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Advanced Studies for PEM Fuel Cells in Hydrogen-Fueled Vehicles

A special issue of Energies (ISSN 1996-1073). This special issue belongs to the section "A5: Hydrogen Energy".

Deadline for manuscript submissions: closed (14 April 2023) | Viewed by 24033

Special Issue Editor

Associate Professor, Faculty of Electrical Engineering, Mechanical Engineering and Naval Architecture, University of Split, 21000 Split, Croatia
Interests: thermodynamics; heat and mass transfer; heating, ventilation, and air conditioning; hydrogen powered vehicles; metal hydrides for hydrogen storage and compression; renewable energy sources; PEM fuel cells
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Special Issue Information

Dear Colleagues,

Fuel cells have a promising chance of becoming the devices of the future in the production of electrical work (electricity) from a range of different chemical fuels. Interest in fuel cells has increased in recent decades due to the negative facts related to the production of electrical work via conventional combustion of fossil fuels. The disadvantages include insufficiently effective conversion into a usable form, environmental pollution, exploitation of global reserves, political domination, and control over countries which are rich in fossil fuels.

Fuel cells offer more efficient conversion when using fossil fuels, and their technology offers further advantages when the fuel is hydrogen from renewable fuels or hydrogen from other renewable sources. They are devices that reduce CO2 emissions per unit of electricity produced when fossil fuels are the primary source and make the use of renewable fuels and renewable sources in transport practical.

While much effort is devoted to fuel cells in hydrogen-fueled vehicles, there is a pressing need to innovate and demonstrate technologies to be implemented in this area. This Special Issue is focused on bringing together innovative developments, technologies, and solutions in the field of fuel cells in hydrogen-fueled vehicles.

Dr. Ivan Tolj
Guest Editor

Manuscript Submission Information

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Keywords

  • PEM fuel cells
  • Hydrogen-fueled vehicles
  • Electric vehicles
  • Metal hydride hydrogen storage

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Published Papers (9 papers)

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Research

18 pages, 6065 KiB  
Article
Optimal Sizing of Battery and Super-Capacitor Based on the MOPSO Technique via a New FC-HEV Application
by Abdeldjalil Djouahi, Belkhir Negrou, Boubakeur Rouabah, Abdelbasset Mahboub and Mohamed Mahmoud Samy
Energies 2023, 16(9), 3902; https://doi.org/10.3390/en16093902 - 5 May 2023
Cited by 8 | Viewed by 1273
Abstract
In light of the energy and environment issues, fuel cell vehicles have many advantages, including high efficiency, low-temperature operation, and zero greenhouse gas emissions, making them an excellent choice for urban environments where air pollution is a significant problem. The dynamics of fuel [...] Read more.
In light of the energy and environment issues, fuel cell vehicles have many advantages, including high efficiency, low-temperature operation, and zero greenhouse gas emissions, making them an excellent choice for urban environments where air pollution is a significant problem. The dynamics of fuel cells, on the other hand, are relatively slow, owing principally to the dynamics of the air compressor and the dynamics of manifold filling. Because these dynamics can limit the overall performance of fuel cell vehicles, two key technologies that have emerged as critical components of electric vehicle powertrains are batteries and supercapacitors. However, choosing the best hybrid energy storage system that combines a battery and a supercapacitor is a critical task nowadays. An electric vehicle simulated application by MATLAB Code is modeled in this article using the multi-objective particle swarm optimization technique (MOPSO) to determine the appropriate type of batteries and supercapacitors in the SFTP-SC03 drive cycle. This application optimized both component sizing and power management at the same time. Batteries of five distinct types (Lithium, Li-ion, Li-S, Ni-Nicl2, and Ni-MH) and supercapacitors of two different types (Maxwell BCAP0003 and ESHSR-3000CO) were used. Each storage component is distinguished by its weight, capacity, and cost. As a consequence, using a Li-ion battery with the Maxwell BCAP0003 represented the optimal form of hybrid storage in our driving conditions, reducing fuel consumption by approximately 0.43% when compared to the ESHSR-3000CO. Full article
(This article belongs to the Special Issue Advanced Studies for PEM Fuel Cells in Hydrogen-Fueled Vehicles)
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14 pages, 3365 KiB  
Article
Proton-Exchange Membrane Fuel Cell Balance of Plant and Performance Simulation for Vehicle Applications
by Tino Vidović, Ivan Tolj, Gojmir Radica and Natalia Bodrožić Ćoko
Energies 2022, 15(21), 8110; https://doi.org/10.3390/en15218110 - 31 Oct 2022
Cited by 4 | Viewed by 4040
Abstract
In this study, a newly developed zero-dimensional electrochemical model was used for modeling and controlling proton-exchange membrane fuel cell (PEMFC) performance. Calibration of the model was performed with measurements from the fuel cell stack. Subsequently, a compressor and a humidifier on the cathode [...] Read more.
In this study, a newly developed zero-dimensional electrochemical model was used for modeling and controlling proton-exchange membrane fuel cell (PEMFC) performance. Calibration of the model was performed with measurements from the fuel cell stack. Subsequently, a compressor and a humidifier on the cathode side were sized and added to the existing model. The aim of this work was to model the PEMFC stack and balance of plant (BoP) components in detail to show the influence of operating parameters such as cathode pressure, stack temperature and cathode stoichiometric ratio on the performance and efficiency of the overall system compared to the original model using a newly developed real-time model. The model managed to predict the profile of essential parameters, such as temperature, pressure, power, voltage, etc. The most important conclusions from this particular case are: the cell power output is only slightly changed with the variations in stoichiometric ratio of the cathode side and adding an external compressor is valid only for high current applications, but in those cases, there is 10–22% power gain. Stack temperature is a very influential parameter. Optimal temperatures were determined through design of experiments (DoE) and for this case are in the 40–60 °C range, where for low current applications lower temperatures are better due lower activation loss (8% difference between 80 °C and 40 °C at 20 A current). For high current applications, due to lower ohmic losses, higher temperatures are desirable. Full article
(This article belongs to the Special Issue Advanced Studies for PEM Fuel Cells in Hydrogen-Fueled Vehicles)
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16 pages, 5140 KiB  
Article
A Closed-Loop Water Management Methodology for PEM Fuel Cell System Based on Impedance Information Feedback
by Xinjie Xu, Kai Li, Zhenjie Liao, Jishen Cao and Renkang Wang
Energies 2022, 15(20), 7561; https://doi.org/10.3390/en15207561 - 13 Oct 2022
Cited by 4 | Viewed by 1570
Abstract
Water management is an important issue for proton exchange membrane fuel cells (PEMFC). The research mainly focuses on the diagnosis and treatment of faults. However, faults harm PEMFC and cause its durability decay, whatever duration they last. This study designs a closed-loop water [...] Read more.
Water management is an important issue for proton exchange membrane fuel cells (PEMFC). The research mainly focuses on the diagnosis and treatment of faults. However, faults harm PEMFC and cause its durability decay, whatever duration they last. This study designs a closed-loop water management system to control the water content in a reasonable range which can not only avoid the faults of hydration and flooding but also improve the performance and durability of PEMFC. The proposed system introduces the measurement methodology based on the phase of single-frequency impedance, which corresponds numerically well with the water content. Moreover, two preferred operating conditions, cathode air stoichiometry and stack temperature, are adopted to regulate the water content with a trade-off between the time cost and power loss. The open-loop characteristics of water content on the temperature and air stoichiometry are studied to design the corresponding control strategy. Findings suggest that air stoichiometry is suitable for large regulation requirements of water content, while the temperature is suitable to meet small demands. Finally, the proposed closed-loop water management system is validated by experiments in variable-load and constant-load with disturbance situations. The results indicate that the proposed system effectively controls the water content within a 3% deviation from the desired value. Full article
(This article belongs to the Special Issue Advanced Studies for PEM Fuel Cells in Hydrogen-Fueled Vehicles)
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16 pages, 3853 KiB  
Article
Water Recuperation from Hydrogen Fuel Cell during Aerial Mission
by Lev Zakhvatkin, Alex Schechter and Idit Avrahami
Energies 2022, 15(18), 6848; https://doi.org/10.3390/en15186848 - 19 Sep 2022
Cited by 2 | Viewed by 3144
Abstract
A water recuperation system (WRS) from an open-cathode proton exchange membrane fuel cell (PEMFC) is designed to increase the energy density of hydrogen production by hydrolysis of metal hydrides. WRS may significantly reduce the water weight in the carried fuel. The design is [...] Read more.
A water recuperation system (WRS) from an open-cathode proton exchange membrane fuel cell (PEMFC) is designed to increase the energy density of hydrogen production by hydrolysis of metal hydrides. WRS may significantly reduce the water weight in the carried fuel. The design is based on circulating the humid air through the PEMFC stack in a closed dome. To ensure oxygen supply to the PEMFC, the WRS has a ventilation inlet and an exhaust outlet. The required conditions for ventilation flow are developed theoretically and examined experimentally in a WRS prototype with a commercial PEMFC at 20–100 W. The experimental system includeds a closed dome, an edge cooling system for the PEMFC, a controllable ventilation air inlet, and an exhaust port. The humid exhaust air was cooled down to the ambient temperature to improve vapor condensation. Results show high efficiency (80% recuperated water from prediction), with a potential to achieve gravimetric hydrogen storage capacity (GHSC) of >6 wt% at an ambient temperature of 27 °C. The described principle may be applied for small fixed-wing drones where the cold ambient air may be utilized both for providing oxygen supply and for thermal management of the PEMFC and the humid exhaust, thus allowing higher GHSC. Full article
(This article belongs to the Special Issue Advanced Studies for PEM Fuel Cells in Hydrogen-Fueled Vehicles)
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20 pages, 10422 KiB  
Article
Research on Energy Management Strategy of Fuel Cell Vehicle Based on Multi-Dimensional Dynamic Programming
by Yanwei Liu, Jiansheng Liang, Jiaqing Song and Jie Ye
Energies 2022, 15(14), 5190; https://doi.org/10.3390/en15145190 - 18 Jul 2022
Cited by 13 | Viewed by 1683
Abstract
The powertrain of a fuel cell vehicle typically consists of two energy sources: a proton electrolyte membrane fuel cell (PEMFC) stack and a battery package. In this paper, multi-dimensional dynamic programming (MDDP) is used to solve the energy management strategy (EMS) of fuel [...] Read more.
The powertrain of a fuel cell vehicle typically consists of two energy sources: a proton electrolyte membrane fuel cell (PEMFC) stack and a battery package. In this paper, multi-dimensional dynamic programming (MDDP) is used to solve the energy management strategy (EMS) of fuel cell hybrid powertrain. This study built a fuel cell hybrid powertrain model, in which the battery model is built based on the Thevenin equivalent circuit. In order to improve the calculating efficiency and maintain the accuracy of the algorithm, the state variables in each stage are divided into primary and secondary. In the reverse solution process, the corresponding relationship between the multi state variables grid and the optimal cumulative function has been changed from three-dimensional to two-dimensional. The EMS based on MDDP is applied to component sizing of a commercial vehicle. Simulations were conducted using MATLAB under the C-WTVC working condition. By analyzing the fuel economy and system durability, the optimal component combination of comprehensive performance is obtained. Compared with the EMS based on dynamic programming (DP), the proposed method effectively improves the calculation accuracy: the hydrogen consumption can be reduced by 3.10%, and the durability of the fuel cell and battery can be improved by 1.08% and 0.13%, respectively. Full article
(This article belongs to the Special Issue Advanced Studies for PEM Fuel Cells in Hydrogen-Fueled Vehicles)
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18 pages, 2568 KiB  
Article
Dehydrogenation of Metal Hydride Reactor-Phase Change Materials Coupled with Light-Duty Fuel Cell Vehicles
by Serge Nyallang Nyamsi, Ivan Tolj and Michał Jan Gęca
Energies 2022, 15(9), 2982; https://doi.org/10.3390/en15092982 - 19 Apr 2022
Cited by 6 | Viewed by 2086
Abstract
The popularity of using phase change materials (PCMs) for heat storage and recovery of metal hydrides’ reaction has grown tremendously. However, a fundamental study of the coupling of such a system with a low-temperature PEM (polymer electrolyte membrane) fuel cell is still lacking. [...] Read more.
The popularity of using phase change materials (PCMs) for heat storage and recovery of metal hydrides’ reaction has grown tremendously. However, a fundamental study of the coupling of such a system with a low-temperature PEM (polymer electrolyte membrane) fuel cell is still lacking. This work presents a numerical investigation of the dehydrogenation performance of a metal hydride reactor (MHR)-PCM system coupled with a fuel cell. It is shown that to supply the fuel cell with a constant H2 flow rate, the PCM properties need to be in an optimized range. The effects of some design parameters (PCM freezing point, the initial desorption temperature, the nature and the size of the PCM) on the dehydrogenation performance of MHR-PCM system are discussed in detail. The results showed that the MHR-PCM could supply hydrogen at 12 NL/min only for 20 min maximum due to the significant endothermic effect occurring in the MHR. However, reducing the requested H2 flowrate to 5.5 NL/min, the hydrogen desorption to a fuel cell is prolonged to 79 min. Moreover, this system can accommodate different PCMs such as paraffin and salt hydrates for comparable performance. This study demonstrates the ability of MHR-PCM systems to be used as range extenders in light-duty fuel cell vehicles. Full article
(This article belongs to the Special Issue Advanced Studies for PEM Fuel Cells in Hydrogen-Fueled Vehicles)
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17 pages, 7245 KiB  
Article
Control Strategy Assessment for Improving PEM Fuel Cell System Efficiency in Fuel Cell Hybrid Vehicles
by Sara Luciani and Andrea Tonoli
Energies 2022, 15(6), 2004; https://doi.org/10.3390/en15062004 - 9 Mar 2022
Cited by 26 | Viewed by 4115
Abstract
Concerns about climate change, air pollution, and the depletion of oil resources have prompted authorities to enforce increasingly strict rules in the automotive sector. There are several benefits to implementing fuel cell hybrid vehicles (FCHV) in the transportation sector, including the ability to [...] Read more.
Concerns about climate change, air pollution, and the depletion of oil resources have prompted authorities to enforce increasingly strict rules in the automotive sector. There are several benefits to implementing fuel cell hybrid vehicles (FCHV) in the transportation sector, including the ability to assist in reducing greenhouse gas emissions by replacing fossil fuels with hydrogen as energy carriers. This paper examines different control strategies for optimizing the power split between the battery and PEM fuel cell in order to maximize the PEM fuel cell system efficiency and reduce fuel consumption. First, the vehicle and fuel cell system models are described. A forward approach is considered to model the vehicle dynamics, while a semi-empirical and quasi-static model is used for the PEM fuel cell. Then, different rule-based control strategies are analyzed with the aim of maximizing fuel cell system efficiency while ensuring a constant battery state of charge (SOC). The different methods are evaluated while the FCHV is performing both low-load and high-load drive cycles. The hydrogen consumption and the overall fuel cell system efficiency are considered for all testing conditions. The results highlight that in both low-load cycles and high-load cycles, the best control strategies achieve a fuel cell system efficiency equal or greater to 33%, while achieving a fuel consumption 30% less with respect to the baseline control strategy in low-load drive cycles. Full article
(This article belongs to the Special Issue Advanced Studies for PEM Fuel Cells in Hydrogen-Fueled Vehicles)
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13 pages, 4014 KiB  
Article
Pore-Filled Proton-Exchange Membranes with Fluorinated Moiety for Fuel Cell Application
by Hyeon-Bee Song, Jong-Hyeok Park, Jin-Soo Park and Moon-Sung Kang
Energies 2021, 14(15), 4433; https://doi.org/10.3390/en14154433 - 22 Jul 2021
Cited by 11 | Viewed by 2370
Abstract
Proton-exchange membrane fuel cells (PEMFCs) are the heart of promising hydrogen-fueled electric vehicles, and should lower their price and further improve durability. Therefore, it is necessary to enhance the performances of the proton-exchange membrane (PEM), which is a key component of a PEMFC. [...] Read more.
Proton-exchange membrane fuel cells (PEMFCs) are the heart of promising hydrogen-fueled electric vehicles, and should lower their price and further improve durability. Therefore, it is necessary to enhance the performances of the proton-exchange membrane (PEM), which is a key component of a PEMFC. In this study, novel pore-filled proton-exchange membranes (PFPEMs) were developed, in which a partially fluorinated ionomer with high cross-linking density is combined with a porous polytetrafluoroethylene (PTFE) substrate. By using a thin and tough porous PTFE substrate film, it was possible to easily fabricate a composite membrane possessing sufficient physical strength and low mass transfer resistance. Therefore, it was expected that the manufacturing method would be simple and suitable for a continuous process, thereby significantly reducing the membrane price. In addition, by using a tri-functional cross-linker, the cross-linking density was increased. The oxidation stability was greatly enhanced by introducing a fluorine moiety into the polymer backbone, and the compatibility with the perfluorinated ionomer binder was also improved. The prepared PFPEMs showed stable PEMFC performance (as maximum power density) equivalent to 72% of Nafion 212. It is noted that the conductivity of the PFPEMs corresponds to 58–63% of that of Nafion 212. Thus, it is expected that a higher fuel cell performance could be achieved when the membrane resistance is further lowered. Full article
(This article belongs to the Special Issue Advanced Studies for PEM Fuel Cells in Hydrogen-Fueled Vehicles)
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23 pages, 58902 KiB  
Article
Assessment of Sensitivity to Evaluate the Impact of Operating Parameters on Stability and Performance in Proton Exchange Membrane Fuel Cells
by Mingzhang Pan, Chengjie Pan, Jinyang Liao, Chao Li, Rong Huang and Qiwei Wang
Energies 2021, 14(14), 4069; https://doi.org/10.3390/en14144069 - 6 Jul 2021
Cited by 7 | Viewed by 2095
Abstract
As a highly nonlinear system, the performance of proton exchange membrane fuel cell (PEMFC) is controlled by various parameters. If the effects of all parameters are considered during the performance optimization, low working efficiency and waste of resources will be caused. The development [...] Read more.
As a highly nonlinear system, the performance of proton exchange membrane fuel cell (PEMFC) is controlled by various parameters. If the effects of all parameters are considered during the performance optimization, low working efficiency and waste of resources will be caused. The development of sensitivity analysis for parameters can not only exclude the parameters which have slight effects on the system, but also provide the reasonable setting ranges of boundary values for simulation of performance optimization. Therefore, sensitivity analysis of parameters is considered as one of the methods to optimize the fuel cell performance. According to the actual operating conditions of PEMFC, the fluctuation ranges of seven sets of parameters affecting the output performance of PEMFC are determined, namely cell operating temperature, anode/cathode temperature, anode/cathode pressure, and anode/cathode mass flow rate. Then, the control variable method is used to qualitatively analyze the sensitivity of main parameters and combines with the Monte Carlo method to obtain the sensitivity indexes of the insensitive parameters under the specified current density. The results indicate that among these parameters, the working temperature of the fuel cell is the most sensitive to the output performance under all working conditions, whereas the inlet temperature is the least sensitive within the range of deviation. Moreover, the cloud maps of water content distribution under the fluctuation of three more sensitive parameters are compared; the results verify the simulated data and further reveal the reasons for performance changes. The workload of PEMFC performance optimization will be reduced based on the obtained results. Full article
(This article belongs to the Special Issue Advanced Studies for PEM Fuel Cells in Hydrogen-Fueled Vehicles)
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