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16 Results Found

  • Article
  • Open Access
20 Citations
5,131 Views
17 Pages

CO2 Separation in Nanocomposite Membranes by the Addition of Amidine and Lactamide Functionalized POSS® Nanoparticles into a PVA Layer

  • Gabriel Guerrero,
  • May-Britt Hägg,
  • Christian Simon,
  • Thijs Peters,
  • Nicolas Rival and
  • Christelle Denonville

In this article, we studied two different types of polyhedral oligomeric silsesquioxanes (POSS®) functionalized nanoparticles as additives for nanocomposite membranes for CO2 separation. One with amidine functionalization (Amidino POSS®) and...

  • Article
  • Open Access
17 Citations
3,259 Views
14 Pages

Thermoplastic Starch Composites Reinforced with Functionalized POSS: Fabrication, Characterization, and Evolution of Mechanical, Thermal and Biological Activities

  • Raja Venkatesan,
  • Ramkumar Vanaraj,
  • Krishnapandi Alagumalai,
  • Shakila Parveen Asrafali,
  • Chaitany Jayprakash Raorane,
  • Vinit Raj and
  • Seong-Cheol Kim

17 October 2022

Rapid advancements in materials that offer the appropriate mechanical strength, barrier, and antimicrobial activity for food packaging are still confronted with significant challenges. In this study, a modest, environmentally friendly method was used...

  • Article
  • Open Access
11 Citations
3,459 Views
14 Pages

20 January 2021

Honeycomb films pore-filled with metal (Au, Ag, and Cu) nanoparticles were successfully prepared by combining the breath figure method and an in situ reduction reaction. First, a polyhedral oligomeric silsesquioxane (POSS)-based star-shaped polymer s...

  • Review
  • Open Access
369 Citations
28,663 Views
31 Pages

Polyhedral Oligomeric Silsesquioxane (POSS)-Containing Polymer Nanocomposites

  • Ebunoluwa Ayandele,
  • Biswajit Sarkar and
  • Paschalis Alexandridis

6 December 2012

Hybrid materials with superior structural and functional properties can be obtained by incorporating nanofillers into polymer matrices. Polyhedral oligomeric silsesquioxane (POSS) nanoparticles have attracted much attention recently due to their nano...

  • Article
  • Open Access
18 Citations
5,493 Views
13 Pages

18 October 2019

In this study, we investigated the influence of methacryl-functionalized polyhedral oligomeric silsesquioxane (MA-POSS) nanoparticles as a plasticizer and thermal stabilizer for a poly(vinyl chloride) (PVC) homopolymer and for a poly(vinyl chloride)/...

  • Article
  • Open Access
12 Citations
4,218 Views
13 Pages

12 February 2019

Giant surfactants refer to a new kind of amphiphile by incorporating functional molecular nanoparticles with polymer tails. As a size-amplified counterpart of small-molecule surfactants, they serve to bridge the gap between small-molecule surfactants...

  • Review
  • Open Access
86 Citations
16,082 Views
20 Pages

7 June 2016

The organic/inorganic hybrid materials from polyhedral oligomeric silsesquioxane (POSS, inorganic nanoparticles) and polybenzoxazine (PBZ) have received much interesting recently due to their excellent thermal and mechanical properties, flame retarda...

  • Article
  • Open Access
17 Citations
4,769 Views
17 Pages

POSS Nanofiller-Induced Enhancement of the Thermomechanical Properties in a Fluoroelastomer Terpolymer

  • Daphné Berthier,
  • Marie-Pierre Deffarges,
  • Nicolas Berton,
  • Mathieu Venin,
  • Florian Lacroix,
  • Bruno Schmaltz,
  • Yohan Tendron,
  • Eric Pestel,
  • François Tran-Van and
  • Stéphane Méo

6 August 2018

The present study reports on the use of three types of polyhedral oligomeric silsesquioxanes (POSS) nanoparticles with various organic substituents as fillers in a fluoroelastomer (FKM). A series of/POSS elastomer composite thin films is prepared. Mi...

  • Article
  • Open Access
5 Citations
2,078 Views
19 Pages

Effect of Amino-Functionalized Polyhedral Oligomeric Silsesquioxanes on Structure-Property Relationships of Thermostable Hybrid Cyanate Ester Resin Based Nanocomposites

  • Olga Grigoryeva,
  • Alexander Fainleib,
  • Olga Starostenko,
  • Diana Shulzhenko,
  • Agustin Rios de Anda,
  • Fabrice Gouanve,
  • Eliane Espuche and
  • Daniel Grande

9 December 2023

Nanocomposites of cyanate ester resin (CER) filled with three different reactive amino-functionalized polyhedral oligomeric silsesquioxane (POSS) were synthesized and characterized. The addition of a small quantity (0.1 wt.%) of amino-POSS chemically...

  • Article
  • Open Access
11 Citations
2,565 Views
14 Pages

Effect of Bioactive and Antimicrobial Nanoparticles on Properties and Applicability of Dental Adhesives

  • Marietta Kreutz,
  • Christian Kreutz,
  • Philipp Kanzow,
  • Tobias T. Tauböck,
  • Phoebe Burrer,
  • Christine Noll,
  • Oliver Bader,
  • Bianca Rohland,
  • Annette Wiegand and
  • Marta Rizk

1 November 2022

The aim of the study was to examine the applicability of bioactive and antibacterial nanoparticles to an experimental adhesive. The adhesive (60 wt% BisGMA, 15 wt% TEGDMA, 25 wt% HEMA) was mixed with combinations of 5 wt% methacryl-functionalized pol...

  • Article
  • Open Access
26 Citations
11,242 Views
13 Pages

21 September 2011

Our continuing quest to improve the performance of polymer composites under moist and saltwater environments has gained momentum in recent years with the reinforcement of inorganic nanoparticles into the polymer. The key to mitigate degradation of co...

  • Article
  • Open Access
11 Citations
4,246 Views
24 Pages

Unlocking the Potential Use of Reactive POSS as a Coagent for EPDM/PP-Based TPV

  • Nazlı Yazıcı Çakır,
  • Özgenur İnan,
  • Merve Ergün,
  • Mehmet Kodal and
  • Güralp Özkoç

11 May 2023

Thermoplastic vulcanizates (TPVs) are multifunctional materials consisting of two or more phases with solid elastomeric properties at room temperatures and fluid-like properties above their melting point. They are produced through a reactive blending...

  • Review
  • Open Access
563 Views
22 Pages

26 December 2025

In recent years, hybrid polymer/POSS (Polyhedral Oligomeric Silsesquioxane) systems have attracted particular attention, combining the advantages of organic and inorganic components. This paper reports on the thermal and thermo-oxidative degradation...

  • Review
  • Open Access
112 Citations
15,970 Views
34 Pages

20 May 2014

The covalent incorporation of inorganic building blocks into a polymer matrix to obtain stable and robust materials is a widely used concept in the field of organic-inorganic hybrid materials, and encompasses the use of different inorganic systems in...

  • Article
  • Open Access
46 Citations
10,777 Views
16 Pages

17 June 2014

In this study, we prepared a mesoporous carbon with hexagonally packed mesopores through evaporation-induced self-assembly (EISA)—with the diblock copolymer poly(ethylene oxide-b-ε-caprolactone) (PEO-b-PCL) as the template (EO114CL84), phenolic resin...

  • Article
  • Open Access
6 Citations
2,964 Views
17 Pages

Synthesis and Characterization of New Nanohybrids Based on Carboxymethyl Scleroglucan and Silica Nanoparticles

  • Rubén H. Castro,
  • Laura M. Corredor,
  • Isidro Burgos,
  • Sebastián Llanos,
  • Camilo A. Franco,
  • Farid B. Cortés,
  • Eduardo A. Idrobo and
  • Arnold R. Romero Bohórquez

10 March 2024

In this study, two new nanohybrids (NH-A and NH-B) were synthesized through carbodiimide-assisted coupling. The reaction was performed between carboxymethyl-scleroglucans (CMS-A and CMS-B) with different degrees of substitution and commercial amino-f...