens, Greece
Interests: catalysis; environmental depollution; characterization of materials; nanomaterials

Special Issue Information

Dear Colleagues,

Over the last decade, the general public has become increasingly interested in environmental protection including cleaning air and water and also sustainable ways of producing energy. Access to clean water should not be taken as a given in any part of the world and the increasing atmospheric concentration of CO2 heavily affects Earth’s climate.

Since the pioneering work of Fujishima and Honda (A. Fujishima, K. Honda, Nature 238, 1972, 37–38), the field of photocatalysis has attracted the attention of the scientific community. An ever-increasing number of publications focus on using solar light efficiently both to degrade harmful gaseous (e.g., NOx) or liquid pollutants (e.g., pharmaceuticals in wastewater effluents) and to reduce atmospheric CO2 concentration.

In the field of photocatalysis, one family of materials stands out as the most studied: metal oxides. Metal oxides provide a unique selection of properties such as (but not limited to) low-cost and toxicity, high availability, semiconductivity, a great variety of synthesis processes and modification techniques, and tunable light-absorbing capabilities. Their most prominent drawback – a usually very large bandgap – can today be addressed synthetically by strategies such as doping or compounding.

Submissions to this Special Issue on “Environmental Remediation via Metal-Oxide-Mediated Heterogeneous Photocatalysis” are welcome in the form of original research papers or short reviews about the use of metal oxides in the following photocatalytic processes: CO2 conversion to useful products and platform chemicals; NOx reduction; degradation of emerging contaminants present in water; novel design of photocatalytic reactors; identification of kinetics, intermediates, and products from photocatalytic processes.

Dr. Nikolaos G. Moustakas
Dr. Fotis Katsaros
Guest Editors

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Keywords

  • Heterogeneous photocatalysis
  • Environmental remediation using photocatalysis
  • Photocatalytic CO2 reduction
  • NOx reduction
  • Emerging contaminants in wastewater effluents
  • Metal oxides
  • Novel photoreactor designs
  • Kinetics in photocatalytic processes
  • Identification of intermediates and products from photocatalytic processes
  • Advanced oxidation processes (by photocatalysis)

Published Papers (2 papers)

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Research

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12 pages, 1462 KiB  
Article
Ordered Mesoporous TiO2: The Effect of Structure, Residual Template and Metal Doping on Photocatalytic Activity
by Ahmed M. Mohammed, Ahmet E. Becerikli, Simon Ristig, Norbert Steinfeldt and Jennifer Strunk
Catalysts 2023, 13(5), 895; https://doi.org/10.3390/catal13050895 - 16 May 2023
Cited by 2 | Viewed by 1133
Abstract
Using a series of ordered mesoporous TiO2 (om-TiO2) with and without Ce or Cu doping, the effects of structure, metal doping and residual template species in the structure are systematically evaluated in terms of products formed during a CO2 [...] Read more.
Using a series of ordered mesoporous TiO2 (om-TiO2) with and without Ce or Cu doping, the effects of structure, metal doping and residual template species in the structure are systematically evaluated in terms of products formed during a CO2 photoreduction process. It is found that the ordered mesoporous structure contributes significantly in the hydrogen evolution reaction from the splitting of gaseous water. No cocatalyst was needed to achieve high hydrogen yields. While carbon-containing products are also observed, the presence of remainders of the organic template used in the synthesis process does not allow an unambiguous identification of the source of products. Small amounts of metal doping do not majorly influence the hydrogen evolution, thus the mesoporous structure can eventually be identified as the main cause for the improved performance. Full article
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44 pages, 4493 KiB  
Review
Application of TiO2-Based Photocatalysts to Antibiotics Degradation: Cases of Sulfamethoxazole, Trimethoprim and Ciprofloxacin
by Anastasiya Kutuzova, Tetiana Dontsova and Witold Kwapinski
Catalysts 2021, 11(6), 728; https://doi.org/10.3390/catal11060728 - 12 Jun 2021
Cited by 68 | Viewed by 6626
Abstract
The extensive application of antibiotics in human and veterinary medicine has led to their widespread occurrence in a natural aquatic environment. Global health crisis is associated with the fast development of antimicrobial resistance, as more and more infectious diseases cannot be treated more [...] Read more.
The extensive application of antibiotics in human and veterinary medicine has led to their widespread occurrence in a natural aquatic environment. Global health crisis is associated with the fast development of antimicrobial resistance, as more and more infectious diseases cannot be treated more than once. Sulfamethoxazole, trimethoprim and ciprofloxacin are the most commonly detected antibiotics in water systems worldwide. The persistent and toxic nature of these antibiotics makes their elimination by conventional treatment methods at wastewater treatment plants almost impossible. The application of advanced oxidation processes and heterogeneous photocatalysis over TiO2-based materials is a promising solution. This highly efficient technology has the potential to be sustainable, cost-efficient and energy-efficient. A comprehensive review on the application of various TiO2-based photocatalysts for the degradation of sulfamethoxazole, trimethoprim and ciprofloxacin is focused on highlighting their photocatalytic performance under various reaction conditions (different amounts of pollutant and photocatalyst, pH, light source, reaction media, presence of inorganic ions, natural organic matter, oxidants). Mineralization efficiency and ecotoxicity of final products have been also considered. Further research needs have been presented based on the literature findings. Among them, design and development of highly efficient under sunlight, stable, recyclable and cost-effective TiO2-based materials; usage of real wastewaters for photocatalytic tests; and compulsory assessment of products ecotoxicity are the most important research tasks in order to meet requirements for industrial application. Full article
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