Search for Articles:
Title / Keyword
Author / Affiliation / Email
Journal
Article Type
 
 
Advanced Search
 
Section
Special Issue
Volume
Issue
Number
Page
 
6.6
5.0
Journals
Polymers
Special Issues
Natural Fibres and their Composites
share announcement

Natural Fibres and their Composites

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Biomacromolecules, Biobased and Biodegradable Polymers".

Deadline for manuscript submissions: closed (31 May 2020) | Viewed by 55846

Printed Edition Available!
A printed edition of this Special Issue is available here.

Special Issue Editor

Prof. Dr. Vincenzo Fiore

E-Mail Website
Guest Editor
Department of Engineering, University of Palermo, Viale delle Scienze ed.6, 90128 Palermo, Italy
Interests: natural fibres; polymer composites; biobased materials; hybrid composites; fiber-matrix adhesion; structural joints; mechanical properties
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

A rising interest in environmentally friendly fibre reinforced composites (i.e., derived from renewable resources) has been recorded over the last decades due to the rising global awareness of environmental issues. In this context, natural fibres from different biorenewable resources (i.e., vegetal, mineral and animal sources) have attracted great attention both from academia and from several industrial fields thanks to their specific properties, low prices, great availability, health advantages, easy processing, renewability, biodegradability and recyclability.

This Special Issue aims to present the developments made in the field of natural fibres and their composites, including but not limited to the following aspects:

  • Fibre extraction and retting processes;
  • Characterization of fibre properties;
  • Fibre treatments;
  • Manufacturing processes of composites;
  • Characterization of composite properties;
  • Evaluation of composite aging resistance.

Authors are invited to submit original research as well as review papers to this Special Issue.

Prof. Dr. Vincenzo Fiore
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Polymers is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • natural fibres;
  • polymer composites;
  • bio-based materials;
  • hybrid composites;
  • fibre–matrix adhesion

Published Papers (15 papers)

Download All Papers
Order results
Result details
Show export options expand_more Show export options expand_less
Select all
Export citation of selected articles as:

Editorial

Jump to: Research

3 pages, 181 KiB  
Editorial
Natural Fibres and Their Composites
by Vincenzo Fiore
Polymers 2020, 12(10), 2380; https://doi.org/10.3390/polym12102380 - 15 Oct 2020
Cited by 3 | Viewed by 1258
Abstract
Due to several promising properties, such as their low density and specific properties, low price, easy processing, health advantages, renewability and recyclability, increasing attention was paid in the last years to natural fibres as alternatives to synthetic counterparts for the reinforcement of polymeric [...] Read more.
Due to several promising properties, such as their low density and specific properties, low price, easy processing, health advantages, renewability and recyclability, increasing attention was paid in the last years to natural fibres as alternatives to synthetic counterparts for the reinforcement of polymeric based composites [...] Full article
(This article belongs to the Special Issue Natural Fibres and their Composites)

Research

Jump to: Editorial

11 pages, 8798 KiB  
Article
Development of Thermoplastic Starch (TPS) Including Leather Waste Fragments
by Silvio Pompei, Jacopo Tirillò, Fabrizio Sarasini and Carlo Santulli
Polymers 2020, 12(8), 1811; https://doi.org/10.3390/polym12081811 - 12 Aug 2020
Cited by 4 | Viewed by 3191
Abstract
A thermoplastic starch (TPS) material is developed, based on corn starch plasticized with glycerol and citric acid in a 9:3:1 ratio and further bonded with isinglass and mono- and diglycerides of fatty acids (E471). In TPS, leather fragments, in the amount of 7.5 [...] Read more.
A thermoplastic starch (TPS) material is developed, based on corn starch plasticized with glycerol and citric acid in a 9:3:1 ratio and further bonded with isinglass and mono- and diglycerides of fatty acids (E471). In TPS, leather fragments, in the amount of 7.5 15 or 22.5 g/100 g of dry matter, were also introduced. The mixture was heated at a maximum temperature of 80 °C, then cast in an open mold to obtain films with thickness in the range 300 ± 50 microns. The leather fragments used were based on collagen obtained from production waste from shoemaking and tanned with tannins obtained from smoketree (Rhus cotinus), therefore free from chromium. Thermogravimetric (TGA) tests suggested that material degradation started at a temperature around 285 °C, revealing that the presence of leather fragments did not influence the occurrence of this process in TPS. Tensile tests indicated an increase in tensile properties (strength and Young’s modulus) with increasing leather content, albeit coupled, especially at 22.5 wt%, with a more pronounced brittle behavior. Leather waste provided a sound interface with the bulk of the composite, as observed under scanning electron microscopy. The production process indicated a very limited degradation of the material after exposure to UV radiation for eight days, as demonstrated by the slight attenuation of amide I (collagen) and polysaccharide FTIR peaks. Reheating at 80 °C resulted in a weight loss not exceeding 3%. Full article
(This article belongs to the Special Issue Natural Fibres and their Composites)
►▼ Show Figures

Figure 1

15 pages, 3733 KiB  
Article
Effect of Fique Fibers in the Behavior of a New Biobased Composite from Renewable Mopa-Mopa Resin
by José Herminsul Mina Hernandez, Edward Fernando Toro Perea, Katherine Caicedo Mejía and Claudia Alejandra Meneses Jacobo
Polymers 2020, 12(7), 1573; https://doi.org/10.3390/polym12071573 - 16 Jul 2020
Cited by 6 | Viewed by 2587
Abstract
A fully biobased composite was developed using a natural resin from the Elaeagia Pastoensis Mora plant, known as Mopa-Mopa reinforced with fique fibers. Resin extraction was through solvent processing reaching an efficient extraction process of 92% and obtaining a material that acted as [...] Read more.
A fully biobased composite was developed using a natural resin from the Elaeagia Pastoensis Mora plant, known as Mopa-Mopa reinforced with fique fibers. Resin extraction was through solvent processing reaching an efficient extraction process of 92% and obtaining a material that acted as a matrix without using any supplementary chemical modifications as it occurs with most of the biobased resins. This material was processed by the conventional transform method (hot compression molding) to form the plates from which the test specimens were extracted. From physicochemical and mechanical characterization, it was found that the resin had obtained a tensile strength of 15 MPa that increased to values of 30 MPa with the addition of 20% of the fibers with alkalization treatment. This behavior indicated a favorable condition of the fiber-matrix interface in the material. Similarly, the evaluation of the moisture adsorption in the components of the composite demonstrated that such adsorption was mainly promoted by the presence of the fibers and had a negative effect on a plasticization phenomenon from humidity that reduced the mechanical properties for all the controlled humidities (47%, 77% and 97%). Finally, due to its physicochemical and mechanical behavior, this new biobased composite is capable of being used in applications such as wood–plastic (WPCs) to replace plastic and/or natural wood products that are widely used today. Full article
(This article belongs to the Special Issue Natural Fibres and their Composites)
►▼ Show Figures

Graphical abstract

13 pages, 1514 KiB  
Article
Characterization Study of Empty Fruit Bunch (EFB) Fibers Reinforcement in Poly(Butylene) Succinate (PBS)/Starch/Glycerol Composite Sheet
by Rafiqah S. Ayu, Abdan Khalina, Ahmad Saffian Harmaen, Khairul Zaman, Tawakkal Isma, Qiuyun Liu, R. A. Ilyas and Ching Hao Lee
Polymers 2020, 12(7), 1571; https://doi.org/10.3390/polym12071571 - 15 Jul 2020
Cited by 79 | Viewed by 4570
Abstract
In this study, a mixture of thermoplastic polybutylene succinate (PBS), tapioca starch, glycerol and empty fruit bunch fiber was prepared by a melt compounding method using an industrial extruder. Generally, insertion of starch/glycerol has provided better strength performance, but worse thermal and water [...] Read more.
In this study, a mixture of thermoplastic polybutylene succinate (PBS), tapioca starch, glycerol and empty fruit bunch fiber was prepared by a melt compounding method using an industrial extruder. Generally, insertion of starch/glycerol has provided better strength performance, but worse thermal and water uptake to all specimens. The effect of fiber loading on mechanical, morphological, thermal and physical properties was studied in focus. Low interfacial bonding between fiber and matrix revealed a poor mechanical performance. However, higher fiber loadings have improved the strength values. This is because fibers regulate good load transfer mechanisms, as confirmed from SEM micrographs. Tensile and flexural strengths have increased 6.0% and 12.2%, respectively, for 20 wt% empty fruit bunch (EFB) fiber reinforcements. There was a slightly higher mass loss for early stage thermal decomposition, whereas regardless of EFB contents, insignificant changes on decomposition temperature were recorded. A higher lignin constituent in the composite (for high natural fiber volume) resulted in a higher mass residue, which would turn into char at high temperature. This observation indirectly proves the dimensional integrity of the composite. However, as expected, with higher EFB fiber contents in the composite, higher values in both the moisture uptake and moisture loss analyses were found. The hydroxyl groups in the EFB absorbed water moisture through formation of hydrogen bonding. Full article
(This article belongs to the Special Issue Natural Fibres and their Composites)
►▼ Show Figures

Figure 1

21 pages, 5572 KiB  
Article
Mechanical and Rheological Behaviour of Composites Reinforced with Natural Fibres
by Mariana D. Stanciu, Horatiu Teodorescu Draghicescu, Florin Tamas and Ovidiu Mihai Terciu
Polymers 2020, 12(6), 1402; https://doi.org/10.3390/polym12061402 - 22 Jun 2020
Cited by 23 | Viewed by 3485
Abstract
The paper deals with the mechanical behaviour of natural fibre composites subjected to tensile test and dynamic mechanical analysis (DMA). Three types of natural fibre composites were prepared and tested: wood particle reinforced composites with six different sizes of grains (WPC); hemp mat [...] Read more.
The paper deals with the mechanical behaviour of natural fibre composites subjected to tensile test and dynamic mechanical analysis (DMA). Three types of natural fibre composites were prepared and tested: wood particle reinforced composites with six different sizes of grains (WPC); hemp mat reinforced composites (HMP) and flax reinforced composite with mixed wood particles (FWPC). The tensile test performed on universal testing machine LS100 Lloyd’s Instrument highlights the elastic properties of the samples, as longitudinal elasticity modulus; tensile rupture; strain at break; and stiffness. The large dispersion of stress–strain curves was noticed in the case of HMP and FWPC by comparison to WPC samples which present high homogeneity of elastic–plastic behaviour. The DMA test emphasized the rheological behaviour of natural fibre composites in terms of energy dissipation of a material under cyclic load. Cole–Cole plots revealed the connection between stored and loss heat energy for studied samples. The mixture of wood particles with a polyester matrix leads to relative homogeneity of composite in comparison with FWPC and HMP samples which is visible from the shape of Cole–Cole curves. The random fibres from the hemp mat structure lead to a heterogeneous nature of composite structure. The elastic and viscous responses of samples depend on the interface between fibres and matrix. Full article
(This article belongs to the Special Issue Natural Fibres and their Composites)
►▼ Show Figures

Figure 1

25 pages, 4172 KiB  
Article
Sustainable Micro and Nano Additives for Controlling the Migration of a Biobased Plasticizer from PLA-Based Flexible Films
by Laura Aliotta, Alessandro Vannozzi, Luca Panariello, Vito Gigante, Maria-Beatrice Coltelli and Andrea Lazzeri
Polymers 2020, 12(6), 1366; https://doi.org/10.3390/polym12061366 - 17 Jun 2020
Cited by 37 | Viewed by 4663
Abstract
Plasticized poly(lactic acid) (PLA)/poly(butylene succinate) (PBS) blend-based films containing chitin nanofibrils (CN) and calcium carbonate were prepared by extrusion and compression molding. On the basis of previous studies, processability was controlled by the use of a few percent of a commercial acrylic copolymer [...] Read more.
Plasticized poly(lactic acid) (PLA)/poly(butylene succinate) (PBS) blend-based films containing chitin nanofibrils (CN) and calcium carbonate were prepared by extrusion and compression molding. On the basis of previous studies, processability was controlled by the use of a few percent of a commercial acrylic copolymer acting as melt strength enhancer and calcium carbonate. Furthermore, acetyl n-tributyl citrate (ATBC), a renewable and biodegradable plasticizer (notoriously adopted in PLA based products) was added to facilitate not only the processability but also to increase the mechanical flexibility and toughness. However, during the storage of these films, a partial loss of plasticizer was observed. The consequence of this is not only correlated to the change of the mechanical properties making the films more rigid but also to the crystallization and development of surficial oiliness. The effect of the addition of calcium carbonate (nanometric and micrometric) and natural nanofibers (chitin nanofibrils) to reduce/control the plasticizer migration was investigated. The prediction of plasticizer migration from the films’ core to the external surface was carried out and the diffusion coefficients, obtained by regression of the experimental migration data plotted as the square root of time, were evaluated for different blends compositions. The results of the diffusion coefficients, obtained thanks to migration tests, showed that the CN can slow the plasticizer migration. However, the best result was achieved with micrometric calcium carbonate while nanometric calcium carbonate results were less effective due to favoring of some bio polyesters’ chain scission. The use of both micrometric calcium carbonate and CN was counterproductive due to the agglomeration phenomena that were observed. Full article
(This article belongs to the Special Issue Natural Fibres and their Composites)
►▼ Show Figures

Graphical abstract

16 pages, 5538 KiB  
Article
Dog Wool Microparticles/Polyurethane Composite for Thermal Insulation
by Francisco Claudivan da Silva, Helena P. Felgueiras, Rasiah Ladchumananandasivam, José Ubiragi L. Mendes, Késia Karina de O. Souto Silva and Andrea Zille
Polymers 2020, 12(5), 1098; https://doi.org/10.3390/polym12051098 - 11 May 2020
Cited by 8 | Viewed by 2707
Abstract
A polyurethane (PU)-based eco-composite foam was prepared using dog wool fibers as a filler. Fibers were acquired from pet shops and alkaline treated prior to use. The influence of their incorporation on the PU foams’ morphological, thermal, and mechanical properties was investigated. The [...] Read more.
A polyurethane (PU)-based eco-composite foam was prepared using dog wool fibers as a filler. Fibers were acquired from pet shops and alkaline treated prior to use. The influence of their incorporation on the PU foams’ morphological, thermal, and mechanical properties was investigated. The random and disorganized presence of the microfibers along the foam influence their mechanical performance. Tensile and compression strengths were improved with the increased amount of dog wool microparticles on the eco-composites. The same occurred with the foams’ hydration capacity. The thermal capacity was also slightly enhanced with the incorporation of the fillers. The fillers also increased the thermal stability of the foams, reducing their dilatation with heating. The best structural stability was obtained using up to 120 °C with a maximum of 15% of filler. In the end, the dog wool waste was rationally valorized as a filler in PU foams, demonstrating its potential for insulation applications, with a low cost and minimal environmental impact. Full article
(This article belongs to the Special Issue Natural Fibres and their Composites)
►▼ Show Figures

Graphical abstract

11 pages, 3546 KiB  
Article
Polypropylene/Basalt Fabric Laminates: Flexural Properties and Impact Damage Behavior
by Pietro Russo, Ilaria Papa, Vito Pagliarulo and Valentina Lopresto
Polymers 2020, 12(5), 1079; https://doi.org/10.3390/polym12051079 - 08 May 2020
Cited by 13 | Viewed by 2277
Abstract
Recently, the growing interests into the environmental matter are driving the research interest to the development of new eco-sustainable composite materials toward the replacement of synthetic reinforcing fibers with natural ones and exploiting the intrinsic recyclability of thermoplastic resins even for uses in [...] Read more.
Recently, the growing interests into the environmental matter are driving the research interest to the development of new eco-sustainable composite materials toward the replacement of synthetic reinforcing fibers with natural ones and exploiting the intrinsic recyclability of thermoplastic resins even for uses in which thermosetting matrices are well consolidated (e.g., naval and aeronautical fields). In this work, polypropylene/basalt fabric composite samples were prepared by film stacking and compression molding procedures. They have been studied in terms of flexural and low-velocity impact behavior. The influence related to the matrix modification with a pre-optimized amount of maleic anhydride grafted PP as coupling agent was studied. The mechanical performances of the composite systems were compared with those of laminates consisting of the pure matrix and obtained by hot-pressing of PP pellets and PP films used in the stacking procedure. Results, on one side, demonstrated a slight reduction of both static and dynamic parameters at the break for specimens from superimposed films to ones prepared from PP pellets. Moreover, an outstanding improvement of mechanical performances was shown in the presence of basalt layers, especially for compatibilized samples. Full article
(This article belongs to the Special Issue Natural Fibres and their Composites)
►▼ Show Figures

Figure 1

18 pages, 18797 KiB  
Article
Falling Weight Impact Damage Characterisation of Flax and Flax Basalt Vinyl Ester Hybrid Composites
by Hom Nath Dhakal, Elwan Le Méner, Marc Feldner, Chulin Jiang and Zhongyi Zhang
Polymers 2020, 12(4), 806; https://doi.org/10.3390/polym12040806 - 03 Apr 2020
Cited by 11 | Viewed by 2511
Abstract
Understanding the damage mechanisms of composite materials requires detailed mapping of the failure behaviour using reliable techniques. This research focuses on an evaluation of the low-velocity falling weight impact damage behaviour of flax-basalt/vinyl ester (VE) hybrid composites. Incident impact energies under three different [...] Read more.
Understanding the damage mechanisms of composite materials requires detailed mapping of the failure behaviour using reliable techniques. This research focuses on an evaluation of the low-velocity falling weight impact damage behaviour of flax-basalt/vinyl ester (VE) hybrid composites. Incident impact energies under three different energy levels (50, 60, and 70 Joules) were employed to cause complete perforation in order to characterise different impact damage parameters, such as energy absorption characteristics, and damage modes and mechanisms. In addition, the water absorption behaviour of flax and flax basalt hybrid composites and its effects on the impact damage performance were also investigated. All the samples subjected to different incident energies were characterised using non-destructive techniques, such as scanning electron microscopy (SEM) and X-ray computed micro-tomography (πCT), to assess the damage mechanisms of studied flax/VE and flax/basalt/VE hybrid composites. The experimental results showed that the basalt hybrid system had a high impact energy and peak load compared to the flax/VE composite without hybridisation, indicating that a hybrid approach is a promising strategy for enhancing the toughness properties of natural fibre composites. The πCT and SEM images revealed that the failure modes observed for flax and flax basalt hybrid composites were a combination of matrix cracking, delamination, fibre breakage, and fibre pull out. Full article
(This article belongs to the Special Issue Natural Fibres and their Composites)
►▼ Show Figures

Graphical abstract

21 pages, 18748 KiB  
Article
Effect of Carbon Nanostructures and Fatty Acid Treatment on the Mechanical and Thermal Performances of Flax/Polypropylene Composites
by Pietro Russo, Libera Vitiello, Francesca Sbardella, Jose I. Santos, Jacopo Tirillò, Maria Paola Bracciale, Iván Rivilla and Fabrizio Sarasini
Polymers 2020, 12(2), 438; https://doi.org/10.3390/polym12020438 - 13 Feb 2020
Cited by 17 | Viewed by 3250
Abstract
Four different strategies for mitigating the highly hydrophilic nature of flax fibers were investigated with a view to increase their compatibility with apolar polypropylene. The effects of two carbon nanostructures (graphene nanoplatelets (GNPs) and carbon nanotubes (CNTs)), of a chemical modification with a [...] Read more.
Four different strategies for mitigating the highly hydrophilic nature of flax fibers were investigated with a view to increase their compatibility with apolar polypropylene. The effects of two carbon nanostructures (graphene nanoplatelets (GNPs) and carbon nanotubes (CNTs)), of a chemical modification with a fatty acid (stearic acid), and of maleated polypropylene on interfacial adhesion, mechanical properties (tensile and flexural), and thermal stability (TGA) were compared. The best performance was achieved by a synergistic combination of GNPs and maleated polypropylene, which resulted in an increase in tensile strength and modulus of 42.46% and 54.96%, respectively, compared to baseline composites. Stearation proved to be an effective strategy for increasing the compatibility with apolar matrices when performed in an ethanol solution with a 0.4 M concentration. The results demonstrate that an adequate selection of surface modification strategies leads to considerable enhancements in targeted properties. Full article
(This article belongs to the Special Issue Natural Fibres and their Composites)
►▼ Show Figures

Graphical abstract

14 pages, 1446 KiB  
Article
Modeling the Stiffness of Coupled and Uncoupled Recycled Cotton Fibers Reinforced Polypropylene Composites
by Albert Serra, Quim Tarrés, Miquel-Àngel Chamorro, Jordi Soler, Pere Mutjé, Francesc X. Espinach and Fabiola Vilaseca
Polymers 2019, 11(10), 1725; https://doi.org/10.3390/polym11101725 - 21 Oct 2019
Cited by 12 | Viewed by 3049
Abstract
The stiffness of a composite material is mainly affected by the nature of its phases and its contents, the dispersion of the reinforcement, as well as the morphology and mean orientation of such reinforcement. In this paper, recovered dyed cotton fibers from textile [...] Read more.
The stiffness of a composite material is mainly affected by the nature of its phases and its contents, the dispersion of the reinforcement, as well as the morphology and mean orientation of such reinforcement. In this paper, recovered dyed cotton fibers from textile industry were used as reinforcement for a polypropylene matrix. The specific dye seems to decrease the hydrophilicity of the fibers and to increase its chemical compatibility with the matrix. The results showed a linear evolution of the Young’s moduli of the composites against the reinforcement contents, although the slope of the regression line was found to be lower than that for other natural strand reinforced polypropylene composites. This was blamed on a growing difficulty to disperse the reinforcements when its content increased. The micromechanics analysis returned a value for the intrinsic Young’s modulus of the cotton fibers that doubled previously published values. The use of two different micromechanics models allowed evaluating the impact of the morphology of the fibers on the Young’s modulus of a composite. Full article
(This article belongs to the Special Issue Natural Fibres and their Composites)
►▼ Show Figures

Graphical abstract

18 pages, 14113 KiB  
Article
Effect of Graphene Oxide Coating on Natural Fiber Composite for Multilayered Ballistic Armor
by Ulisses Oliveira Costa, Lucio Fabio Cassiano Nascimento, Julianna Magalhães Garcia, Sergio Neves Monteiro, Fernanda Santos da Luz, Wagner Anacleto Pinheiro and Fabio da Costa Garcia Filho
Polymers 2019, 11(8), 1356; https://doi.org/10.3390/polym11081356 - 16 Aug 2019
Cited by 68 | Viewed by 6774
Abstract
Composites with sustainable natural fibers are currently experiencing remarkably diversified applications, including in engineering industries, owing to their lower cost and density as well as ease in processing. Among the natural fibers, the fiber extracted from the leaves of the Amazonian curaua plant [...] Read more.
Composites with sustainable natural fibers are currently experiencing remarkably diversified applications, including in engineering industries, owing to their lower cost and density as well as ease in processing. Among the natural fibers, the fiber extracted from the leaves of the Amazonian curaua plant (Ananas erectifolius) is a promising strong candidate to replace synthetic fibers, such as aramid (Kevlar™), in multilayered armor system (MAS) intended for ballistic protection against level III high velocity ammunition. Another remarkable material, the graphene oxide is attracting considerable attention for its properties, especially as coating to improve the interfacial adhesion in polymer composites. Thus, the present work investigates the performance of graphene oxide coated curaua fiber (GOCF) reinforced epoxy composite, as a front ceramic MAS second layer in ballistic test against level III 7.62 mm ammunition. Not only GOCF composite with 30 vol% fibers attended the standard ballistic requirement with 27.4 ± 0.3 mm of indentation comparable performance to Kevlar™ 24 ± 7 mm with same thickness, but also remained intact, which was not the case of non-coated curaua fiber similar composite. Mechanisms of ceramic fragments capture, curaua fibrils separation, curaua fiber pullout, composite delamination, curaua fiber braking, and epoxy matrix rupture were for the first time discussed as a favorable combination in a MAS second layer to effectively dissipate the projectile impact energy. Full article
(This article belongs to the Special Issue Natural Fibres and their Composites)
►▼ Show Figures

Figure 1

12 pages, 3019 KiB  
Article
The Relationships between the Working Fluids, Process Characteristics and Products from the Modified Coaxial Electrospinning of Zein
by Menglong Wang, Tao Hai, Zhangbin Feng, Deng-Guang Yu, Yaoyao Yang and SW Annie Bligh
Polymers 2019, 11(8), 1287; https://doi.org/10.3390/polym11081287 - 01 Aug 2019
Cited by 76 | Viewed by 6008
Abstract
The accurate prediction and manipulation of nanoscale product sizes is a major challenge in material processing. In this investigation, two process characteristics were explored during the modified coaxial electrospinning of zein, with the aim of understanding how this impacts the products formed. The [...] Read more.
The accurate prediction and manipulation of nanoscale product sizes is a major challenge in material processing. In this investigation, two process characteristics were explored during the modified coaxial electrospinning of zein, with the aim of understanding how this impacts the products formed. The characteristics studied were the spreading angle at the unstable region (θ) and the length of the straight fluid jet (L). An electrospinnable zein core solution was prepared and processed with a sheath comprising ethanolic solutions of LiCl. The width of the zein nanoribbons formed (W) was found to be more closely correlated with the spreading angle and straight fluid jet length than with the experimental parameters (the electrolyte concentrations and conductivity of the shell fluids). Linear equations W = 546.44L − 666.04 and W = 2255.3θ − 22.7 could be developed with correlation coefficients of Rwl2 = 0.9845 and Rwθ2 = 0.9924, respectively. These highly linear relationships reveal that the process characteristics can be very useful tools for both predicting the quality of the electrospun products, and manipulating their sizes for functional applications. This arises because any changes in the experimental parameters would have an influence on both the process characteristics and the solid products’ properties. Full article
(This article belongs to the Special Issue Natural Fibres and their Composites)
►▼ Show Figures

Graphical abstract

17 pages, 3852 KiB  
Article
Effects of Fiber Surface Grafting with Nano-Clay on the Hydrothermal Ageing Behaviors of Flax Fiber/Epoxy Composite Plates
by Anni Wang, Guijun Xian and Hui Li
Polymers 2019, 11(8), 1278; https://doi.org/10.3390/polym11081278 - 31 Jul 2019
Cited by 29 | Viewed by 3775
Abstract
Flax fiber has high sensitivity to moisture, and moisture uptake leads to the decrease of mechanical properties and distortion in shape. This paper attempts to graft flax fabric with nano-clay, with assistance from a silane-coupling agent, in order to improve hygrothermal resistance. The [...] Read more.
Flax fiber has high sensitivity to moisture, and moisture uptake leads to the decrease of mechanical properties and distortion in shape. This paper attempts to graft flax fabric with nano-clay, with assistance from a silane-coupling agent, in order to improve hygrothermal resistance. The nano-clay grafted flax fabric reinforced epoxy (FFRP) composite produced through vacuum assisted resin infusion (VARI) process were subjected to 80% RH chamber for 12 weeks at 20, 40 and 70 °C, respectively. Moisture uptake, dimensional stability, and tensile properties was studied as a function of humidity exposure. Through SEM and FTIR, the effects of hygrothermal exposure was elucidated. In comparison to control FFRP plates, nano-clay grafting decreases saturation moisture uptake and the coefficient of diffusion of FFRP by 38.4% and 13.2%, respectively. After exposure for six weeks, the retention rate of the tensile modulus of the nano-clay grafted flax fiber based FFRP increased by 33.8% compared with that of the control ones. Nano-clay grafting also reduces the linear moisture expansion coefficient of FFRPs by 8.4% in a radial direction and 10.9% in a weft direction. Full article
(This article belongs to the Special Issue Natural Fibres and their Composites)
►▼ Show Figures

Figure 1

16 pages, 4178 KiB  
Article
Flax, Basalt, E-Glass FRP and Their Hybrid FRP Strengthened Wood Beams: An Experimental Study
by Bo Wang, Erik Valentine Bachtiar, Libo Yan, Bohumil Kasal and Vincenzo Fiore
Polymers 2019, 11(8), 1255; https://doi.org/10.3390/polym11081255 - 29 Jul 2019
Cited by 31 | Viewed by 4931
Abstract
In this study, the structural behavior of small-scale wood beams externally strengthened with various fiber strengthened polymer (FRP) composites (i.e., flax FRP (FFRP), basalt FRP (BFRP), E-glass FRP (“E” stands for electrical resistance, GFRP) and their hybrid FRP composites (HFRP) with different fiber [...] Read more.
In this study, the structural behavior of small-scale wood beams externally strengthened with various fiber strengthened polymer (FRP) composites (i.e., flax FRP (FFRP), basalt FRP (BFRP), E-glass FRP (“E” stands for electrical resistance, GFRP) and their hybrid FRP composites (HFRP) with different fiber configurations) were investigated. FRP strengthened wood specimens were tested under bending and the effects of different fiber materials, thicknesses and the layer arrangements of the FRP on the flexural behavior of strengthened wood beams were discussed. The beams strengthened with flax FRP showed a higher flexural loading capacity in comparison to the beams with basalt FRP. Flax FRP provided a comparable enhancement in the maximum load with beams strengthened with glass FRP at the same number of FRP layers. In addition, all the hybrid FRPs (i.e., a combination of flax, basalt and E-glass FRP) in this study exhibited no significant enhancement in load carrying capacity but larger maximum deflection than the single type of FRP composite. It was also found that the failure modes of FRP strengthened beams changed from tensile failure to FRP debonding as their maximum bending load increased. Full article
(This article belongs to the Special Issue Natural Fibres and their Composites)
►▼ Show Figures

Graphical abstract

Show export options expand_more Show export options expand_less
Select all
Export citation of selected articles as:
 
Displaying articles 1-15
Back to TopTop