Search Results (157)

Norway spruce (Picea abies L. Karst) wood is a preferred resonance material for musical instruments, but the surface coatings used to protect it also alter its acoustic behaviour. In this study, the effects of nitrocellulose and polyurethane coatings on spruce lamellas during an ageing period of 300 days were investigated. Gloss, hardness, impact resistance, resonance frequencies, vibration damping (tan δ) and acoustic conversion efficiency (ACE) were measured. Both coatings initially reduced the resonance frequencies and moduli of elasticity (E), while increasing the tan δ and reducing the ACE, with the nitrocellulose having a greater effect. Ageing led to greater hardness, lower tan δ and improved ACE, which can be attributed to the progressive curing of the coatings. The strong correlation between hardness and acoustic parameters suggests that mechanical surface properties may serve as predictors of acoustic effectiveness. Polyurethane maintained acoustic performance better than nitrocellulose, although impact resistance decreased with ageing. These results emphasize the importance of choosing coating systems that balance durability and long-term acoustic requirements in instrument making. Full article

Solid-state spin centers are at the forefront of developing advanced quantum technologies, engaging in applications of sensing, communication and computing. A semiconductor host matrix compatible with existing silicon technology provides a robust platform for holding spin defects and an opportunity for external manipulation. In this article, negatively charged nitrogen-vacancy (NV) centers in the hexagonal hh position in a 6H polytype silicon carbide crystal was studied using high-frequency (94 GHz) electron paramagnetic (EPR) and electron nuclear double resonances (ENDOR) spectroscopy. Experimentally determined values of hyperfine and quadrupole interactions of ¹⁴N were compared with the values obtained for the centers in NV_k2k1 positions. The distribution of spin density of the defect within a supercell of the SiC crystal lattice was calculated using the density functional theory approach. The theoretical estimation of electron-nuclear interaction constants turned out to be in close agreement with the experimental values, which allows us to refine the microscopic model of a point defect. The temperature dependence of the spin Hamiltonian values (δA/δT ≅ 180 Hz/K) was studied with the possibility of observing the ¹⁴N NMR signal at room temperature. The fundamental knowledge gained about interactions’ parameters’ behavior lays the foundation for the creation of promising quantum platforms. Full article

We perform a systematic investigation of low-lying singly charmed dibaryon systems with $J=1$, $I=0,{\displaystyle \frac{1}{2}},1,{\displaystyle \frac{3}{2}},2,{\displaystyle \frac{5}{2}}$ and strangeness $S=-1,-2,-3,-4,-5$ in the chiral quark model. According to the analysis of effective potentials, dibaryon systems characterized by lower isospin and magnitude of strangeness exhibit stronger attractive interactions, which may enhance their tendency to form bound states. Experimental efforts may therefore prioritize the search for such configurations. The bound-state calculation results indicate that we have obtained some single-channel bound states, which are $\mathrm{\Sigma }{\mathrm{\Sigma }}_c$, $\mathrm{\Sigma }{\mathrm{\Sigma }}_c^{*}$, ${\mathrm{\Sigma }}^{*}{\mathrm{\Sigma }}_c$, ${\mathrm{\Sigma }}^{*}{\mathrm{\Sigma }}_c^{*}$ with $I=0,S=-1$; ${\mathrm{\Sigma }}_c\mathrm{\Delta }$, ${\mathrm{\Sigma }}_c^{*}\mathrm{\Delta }$ with $I={\displaystyle \frac{1}{2}},S=0$; $\mathrm{\Sigma }{\mathrm{\Sigma }}_c$ with $I=1,S=-1$; ${\mathrm{\Sigma }}_c\mathrm{\Delta }$ with $I={\displaystyle \frac{3}{2}},S=0$; and ${\mathrm{\Xi }}^{*}{\mathrm{\Sigma }}_c^{*}$ with $I={\displaystyle \frac{3}{2}},S=-2$. However, these states can decay through open channels. We have listed both these single-channel bound states and their corresponding decay channels in this work for experimental reference and search. In the future, we need to study the scattering processes of the open channels further to confirm whether these states are resonance states. Full article

Mercury exposure has been linked to male infertility. Given that mercury chloride (HgCl₂) may promote an oxido-inflammatory milieu associated with pathophysiological derangements, it is hypothesised that Thymoquinone (TQ), an antioxidant and anti-inflammatory agent, may mitigate the gradual harmful effects of mercury exposure on rat testes, epididymis, and hypothalamus, as these organs are vital to reproductive function. To test this hypothesis, 40 rats (strain: Wistar; sex: male) were randomly assigned to five cohorts of eight rats each. After a 7-day acclimation, treatments were dispensed for 28 consecutive days accordingly: Cohort I: distilled water only, as control; Cohort II: HgCl₂ only (20 µg/mL); Cohort III: TQ only (2.5 mg/kg); Cohort IV: HgCl₂ + TQ (20 µg/mL + 2.5 mg/kg); and Cohort V: HgCl₂ + TQ (20 µg/mL + 5 mg/kg). Co-treatment with TQ preserved the body and organ weight of the HgCl₂ exposed animals. However, TQ did not reduce HgCl₂-induced dysfunction in sperm function and morphology. The serum follicle-stimulating hormone (FSH), luteinising hormone (LH), and testosterone were increased significantly (p < 0.05) by TQ co-treatment, while decreasing the prolactin level. TQ administration also increased (p < 0.05) testicular enzymes, including alkaline phosphatase (ALP), lactate dehydrogenase (LDH), acid phosphatase (ACP), and glucose-6-phosphate dehydrogenase (G6PD) activities, which HgCl₂ decreased. TQ administration increased (p < 0.05) HgCl₂-induced decreases in catalase (CAT), superoxide dismutase (SOD), glutathione peroxidase (GPx), glutathione (GSH), glutathione-s-transferase (GST), and total sulfhydryl group (TSH) levels in the testes, epididymis, and hypothalamus of experimental rats. Further, TQ reduced HgCl₂-mediated increases in RONS-reactive oxygen and nitrogen species; LPO–lipid peroxidation; PC–protein carbonyl formation; and XO–xanthine oxidase activity. Furthermore, levels of inflammatory biomarkers, including tumour necrosis factor alpha (TNF-α), nitric oxide (NO), interleukin-1 beta (IL-1β), and myeloperoxidase (MPO), were decreased (p < 0.05) in the co-treated groups, with a higher dose of TQ (5.0 mg/kg) showing a more pronounced protective effect. Additionally, TQ co-administration increased Bax and decreased Bcl-2 and p53 protein levels (p < 0.05), thereby protecting the rats’ testes, epididymis, and hypothalamus from HgCl₂-induced apoptosis. Molecular docking simulation analysis revealed TQ interaction dynamics with PPAR-α and PPAR-δ to suppress NF-kB-mediated pro-inflammatory sequela as well as activate Nrf-2-mediated antioxidant defence system. These predicted biological effects of TQ resonate with the findings from the in vivo studies. Therefore, supplementation with TQ may help reduce chemical-induced toxicities, including HgCl₂‘s reproductive toxicity. Full article

Aluminum nitride (AlN) powder, a cornerstone material for advanced ceramics. This study examines the low-temperature formation of AlN crystals as well as their phase transformation by employing amorphous aluminum oxalate (AAO) as a novel precursor for carbothermal reduction, contrasting it with conventional aluminum hydroxide (Al(OH)₃). Through characterization using X-ray diffraction (XRD), scanning electron microscopy (SEM), High-Resolution Transmission Electron Microscope (HRTEM), ²⁷Al Magic-Angle Spinning Nuclear Magnetic Resonance (²⁷Al-MAS-NMR) energy-dispersive spectroscopy (EDS), and Fourier-transform infrared spectroscopy (FTIR), we unraveled the phase evolution pathways and the formation of AlN. Key findings reveal striking differences between the two precursors. When Al(OH)₃ was used, no AlN phase was detected at 1350 °C, and even at 1500 °C, the AlN obtained with significant residual alumina impurities. In contrast, the AAO precursor demonstrated exceptional efficiency: nano-sized α-Al₂O₃ formed at 1050 °C, followed by the emergence of AlN phases at 1200 °C, ultimately gaining the pure AlN at 1500 °C. The phase transformation sequence—Al(OH)₃ → γ-Al₂O₃ (950 °C) → (α-Al₂O₃ + δ-Al₂O₃) (1050 °C) → (AlN + α-Al₂O₃) (1200 °C~ 1350 °C) → AlN (≥1500 °C)—highlights the pivotal role of nano-sized α-Al₂O₃ in enabling low-temperature nano AlN synthesis. By leveraging the unique properties of AAO, we offer a transformative strategy for synthesizing nano-sized AlN powders, with profound implications for the ceramics industry. Full article

Perfect absorbers operating in the terahertz (THz) band are key enablers for next-generation wireless systems. However, conventional metal–dielectric designs suffer from Ohmic losses and limited reconfigurability. Here, we propose an all-dielectric indium antimonide (InSb) cylindrical pillar metasurface that achieves near-unity absorption at $f_0=1.83$ THz with a high quality factor of $Q=72.3$. Critical coupling between coexisting electric and magnetic dipoles enables perfect impedance matching, while InSb’s low damping minimizes energy loss. The resonance is tunable via temperature and magnetic bias at sensitivities of $S_T\approx 2.8\mathrm{GHz}·{\mathrm{K}}^{-1}$, $S_B^{\mathrm{TE}}\approx -132.7\mathrm{GHz}·{\mathrm{T}}^{-1}$, and $S_B^{\mathrm{TM}}\approx -34.7\mathrm{GHz}·{\mathrm{T}}^{-1}$, respectively, without compromising absorption strength. At zero magnetic bias ($B=0$), the metasurface is polarization-independent under normal incidence; under magnetic bias ($B\ne 0$), it maintains near-unity absorbance for both TE and TM, while the resonance frequency becomes polarization-dependent. Additionally, the 90% absorptance bandwidth ($\Delta f_{A\ge 0.9}$) can be modulated from 8.3 GHz to 3.3 GHz with temperature, or broadened from 8.5 GHz to 14.8 GHz under magnetic bias. This allows gapless suppression of up to 14 consecutive 1 GHz-spaced channels. This standards-agnostic bandwidth metric illustrates dynamic spectral filtering for future THz links and beyond-5G/6G research. Owing to its sharp selectivity, dual-mode tunability, and metal-free construction, the proposed absorber offers a compact and reconfigurable platform for advanced THz filtering applications. Full article

This work establishes the first derivation of geometry-dependent Kirchhoff’s laws via conformal symmetry, enabling new types of self-sustaining circuits unattainable in classical lumped-element theory. Building on Bessel-Hagen’s extension of Noether’s theorem to Maxwell’s equations, we develop a conformal circuit formalism that fundamentally extends traditional circuit theory through two key innovations: (1) Geometry-dependent weighting factors ($w_i\propto a_i^{-1}$) in Kirchhoff’s laws derived from scaling symmetry; (2) A dilaton-like field ($\delta$) mediating energy exchange between circuits and conformal backgrounds. Unlike prior symmetry applications in electromagnetism, our approach directly maps the 15-parameter conformal group to component-level circuit transformations, predicting experimentally verifiable phenomena: (i) $10.2\%$ deviations from classical current division in RF splitters; (ii) $4.2\%$ resonant frequency shifts with $2.67\times$ Q-factor enhancement; (iii) Power-law scaling ($J_z\propto a^{-2}$) in cylindrical conductors. This theoretical framework proposes how conformal symmetry could enable novel circuit behaviors, including potential self-sustaining oscillations, subject to experimental validation. Full article

Developing an understanding of phenomena driven by the emergence of hadron mass (EHM) is one of the most challenging problems in the Standard Model. This discussion focuses on the impact of results on nucleon resonance ($N^{*}$) electroexcitation amplitudes (or ${\gamma }_{v}p{N}^{*}$ electrocouplings) obtained from experiments during the 6 GeV era in Hall B at Jefferson Lab on understanding EHM. Analyzed using continuum Schwinger function methods (CSMs), these results have revealed new pathways for the elucidation of EHM. A good description of the $\Delta \left(1232\right)3/2^{+}$, $N\left(1440\right)1/2^{+}$, and $\Delta \left(1600\right)3/2^{+}$ electrocouplings, achieved by CSM analyses that express a realistic dressed quark mass function, sheds light on the strong interaction dynamics underlying EHM. Extensions to $N^{*}$ studies for higher-mass states are outlined, as well as experimental results anticipated in the 12 GeV era at Jefferson Lab and those that would be enabled by a further increase in the beam energy to 22 GeV. Full article

The Upper Lianggaoshan (LGS) Formation in the northeastern Sichuan Basin, composed of shale with interbedded siltstone, is a promising target layer for shale oil. Accurate evaluation of pore structures is essential for effective exploration of shale oil. This study investigated pore structures of siltstone and shale samples from the Upper LGS Formation using low-pressure CO₂ adsorption (LTCA), low-temperature N₂ adsorption (LTNA), high-pressure mercury intrusion (HPMI), and nuclear magnetic resonance (NMR) methods. The single-exponent and multifractal dimensions of samples were determined, and the relationships between fractal dimensions and pore structures were explored. Results show that the pore size distribution (PSD) of siltstone and shale samples exhibits multi-peak characteristics, with mesopores (2–50 nm) being dominant in the total pore volumes. The multi-scaled pores in shale and siltstone samples exhibit fractal characteristics. The average values of single-fractal dimensions (D₁, D₂) obtained by LTNA data are 2.39 and 2.62 for shale samples, and 2.24 and 2.59 for siltstone samples, respectively. Compared to siltstones, the pore structures of shale samples exhibit greater complexity, indicated by larger fractal dimensions. The samples from subsections Liang 2 and Liang 3 exhibit greater heterogeneity compared to subsection Liang 1. The single-fractal dimensions of micropores and mesopores show positive correlations with specific surface area (SSA) and pore volume (PV), while the fractal dimension of macropores shows a negative correlation with average pore diameter and median radius. The average values of single-fractal dimension D₃ obtained from HPMI data are 2.9644 and 2.9471 for shale and siltstone samples, respectively, indicating more complex structures of macropores in shale samples compared to siltstone samples. The average value of $\Delta D^{NMR}$ and singularity strength range Δα obtained by a multifractal model for core samples from subsection Liang 1 are 1.868 and 2.155, respectively, which are the smallest among all of the three subsections, indicating that the heterogeneity of pore structures of subsection Liang 1 is the weakest. This research provides valuable guidance for shale oil development in the northeastern Sichuan Basin, China. Full article

This work presents a comprehensive technological study of dielectric resonator-based microstrip filters (DRMFs), encompassing the design, fabrication, and rigorous characterization of the $T{E}_{01\delta }$ mode. Through systematic coupling analysis, we demonstrate filters featuring novel input–output coupling techniques and innovative implementations of both transmission zeros (4-2-0 configuration) and equalization zeros (4-0-2 configuration), specifically designed for demanding space and radar receiver applications, while the loaded quality factor ($Q_L$) and insertion loss do not match those of dielectric resonator cavity filters (DRCFs), our solution significantly surpasses conventional microstrip filters (MFs), achieving $Q_L$> 3000 compared to typical $Q_L$≈ 200 for coupled-line MFs in X-band. The fabricated filters exhibit exceptional performance as follows: input reflection ($S_{11}$) below −18 dB (4-2-0) and −16.5 dB (4-0-2), flat transmission response ($S_{21}$), and out-of-band rejection exceeding −30 dB. Mechanical tuning enables precise control of input–output coupling, inter-resonator coupling, cross-coupling, and frequency synthesis, while equalization zeros provide tailored group delay characteristics. This study positions DRMFs as a viable intermediate technology for high-performance RF systems, bridging the gap between conventional solutions. Full article

Alcoholic beverages represent a sector of significant economic and cultural importance but are also susceptible to fraud and adulteration, which can compromise their quality and authenticity. Isotopic analyses have become increasingly valuable tools for tracing the geographical origin and ensuring the quality control of products such as wine, beer, and distilled spirits. This literature review examines the main isotopic analysis techniques employed in this field, including Isotope Ratio Mass Spectrometry (IRMS) and Site-Specific Natural Isotope Fractionation by Nuclear Magnetic Resonance (SNIF-NMR), with a particular focus on the insights derived from the isotopic ratios of various elements, notably δ(²H), δ(¹³C), δ(¹⁸O), δ(¹⁵N) and δ(³⁴S). Full article

This study investigates the coupled effects of waste rock-to-tailings ratio (WTR) and curing temperature on the pore structure and mechanical performance of cemented tailings waste rock backfill (CTRB). Four WTRs (6:4, 7:3, 8:2, 9:1) and curing temperatures (20–50 °C) were tested. Low-field nuclear magnetic resonance (NMR) was used to characterize pore size distributions and derive fractal dimensions ($D_a$, $D_b$, $D_c$) at micropore, mesopore, and macropore scales. Uniaxial compressive strength (UCS) and elastic modulus (E) were also measured. The results reveal that (1) the micropore structure complexity was found to be a key indicator of structural refinement, while excessive temperature led to pore coarsening and strength reduction. $D_a$ = 2.01 reaches its peak at WTR = 7:3 and curing temperature = 40 °C; (2) at this condition, the UCS and E achieved 20.5 MPa and 1260 MPa, increasing by 45% and 38% over the baseline (WTR = 6:4, 20 °C); (3) when the temperature exceeded 40 °C, $D_a$ dropped significantly (e.g., to 1.51 at 50 °C for WTR = 7:3), indicating thermal over-curing and micropore coarsening; (4) correlation analysis showed strong negative relationships between total pore volume and mechanical strength ($R$ = −0.87 for ${\mathsf{\delta }}_a\mathrm{v}\mathrm{s}.\mathrm{U}\mathrm{C}\mathrm{S}),$ and a positive correlation between $D_a$ and UCS (R = 0.43). (5) multivariate regression models incorporating pore volume fractions, $T_2$ relaxation times, and fractal dimensions predicted $\mathrm{U}\mathrm{C}\mathrm{S}$ and E with R² > 0.98; (6) the hierarchical sensitivity of fractal dimensions follows the order micro-, meso-, macropores. This study provides new insights into the microstructure–mechanical performance relationship in CTRB and offers a theoretical and practical basis for the design of high-performance backfill materials in deep mining environments. Full article

Purpose: Obesity’s metabolic consequences are well documented; however, its neurobiological underpinnings remain elusive. This systematic review addresses a critical gap by synthesizing evidence on obesity-induced neuroplasticity across structural, functional, and molecular domains through advanced neuroimaging. Methods: According to PRISMA guidelines, we systematically searched (2015–2024) across PubMed/Web of Science, employing MeSH terms: (“Obesity” [Majr]) AND (“Neuroimaging” [Mesh] OR “Magnetic Resonance Imaging” [Mesh]). A total of 104 studies met the inclusion criteria. The inclusion criteria required the following: (1) multimodal imaging protocols (structural MRI/diffusion tensor imaging/resting-state functional magnetic resonance imaging (fMRI)/positron emission tomography (PET)); (2) pre-/post-intervention longitudinal design. Risk of bias was assessed via the Newcastle-Ottawa Scale. Key Findings: 1. Structural alterations: 7.2% mean gray matter reduction in prefrontal cortex (Cohen’s d = 0.81). White matter integrity decline (FA reduction β = −0.33, p < 0.001) across 12 major tracts. 2. Functional connectivity: Resting-state hyperactivity in mesolimbic pathways (fALFF + 23%, p-FDR < 0.05). Impaired fronto–striatal connectivity (r = −0.58 with BMI, 95% CI [−0.67, −0.49]). 3. Interventional reversibility: Bariatric surgery restored prefrontal activation (Δ = +18% vs. controls, p = 0.002). Neurostimulation (transcranial direct current stimulation (tDCS) enhanced cognitive control (post-treatment β = 0.42, p = 0.009). Conclusion: 1. Obesity induces multidomain neural reorganization beyond traditional reward circuits. 2. Neuroimaging biomarkers (e.g., striatal PET-dopamine binding potential) predict intervention outcomes (AUC = 0.79). 3. Precision neuromodulation requires tripartite integration of structural guidance, functional monitoring, and molecular profiling. Findings highlight neuroimaging’s pivotal role in developing stage-specific therapeutic strategies. Full article

Peroxisome proliferator-activated receptors (PPARs), composed of the α/δ/γ subtypes, are ligand-activated nuclear receptors/transcription factors that sense endogenous fatty acids or therapeutic drugs to regulate lipid/glucose metabolism and oxidative stress. PPAR forms a multiprotein complex with a retinoid X receptor and corepressor complex in an unliganded/inactive state, and ligand binding induces the replacement of the corepressor complex with the coactivator complex to initiate the transcription of various genes, including the metabolic and antioxidant ones. We investigated the processes by which the corepressor is replaced with the coactivator or in which two coactivators compete for the PPARα/δ/γ-ligand-binding domains (LBDs) using single- and dual-emission fluorescence resonance energy transfer (FRET) assays. Single-FRET revealed that the respective PPARα/δ/γ-selective agonists (pemafibrate, seladelpar, and pioglitazone) induced the dissociation of the two corepressor peptides, NCoR1 and NCoR2, from the PPARα/δ/γ-LBDs and the recruitment of the two coactivator peptides, CBP and TRAP220. Meanwhile, dual-FRET demonstrated that these processes are simultaneous and that the four coactivator peptides, CBP, TRAP220, PGC1α, and SRC1, were competitively recruited to the PPARα/δ/γ-LBDs with different preferences upon ligand activation. Furthermore, the five newly obtained cocrystal structures using X-ray diffraction, PPARα-LBDs–NCoR2/CBP/TRAP220/PGC1α and PPARγ-LBD–NCoR2, were co-analyzed with those from our previous studies. This illustrates that these coactivators bound to the same PPARα-LBD loci via their consensus LXXLL motifs in the liganded state; that NCoR1/NCoR2 corepressors bound to the same loci via the IXXXL sequences within their consensus LXXXIXXXL motifs in the unliganded state; and that ligand activation induced AF-2 helix 12 formation that interfered with corepressor binding and created a binding space for the coactivator. These PPARα/γ-related biochemical and physicochemical findings highlight the coregulator dynamics on limited PPARα/δ/γ-LBDs loci. Full article

In this study, a novel bio-based oxazine resin was synthesized through the reaction of naturally renewable materials: cardanol and furfurylamine. The molecular structure of the target product was confirmed via comprehensive characterization techniques, including Fourier-transform Infrared Spectroscopy (FT-IR), Gel Permeation Chromatography (GPC), Mass Spectrometry (MS), and Nuclear Magnetic Resonance (NMR). Differential Scanning Calorimetry (DSC) revealed that the curing process of cardanol-furfurylamine oxazine (CFZ) exhibited three exothermic peaks (~140, ~240, ~270 °C), which not only helped to optimize the processing conditions but also effectively enhanced the material properties. In the modification experiments, CFZ had been blended and cured with benzoxazine (BZ) at the mass ratios of 2:98, 5:95, 10:90, 20:80, and 40:60. Dynamic Mechanical Thermal Analysis (DMTA) further showed an elevated Loss Factor (tan δ) peak of CFZ-BZ resin, suggesting significantly enhanced toughness. Notably, when the content of the CFZ resin in the composite reached only 5%, the storage modulus achieved its maximum value, highlighting that minimal addition of CFZ resin can optimize the rigidity of the composite, which would drastically reduce material costs and simplify the process. Impact strength testing demonstrated that the impact resistance of CFZ-BZ resin was 6.42 times higher than that of pristine BZ. By integrating renewable materials with rational molecular design, this novel oxazine resin synergistically combines high-temperature resistance, superior toughness, and efficient modification at low loading, positioning it as a promising candidate to replace conventional petroleum-based resins in aerospace, renewable energy, and electronic packaging applications. Full article