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Catalysts, Volume 8, Issue 3

2018 March - 30 articles

Cover Story: Sabine Berteina-Raboin’s team has developed an efficient total synthesis of abscisic acid (ABA) and some analogues. The construction of these compounds was achieved through a series of reactions involving a solvent-free Mizoroki-Heck reaction. ABA is a natural product (phytohormone) that has recently exhibit interesting biological activities in blood sugar regulation, emphasizing the need for simple and direct access to new analogues based on the ABA framework. The strategy relied on a palladium catalyzed Heck cross-coupling as key reaction performed under solvent and ligand-free conditions. After a careful optimization, the team succeeded to access various (E/Z)-dienes and (E/E/Z)-trienes in moderate to good yields without racemization and applied the same approach to the synthesis of the ABA in an environmentally sound manner. View the paper here.
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Articles (30)

  • Review
  • Open Access
16 Citations
7,220 Views
22 Pages

20 March 2018

Platinum group metal phosphides are reviewed as catalytic materials for hydroprocessing and syngas-related catalysis. Starting from synthetic procedures leading to highly disperse nano-particular compounds, their properties in the applications are di...

  • Article
  • Open Access
3 Citations
4,074 Views
14 Pages

The PT/S-Box of Modular Cellulase AcCel12B Plays a Key Role in the Hydrolysis of Insoluble Cellulose

  • Yuwei Li,
  • Junling Wang,
  • Limei Wang,
  • Hao Tong,
  • Mingwei Bu,
  • Gui Gao,
  • Weiwei Han and
  • Zuoming Zhang

20 March 2018

Cellulases play key roles in the degradation of lignocellulosic materials. The function and mechanism of the catalytic domain (CD) and carbohydrate-binding module (CBM) of cellulases were earlier revealed by analysis and characterization of protein s...

  • Review
  • Open Access
80 Citations
12,915 Views
28 Pages

Recent Progress in Asymmetric Catalysis and Chromatographic Separation by Chiral Metal–Organic Frameworks

  • Suchandra Bhattacharjee,
  • Muhammad Imran Khan,
  • Xiaofang Li,
  • Qi-Long Zhu and
  • Xin-Tao Wu

19 March 2018

Metal–organic frameworks (MOFs), as a new class of porous solid materials, have emerged and their study has established itself very quickly into a productive research field. This short review recaps the recent advancement of chiral MOFs. Here, we pre...

  • Article
  • Open Access
27 Citations
6,961 Views
13 Pages

19 March 2018

Adipic acid is an important raw chemical for the commercial production of polyamides and polyesters. The traditional industrial adipic acid production utilizes nitric acid to oxidize KA oil (mixtures of cyclohexanone and cyclohexanol), leading to the...

  • Article
  • Open Access
14 Citations
6,181 Views
18 Pages

Catalytic Conversion of Model Tars over Carbon-Supported Ni and Fe

  • Luis E. Arteaga-Pérez,
  • Aaron M. Delgado,
  • Mauricio Flores,
  • Patricia Olivera,
  • Kimberley Matschuk,
  • Christian Hamel,
  • Tim Schulzke and
  • Romel Jiménez

17 March 2018

Tar removal from gasification gases is a determinant step to guarantee the operational feasibility of gasification-to-chemicals/energy systems. This study aimed to develop novel carbon-supported catalysts for the elimination of tarry aromatics (tolue...

  • Article
  • Open Access
25 Citations
6,491 Views
14 Pages

Catalytic Oxidation of Chlorobenzene over Ruthenium-Ceria Bimetallic Catalysts

  • Meng Ye,
  • Li Chen,
  • Xiaolong Liu,
  • Wenqing Xu,
  • Tingyu Zhu and
  • Guanyi Chen

16 March 2018

A series of Ru-based mono and bimetallic materials were prepared and evaluated in the catalytic oxidation of chlorobenzene. Among the different Ru-based catalysts, 1Ru/TiO2(P25) was the most active catalyst and contributed the lowest complete oxidati...

  • Communication
  • Open Access
24 Citations
8,296 Views
9 Pages

Functional Analysis of Methylomonas sp. DH-1 Genome as a Promising Biocatalyst for Bioconversion of Methane to Valuable Chemicals

  • Anh Duc Nguyen,
  • In Yeub Hwang,
  • Ok Kyung Lee,
  • Dong Hoon Hur,
  • Young Chan Jeon,
  • Susila Hadiyati,
  • Min-Sik Kim,
  • Sung Ho Yoon,
  • Haeyoung Jeong and
  • Eun Yeol Lee

16 March 2018

Methylomonas sp. DH-1, newly isolated from the activated sludge of a brewery plant, has been used as a promising biocatalytic platform for the conversion of methane to value-added chemicals. Methylomonas sp. DH-1 can efficiently convert methane and p...

  • Article
  • Open Access
28 Citations
6,578 Views
14 Pages

Photocatalytic Performance and Degradation Mechanism of Aspirin by TiO2 through Response Surface Methodology

  • Lezhuo Li,
  • Qiuling Ma,
  • Sanfan Wang,
  • Sanxiang Song,
  • Bo Li,
  • Ruonan Guo,
  • Xiuwen Cheng and
  • Qingfeng Cheng

16 March 2018

In the present work, the photocatalytic performance of P25TiO2 was investigated by means of the degradation of aspirin, while the reaction system was systematically optimized by central composite design (CCD) based on the response surface methodology...

  • Article
  • Open Access
7 Citations
5,961 Views
16 Pages

Highly Active and Selective Supported Rhenium Catalysts for Aerobic Oxidation of n-Hexane and n-Heptane

  • Gopal S. Mishra,
  • Elisabete C. B. A. Alegria,
  • Armando J. L. Pombeiro and
  • Luísa M. D. R. S. Martins

15 March 2018

A series of derivative C-scorpionate rhenium complexes, i.e., [ReCl2{NNC(O)C6H5}(Hpz)(PPh3)2] (A) (where Hpz is pyrazole), [ReCl2{NNC(O)C6H5}(Hpz)2(PPh3)] (B), [ReClF{NNC(O)C6H5}(Hpz)2(PPh3)] (C), and their precursor [ReOCl3(PPh3)2] (D), immobilized...

  • Feature Paper
  • Article
  • Open Access
9 Citations
5,922 Views
9 Pages

15 March 2018

Abscisic acid (ABA) is a natural product, which is a well-known phytohormone. However, this molecule has recently exhibited interesting biological activities, emphasizing the need for a simple and direct access to new analogues based on the ABA frame...

  • Review
  • Open Access
42 Citations
11,654 Views
16 Pages

Waste into Fuel—Catalyst and Process Development for MSW Valorisation

  • Izabela S. Pieta,
  • William S. Epling,
  • Alicja Kazmierczuk,
  • Pawel Lisowski,
  • Robert Nowakowski and
  • Ewa M. Serwicka

14 March 2018

The present review paper highlights recent progress in the processing of potential municipal solid waste (MSW) derived fuels. These wastes come from the sieved fraction ( < 40 mm), which, after sorting, can differ in biodegradable fraction conten...

  • Article
  • Open Access
47 Citations
7,401 Views
16 Pages

13 March 2018

In the present study, a nanocomposite material g-C3N4/Fe-TiO2 has been prepared successfully by a simple one-step hydrothermal process and its structural properties were thoroughly studied by various characterization techniques, such as X-ray diffrac...

  • Article
  • Open Access
9 Citations
6,340 Views
22 Pages

A Comparative Study of Mn/Co Binary Metal Catalysts Supported on Two Commercial Diatomaceous Earths for Oxidation of Benzene

  • Marco Tomatis,
  • Honghui Xu,
  • Chaohui Wei,
  • Matthew Thomas Bishop,
  • Jun He,
  • Chengjun Wang,
  • Ming Zhao,
  • Hang Xiao,
  • Huan Yu and
  • Bencan Tang
  • + 1 author

12 March 2018

Two commercial diatomaceous earths were used as supports for the preparation of Mn/Co binary metal catalysts at different metal loads (5 to 10 wt % Mn and 5 to 15 wt % Co) by incipient wetness deposition. The activity of the prepared catalysts toward...

  • Review
  • Open Access
107 Citations
10,960 Views
18 Pages

11 March 2018

Two major green house gases (CO2 and CH4) can be converted into useful synthetic gas (H2 and CO) during dry reforming of methane (DRM) reaction, and a lot of scientific efforts has been made to develop efficient catalysts for dry reforming of methane...

  • Article
  • Open Access
4 Citations
4,087 Views
8 Pages

9 March 2018

In this study, mesoporous and nonporous silica-supported Pd complexes were synthesized and characterized. Variable-temperature XAFS measurements and a curve-fitting analysis showed a slightly larger contribution of σ2static when the Pd complexes were...

  • Article
  • Open Access
43 Citations
6,167 Views
18 Pages

Synthesis of Rectorite/Fe3O4/ZnO Composites and Their Application for the Removal of Methylene Blue Dye

  • Huanhuan Wang,
  • Peijiang Zhou,
  • Rui Guo,
  • Yifei Wang,
  • Hongju Zhan and
  • Yunfei Yuan

9 March 2018

A novel series of rectorite-based magnetic zinc oxide (ZnO) photocatalysts (REC/Fe3O4/ZnO) was synthesized and characterized in the present work. The fabricated REC/Fe3O4/ZnO composite possessed a high specific surface area and high capacity of adsor...

  • Article
  • Open Access
42 Citations
7,114 Views
10 Pages

9 March 2018

A novel composite composed of (5, 10, 15, 20-tetraphenyl) porphinato manganese sensitized p-type CuFe2O4 was developed for constructing the photocathode of a tandem photoelectrochemical (PEC) cell. The prepared material was characterized by X-ray dif...

  • Feature Paper
  • Article
  • Open Access
22 Citations
9,179 Views
14 Pages

9 March 2018

Natural hydroxy fatty acids are relevant starting materials for the production of a number of industrial fine chemicals, such as different high-value flavour ingredients. Only a few of the latter hydroxy acid derivatives are available on a large scal...

  • Article
  • Open Access
5 Citations
5,512 Views
11 Pages

Synthesis of Tetrahydropyran from Tetrahydrofurfuryl Alcohol over Cu–Zno/Al2O3 under a Gaseous-Phase Condition

  • Fengyuan Zhang,
  • Bin Zhang,
  • Xincheng Wang,
  • Long Huang,
  • Dekun Ji,
  • Songsong Du,
  • Lei Ma and
  • Shijing Lin

6 March 2018

Tetrahydropyran (THP) represents an O-containing hetero-cyclic compound that can be used as a promising solvent or monomer for polymer synthesis. In this work, Cu–ZnO/Al2O3 catalysts have been prepared by a facile precipitation–extrusion method and u...

  • Review
  • Open Access
15 Citations
6,688 Views
19 Pages

2 March 2018

Multifunctionality is the hallmark of most modern commercial heterogeneous catalyst systems in use today, including those used for the selective ammoxidation of propylene to acrylonitrile. It is the quintessential principle underlying commercial cata...

  • Article
  • Open Access
7 Citations
6,460 Views
13 Pages

Selective Hydrogenation of Benzene to Cyclohexene over Ru-Zn Catalysts: Mechanism Investigation on NaOH as a Reaction Additive

  • Haijie Sun,
  • Zhihao Chen,
  • Chenggang Li,
  • Lingxia Chen,
  • Zhikun Peng,
  • Zhongyi Liu and
  • Shouchang Liu

2 March 2018

Ru-Zn catalysts were synthesized via a precipitation method, and the mechanism of NaOH modifying Ru-Zn catalysts on the selective hydrogenation of benzene to cyclohexene was thoroughly investigated. Fresh as well as used catalysts were characterized...

  • Feature Paper
  • Article
  • Open Access
11 Citations
5,685 Views
10 Pages

1 March 2018

Amphiphilic phosphotungstic acid (A-PTA) and Ni2P/SBA-15 catalysts were prepared to apply for selective oxidation of refractory sulfur compounds in light cycle oils and hydrotreating of the oxidized S compounds, respectively. Physical properties of t...

  • Article
  • Open Access
117 Citations
8,546 Views
14 Pages

28 February 2018

This study presents a one-step encapsulation method for synthesizing X-shaped zeolitic imidazolate frameworks (ZIF-8) and immobilizing Rhizomucor miehei lipase (RML). We proved that the morphological structure of ZIF-8 had changed after immobilizatio...

  • Article
  • Open Access
3 Citations
4,565 Views
10 Pages

28 February 2018

In this study, α-Fe2O3 spherical particles with an average diameter of approximately 200 nm were synthesized by a solvothermal method for use as both a catalyst and medium for a Pd catalyst. The kinetics of CO oxidation over powders of α-Fe2O3 spheri...

  • Article
  • Open Access
9 Citations
8,277 Views
12 Pages

Methyl Chloride Synthesis over Metal Chlorides-Modified Mesoporous Alumina Catalyst

  • Yuwen Ji,
  • Feilong Zhang,
  • Feng Yu,
  • Jianshu Zhang and
  • Jinli Zhang

28 February 2018

Mesoporous alumina has been successfully prepared using sucrose as templates. Mesoporous alumina-based catalysts, neat and impregnated with metal chlorides, were tested for gas phase methyl chloride synthesis from methanol and HCl. The catalysts were...

  • Article
  • Open Access
51 Citations
7,490 Views
15 Pages

Enhanced Low Temperature NO Reduction Performance via MnOx-Fe2O3/Vermiculite Monolithic Honeycomb Catalysts

  • Ke Zhang,
  • Feng Yu,
  • Mingyuan Zhu,
  • Jianming Dan,
  • Xugen Wang,
  • Jinli Zhang and
  • Bin Dai

28 February 2018

Selective catalytic reduction of NOx by ammonia (NH3-SCR) was the most efficient and economic technology for De-NOx applications. Therefore, a series of MnOx/vermiculite (VMT) and MnOx-Fe2O3/VMT catalysts were prepared by an impregnation method for t...

  • Article
  • Open Access
18 Citations
6,416 Views
15 Pages

28 February 2018

Herein, a promising method to prepare efficient N-doped porous carbon-supported Fe2O3 nanoparticles (Fe2O3/N-PCs) ORR electrocatalysts is presented. The porous carbon was derived from a biomass i.e., mulberry leaf through a cost-effective approach. T...

  • Feature Paper
  • Article
  • Open Access
10 Citations
5,280 Views
20 Pages

Tungsten-Based Mesoporous Silicates W-MMM-E as Heterogeneous Catalysts for Liquid-Phase Oxidations with Aqueous H2O2

  • Nataliya Maksimchuk,
  • Irina Ivanchikova,
  • Olga Zalomaeva,
  • Yurii Chesalov,
  • Alexandr Shmakov,
  • Vladimir Zaikovskii and
  • Oxana Kholdeeva

27 February 2018

Mesoporous tungsten-silicates, W-MMM-E, have been prepared following evaporation-induced self-assembly methodology and characterized by elemental analysis, XRD, N2 adsorption, STEM-HAADF (high angle annular dark field in scanning-TEM mode), DRS UV-vi...

  • Review
  • Open Access
22 Citations
9,630 Views
36 Pages

The Role of Yeast-Surface-Display Techniques in Creating Biocatalysts for Consolidated BioProcessing

  • Ian Dominic Flormata Tabañag,
  • I-Ming Chu,
  • Yu-Hong Wei and
  • Shen-Long Tsai

25 February 2018

Climate change is directly linked to the rapid depletion of our non-renewable fossil resources and has posed concerns on sustainability. Thus, imploring the need for us to shift from our fossil based economy to a sustainable bioeconomy centered on bi...

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Catalysts - ISSN 2073-4344