Water, Volume 16, Issue 3 (February-1 2024) – 146 articles

Constructed wetlands are a versatile technology for various treatment approaches, especially in emerging countries. The research aims to study and optimize the hybridizing process of a vertical subsurface flow constructed wetland with adsorption technology to provide energy-efficient and sustainable removal of heavy metals and bulk organics before their discharge into water bodies or water reuse for irrigation. This study focuses on the adsorption of selected heavy metals present in sewage from Kanpur, India, a cluster of tanning industries and other relevant industrial polluters, investigating the pollutant adsorption onto activated carbon and zeolites in batch and column tests. The results of the batch tests indicated high zeolite loading rates for lead (91.6 mg/g), chromium (60.8 mg/g) and copper (47.4 mg/g). In the column tests applying different adsorbent combinations and ratios, the average removal rates were as follows: 54.6% for cadmium, 14.1% for chromium, 52.4% for copper, 2.2% for iron, 29.2% for manganese, 26.6% for nickel, 35.2% for lead and 44.6% for zinc. The column tests conducted in preparation for field testing in pilot wetlands showed that shorter retention times and background bulk organic concentrations, as well as high ammonium concentrations, negatively affected heavy metal removal by reducing the adsorption and ion exchange capacity of the adsorbents. Full article

With the continuous advancement of the economy, the issues of resource scarcity and environmental damage are becoming increasingly severe. For example, in terms of water resources, the problems of environmental pollution and ecological imbalance in the water caused by industrial and agricultural wastewater are becoming more serious. In order to reduce water pollution, protect water resources, promote ecological balance, and reduce environmental risks, it is necessary to strengthen water environment management. This study uses the Malmquist DEA model to conduct a study on the green technology innovation efficiency (GTIE) of 24 water environment governance companies from 2019 to 2022. Corporate Research & Development investment and employee compensation are used as the input indicators, while the number of color patents obtained and operating income are employed as the output indicators. The evaluation criteria include pure technical efficiency, comprehensive technical efficiency, scale efficiency, and total factor productivity. The results show that there is significant room for improvement in the GTIE of the listed Chinese water environment governance enterprises, and there are considerable differences among different enterprises. The GTIE is significantly influenced by technological progress, the enterprise size, and the equity ratio. Therefore, water environment management enterprises should enhance their efforts in technological research and development and talent training, optimize resource allocation, improve the efficiency of green technology innovation, and effectively fulfill their social responsibilities. These measures will promote the efficient utilization of ecological water, the restoration of the water environment, and the establishment of a clean ecological environment. Full article

The optimization of the production scheme for enhanced geothermal systems (EGS) in geothermal fields is crucial for enhancing heat production efficiency and prolonging the lifespan of thermal reservoirs. In this study, the 4100–4300 m granite diorite stratum in the Zhacang geothermal field was taken as the target stratum to establish a numerical model of water-heat coupling of three vertical wells. However, relying solely on numerical simulation for optimization is time-consuming and challenging for the determination of the globally optimal production plan. The present study proposes a comprehensive evaluation method for optimizing the performance of EGS power generation based on the integration of particle swarm optimization with backpropagation neural network (PSO-BPNN) and analytic hierarchy process (AHP). Five different PSO-BPNN models were constructed based on the numerical simulation data to predict different EGS power generation performance indexes, including the production temperature, the injection pressure, the total electricity generation, the electric energy efficiency and the levelized cost of electricity. Based on these PSO-BPNN models, the weights of various thermal development evaluation indexes were calculated by AHP to conduct a comprehensive evaluation of the power generation performance of the three vertical wells EGS. The results show that the PSO-BPNN model has good prediction accuracy for EGS prediction of various performance indicators, with a coefficient of determination (R²) exceeding 0.999. The AHP evaluation of all production schemes reveals that the optimal power generation scheme entails a well spacing of 580 m, water injection rate of 56 kg/s, injection temperature of 38 °C and fracture permeability of 2.0 × 10⁻¹⁰ m². Over a span of 30 years, this scheme can provide a total power generation capacity amounting to 1775 GWh, with an associated LCOE value of 0.03837 USD/kWh. This not only provides a reference for the development and optimization of geothermal systems in the Zhacang geothermal field but also provides a new idea for the optimization design of other geothermal projects. Full article

Given the fact that the high frequency of extreme weather events globally, in particular typhoons, has more of an influence on flood forecasting, there is a great need to further understand the impact of typhoon events on design storms. The main objectives of this paper are to examine the magnitude, occurrence, and mechanism of typhoon events in southeast coastal China and their contribution to the design storm study. We take Shanghai, which is a typical metropolitan region in the Yangtze River Delta, China, as an example. The impact of typhoons on the rainfall frequency analysis is quantitatively evaluated using stochastic storm transposition (SST)-based intensity–duration–frequency (IDF) estimates with various temporal and spatial structures under different return periods. The results show that there is significant variability in the storm magnitude within the transposition domain across different durations, highlighting the spatiotemporal heterogeneity over the coastal area. Moreover, the probability of random storm transposition exhibits an uneven distribution. The frequency of typhoon rainfall events within the transposition domain is notably high, and there is considerable variability in the structure of rainfall. Typhoon rainfall amplifies the intensity of design storms, and its contribution increases with return periods. The variability in design storms increases accordingly. Based on the advantages of SST, which retains the spatiotemporal structure of the rainfall in the generated scenarios, the overall framework provides an effective way to examine the impact of diverse characteristics of typhoon rainfall on frequency analysis and facilitate a deeper exploration of the direct impact of various types of extreme storms on the intensity, spatial, and temporal distributions of design storms amidst evolving environmental conditions over this metropolitan region. Full article

The hydrological cycle should be scrutinized and investigated under recent climate change scenarios to ensure global water management and to increase its utilization. Although the FAO proposed the use of the Penman–Monteith (PM) equation worldwide to predict evapotranspiration (ET), which is one of the most crucial components of the hydrological cycle, its complexity and time-consuming nature, have led researchers to examine alternative methods. In this study, the performances of numerous temperature-driven ET methods were examined relative to the PM using daily climatic parameters from central stations in 11 districts of the Kahramanmaras province. Owing to its geographical location and other influencing factors, the city has a degraded Mediterranean climate with varying elevation gradients, while its meteorological patterns (i.e., temperature and precipitation) deviate from those of the main Mediterranean climate. A separate evaluation was performed via ten different statistical metrics, and spatiotemporal ET variability was reported for the districts. This study revealed that factors such as altitude, terrain features, slope, aspect geography, solar radiation, and climatic conditions significantly impact capturing reference values, in addition to temperature. Moreover, an assessment was conducted in the region to evaluate the effect of modified ET formulae on simulations. It can be drawn as a general conclusion that the Hargreaves–Samani and modified Blaney–Criddle techniques can be utilized as alternatives to PM in estimating ET, while the Schendel method exhibited the lowest performance throughout Kahramanmaras. Full article

Floods are probably the most hazardous global natural event as well as the main cause of human losses and economic damage. They are often hard to predict, but their consequences may be reduced by taking the right precautions. In this sense, hydraulic infrastructures, such as dams, are generally the most widely used management elements to significantly mitigate this natural risk. However, others, such as linear ones, mainly ditches and canals, can both in themselves be potentially active risk-generating factors and vectors of flooding risk propagation. The aim of this research is to develop an accurate and detailed technique for assessing the intrinsic risk of these infrastructures due to flood events. This is performed based on two key factors: the proximity to urban areas and the water level reached in the infrastructures. Consequently, this research is developed through a double geomatic and hydraulic component organized into four steps: topological processing, parameter computation, risk calculation, and development of the Risk Colored Snake (RCS) technique. This was successfully applied to the network of irrigation ditches of Almoradí in Alicante (Spain), which is characterized by a high exposure level to flood hazards. RCS is a valuable tool to easily assess the potential risk of each section of the linear hydraulic infrastructures. By means of color-coding RCS, it is simpler for the end user to quickly detect potentially problematic locations in an accurate and detailed manner. Full article

Modified sludge biochar, recognized for its notable economic and environmental benefits, demonstrates potential as an effective catalyst for peroxydisulfate (PDS) activation. Nevertheless, the specific mechanisms underlying its catalytic performance require more comprehensive investigation. In this study, a modified biochar (TSBC) doped with oxygen (O) and nitrogen (N) atoms was synthesized from sewage sludge and tannin extract, which significantly enhanced the activation of PDS for the degradation of sulfamethoxazole (SMX). The TSBC/PDS system demonstrated robust performance for SMX degradation, achieving over 90% efficiency over a wide pH range (3–10). Subsequent quenching experiments demonstrated that TSBC predominantly catalyzed PDS to generate $\mathrm{O}_2^1$, which effectively degraded SMX via a non-radical pathway. The O- and N-containing functional groups in TSBC were identified as the primary catalytic sites. Besides, density functional theory (DFT) calculations revealed that the incorporation of graphitic N significantly improved the adsorption capacity of PDS on the TSBC surface. Furthermore, based on the identification of intermediates and theoretical calculations, SMX was degraded mainly by two different pathways: S-N cleavage and $\mathrm{O}_2^1$ oxidation. This study offers a foundational framework for the targeted modification of sludge biochar, thereby expanding its applications. Full article

The world’s water infrastructures suffer from inefficiencies, such as high energy consumption and water losses due to inadequate management practices and feeble pressure regulation, leading to frequent water and energy losses. This strains vital water and energy resources, especially in the face of the worsening challenges of climate change and population growth. A novel method is presented that integrates micro-hydropower plants, with pumps as turbines (PATs), in the water network in the city of Funchal. Sensitivity analyses evaluated the microgrid’s response to variations in the cost of energy components, showing favorable outcomes with positive net present value (NPV). PV solar and micro-wind turbines installed exclusively at the selected PRV sites within the Funchal hydro grid generate a combined 153 and 55 MWh/year, respectively, supplementing the 406 MWh/year generated by PATs. It should be noted that PATs consistently have the lowest cost of electricity (LCOE), confirming their economic viability and efficiency across different scenarios, even after accounting for reductions in alternative energy sources and grid infrastructure costs. Full article

More water utilities are adopting aquifer storage and recovery (ASR) to balance long-term water supply and demand. Due to large implementation and operation costs, ASR projects need to be optimized, particularly for energy use, which is a major operating expense. This study examines the relationships among energy use, recharge, and recovery at two ASR projects in the western United States. The major finding is an economy of scale for recovery processes, but not for gravity-fed recharge processes. The economy of scale found is as follows: the energy intensity recovered decreases with volume. This suggests it is more energy-efficient to recover large volumes of water in one interval instead of recovering smaller volumes at more frequent intervals. The H2Oaks recovery process experienced a 78% decrease in energy intensity from 0 to 50,000 m³ recovered, while the Sand Hollow site experienced a 43% decrease in energy intensity from 0 to 50,000 m³ recovered. Statistical analyses of the recovery process showed p values lower than 0.0001, R² values between 0.43 and 0.57, and a RMSE value between 0.55 and 2.1, indicating the presence of a moderate correlation between energy and volume. This economy of scale has been observed in multiple instances in water and wastewater treatment. This finding not only has applications to ASR but also to all recovery or recharge wells, whether or not they are paired with each other. Furthermore, this study confirms the need for more reliable and accessible energy data to fully understand the implications of the energy–water nexus. Full article

Utah Lake is one of the largest freshwater bodies in the West and a valuable resource for agricultural and recreational activities in the region. However, it has suffered elevated trace metal and nutrient levels since the pioneer settlement in 1847. The objectives of this project were as follows: (1) investigate the temporal and spatial variations of trace metal and nutrient concentrations in Utah Lake and its tributaries; (2) model trace metal and nutrient concentrations across the lake using GIS spatial analysis techniques. We collected floc layer sediment samples quarterly as well as monthly water samples for trace metal and nutrient analyses at designated sites. GIS spatial analysis techniques were used to model the trace metal and nutrient concentrations in the lake. Elevated trace metal concentrations in river and lake water samples have been detected, especially in the month of June. The GIS modeling revealed that the highest trace metal and nutrient concentrations were located at the deepest part of the lake and near the Spanish Fork River inlet, respectively. Moreover, the results indicate that Utah Lake is not well mixed horizontally but well mixed vertically. Our findings can help state agencies address issues in water quality and management related to human–environment interactions. Full article

As extreme climate events become more common with global warming, groundwater is increasingly vital for combating long-term drought and ensuring socio-economic and ecological stability. Currently, the mechanism of meteorological drought propagation to groundwater drought is still not fully understood. This study focuses on the North China Plain (NCP), utilizing statistical theories, spatiotemporal kriging interpolation, and the Mann–Kendall trend test to examine the spatial and temporal distribution characteristics of groundwater from 2005 to 2021. Based on drought theory, the characteristics and propagation process of drought are further quantified. Key findings reveal the following: (1) Shallow groundwater depths in the NCP follow a zonal pattern from the western mountains to the eastern plains and coastal areas. Over two-thirds of this region showed an increase in groundwater depth at a rate of 0–0.05 m/a; (2) Groundwater drought frequency typically ranges from 3 to 6 times, with an average duration of 10 to 30 months and average severity between 10 and 35; (3) Delayed effects last between 0 to 60 months, with attenuation effects varying from 0 to 3 and prolonged effects extending from 0 to 16. Additionally, delayed effects intensify with increasing time scales, while prolonged effects weaken. Notably, both delayed and prolonged effects in the north of the NCP are more pronounced than in the south of the region. This study quantifies the process by which meteorological drought propagates to groundwater drought, offering a new perspective for understanding the interaction between groundwater and meteorological drought. It holds significant scientific importance for monitoring drought and managing water resources in the context of global climate change. Full article

Acid in situ leaching (ISL) is a common approach to the recovery of uranium in the subsurface. In acid ISL, there are numerous of chemical reactions among the injected sulfuric acid, groundwater, and porous media containing ore layers. A substantial amount of radioactive elements including U, Ra, Rn, as well as conventional elements like K, Na, and Ca, and trace elements such as As, Cd, and Pb, are released into the groundwater. Thus, in acid ISL, understanding the transport and reactions of these substances and managing pollution control is crucial. In this study, a three-dimensional reactive transport modeling (RTM) using TOUGHREACT was built to investigate the dynamic reactive migration process of UO₂²⁺, H⁺, and SO₄²⁻ at a typical uranium mine of Bayan-Uul. The model considering the partial penetration through wellbore in confined aquifer and complex chemical reactions among main minerals like uranium, K-feldspar, calcite, dolomite, anhydrite, gypsum, iron minerals, clay minerals, and other secondary minerals. The results show that after mining for one year, from the injection well to the extraction well, the spatial distribution of uranium volume fraction does not consistently increase or decrease, but it decreases initially and then increases. After mining for one year, the concentration front of UO₂²⁺ is about 20 m outside the mining area, the high concentration zone is mainly inside the mining area. The concentration front of H⁺ is no more than 50 m. SO₄²⁻ is the index with the highest concentration among the three indexes, the concentration front of SO₄²⁻ is no more than 100 m. The concentration breakthrough curve of the observation well 10 m from the mining area indicates that the concentrations of the three indicators began to significantly rise approximately after mining 0.05 years, reached the maximum value after mining 0.08 to 0.1 years, and then stabilized. The parameter sensitivity of absolute permeability and specific surface area of minerals shows that the concentration of H⁺ and SO₄²⁻ is positively correlated with absolute permeability. The concentration of H⁺ is negatively correlated with the specific surface area of calcite, anhydrite, K-feldspar, gypsum, hematite, and dolomite. The concentration of SO₄²⁻ is positively correlated with the specific surface area of K-feldspar and Hematite, and negatively correlated with the specific surface area of calcite, anhydrite, gypsum, and dolomite. The influence analysis of pumping ratio and non-uniform injection ratio shows that the non-uniform injection scheme has a more significant impact on pollution control. The water table, streamline, capture envelope, and the concentration breakthrough curve of five schemes with different pumping ratios and non-uniform injection ratio were obtained. The water table characteristics of five schemes shown that increase in the pumping ratio and the non-uniform injection ratio, the water table convex near the outer injection well is weakened and the groundwater depression cone near the pumping well is strengthened. This characteristic of water table exerts a notable retarding influence on the migration of pollutants from the mining area to the outside. For the scheme with a pumping ratio is 0 (the total pumping flow rate is equal to the total injection flow rate) and a non-uniform injection ratio is 0 (the flow rate of inner injection well Q1,Q2,Q3 is equal to the flow rate of outer injection well Q4,Q5,Q6), the streamline characteristics shown that a segment of the streamline of is diverging from inner region to the outer region. For other schemes, the streamline exhibits a convergent feature. It is indicated that by increasing the pumping ratio and non-uniform injection ratio, a closure flow field can be established, confining the groundwater pollutants resulting from mining within the capture envelope. Hence, the best scheme for preventing pollution migration is the scheme with a pumping ratio is 0 (the total pumping flow rate is equal to the total injection flow rate) and a non-uniform injection ratio is 0.1 (the flow rate of inner injection well Q₁,Q₂,Q₃ is 10% more than the flow rate of outer injection well Q₄,Q₅,Q₆). In this scheme, the optimal stable concentration of UO₂²⁺, H⁺, and SO₄²⁻ at the observation well obtained by RTM is lower than other schemes, and the values are 0.00316 mol/kg, 2.792 (pH), and 0.0952 mol/kg. The inner well injection rate is 194.09 m³/d, the outer well injection rate is 158.89 m³/d, and the pumping rate is 264.00 m³/d. Numerical simulation analysis suggests that a scheme with a larger non-uniform injection ratio is more conducive to the formation of a strong hydraulic capture zone, thereby controlling the migration of pollutants in the acid ISL. A reasonable suggestion is to adopt non-uniform injection mining mode in acid ISL. Full article

Microplastics (MPs) are abundant in soil and the subsurface environment. They can co-transport with pathogens or act as vectors for pathogens, potentially causing severe ecological harm. The interaction of MPs with pathogens is an important topic. To describe the origins and features of MPs in the subsurface environment, we evaluated relevant studies conducted in the laboratory and field groundwater habitats. We explore the interactions between pathogens and microplastics from three perspectives including the respective physicochemical properties of microplastics and pathogens, external environmental factors, and the binding between microplastics and pathogens. The effects of some interaction mechanisms and environmental factors on their co-transport are discussed. The key factors affecting their interaction are the particle size, specific surface area, shape and functional groups of MPs, the zeta potential and auxiliary metabolic genes of pathogens, and the hydrophobicity of both. Environmental factors indirectly affect MPs and the interaction and co-transport process of pathogens by changing their surface properties. These findings advance our knowledge of the ecological behavior of MPs–pathogens and the associated potential health hazards. Full article

Under climate change, the frequency of drought-flood abrupt alternation (DFAA) events is increasing in Southeast China. However, there is limited research on the evolution characteristics of DFAA in this region. This study evaluated the effectiveness of the drought and flood indexes including SPI (Standardized Precipitation Index), SPEI (Standardized Precipitation Evapotranspiration Index), and SWAP (Standardized Weighted Average Precipitation Index) in identifying DFAA events under varying days of antecedent precipitation. Additionally, the evolution characteristics of DFAA events in Fujian Province from 1961 to 2021 were explored. The results indicate that (1) SPI-12d had the advantages of high effectiveness, optimal generalization accuracy, and strong generalization ability of identification results, and it can be used as the optimal identification index of DFAA events in Southeast China. (2) There was an overall increase in DFAA events at a rate of 1.8 events/10a. The frequency of DFAA events showed a gradual increase from the northwest to the southeast. (3) DTF events were characterized by moderate drought to flood, particularly in February, July, and August, while FTD events were characterized by light/moderate flood to drought, with more events occurring from June to October. (4) DTF event intensity increased in the northern and western regions from 1961 to 2021. For FTD events, the intensity notably increased in the western region from 1961 to 2001, while a significant increase occurred in all regions except the central region from 2001 to 2021. These findings emphasize the need for precautionary measures to address the increasing frequency and severity of DFAA events in Southeast China. Full article

In South China, due to climatic factors, highly weathered granite is distributed across a large area and easily disintegrates after encountering water, causing many geological disasters and other problems. To determine the disintegration mechanism of highly weathered granite in South China, disintegration tests were carried out on highly weathered granite in the Fuzhou area under different immersion durations, cycle times, and flow rates, with the help of a self-designed disintegration test device. Moreover, the disintegration mechanism of the highly weathered granite was revealed using nuclear magnetic resonance (NMR) technology. The results demonstrated an increase in the cumulative relative disintegration with prolonged immersion time and the number of dry-wet cycles. Beyond a certain flow rate, the cumulative relative disintegration amount stabilized. There was a strong correlation between the steady disintegration rate and immersion time (or dry-wet cycles). The disintegration process of the highly weathered granite was divided into three stages: rapid, moderate, and stable disintegration. Notably, disintegration primarily occurred around the large pores. This study revealed that the variation in the immersion time (or wet-dry-scouring cycles) was fundamentally linked to changes in the relative volume of the large pores in the rock samples. These findings provide valuable insights for predicting and mitigating surface disasters on highly weathered granite slopes. Full article

In addition to changes in the amount of rain, changes in land use upstream are considered a factor that directly affects the maximum runoff flow in a basin, especially in areas that have experienced floods and flash floods. This research article presents the application of the SWAT model to assess runoff in areas that have experienced flash floods, in order to analyze the proportion of land use change to the maximum runoff. Study areas that experienced flash floods were in three basins in Thailand (Lam Saphung Basin, Phrom River Basin, and Chern River Basin Part 1, which is a sub-basin of the Nam Chi River Basin). This study analyzed two main factors that influenced runoff in the river basin by considering two simulation situations: (1) changes in land use affecting runoff assessed by considering land use maps in 2006, 2008, 2010, 2015, 2017, 2019, and 2021 when using rainfall data only in the year 2021 for all cases and (2) changes in the amount of rainfall influencing runoff by considering the rainfall records in 2006, 2008, 2010, 2015, 2017, 2019, and 2021 when using the land use data only in the year 2021 for all cases. The results of the study found that the SWAT model can be effectively applied to estimate annual runoff in areas that have experienced flash floods under eight parameters with R² values of 0.74, 0.82, and 0.74 for the Lam Saphung River Basin, Phrom River Basin, and Chern River Basin Part 1, respectively. In addition, it was found that the proportion of land use changes that involved changes from forested areas to residential areas was the greatest from 2008 to 2010 in the Phrom River Basin and Chern River Basin Part 1. This resulted in an increase in the maximum runoff amounts of 77.78% and 46.87%, respectively. When land use was constant, it was found that the rainfall in 2010, which was the highest, also had the greatest impact on the runoff in all three areas. Full article

The mountainous areas of Southwest China have the characteristics of valley deep-cutting, a large topographic gradient, complex geological structures, etc. With the development of infrastructure construction in the area, the construction of bridges across valleys has gradually increased, and the phenomenon of slope failure occurs more and more frequently. As the weak interlayer, the fault fracture zones have a significant influence on the geological structure and stability of slopes, while the complexity of the mechanism of the deformation and failure of slopes increases with the combination of the development of the fracture zones and toppling deformation. This paper took the toppling bank slope of bridge foundations developed with fault fracture zones in Lancang River as the research object. Through an on-site field survey and geological survey technologies, it identified the distribution range of the fracture zones on the bank slope and determined the characteristics of the rock mass in the fracture zones. A stability evaluation model for the bank slope of the bridge foundations was established using the limit equilibrium method and discrete element method. Based on the two-dimensional limit equilibrium analysis, the potential failure modes of the bank slope were explored, and the stability of the bank slope under bridge loads was calculated. Through the three-dimensional geological model of the bank slope, including the fracture zones and toppling bodies, the three-dimensional discrete element numerical simulation method was adopted to simulate and calculate the deformation and failure process of the bank slope under different bridge loads and working conditions. According to the calculation results, the influence of bridge loads and reservoir water on the stability of the bank slope was analyzed from the perspectives of displacement, plastic zone, stability coefficient, and other factors. The formation process of the plastic zone and the development of the sliding surface were revealed, the incentive mechanism of bridge loads and reservoir water on the deformation and failure of the bank slope was analyzed, and the influence of fault fracture zones on the stability of the bank slope and the development of toppling deformation was determined. The results indicate that the fault fracture zones are important geological structures that affect the deformation and failure of the bank slope as a weak interlayer. Under the influence of bridge loads and reservoir water, the stability of the bank slope is affected by the quality of the rock mass and the development of the fault fracture zones, resulting in the unmet need for safety requirements and maybe leading to instability. Based on the calculation results of the stability evaluation prediction model for the bridge foundation bank slope and the engineering geological conditions, the bridge scheme has been selected. Full article

Global croplands, pastures, and human settlements have expanded in recent decades. This is accompanied by large increases in energy, water, and fertilizer consumption, along with considerable losses of biodiversity. In sub-Saharan Africa, policies are implemented without critical consideration; e.g., agricultural expansions impair ecosystem services. We studied land use/cover and the associated rate of change for four time epochs, i.e., 1991, 2001, 2011, and 2021. This employed remote sensing and GIS techniques for analysis, while future projections were modeled using cellular automata and the Markov chain. The kappa coefficient statistics were used to assess the accuracy of the final classified image, while reference images for accuracy assessment were developed based on ground truthing. Overall change between 1991 and 2021 showed that major percentage losses were experienced by water, forest, woodland, and wetland, which decreased by 8222 Ha (44.11%), 426,161 Ha (35.72%), 399,584 Ha (35.01%), and 105,186 Ha (34.82%), respectively. On the other hand, a percentage increase during the same period was experienced in cultivated land, built-up areas, and grasslands, which increased by 659,346 Ha (205.28%), 11,894 Ha (159.93%), and 33,547 Ha (98.47%), respectively. However, this expansion of thirsty sectors has not reversed the increasing amount of water discharged out of the Kilombero River catchment. We recommend the promotion of agroforests along with participatory law enforcement and capacity building of local communities’ institutions. Full article

China has a vast territory and a long history of inland navigation. This paper is based on the Shaying River Shenqiu hub project, and a normal physical model with a geometric scale of 65 was established to simulate the characteristics of water and sediment in the entrance area of the project. By setting different working conditions and measuring and analyzing the velocity flow pattern of the wharf area, planning suggestions for the artificial channel with straight cut-off can be given. Simultaneously, the study simulates the natural sediment deposition state in typical years, observing changes in terrain and evaluating their impact on navigation, thereby validating the rationality of scouring and desilting processes. The research findings indicate that in the reconstructed river wharf’s entrance area, the flow velocity is low, and the flow pattern is stable, ensuring that the transverse flow velocities along the recommended route meet the requirements for vessel navigation. Post-scouring from the regulating gate discharge, downstream deposition decreases, with a sediment flushing efficiency reaching 68.5%. Under the specified conditions, the thickness of sediment deposition after scouring does not negatively affect the water level for ships entering or departing the wharf. The results of this study may offer valuable reference insights for the planning of artificial rivers in similar terrains. Full article

The Volga River is the largest river in Europe in terms of basin area (1.36 mio. km²), length (3531 km), and water content (annual flow 254 km³). We conduct long-term water quality studies in the Volga headwaters: in the Upper Volga Lakes, the free-flowing section, as well as in the Ivankovskoye and Uglich Reservoirs. At the source of the river, the water is very soft, slightly mineralized, characterized by high color indicators (up to 400 degrees Pt-Co scale) and permanganate oxidation (60.3–72 mgO/L). In the Upper Volga Lakes, water mineralization increases to 110 mg/L, and the color of the water decreases significantly. In the Ivankovo Reservoir, higher concentrations of manganese and BOD₅ are noted than in the Volga above Tver. Based on total phosphorus concentrations, the Upper Volga Reservoir (Lake Volgo) and the free-flowing section of the Upper Volga (from Selizharovo to Tver) belong to the “mesotrophic” class, and the Ivankovskoye Reservoir belongs to the “eutrophic” class. We characterize the Volga headwaters based on physico-chemical parameters “balanced” and discuss the relevance of “natural pollution”. Especially the free-flowing section comprises an important reference section for lowland rivers; thus, long-term monitoring of abiotic and biotic aspects is an important issue. Full article

This study combined the characteristics of rock mass structure, channel characteristics of main and tributary rivers, and flow conditions in the Three Gorges Reservoir area of the Yangtze River and designed and constructed a three-dimensional granular rock shallow-water landslide surge model test system under dynamic water flow conditions. The main influencing variables, including the volume of the landslide body, the inclination of the sliding surface, the water depth of the channel, and the flow velocity, were determined. A four-factor four-level orthogonal test design and a single-factor test design were combined to determine 28 sets of test conditions. Based on existing field surveys and physical model test simulation results, the motion process of the landslide body was divided into four stages: starting, accelerating, slowly accelerating or decelerating, and rapidly decelerating. The variations in the motion and velocity of the landslide body over time were determined by analyzing the image sequence extracted using a high-speed camera. The morphological characteristics of the landslide accumulation body were analyzed, and the submerged rate of the landslide body was statistically calculated. The relationship between the maximum bottom width of the landslide underwater accumulation body and the volume of the underwater accumulation body was established. Full article

This paper analyzes the spatiotemporal changes and patterns of a regional water environment based on the hydrological and water quality monitoring times and the geographical locations of the monitoring sections in the research area, the plain of Cixi, eastern China. Based on the calculation of runoff generation and concentration in the coastal plain river network and based on the characteristics and impact evaluation of the regional water pollution, the migration and diffusion mechanisms of surface water pollutants were studied for different sources and characteristics of pollutants entering the river in different river sections. The analytic results show that the water environment and water resource security of the coastal plain mainly cause the problem of eutrophication in the water bodies, and the input of nitrogen and phosphorus from land sources is the main cause of eutrophication in the water bodies, mainly including the production and discharge of domestic sewage, nutrient loss in aquaculture water bodies, affecting agricultural activities, etc. The evaluation also demonstrates that with the development of coastal zones and the rapid development of coastal towns, as the population in coastal plain areas continues to increase, industrial development and population growth are the main driving factors for water quality changes. Full article

The calibration and validation of hydrological model simulation performance and model applicability evaluation in Gansu Province is the foundation of the application of the flash flood early warning and forecasting platform in Gansu Province. It is difficult to perform the simulation for Gansu Province due to the fact that it covers a wide range, from north to south, with multiple climate types and diverse landforms. The China Flash Flood Hydrological Model (CNFF) was implemented in this study. A total of 11 model clusters and 289 distributed hydrological models were divided based on hydrology, climate, and land-use factors, among others. A spatiotemporally mixed runoff method and the Event-Specific Geomorphological Instantaneous Unit Hydrograph (GIUH) were applied based on large-scale fast parallel computation. To improve model calibration and validation efficiency, the RSA method (Regionalized Sensitivity Analysis) was used for CNFF model parameter sensitivity analysis, which could reduce the number of model parameters that need to be adjusted during the calibration period. Based on the model sensitivity analysis results, the CNFF was established in Gansu Province to simulate flood events in eight representative watersheds. The average NSE, RE_Q, and E_T were 0.76 and 0.73, 9.1% and 12.6%, and 1.2 h and 1.7 h, respectively, in the calibration and validation period. In general, the CNFF model shows a good performance in multiple temporal and spatial scales, thus providing a scientific basis for flash flood early warning and analysis in Gansu Province. Full article

The article considers a mathematical model of the hydrolithospheric process taking into account the skin effect. A methodology for using the results of groundwater inflow testing to determine the parameters of approximating models that take into account skin effects is presented. In addition, the problems of modeling hydrodynamic processes taking into account random factors are considered. A statistical analysis of well monitoring data was carried out and an algorithm for studying processes was developed. Using the obtained approximating models, a procedure for solving the problem of selecting the optimal number of production wells has been developed. Based on the results of the groundwater inflow testing, the prospects for the development and use of new aquifers can be determined. Full article

Chlorine decay over time and distance travelled poses challenges in maintaining consistent chlorine levels from treatment plants to demand nodes in water distribution networks (WDNs). Many studies have focused on optimizing chlorine booster systems and addressing dosage and location. This study proposes a chlorine injection optimization model for maintaining spatial and temporal chlorine residuals within an acceptable range. First, the approach involves identifying potential pathways from the source to demand nodes using a breadth-first search (BFS) algorithm. Subsequently, the required chlorine injection to maintain a 0.2 mg/L residual chlorine level at demand nodes is estimated based on water age. Finally, a single-objective genetic algorithm optimizes the chlorine injection schedule at the source. The results demonstrated that chlorine estimation based on water age exhibited promising results with an average error below 10%. In addition, the four-interval injection scheme performed well in adapting to changing demand patterns, making the method robust to varying demand patterns. Moreover, the model could accommodate fluctuating water temperature conditions according to operating seasons. This study provides valuable insights into effectively managing chlorine levels and operations of WDNs, and paves the way for using water age for chlorine estimation. Full article

Microalgae offer a promising solution for efficiently treating high-nitrogen wastewater and recovering valuable nutrients. To optimize microalgae growth and nutrient assimilation, case-dependent studies are essential to demonstrate the process’s potential. This study aimed to evaluate the treatment capacity of high-nitrogen anaerobic digestion effluent as a nutrient source for a C. sorokiniana microalgal culture in a tubular photobioreactor. The study had two primary objectives: to assess how the concentration and composition of the digestate influence microalgae growth, and to identify the preferred nitrogen forms assimilated by the microalgae during long-term, continuous operation. A 20 L tubular airlift bioreactor was constructed and used in batch mode; various digestate concentrations were examined with ammonia nitrogen levels reaching to 160 mg/L. These experiments revealed a biomass growth rate of up to 130 mg/L/d and an ammonia nitrogen assimilation rate ranging from 8.3 to 12.5 mg/L/d. The presence of phosphorous proved essential for microalgae growth, and the growth entered a stationary phase when the initial phosphorous was fully assimilated. A nitrogen-to-phosphorous (N/P) ratio of 10 supported efficient species growth. While ammonia was the preferred nitrogen form for microalgae, they could also utilize alternative forms such as organic and nitrate nitrogen, depending on the specific digestate properties. The results from the continuous photobioreactor operation confirmed the findings from the batch mode, especially regarding the initial nitrogen and phosphorous content. An important condition for nearly complete ammonia removal was the influent dilution rate, to balance the nitrogen assimilation rate. Moreover, treated effluent was employed as dilution medium, contributing to a more environmentally sustainable water management approach for the entire process, at no cost to the culture growth rate. Full article

This study evaluates the suitability of treated wastewater (TWW: secondary effluent and membrane effluent) for crop irrigation and the resultant impact on crop growth and soil physicochemical characteristics. Carrot seeds (Daucus carota subsp. sativus) were grown on loam soil and irrigated with tap water (Tap), secondary effluent (SE), and membrane effluent (ME) until maturity. Bacteriological analyses showed four log counts of E. coli and thermotolerant coliforms for secondary effluent, making it unsafe for the irrigation of carrots. Tap water and membrane effluent fulfilled the microbial limit for water reuse and were suitable for irrigation. The sodium absorption ratio, Kelly index, and magnesium hazard assessments indicated that all three irrigation water streams were suitable for irrigation. The average mass of carrot fruits for Tap, SE, and ME was 2.14 g, 3.96 g, and 3.03 g, respectively. A similar trend was observed for the dry matter composition: Tap had 15.9%, SE had 18.3%, and ME had 16.6%. The soil pH increased from 7.08 to 7.26, 7.39, and 7.33 for tap water-, secondary effluent-, and membrane effluent-irrigated soils, respectively. Nitrate-nitrogen and potassium levels increased in the TWW-irrigated soil, while that of the tap water-irrigated soil decreased. Sodium levels in the TWW-irrigated soil increased significantly but did not induce soil sodicity. The application of the TWW enhanced the growth of the carrot plants and increased the soil nutrient levels. Hence, using TWW in agricultural irrigation could promote food production and also limit the overdependency on freshwater resources. However, TWW should be disinfected by using UV disinfection and ozonation to reduce the risk of microbial contamination. Such disinfection methods may not lead to the formation of toxic byproducts, and therefore secondary pollution to crops is not anticipated. Full article

The increasing share of renewables in electricity grids comes with a challenge of energy surpluses and deficits, which needs be handled by demand side management (DSM) and storage options. Within this approach, wastewater treatment plants (WWTPs), with flexible energy consumption and production processes and storage units, can contribute to stabilizing the grids and integrating more renewables. In this study, the operation of a real WWTP was optimized by mixed integer linear programming (MILP) to minimize its indirect carbon dioxide (CO₂) emissions. The operation of the WWTP was shown to be flexible in following the CO₂ emission factor of the electricity grid, which was possible with the utilization of the WWTP’s storage units and flexible co-substrate feeding. As a result, by changing only the operational behavior of the WWTP, its indirect CO₂ emissions decreased by 4.8% due to the higher share of renewables in the electricity grid. The CO₂ emissions were shown to decrease further up to 6.9% by adding virtual storage units. Full article

Green roofs (GRs) have been researched for decades, yet their implementation remains constrained due to several reasons, including their limited appeal to policymakers and the public. Biochar, a carbon-rich material, has been recently introduced as an amendment to GR substrate to enhance the performance of GRs through reduced runoff volume, improved runoff quality, and increased soil fertility. This paper aims to investigate the impact of biochar amendment on the hydrological performance of newly established GRs. Six 1 m × 1 m GR test beds were constructed, comprising of five biochar-amended GR test beds, and one conventional test bed (without any biochar in its substrate). The water retention capacity and runoff outflow delay of the six test beds were studied with the application of artificial rainfall using a nozzle-based simulator. Biochar was found to increase the water retention capacity and effectively delay runoff outflow in the biochar-amended GRs. After nine artificial rainfall events of 110.7 mm rainfall in total, 39.7 to 58.9 L of runoff was retained by the biochar-amended GRs as compared to 37.9 L of runoff retained by the conventional GR. Additionally, the test bed without biochar quickly started releasing runoff after 300 to 750 s, whereas test beds with fine biochar particles could delay runoff outflow by 700 to 1100 s. The performance of the non-biochar and biochar-amended test beds varies according to the values of biochar-related variables such as biochar particle sizes, amendment rates, and application methods. The observational data illustrated that the GR test bed with medium biochar particles applied to the bottom layer of the GR substrate was the optimal biochar-GR design. This selection was determined by the combined performance of high retention rates, long runoff outflow delays, and few other factors, such as lesser loss of biochar caused by wind and/or water. Full article