Laser Surface Engineering for Tribology

Laser cladding is a new technology to fabricate a coating on the surface of a metal substrate. The properties on copper substrates are usually not very good due to the high thermal conductivity and reflectivity. The appropriate preheating temperature is helpful to fabricate coatings with good quality and properties, especially for copper substrates. In order to investigate the effect of different preheating temperatures, four coatings with different preheating temperatures (100, 200, 300 and 400 °C) were fabricated via a laser on a copper substrate. The microstructures and properties of four coatings were investigated using SEM, XRD, EDS, a Vickers microhardness meter, a wear tester and an electrochemical workstation. The results show that the elements from Ni-based alloy powder were uniformly distributed among the binding region, which obtained a good metallurgical bonding. The microstructure was mainly composited of cellular, dendrite and plane crystals, and the main reinforced phases were γ (Fe, Ni), Cr_0.09Fe_0.7Ni_0.21, WC and Ni₃B. The values of average microhardness of the four coatings were 614.3, 941.6, 668.1 and 663.1 HV_0.5, respectively. The wear rates of the four coatings were 9.7, 4.9, 12.5 and 13.3 × 10⁻⁵ mm³·N⁻¹·m⁻¹, respectively, which were less than that of the copper substrate (4.3 × 10−3 mm³·N⁻¹·m⁻¹). The decrease in wear rate was due to the existence of the reinforced phases, such as WC, Ni₃B, M₇C₃ (M=Fe, Cr) and Cr_0.09Fe_0.7Ni_0.21. The fine crystals in the coating preheated at 200 °C also improved the wear resistance. Additionally, the minimum values of corrosion current density were 3.26 × 10⁻⁵, 2.34 × 10⁻⁷, 4.02 × 10⁻⁶ and 4.21 × 10⁻⁶ mA·mm⁻², respectively. It can be seen that the coating preheated at 200 °C had higher microhardness, lower wear rates and better corrosion resistance due to the existence of reinforced phases and fine and uniform crystals. Full article

Laser clad AlCr2FeCoNiNbx (x = 0, 0.5, 1.0, 1.5, 2.0, with x values in molar ratio) high-entropy alloy (HEA) coatings were fabricated on Q345 carbon steel. This study delves into the impact of Nb incorporation on the reciprocating sliding wear resistance of these laser clad coatings against a Φ6 mm silicon nitride ball. The microstructure of the as-clad AlCr2FeCoNiNbx coatings transformed from a single Face-Centered Cubic (FCC) solid solution (when x = 0) to the hypoeutectic state (when x = 0.5) and progressed to the hypereutectic state (when x ≥ 1.0). This evolution was marked by an increase in the Laves phase and a decrease in FCC. Consequently, the HEA coatings exhibited a gradually increasing Vickers hardness, reaching a peak at HV 820. Despite a decline in corrosion resistance, there was a notable enhancement in wear resistance, and the friction of the HEA coating could be reduced by Nb addition. The phase evolution induced by Nb addition led to a shift in the predominant wear mechanism from delamination wear to abrasive wear. The wear rate of Nb0.5 was impressively low, at 6.2 × 10⁻⁶ mm N⁻¹ m⁻¹ when reciprocating sliding under 20 N in air. In comparison to Nb0, Nb0.5 showcased 3.6, 7.2, and 6.5 times higher wear resistance at 5 N, 10 N, and 20 N, respectively. Under all applied loads, Nb1.5 has the lowest wear rate among all HEA coatings. This substantiates that the subtle introduction of Laves phase-forming elements to modulate hardness and oxidation ability proves to be an effective strategy for improving the wear resistance of HEA coatings. Full article

Inconel 718 (IN718), a Ni-based superalloy, is immensely popular in the aerospace, nuclear, and chemical industries. In these industrial fields, IN718 parts fabricated using conventional and additive manufacturing routes require subsequent machining to meet the dimensional accuracy and surface quality requirements of practical applications. The machining of IN718 has been a prominent research topic for conventionally cast, wrought, and forged parts. However, very little attention has been given to the machinability of IN718 additively manufactured using laser metal deposition (LMD). This lack of research can lead to numerous issues derived from the assumption that the machining behavior corresponds to conventionally fabricated parts. To address this, our study comprehensively assesses the machinability of LMDed IN718 in dry and minimum quantity lubrication (MQL) cutting environments. Our main goal is to understand how LMD process variables and the cutting environment affect cutting forces, tool wear, surface quality, and energy consumption when working with LMDed IN718 walls. To achieve this, we deposited IN718 on SS309L substrates while varying the following LMD process parameters: laser power, powder feed rate, and scanning speed. The results unveil that machining the deposited wall closer to the substrate is significantly more difficult than away from the substrate, owing to the variance in hardness along the build direction. MQL greatly improves machining across all processing parameters regardless of the machining location along the build direction. Laser power is identified as the most influential parameter, along with the recommendation for a specific combination of power feed rate and scanning speed, providing practical guidelines for optimizing the machining process. While MQL positively impacts machinability, hourly energy consumption remains comparable to dry cutting. This work offers practical guidance for improving the machinability of LMDed IN718 walls and the successful adoption of LMD and the additive–subtractive machining chain. The outcomes of this work provide a significant and critical understanding of location-dependent machinability that can help develop targeted approaches to overcome machining difficulties associated with specific areas of the LMDed structure. The finding that MQL significantly improves machining across all processing parameters, particularly in the challenging bottom region, offers practical guidance for selecting optimal cutting conditions. The potential economic benefits of MQL in terms of tool longevity without a substantial increase in energy costs is also highlighted, which has implications for incorporating MQL in several advanced manufacturing processes. Full article

In this study, the potential of Fe₃Al coating material as an environmentally friendly alternative to coatings containing critical elements for brake discs was investigated. A buffer layer of Cr–Mo steel (Ferro 55) that was about 500 µm thick was applied on a gray cast iron disc to enhance the coating quality and prevent the formation of hot cracks during solidification. The microstructural analysis of the cross-section of the coating showed that the buffer layer diffused into the Fe₃Al coating, forming a combination of Fe₃Al, Fe, and Fe₃AlC_0.5 phases. The tribological properties of the Fe₃Al-coated disc were evaluated using pin-on-disc tests against two different copper-free friction materials extracted from commercial brake pads. The wear results show a coefficient of friction comparable to that of an uncoated disc (≈0.55), but with a reduction in particulate matter (PM) emissions, which decreased from 600 to 476 #/cm³. The last issue is an interesting aspect that is gaining increasing importance in view of the upcoming international standards. Full article

Friction involved in metal-forming processes typically leads to the wear of tool and die surfaces, and in turn shortens the tool’s service life. A thriving need for reducing surface friction requires the tool surface to be modified. This paper presents the surface modification of SKH51 tool steel, on which the hexagonal array of micro-dimples is fabricated by a nanosecond pulse laser. Using the average laser power of 25 W can create decent dimples for trapping lubricant and enabling hydraulic pressure at the surfaces in contact. The effect of dimple density and sliding speed on the coefficient of friction was examined in this study through the pin-on-disc test, in which a stainless steel pin was applied against the tool steel disc with a constant load. The laser-textured tool steel surface with a dimple density of 35% had a friction coefficient of 0.087, which was lower than that of the untextured surface by 12.6% when using a sliding speed of 15 cm/s. In addition to friction reduction, there was no substantial wear found on the laser-textured surface compared to the untextured sample. The findings of this study can be a processing guideline and benefit the treatment of tool and die surfaces for friction and wear reduction in metal-forming and related processes. Full article

CoCrFeNi high-entropy alloy (HEA) exhibits excellent mechanical properties but relatively poor wear resistance. In particular, when the load reaches a certain level and the deformation mechanism of the CoCrFeNi HEA changes, the formation of shear bands leads to a significant increase in wear rate. Although numerous studies have been conducted on alloying strategies to improve the wear resistance of alloys, there is still limited research on the influence of deformation mechanism adjustment on wear resistance. Therefore, in order to fill this research gap, this study aims to use boron doping to regulate the deformation mechanism and successfully improve the wear resistance of CoCrFeNi HEA by 35 times. By observing the subsurface microstructure, the mechanism behind the significant improvement in wear resistance was further revealed. The results indicate that the reduction of shear bands and the formation of nanostructured mixed layers significantly improve wear resistance. The proposed strategy of boron doping to change the deformation mechanism and improve wear resistance is expected to provide new enlightenment for the development of wear-resistant HEAs. Full article

In this work, laser processing technology was utilized to fabricate micro-textures on the surface of 42CrMo steel to improve its wear resistance under high load conditions and provide an effective method to solve the wear of tooth plates in oil drilling wellhead machinery. Firstly, the friction process of the textured components was conducted by finite element analysis. Additionally, various forms of textures were compared and measured by this method to optimize the shape and parameters of the patterns. Secondly, three types of texture shapes, such as micro-dimples, micro-grooves, and reticular grooves, were created on the surface of 42CrMo steel. Lastly, the tribological characteristics of the micro-textures were analyzed in the dry friction experiments. Compared with the untextured surface, the wear resistance of the textured 42CrMo steel has been improved, and the anti-wear property of the micro-dimples was better than micro-grooves and reticular grooves. Along the direction of friction sliding, the wear of the front end is more worn than the rear end. Micro-dimples with a diameter of 0.8 mm, a spacing of 1.2 mm, and an area occupancy of 34.8% were fabricated at an output power of 200 W and a frequency of 5 Hz. The wear of the textured surface has been reduced by more than 80% in the process of ring-block dry friction with a load of 50 N, a rotation speed of 35 r/min, and a time of 15 min. The wear mechanism is mainly abrasive wear. The results showed that the hardness of the surface could be improved by laser hardening. In addition, micro-dimples on 42CrMo steel can store abrasive particles, mitigate the formation of furrows and reduce the abrasive wear of tooth plates. Full article

In situ NbC-reinforced laser cladding Ni45 coatings have the advantages of high bond strengths, low dilution rates, small heat-affected zones and good wear resistance and have broad application prospects in the field of surface strengthening and repair of workpieces such as automotive molds and engine turbines. Previous studies have mostly used pure niobium powder for in situ synthesis to prepare Ni-based NbC coatings with a high production cost. In this paper, NbC was successfully synthesized in situ in Ni45 powder using inexpensive FeNb65 and Cr3C2. The prepared coating has a uniform microstructure and excellent wear resistance, and the reinforced phases are mainly NbC and Cr23C6. Coating 4# with 25 wt.% FeNb65 + Cr3C2 has the highest microhardness of 776.3HV0.2, about 1.45 times that of the Ni45 coating, and its wear resistance is 36.36 min/mg, about 60.6 times that of the Cr12MoV steel base material and about 23.76 times that of the Ni45 coating. Full article

Nitriding has long been used to engineer the surfaces of engineering steels to improve their surface and subsurface properties. The role of the surface compound layer (γ′-Fe₄N and/or ε-Fe_2-3N) in improving the tribological and corrosion-resistant properties of nitrided steels has been established. However, there have been very few studies on the response of the compound layer to tribocorrosion in corrosive environments. In this work, the tribocorrosion behavior of a 5 μm thick γ′-Fe₄N nitride layer produced on mild steel (MS) by plasma nitriding has been studied in a NaCl-containing solution under various electrochemical conditions. The results show that at a cathodic potential of −700 mV (saturated calomel electrode, SCE), where mechanical wear is predominant, the total material removal (TMR) from the γ′-Fe₄N layer is 37% smaller than that from the untreated MS, and at open circuit potential, TMR from the layer is 34% smaller than that from the untreated MS, while at an anodic potential of −200 (SCE), the γ′-Fe₄N layer can reduce TMR from mild steel by 87%. The beneficial effect of the γ′-Fe₄N nitride layer in improving the tribocorrosion behavior of mild steel is derived from its high hardness and good corrosion resistance in the test solution and its ability to resist both mechanical wear and corrosion and to reduce wear–corrosion synergism. Full article

Diamond/copper composite coating is promising for wear-resistant applications, owing to the extreme hardness of the diamond reinforcement. Ti-coated diamond/copper composite coatings with various laser powers were successfully fabricated employing the novel manufacturing technology of supersonic laser deposition (SLD). Ti-coated diamond, which was able to enhance the wettability between diamond and copper, was prepared at the optimal parameters via salt bath. Nano-spherical titanium carbides were uniformly distributed on the diamond’s surface to generate a favorable interface bonding with a copper matrix though mechanical interlocking and metallurgical bonding during impact. Furthermore, the results showed that the transition layer acted as a buffer, preventing the breakage of the diamond in the coating. SLD can prevent the graphitization of the diamonds in the coating due to its low processing temperature. The coordination of laser and diamond metallization significantly improved the tribological properties of the diamond/copper composite coatings with the SLD technique. The microhardness of the diamond/copper composite coating at a laser power of 1000 W reached about 172.58 HV_0.1, which was clearly harder than that of the cold sprayed copper. The wear test illustrated that the diamond/copper composite coating at a laser power of 1000 W exhibited a low friction coefficient of 0.44 and a minimal wear rate of 11.85 μm³·N⁻¹·mm⁻¹. SLD technology shows great potential in the field of preparing wear-resistant hard reinforced phase composite coatings. Full article

In order to improve the wear resistance of titanium alloy, a Ti₅Si₃/Ti₃Al composite coating with improved wear resistance was successfully prepared by laser cladding TA2 titanium alloy using the double-layer presetting method of Ti-63 wt.% Al mixed powder layer/Si powder layer. The microstructure, phase composition and wear resistance of the coating were studied using X-ray diffraction (XRD), scanning electron microscopy (SEM) and pin-disk friction and wear method. The results show that the coating is mainly composed of the Ti₅Si₃ primary phase and Ti₅Si₃/Ti₃Al eutectic structure. The microhardness of the coating is higher than that of the matrix. The average microhardness of the coating is about 668 HV_0.1, which is 3.34 times that of the matrix. The coating significantly improves the wear resistance of the TA2 matrix, and the mass wear rate is 1/5.79 of that of the TA2 matrix. The main wear mechanisms of the coating are abrasive wear, adhesive wear and oxidative wear, whereas the main wear mechanisms of the TA2 matrix are adhesive wear and oxidative wear. Full article

The uniformity of microstructure and wear properties exist in the T15 coating for the laser cladding on 42CrMo steel. It can be improved by a post-heat treatment process. Temperature ranges from 1100 to 1240 °C were applied on the cladding layer to investigate the effect of the heat treatment on the wear resistance and hardness gradient. The post-heat treatment can efficiently improve the inhomogeneity of microstructure. The lower wear rate is obtained after the quenching process at 1100 °C, and the wear rate is increased though the tempering process. The carbides at the grain boundary are decomposed and integrated into the matrix during the high temperature quenching process. The carbides are precipitated and dispersed in the grain during the tempering process. The content of martensite and alloy carbide is significantly increased through the heat treatment process. The microhardness of the cladding layer is 910 HV after quenching and 750 HV after tempering. The wear mechanism of the cladding layer is mainly abrasive wear and fatigue wear. The crack and falling off from cladding layers are significantly reduced for the quenching–tempering process. Full article

As one of the lightest structural metals, the application breadth of aluminum alloys is, to some extent, constrained by their relatively low wear resistance and hardness. However, laser cladding technology, with its low dilution rate, compact structure, excellent coating-to-substrate bonding, and environmental advantages, can significantly enhance the surface hardness and wear resistance of aluminum alloys, thus proving to be an effective surface modification strategy. This review focuses on the topic of surface laser cladding materials for aluminum alloys, detailing the application background, process, microstructure, hardness, wear resistance, and corrosion resistance of six types of coatings, namely Al-based, Ni-based, Fe-based, ceramic-based, amorphous glass, and high-entropy alloys. Each coating type’s characteristics are summarized, providing theoretical references for designing and selecting laser cladding coatings for aluminum alloy surfaces. Furthermore, a prediction and outlook for the future development of laser cladding on the surface of aluminum alloys is also presented. Full article