Skip Content
You are currently on the new version of our website. Access the old version .

Materials, Volume 12, Issue 8

2019 April-2 - 165 articles

Cover Story: In our search to discover interesting photophysical materials, we have stumbled upon two tetramethylammonium cyanocuprate(I) 3D networks that display optical memory activity. This behavior is demonstrated by the loss of emission intensity over time during laser irradiation of microcrystalline samples. The reduced intensity can be completely recovered simply by heating the samples. We assign the optical memory behavior to a photo-induced electron transfer between cyanocuprate(I) subunits. Where metallophilic based triplet emission is observed, the rate of reduction is dramatically reduced. Our findings are beneficial in the rational design of optical memory active complexes given the difficulty in predicting their behavior. View this paper.
  • Issues are regarded as officially published after their release is announced to the table of contents alert mailing list .
  • You may sign up for email alerts to receive table of contents of newly released issues.
  • PDF is the official format for papers published in both, html and pdf forms. To view the papers in pdf format, click on the "PDF Full-text" link, and use the free Adobe Reader to open them.

Articles (165)

  • Article
  • Open Access
37 Citations
4,482 Views
14 Pages

25 April 2019

A series of composites was prepared from a diglycidyl ether of bisphenol A (DGEBA) with different graphene filler contents to improve their mechanical performance and thermal stability. Graphene oxide (GO) and GO modified with hexamethylene tetraamin...

  • Article
  • Open Access
4 Citations
4,140 Views
11 Pages

25 April 2019

Small concentrations of alloying elements can modify the α - γ phase transition temperature T c of Fe. We study this effect using an atomistic model based on a set of many-body interaction potentials for iron and several...

  • Article
  • Open Access
8 Citations
4,114 Views
10 Pages

25 April 2019

A tetragonal distortion of the long-time known NaTl structure at 298 K was observed in different experimental setups, including Zintl’s original procedure of reducing Tl(I)-iodide by sodium liquid ammonia solutions. The powder diffraction patte...

  • Feature Paper
  • Communication
  • Open Access
12 Citations
4,878 Views
10 Pages

Multifunctional Operation of an Organic Device with Three-Dimensional Architecture

  • Giuseppe Tarabella,
  • Simone Luigi Marasso,
  • Valentina Bertana,
  • Davide Vurro,
  • Pasquale D’Angelo,
  • Salvatore Iannotta and
  • Matteo Cocuzza

25 April 2019

This work aims to show the feasibility of an innovative approach for the manufacturing of organic-based devices with a true three-dimensional and customizable structure that is made possible by plastic templates, fabricated by additive manufacturing...

  • Article
  • Open Access
28 Citations
5,211 Views
14 Pages

Pronounced Impact of p-Type Carriers and Reduction of Bandgap in Semiconducting ZnTe Thin Films by Cu Doping for Intermediate Buffer Layer in Heterojunction Solar Cells

  • Waqar Mahmood,
  • Saif Ullah Awan,
  • Amad Ud Din,
  • Junaid Ali,
  • Muhammad Farooq Nasir,
  • Nazakat Ali,
  • Anwar ul Haq,
  • Muhammad Kamran,
  • Bushra Parveen and
  • Nazar Abbas Shah
  • + 1 author

25 April 2019

Stabilized un-doped Zinc Telluride (ZnTe) thin films were grown on glass substrates under vacuum using a closed space sublimation (CSS) technique. A dilute copper nitrate solution (0.1/100 mL) was prepared for copper doping, known as an ion exchange...

  • Article
  • Open Access
20 Citations
5,211 Views
22 Pages

Diffusive Steel Scrap Melting in Carbon-Saturated Hot Metal—Phenomenological Investigation at the Solid–Liquid Interface

  • Florian Markus Penz,
  • Johannes Schenk,
  • Rainer Ammer,
  • Gerald Klösch,
  • Krzysztof Pastucha and
  • Michael Reischl

25 April 2019

The oxygen steelmaking process in a Linz-Donawitz (LD) converter is responsible for more than 70% of annual crude steel production. Optimization of the process control and numerical simulation of the LD converter are some of the current challenges in...

  • Article
  • Open Access
114 Citations
8,215 Views
14 Pages

Investigating the Mechanical Properties of ZrO2-Impregnated PMMA Nanocomposite for Denture-Based Applications

  • Saleh Zidan,
  • Nikolaos Silikas,
  • Abdulaziz Alhotan,
  • Julfikar Haider and
  • Julian Yates

25 April 2019

Acrylic resin PMMA (poly-methyl methacrylate) is used in the manufacture of denture bases but its mechanical properties can be deficient in this role. This study investigated the mechanical properties (flexural strength, fracture toughness, impact st...

  • Feature Paper
  • Article
  • Open Access
49 Citations
5,091 Views
17 Pages

Nitrogen-Doped Superporous Activated Carbons as Electrocatalysts for the Oxygen Reduction Reaction

  • María José Mostazo-López,
  • David Salinas-Torres,
  • Ramiro Ruiz-Rosas,
  • Emilia Morallón and
  • Diego Cazorla-Amorós

25 April 2019

Nitrogen-containing superporous activated carbons were prepared by chemical polymerization of aniline and nitrogen functionalization by organic routes. The resulting N-doped carbon materials were carbonized at high temperatures (600–800 °C) in inert...

  • Article
  • Open Access
11 Citations
5,662 Views
13 Pages

Microwave Sintering of SiAlON Ceramics with TiN Addition

  • Özgür Sevgi Canarslan,
  • Roberto Rosa,
  • Levent Köroğlu,
  • Erhan Ayas,
  • Alpagut Kara and
  • Paolo Veronesi

25 April 2019

α-β SiAlON/TiN composites with nominal composition of α:β = 25:75 were fabricated by microwave sintering. The effect of titanium nitride addition on the phases, microstructure, microwave absorption ability and mechanical properties (Vickers hardness...

  • Article
  • Open Access
4 Citations
4,077 Views
15 Pages

A Comparative Study of Experimental Configurations in Synchrotron Pair Distribution Function

  • Jesus D. Zea-Garcia,
  • Angeles G. De la Torre,
  • Miguel A. G. Aranda and
  • Ana Cuesta

25 April 2019

The identification and quantification of amorphous components and nanocrystalline phases with very small crystal sizes, smaller than ~3 nm, within samples containing crystalline phases is very challenging. However, this is important as there are seve...

  • Article
  • Open Access
33 Citations
5,129 Views
9 Pages

Defect Chemistry and Na-Ion Diffusion in Na3Fe2(PO4)3 Cathode Material

  • Navaratnarajah Kuganathan and
  • Alexander Chroneos

25 April 2019

In this work, we employ computational modeling techniques to study the defect chemistry, Na ion diffusion paths, and dopant properties in sodium iron phosphate [Na3Fe2(PO4)3] cathode material. The lowest intrinsic defect energy process (0.45 eV/defec...

  • Article
  • Open Access
17 Citations
4,526 Views
15 Pages

New Organic/Inorganic Pigments Based on Azo Dye and Aluminum-Magnesium Hydroxycarbonates with Various Mg/Al Ratios

  • Anna Marzec,
  • Bolesław Szadkowski,
  • Jacek Rogowski,
  • Waldemar Maniukiewicz,
  • Przemysław Rybiński and
  • Mirosława Prochoń

25 April 2019

This study set out to investigate the impact of aluminum-magnesium hydroxycarbonates (LHs) with various Mg/Al ratios on the formation of hybrid pigments. The colorants were also evaluated for their flame-retardant properties. In the first part of the...

  • Article
  • Open Access
15 Citations
6,524 Views
14 Pages

Microstructure and Mechanical Properties of 34CrMo4 Steel for Gas Cylinders Formed by Hot Drawing and Flow Forming

  • Yuebing Li,
  • Wei Fang,
  • Chuanyang Lu,
  • Zengliang Gao,
  • Xiakang Ma,
  • Weiya Jin,
  • Yufeng Ye and
  • Fenghuai Wang

25 April 2019

An integral manufacturing process with hot drawing and cold flow forming was proposed for large-diameter seamless steel gas cylinders. The main purpose of this study was to find out the effects of the manufacturing process on the microstructure and m...

  • Article
  • Open Access
12 Citations
4,127 Views
12 Pages

25 April 2019

(1) The alloy material 20CrMnTiH is widely used in gear manufacturing, but difficult to process, and its quantity (efficiency) and quality (surface quality) are generally negative correlation indicators. As a difficult but realistic problem, it is of...

  • Article
  • Open Access
9 Citations
3,501 Views
6 Pages

25 April 2019

It is hypothesized that there is no statistically significant impact of drilling speed (DS) on the primary stability (PS) of narrow-diameter implants (NDIs) with varying thread designs placed in dense and soft simulated bone. The aim of this in vitro...

  • Article
  • Open Access
208 Citations
15,876 Views
16 Pages

4D Printing Self-Morphing Structures

  • Mahdi Bodaghi,
  • Reza Noroozi,
  • Ali Zolfagharian,
  • Mohamad Fotouhi and
  • Saeed Norouzi

25 April 2019

The main objective of this paper is to introduce complex structures with self-bending/morphing/rolling features fabricated by 4D printing technology, and replicate their thermo-mechanical behaviors using a simple computational tool. Fused deposition...

  • Article
  • Open Access
14 Citations
4,111 Views
16 Pages

In Vivo Evaluation of the Genotoxic Effects of Poly (Butylene adipate-co-terephthalate)/Polypyrrole with Nanohydroxyapatite Scaffolds for Bone Regeneration

  • Conceição de Maria Vaz Elias,
  • Antônio Luiz Martins Maia Filho,
  • Laryssa Roque da Silva,
  • Fabrício Pires de Moura do Amaral,
  • Thomas J. Webster,
  • Fernanda Roberta Marciano and
  • Anderson Oliveira Lobo

24 April 2019

Here, butylene adipate-co-terephthalate/polypyrrole with nanohydroxyapatite (PBAT/PPy/nHAp) scaffolds were fabricated and characterized. The electrospinning process was carried out using 12 kV, a needle of 23 G, an infusion pump set at 0.3 mL/h, and...

  • Article
  • Open Access
12 Citations
3,582 Views
10 Pages

24 April 2019

Two-dimensional arrays of hollow nanotubes made of TiO 2 are a promising platform for sensing, spectroscopy and light harvesting applications. Their straightforward fabrication via electrochemical anodization, growing nanotube pillars of fini...

  • Article
  • Open Access
8 Citations
3,541 Views
11 Pages

24 April 2019

Selective laser melting (SLM) has been used in many fields recently, especially in the aerospace field. Many studies have been done on mechanical properties of the printed parts, but the dimension accuracy of the inner structure received little atten...

  • Article
  • Open Access
20 Citations
5,793 Views
8 Pages

Old Molecule, New Chemistry: Exploring Silicon Phthalocyanines as Emerging N-Type Materials in Organic Electronics

  • Nathan J. Yutronkie,
  • Trevor M. Grant,
  • Owen A. Melville,
  • Benoît H. Lessard and
  • Jaclyn L. Brusso

24 April 2019

Efficient synthesis of silicon phthalocyanines (SiPc) eliminating the strenuous reaction conditions and hazardous reagents required by classical methods is described. Implementation into organic thin-film transistors (OTFTs) affords average electron...

  • Article
  • Open Access
19 Citations
3,759 Views
15 Pages

24 April 2019

In this paper, the interactions between two parallel cracks are investigated experimentally and numerically. Finite element models have been established to obtain the stress intensity factors and stress distributions of the parallel cracks with diffe...

  • Article
  • Open Access
34 Citations
6,243 Views
17 Pages

24 April 2019

Tool steel play a vital role in modern manufacturing industries due to its excellent properties. AISI D3 is a cold work tool steel which possess high strength, more hardenability and good wear resistance properties. It has a wide variety of applicati...

  • Article
  • Open Access
133 Citations
16,148 Views
17 Pages

Non-Precious Electrodes for Practical Alkaline Water Electrolysis

  • Alejandro N. Colli,
  • Hubert H. Girault and
  • Alberto Battistel

24 April 2019

Water electrolysis is a promising approach to hydrogen production from renewable energy sources. Alkaline water electrolyzers allow using non-noble and low-cost materials. An analysis of common assumptions and experimental conditions (low concentrati...

  • Article
  • Open Access
12 Citations
4,061 Views
19 Pages

24 April 2019

Non-Fourier heat behavior is an important issue for film material. The phenomenon is usually observed in some laser induced thermal responses. In this paper, the non-Fourier heat conduction problems with temperature and thermal flux relaxations are i...

  • Article
  • Open Access
19 Citations
4,798 Views
16 Pages

Characterization of Ablated Bone and Muscle for Long-Pulsed Laser Ablation in Dry and Wet Conditions

  • Hervé Nguendon Kenhagho,
  • Sergey Shevchik,
  • Fatemeh Saeidi,
  • Neige Faivre,
  • Bastian Meylan,
  • Georg Rauter,
  • Raphael Guzman,
  • Philippe Cattin,
  • Kilian Wasmer and
  • Azhar Zam

24 April 2019

Smart laser technologies are desired that can accurately cut and characterize tissues, such as bone and muscle, with minimal thermal damage and fast healing. Using a long-pulsed laser with a 0.5–10 ms pulse width at a wavelength of 1.07 µ...

  • Article
  • Open Access
36 Citations
4,494 Views
11 Pages

24 April 2019

In this work, two indazole derivatives, namely 5-aminoindazole (AIA) and 5-nitroindazole (NIA), were investigated as corrosion inhibitors for carbon steel in 1 M HCl solution by experimental and density functional theory (DFT) methods. The electroche...

  • Article
  • Open Access
25 Citations
3,822 Views
14 Pages

24 April 2019

The cementation factor is necessary to determine porosity via the Archie equation, and its range of values has been suggested in many previous studies. However, the cementation factors in the literature are limited to fully saturated conditions, and...

  • Article
  • Open Access
3 Citations
3,901 Views
12 Pages

24 April 2019

Understanding the mechanism of hydrogen embrittlement (HE) of austenitic steels and developing an effective strategy to improve resistance to HE are of great concern but challenging. In this work, first-principles studies were performed to investigat...

  • Article
  • Open Access
37 Citations
5,713 Views
24 Pages

Push-Pull Chromophores Based on the Naphthalene Scaffold: Potential Candidates for Optoelectronic Applications

  • Corentin Pigot,
  • Guillaume Noirbent,
  • Thanh-Tuân Bui,
  • Sébastien Péralta,
  • Didier Gigmes,
  • Malek Nechab and
  • Frédéric Dumur

24 April 2019

A series of ten push-pull chromophores comprising 1H-cyclopenta[b]naphthalene-1,3(2H)-dione as the electron-withdrawing group have been designed, synthesized, and characterized by UV-visible absorption and fluorescence spectroscopy, cyclic voltammetr...

  • Article
  • Open Access
41 Citations
5,503 Views
12 Pages

24 April 2019

The residual stress introduced by laser shock peening (LSP) is one of the most important factors in improving metallic fatigue life. The shock wave pressure has considerable influence on residual stress distribution, which is affected by the distribu...

  • Communication
  • Open Access
17 Citations
5,730 Views
9 Pages

Enhanced Open-Circuit Voltage in Perovskite Solar Cells with Open-Cage [60]Fullerene Derivatives as Electron-Transporting Materials

  • Edison Castro,
  • Albert Artigas,
  • Anna Pla-Quintana,
  • Anna Roglans,
  • Fang Liu,
  • Frank Perez,
  • Agustí Lledó,
  • X.-Y. Zhu and
  • Luis Echegoyen

23 April 2019

The synthesis, characterization, and incorporation of open-cage [60]fullerene derivatives as electron-transporting materials (ETMs) in perovskite solar cells (PSCs) with an inverted planar (p-i-n) structure is reported. Following optical and electroc...

  • Article
  • Open Access
10 Citations
3,494 Views
12 Pages

23 April 2019

Supersonic impact of particles in their solid state with substrate at a low temperature creates a complex bonding mechanism and surface modification in cold spray coating. Here, we report the formation of a layer of 200 to 300 nm intermetallic at the...

  • Article
  • Open Access
5 Citations
3,358 Views
9 Pages

23 April 2019

Ti-Ni-Si-O nanostructures were synthesized on Ti10Ni5Si alloy through an electrochemical anodization in electrolyte solutions containing ammonium fluoride (NH4F). The anodic oxide structures were affected by the electrochemical anodization parameters...

  • Article
  • Open Access
5 Citations
2,835 Views
14 Pages

Facile Preparation of Charcoal Nanomaterial from Fishery Waste with Remarkable Adsorption Ability

  • Yaning Wang,
  • Yarui Zhou,
  • Lu Cai,
  • Jian Guo,
  • Yong Xu,
  • Hailong Zhang,
  • Lili Ji and
  • Wendong Song

23 April 2019

In this study, modified activated fishbone charcoal (MAFC) was successfully prepared to remove emulsified oil from oily wastewater. Various characteristic techniques, including SEM, XRD, FTIR, and BET, were employed to investigate the morphology, tex...

  • Article
  • Open Access
4 Citations
2,682 Views
14 Pages

23 April 2019

A semi-dieless drawing technology has the advantages of producing a large deformation in a single pass and achieving high-precision dimensions of the finished products. However, instabilities can easily occur in a technique with a large amount of def...

  • Article
  • Open Access
3 Citations
3,617 Views
14 Pages

23 April 2019

As a result of the increasing use of glass fiber reinforced plastic (GFRP) composites in engineering fields, the investigation of scale effect on impact performance for this kind of composite is essential for large scale structure design. The effects...

  • Article
  • Open Access
32 Citations
4,984 Views
15 Pages

23 April 2019

With the development of modern medical implants, there are significantly increasing demands for personalized prosthesis. Corrosion-resistance and dense cobalt alloy specimens have been successfully fabricated by laser metal deposition. The relationsh...

  • Feature Paper
  • Article
  • Open Access
82 Citations
11,419 Views
12 Pages

Calcined Oyster Shell Powder as an Expansive Additive in Cement Mortar

  • Joon Ho Seo,
  • Sol Moi Park,
  • Beom Joo Yang and
  • Jeong Gook Jang

23 April 2019

The present study prepared calcined oyster shell powder having chemical composition and crystal structure of calcium oxide and lime, respectively, and investigated the fresh and hardened properties of cement mortar incorporating calcined oyster shell...

  • Article
  • Open Access
13 Citations
5,398 Views
12 Pages

23 April 2019

Glass fiber reinforced polyolefin composite materials have many advantages regarding their performance and have been widely used in many fields. However, there are few reports on the simultaneously bidirectional self-enhancement of glass fiber reinfo...

  • Article
  • Open Access
29 Citations
6,332 Views
14 Pages

Highly Efficient Nanocarbon Coating Layer on the Nanostructured Copper Sulfide-Metal Organic Framework Derived Carbon for Advanced Sodium-Ion Battery Anode

  • Chiwon Kang,
  • Yongwoo Lee,
  • Ilhwan Kim,
  • Seungmin Hyun,
  • Tae Hoon Lee,
  • Soyeong Yun,
  • Won-Sub Yoon,
  • Youngkwang Moon,
  • Jinkee Lee and
  • Hoo-Jeong Lee
  • + 1 author

23 April 2019

High theoretical capacity and low-cost copper sulfide (CuxS)-based anodes have gained great attention for advanced sodium-ion batteries (SIBs). However, their practical application may be hindered due to their unstable cycling performance and problem...

  • Article
  • Open Access
38 Citations
9,353 Views
21 Pages

23 April 2019

The interest in renewable energies obtained from the resources availed in the ocean has increased during the last few years. However, the harsh atmospheric conditions in marine environments is a major drawback in the design of offshore structures. Th...

  • Article
  • Open Access
10 Citations
3,778 Views
10 Pages

23 April 2019

Lignite is an important natural resource with the application potential covering present and future energy systems, including conventional power plants and gasification systems. Lignite is also a valuable precursor for the production of porous materi...

  • Article
  • Open Access
6 Citations
4,658 Views
9 Pages

Structure and Dynamics of Ferroelectric Domains in Polycrystalline Pb(Fe1/2Nb1/2)O3

  • Hana Ursic,
  • Andreja Bencan,
  • Uros Prah,
  • Mirela Dragomir and
  • Barbara Malic

23 April 2019

A complex domain structure with variations in the morphology is observed at ambient temperature in monoclinic Pb(Fe1/2Nb1/2)O3. Using electron microscopy and piezoresponse force microscopy, it is possible to reveal micrometre-sized wedge, lamellar-li...

  • Article
  • Open Access
19 Citations
4,465 Views
15 Pages

23 April 2019

A three-dimensional numerical model is used to simulate heat transfer and fluid flow phenomena in fiber laser + gas metal arc welding (GMAW) hybrid welding of an aluminum alloy, which incorporates three-phase coupling and is able to depict the keyhol...

  • Article
  • Open Access
33 Citations
3,387 Views
24 Pages

23 April 2019

In working processes, mechanical systems are often affected by both internal and external forces, which are the cause of the forced vibrations of the structures. They can be destroyed if the amplitude of vibration reaches a high enough value. One of...

  • Article
  • Open Access
33 Citations
4,820 Views
15 Pages

Use of Basalt Fiber-Reinforced Tailings for Improving the Stability of Tailings Dam

  • Binbin Zheng,
  • Dongming Zhang,
  • Weisha Liu,
  • Yonghao Yang and
  • Han Yang

22 April 2019

As one of the largest artificial geotechnical structures on earth, the tailings dams are classified as one of the high-risk sources in China’s industry. How to improve the stability and safety of tailings dams remains a challenge for mine opera...

  • Article
  • Open Access
32 Citations
3,648 Views
13 Pages

Enamel Surface Remineralization Effect by Fluorinated Graphite and Bioactive Glass-Containing Orthodontic Bonding Resin

  • Hyung-Jin Nam,
  • You-Min Kim,
  • Yong Hoon Kwon,
  • In-Ryoung Kim,
  • Bong-Soo Park,
  • Woo-Sung Son,
  • Seung-Min Lee and
  • Yong-Il Kim

22 April 2019

All orthodontic appliances are potentially cariogenic. The plaque around the orthodontic appliance can make demineralization on tooth surface causing white spot lesion (WSL). The most effective method to prevent WSL is Fluoride appliance and gargling...

  • Article
  • Open Access
13 Citations
4,598 Views
7 Pages

Effect of Micro-Steps on Twinning and Interfacial Segregation in Mg-Ag Alloy

  • Yi Liu,
  • Xuefei Chen,
  • Kang Wei,
  • Lirong Xiao,
  • Bin Chen,
  • Haibo Long,
  • Yandong Yu,
  • Zhaohua Hu and
  • Hao Zhou

22 April 2019

Twinning structures and their interfacial segregation play a key role in strengthening of magnesium alloys. Micro-steps are frequently existed in the incoherent twin boundaries, while the effect of them on interface and interfacial segregation is sti...

  • Article
  • Open Access
65 Citations
4,603 Views
14 Pages

Uniaxial Compression Behavior of Cement Mortar and Its Damage-Constitutive Model Based on Energy Theory

  • Yunliang Tan,
  • Qingheng Gu,
  • Jianguo Ning,
  • Xuesheng Liu,
  • Zhichuang Jia and
  • Dongmei Huang

22 April 2019

The mechanical properties of mortar materials in construction are influenced both by their own proportions and external loads. The trend of the stress–strain curve in cracks compaction stage has great influence on the relationship between the s...

of 4

Get Alerted

Add your email address to receive forthcoming issues of this journal.

XFacebookLinkedIn
Materials - ISSN 1996-1944