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Keywords = knitted composite

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20 pages, 20993 KiB  
Article
Experimental Structural Template on Tensegrity and Textile Architecture Integrating Physical and Digital Approaches
by Zhiyuan Zhang, Salvatore Viscuso, Alessandra Zanelli and Jinghan Chen
Materials 2025, 18(8), 1721; https://doi.org/10.3390/ma18081721 - 9 Apr 2025
Viewed by 288
Abstract
The construction industry is a major contributor to global carbon emissions, driving the need for sustainable solutions. Ultra-lightweight structures have emerged as an effective approach to reducing material usage and energy consumption. This study explores the potential of ultra-lightweight architectural systems through a [...] Read more.
The construction industry is a major contributor to global carbon emissions, driving the need for sustainable solutions. Ultra-lightweight structures have emerged as an effective approach to reducing material usage and energy consumption. This study explores the potential of ultra-lightweight architectural systems through a learning-by-doing methodology, integrating innovative composite materials, PolRe, and knitting techniques to enhance tensegrity structures for sustainable, deployable, and efficient structural designs. Combining physical modeling, inspired by Frei Otto and Heinz Isler, with digital simulations using Kangaroo 2 and Python, this research employs form-finding and finite element analysis to validate structural performance. A 1:5 scale prototype was constructed using a manual knitting machine adapted from traditional knitting techniques. The integration of elastic meshes and rigid joints produced modular tensegrity systems that balance tension and compression, creating reversible, deployable, and material-efficient solutions. This study bridges conceptual aesthetics with structural efficiency, providing a template for sustainable, ultra-lightweight, textile-based structures. Full article
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23 pages, 6802 KiB  
Article
Thermal Comfort Properties of Biodegradable Hemp and Polylactide Fiber Knitted Fabrics
by Ingrida Padleckienė, Laimutė Stygienė, Sigitas Krauledas, Aušra Abraitienė and Audronė Sankauskaitė
Polymers 2025, 17(7), 903; https://doi.org/10.3390/polym17070903 - 27 Mar 2025
Viewed by 481
Abstract
According to the global strategy of Green course, the production of sustainable textiles using different biodegradable fibres has immense potential for the development of sustainable products. Using one of the most sustainable biobased pure hemp and polylactide fibers yarns, four new biodegradable three-layer [...] Read more.
According to the global strategy of Green course, the production of sustainable textiles using different biodegradable fibres has immense potential for the development of sustainable products. Using one of the most sustainable biobased pure hemp and polylactide fibers yarns, four new biodegradable three-layer weft knitted fabrics with good thermal comfort properties were developed. The inner layer (worn next to the skin) and the middle layer of the knits were formed of hydrophobic polylactide fibers, the outer layer of different amounts (36–55%) of hydrophilic natural hemp fibers. Biodegradable polylactide fiber yarns were used as a replacement for conventional petroleum-based synthetic fibers. Natural hemp fibers are one of the most sustainable fibers derived directly from Cannabis sativa L. plants. The properties of the knitted fabrics were analysed and compared under thermoregulatory-moisture management, thermal resistance, air and water vapour permeability-properties. The results showed that all newly developed knits are ascribed to ‘moisture management’ fabrics according to the summary grading of all indices of moisture management parameters. In addition, it was found that the highest overall moisture management capability is related to the quantity of natural hemp fiber composition in different knitting structures. Based on the overall moisture management capacity (OMMC) index and thermal resistance values of developed knitted fabrics, the performance levels for these materials contacting the skin and intended for the intermediate layer were determined. Full article
(This article belongs to the Section Biobased and Biodegradable Polymers)
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17 pages, 29728 KiB  
Article
Development and Performance of Negative Ion Functional Blended Yarns and Double-Sided Knitted Fabrics Based on ZnO/TM/PET Fiber
by Yingzi Zhang, Mengxin Zhang, Jishu Zhang, Jianbing Wu and Jiajia Peng
Polymers 2025, 17(7), 905; https://doi.org/10.3390/polym17070905 - 27 Mar 2025
Viewed by 388
Abstract
Zinc oxide-modified tourmaline-based negative ion polyester fiber (ZnO/TM/PET), as a new functional fiber with excellent negative ion emission characteristics, is of great significance to human health, and its industrial application needs to be expanded and promoted. In this paper, using zinc oxide, tourmaline, [...] Read more.
Zinc oxide-modified tourmaline-based negative ion polyester fiber (ZnO/TM/PET), as a new functional fiber with excellent negative ion emission characteristics, is of great significance to human health, and its industrial application needs to be expanded and promoted. In this paper, using zinc oxide, tourmaline, and polyethylene terephthalate as the main raw materials, ZnO/TM/PET negative ion functional fiber with 5% ZnO/TM composites was prepared. Then, it was blended with cotton fiber and interknitted with wool yarn and spandex yarn, from which we developed five kinds of negative ion polyester/cotton-blended yarn and four different kinds of knitted double-sided fabric using different equipment and process parameters. The micromorphology of the fiber samples, the basic properties of the blended yarns, and the wearability and functional properties of the knitted fabrics were tested. The results show that the ZnO/TM negative ion additive is randomly dispersed in the polymer matrix without visible conglobation and the fiber has a good appearance. The blending ratio has an important effect on the properties of functional polyester/cotton blended yarn. The higher the ratio of negative ion polyester fiber in the blended yarn, the better the mechanical index of the blended yarn, the higher the negative ion emission, and the lower the hairiness index. The performances of fabric are influenced by the comprehensive action of fiber raw material type, yarn ratio, fabric tightness, and structure. The mechanical properties of the fabric knitted from negative ion polyester/cotton-blended yarn are lower than those made from negative ion polyester filament yarn. In the case of the same fabric structure, the negative ion emission performance, far-infrared emission performance, and antibacterial property of the fabric with a higher ratio of negative ion functional fiber is better than the lower ratio. With the same yarn composition, the negative ion emission performance and air permeability of the fabric with a loose structure are better than that of the fabric with a tight structure, but the moisture permeability, far-infrared emission properties, and antibacterial properties show little difference. Full article
(This article belongs to the Special Issue Technical Textile Science and Technology)
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18 pages, 5121 KiB  
Article
Understanding the Design and Sensory Behaviour of Graphene-Impregnated Textile-Based Piezoresistive Pressure Sensors
by Md Faisal Mahmud, Md Raju Ahmed, Prasad Potluri and Anura Fernando
Sensors 2025, 25(7), 2000; https://doi.org/10.3390/s25072000 - 22 Mar 2025
Viewed by 532
Abstract
Graphene-based textile pressure sensors are emerging as promising candidates for wearable sensing applications due to their high sensitivity, mechanical flexibility, and low energy consumption. This study investigates the design, fabrication, and electromechanical behaviour of graphene-coated nonwoven textile-based piezoresistive pressure sensors, focusing on the [...] Read more.
Graphene-based textile pressure sensors are emerging as promising candidates for wearable sensing applications due to their high sensitivity, mechanical flexibility, and low energy consumption. This study investigates the design, fabrication, and electromechanical behaviour of graphene-coated nonwoven textile-based piezoresistive pressure sensors, focusing on the impact of different electrode materials and fabrication techniques. Three distinct sensor fabrication methods—drop casting, electrospinning, and electro-spraying—were employed to impregnate graphene onto nonwoven textile substrates, with silver-coated textile electrodes integrated to enhance conductivity. The fabricated sensors were characterised for their morphology (SEM), chemical composition (FTIR), and electromechanical response under cyclic compressive loading. The results indicate that the drop-cast sensors exhibited the lowest initial resistance (~0.15 kΩ) and highest sensitivity (10.5 kPa−1) due to their higher graphene content and superior electrical connectivity. Electro-spun and electro-sprayed sensors demonstrated increased porosity and greater resistance fluctuations, highlighting the role of fabrication methods in sensor performance. Additionally, the silver-coated knitted electrodes provided the most stable electrical response, while spun-bonded and powder-bonded nonwoven electrodes exhibited higher hysteresis and resistance drift. These findings offer valuable insights into the optimisation of graphene-based textile pressure sensors for wearable health monitoring and smart textile applications, paving the way for scalable, low-power sensing solutions. Full article
(This article belongs to the Section Chemical Sensors)
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18 pages, 10057 KiB  
Article
Effects of NatureKnit™, a Blend of Fruit and Vegetable Fibers Rich in Naturally Occurring Bound Polyphenols, on the Metabolic Activity and Community Composition of the Human Gut Microbiome Using the M-SHIME® Gastrointestinal Model
by Marlies Govaert, Cindy Duysburgh, Brendan Kesler and Massimo Marzorati
Microorganisms 2025, 13(3), 613; https://doi.org/10.3390/microorganisms13030613 - 7 Mar 2025
Viewed by 1010
Abstract
This study evaluated the impact of a proprietary blend of fruit and vegetable fibers rich in naturally occurring bound polyphenols (commercially marketed as NatureKnitTM), compared to purified fibers (inulin and psyllium), on the human gut microbiome using the validated M-SHIME® [...] Read more.
This study evaluated the impact of a proprietary blend of fruit and vegetable fibers rich in naturally occurring bound polyphenols (commercially marketed as NatureKnitTM), compared to purified fibers (inulin and psyllium), on the human gut microbiome using the validated M-SHIME® gastrointestinal model. A short-term single-stage colonic M-SHIME® experiment (with fecal inoculum from three healthy human donors) was used to evaluate the test products compared to a negative control. Samples were assessed for pH, gas pressure, short-chain fatty acid (SCFA) production, lactate, and ammonium from 0 h to 48 h. Microbial community composition was assessed at 0 h (negative control only), 24 h, and 48 h (lumen) or 48 h (mucosal). All test products were fermented well in the colon as demonstrated by decreases in pH and increases in gas pressure over time; these changes occurred faster with the purified fibers, whereas NatureKnit™ demonstrated slow, steady changes, potentially indicating a gentler fermentation process. SCFA production significantly increased over the course of the 48 h experiment with all test products versus negative control. SCFA production was significantly greater with NatureKnit™ versus the purified fibers. Shifts in the microbial community composition were observed with all test products versus negative control. At the conclusion of the 48 h experiment, the absolute bacterial abundance and the richness of observed bacterial taxa in the lumen compartment was significantly greater with NatureKnit™ compared with inulin, psyllium, and negative control. Overall, NatureKnit™ demonstrated greater or similar prebiotic effects on study measures compared with established prebiotic fibers. Full article
(This article belongs to the Section Gut Microbiota)
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17 pages, 13829 KiB  
Article
Advanced Virtual Fit Technology for Precision Pressure Application in Medical Compression Waistbands
by Seonyoung Youn, Sheng Zhan and Kavita Mathur
Appl. Sci. 2024, 14(22), 10697; https://doi.org/10.3390/app142210697 - 19 Nov 2024
Viewed by 1198
Abstract
The design of medical-grade compression garments is essential for therapeutic efficacy, requiring precise pressure distribution on specific body areas. This study evaluates the effectiveness of virtual fit technology, focusing on CLO3D, in designing these garments. Simulated strain and pressure values from CLO3D were [...] Read more.
The design of medical-grade compression garments is essential for therapeutic efficacy, requiring precise pressure distribution on specific body areas. This study evaluates the effectiveness of virtual fit technology, focusing on CLO3D, in designing these garments. Simulated strain and pressure values from CLO3D were compared to experimental measurements, alongside the development of a CP model using CLO3D’s digitized stretch stiffness (Youn’s CP model). Using a 3D-scanned manikin, the mechanical behavior of eight knit fabrics, including composite structures, was assessed under strain of 5%, 10%, 15%, and 20%. The results showed that CLO3D’s built-in pressure simulation overestimated the pressure, especially in plaited fabrics such as SJP and INTP, with discrepancies of up to 10 kPa at strain levels above 15%. In contrast, the experimental pressure measurements using the Kikuhime and PPS sensors varied within 0.13 to 2.59 kPa. Youn’s CP model provided a closer fit to the experimental data, with deviations limited to within 1.9 kPa. This finding highlights the limitations of CLO3D for precision-required applications and underscores the need for more advanced, customized algorithms in virtual fit technology to ensure reliable compression garment design, particularly in medical contexts, where precise pressure control is critical for patient outcomes. Full article
(This article belongs to the Special Issue Innovative Functional Textiles and Their Applications)
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25 pages, 12953 KiB  
Article
Mechanical Behaviour of Green Epoxy Composites Reinforced with Sheep and Dog Wool from Serra Da Estrela
by Cláudia Antunes, Ana Paula Costa, André Costa Vieira and Joana Costa Vieira
Polymers 2024, 16(22), 3115; https://doi.org/10.3390/polym16223115 - 7 Nov 2024
Viewed by 1079
Abstract
Environmental awareness has led industries and consumers to replace products derived from oil resources with products derived from natural sources. In the case of the composite materials industry, the replacement of synthetic fibres with natural fibres has increased in recent years. To study [...] Read more.
Environmental awareness has led industries and consumers to replace products derived from oil resources with products derived from natural sources. In the case of the composite materials industry, the replacement of synthetic fibres with natural fibres has increased in recent years. To study the influence that different types of natural fibres and different textile manufacturing techniques have on the mechanical properties of composites, bio-based epoxy matrix composites reinforced with different natural animal fibres were produced, some reinforced with sheep’s wool and others with dog wool, which were later subjected to bending and tensile tests. From the authors’ knowledge, there are few studies of composites produced with animal fibres, and even fewer with dog hair. The textile structures used as reinforcement were created using crochet, knitting, and weaving techniques. Prior to the composites production, the fibres were characterized by X-ray Diffraction (X-RD), and the yarns produced from these fibres were subjected to tensile tests. The results obtained suggest that the number of yarns and the diameter of the needles used during the production of the reinforcement have a significant impact on the mechanical properties of the composites. The green epoxy resin composites reinforced with sheep’s wool exhibit higher values of flexural strength, tensile strength, and Young’s modulus than those reinforced with dog wool, with average increases of 36.97%, 45.16%, and 72.99%, respectively. It was also possible to verify that the composites reinforced with woven fabrics and crocheted fabrics exhibit the highest values of tensile strength, flexural strength, and Young’s modulus. Additionally, the composites reinforced with woven fabrics exhibit the highest values of deformation at first failure/break and toughness. Full article
(This article belongs to the Section Polymer Fibers)
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16 pages, 26995 KiB  
Article
Directionally Oriented Reinforcements of Warp-Knitted Fabrics for Composite Preforms
by Katarzyna Pieklak
Materials 2024, 17(21), 5221; https://doi.org/10.3390/ma17215221 - 26 Oct 2024
Cited by 1 | Viewed by 1005
Abstract
This paper focuses on the development of a methodology for the directional structural modification of warp-knitted fabrics by sewing on carbon fiber tapes. Four-, five-, and six-axial geometric systems were designed to optimize the qualitative distribution of stresses on the surface of the [...] Read more.
This paper focuses on the development of a methodology for the directional structural modification of warp-knitted fabrics by sewing on carbon fiber tapes. Four-, five-, and six-axial geometric systems were designed to optimize the qualitative distribution of stresses on the surface of the tested product. Through a numerical experiment in the ANSYS environment, the impact of the change in the axiality of a textile structure on the mechanical properties of the modeled geometric configuration was assessed. This analysis was experimentally verified by measuring the multiaxial force distribution on the knitted surface, which demonstrated that Variant 7, with six axes 30° apart, was the most favorable. Full article
(This article belongs to the Special Issue Advanced Materials: Process, Properties, and Applications)
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19 pages, 3162 KiB  
Case Report
Harnessing the Interactions of Wound Exudate Cells with Dressings Biomaterials for the Control and Prognosis of Healing Pathways
by Shirin Saberianpour, Gianluca Melotto, Lucy Redhead, Nadia Terrazzini, Jaqueline Rachel Forss and Matteo Santin
Pharmaceuticals 2024, 17(9), 1111; https://doi.org/10.3390/ph17091111 - 23 Aug 2024
Cited by 2 | Viewed by 1181
Abstract
The global socioeconomic challenge generated by wounds requires an understanding of healing and non-healing pathways in patients. Also, the interactions occurring between the wound dressing biomaterials with cells relevant to the healing process have not been sufficiently investigated, thus neglecting the role that [...] Read more.
The global socioeconomic challenge generated by wounds requires an understanding of healing and non-healing pathways in patients. Also, the interactions occurring between the wound dressing biomaterials with cells relevant to the healing process have not been sufficiently investigated, thus neglecting the role that wound dressing composition can play in healing. Through the study of six cases of acute surgical wounds, the present work analyses the early (24 h post-surgery) interactions of biochemical and cellular components with (i) Atrauman, a device made of knitted woven synthetic polymeric fibre when used as a primary dressing, and (ii) Melolin, a hydrocolloid engineered as two layers of synthetic and cellulose non-woven fibres when used as a secondary dressing. A pathway towards healing could be observed in those cases where endoglin-expressing cells and M2 macrophages were retained by Atrauman fibres at the interface with the wound bed. On the contrary, cases where the secondary dressing Melolin absorbed these cell phenotypes in its mesh resulted in a slower or deteriorating healing process. The data obtained indicate that a subtraction of progenitor cells by Melolin may impair the healing process and that the analysis of the retrieved wound dressings for biomarkers expressed by cells relevant to wound healing may become an additional tool to determine the patient’s prognosis. Full article
(This article belongs to the Special Issue Development of Specific Dosage Form: Wound Dressing)
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12 pages, 2090 KiB  
Article
Discrimination and Quantification of Cotton and Polyester Textile Samples Using Near-Infrared and Mid-Infrared Spectroscopies
by Maria Luís Paz and Clara Sousa
Molecules 2024, 29(15), 3667; https://doi.org/10.3390/molecules29153667 - 2 Aug 2024
Viewed by 1995
Abstract
In the textile industry, cotton and polyester (PES) are among the most used fibres to produce clothes. The correct identification and accurate composition estimate of fibres are mandatory, and environmentally friendly and precise techniques are welcome. In this context, the use of near-infrared [...] Read more.
In the textile industry, cotton and polyester (PES) are among the most used fibres to produce clothes. The correct identification and accurate composition estimate of fibres are mandatory, and environmentally friendly and precise techniques are welcome. In this context, the use of near-infrared (NIR) and mid-infrared (MIR) spectroscopies to distinguish between cotton and PES samples and further estimate the cotton content of blended samples were evaluated. Infrared spectra were acquired and modelled through diverse chemometric models: principal component analysis; partial least squares discriminant analysis; and partial least squares (PLS) regression. Both techniques (NIR and MIR) presented good potential for cotton and PES sample discrimination, although the results obtained with NIR spectroscopy were slightly better. Regarding cotton content estimates, the calibration errors of the PLS models were 3.3% and 6.5% for NIR and MIR spectroscopy, respectively. The PLS models were validated with two different sets of samples: prediction set 1, containing blended cotton + PES samples (like those used in the calibration step), and prediction set 2, containing cotton + PES + distinct fibre samples. Prediction set 2 was included to address one of the biggest known drawbacks of such chemometric models, which is the prediction of sample types that are not used in the calibration. Despite the poorer results obtained for prediction set 2, all the errors were lower than 8%, proving the suitability of the techniques for cotton content estimation. It should be stressed that the textile samples used in this work came from different geographic origins (cotton) and were of distinct presentations (raw, yarn, knitted/woven fabric), which strengthens our findings. Full article
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17 pages, 4958 KiB  
Article
Characterizing the Sensing Response of Carbon Nanocomposite-Based Wearable Sensors on Elbow Joint Using an End Point Robot and Virtual Reality
by Amit Chaudhari, Rakshith Lokesh, Vuthea Chheang, Sagar M. Doshi, Roghayeh Leila Barmaki, Joshua G. A. Cashaback and Erik T. Thostenson
Sensors 2024, 24(15), 4894; https://doi.org/10.3390/s24154894 - 28 Jul 2024
Viewed by 1755
Abstract
Physical therapy is often essential for complete recovery after injury. However, a significant population of patients fail to adhere to prescribed exercise regimens. Lack of motivation and inconsistent in-person visits to physical therapy are major contributing factors to suboptimal exercise adherence, slowing the [...] Read more.
Physical therapy is often essential for complete recovery after injury. However, a significant population of patients fail to adhere to prescribed exercise regimens. Lack of motivation and inconsistent in-person visits to physical therapy are major contributing factors to suboptimal exercise adherence, slowing the recovery process. With the advancement of virtual reality (VR), researchers have developed remote virtual rehabilitation systems with sensors such as inertial measurement units. A functional garment with an integrated wearable sensor can also be used for real-time sensory feedback in VR-based therapeutic exercise and offers affordable remote rehabilitation to patients. Sensors integrated into wearable garments offer the potential for a quantitative range of motion measurements during VR rehabilitation. In this research, we developed and validated a carbon nanocomposite-coated knit fabric-based sensor worn on a compression sleeve that can be integrated with upper-extremity virtual rehabilitation systems. The sensor was created by coating a commercially available weft knitted fabric consisting of polyester, nylon, and elastane fibers. A thin carbon nanotube composite coating applied to the fibers makes the fabric electrically conductive and functions as a piezoresistive sensor. The nanocomposite sensor, which is soft to the touch and breathable, demonstrated high sensitivity to stretching deformations, with an average gauge factor of ~35 in the warp direction of the fabric sensor. Multiple tests are performed with a Kinarm end point robot to validate the sensor for repeatable response with a change in elbow joint angle. A task was also created in a VR environment and replicated by the Kinarm. The wearable sensor can measure the change in elbow angle with more than 90% accuracy while performing these tasks, and the sensor shows a proportional resistance change with varying joint angles while performing different exercises. The potential use of wearable sensors in at-home virtual therapy/exercise was demonstrated using a Meta Quest 2 VR system with a virtual exercise program to show the potential for at-home measurements. Full article
(This article belongs to the Special Issue Advances in Sensor Technologies for Wearable Applications)
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19 pages, 2159 KiB  
Review
Woven Fabrics for Composite Reinforcement: A Review
by Indraneel R. Chowdhury and John Summerscales
J. Compos. Sci. 2024, 8(7), 280; https://doi.org/10.3390/jcs8070280 - 18 Jul 2024
Cited by 7 | Viewed by 6529
Abstract
Fibres in different textile forms (woven, knitted, stitched, and non-crimp) are used to reinforce composites for multifaced applications, including automotive, aerospace, marine, rail, energy, construction, and defence sectors. Textile fabric-based fibre reinforcements for composites possess some outstanding features, such as good dimensional stability, [...] Read more.
Fibres in different textile forms (woven, knitted, stitched, and non-crimp) are used to reinforce composites for multifaced applications, including automotive, aerospace, marine, rail, energy, construction, and defence sectors. Textile fabric-based fibre reinforcements for composites possess some outstanding features, such as good dimensional stability, subtle conformability, deep draw moldability/processability, lightweightness, high strength and stiffness, and low cost. The greatest advantage of textile fibre-reinforced composites is the freedom to tailor their strength and stiffness properties for specific applications. Therefore, the design of composites involves defining the fabric geometry, stacking sequence, and orientation of fibres to optimise the system. Compared to knitted, stitched, and non-crimp fabrics, woven fabric-based fibre-reinforced composites are widely used in the industry. The properties of woven fabric-reinforced composites depend on several factors, such as types of fibre, compositions, polymeric matrices, and fibre/matrix interfacial strength. Some of the advantages are reduced preforming process steps, good impact and delamination resistance, and thermo-mechanical properties. This review has been written to provide detailed information and discussions, including the fabrication processes, relationship between fabric structure and composite properties, and morphological characteristics encompassing the current state-of-the-art in woven fabrics for composite reinforcement. Full article
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11 pages, 5176 KiB  
Article
Preparation of Al@FTCS/P(VDF-HFP) Composite Energetic Materials and Their Reaction Properties
by Xiang Ke, Lifang Deng, Yanping Wang, Kai Tang, Lei Xiao, Gazi Hao, Peili Li and Xiang Zhou
Materials 2024, 17(13), 3046; https://doi.org/10.3390/ma17133046 - 21 Jun 2024
Cited by 1 | Viewed by 1016
Abstract
Strengthening the interfacial contact between the reactive components effectively boosts the energy release of energetic materials. In this study, we aimed to create a close-knit interfacial contact condition between aluminum nanoparticles (Al NPs) and Polyvinylidene fluoride-hexafluoropropylene (P(VDF-HFP)) through hydrolytic adsorption and assembling 1H, [...] Read more.
Strengthening the interfacial contact between the reactive components effectively boosts the energy release of energetic materials. In this study, we aimed to create a close-knit interfacial contact condition between aluminum nanoparticles (Al NPs) and Polyvinylidene fluoride-hexafluoropropylene (P(VDF-HFP)) through hydrolytic adsorption and assembling 1H, 1H, 2H, 2H-Perfluorododecyltrichlorosilane (FTCS) on the surface of Al NPs. Leveraging hydrogen bonding between –CF and –CH and the interaction between C–F⋯F–C groups, the adsorbed FTCS directly leads to the growth of the P(VDF-HFP) coating layer around the treated Al NPs, yielding Al@FTCS/P(VDF-HFP) energetic composites. In comparison with the ultrasonically processed Al/P(VDF-HFP) mixture, thermal analysis reveals that Al@FTCS/P(VDF-HFP) exhibits a 57 °C lower reaction onset temperature and a 1646 J/g increase in heat release. Associated combustion tests demonstrate a 52% shorter ignition delay, 62% shorter combustion time, and a 288% faster pressurization rate. These improvements in energetic characteristics stem from the reactivity activation of FTCS towards Al NPs by the etching effect to the surface Al2O3. Moreover, enhanced interfacial contact facilitated by the FTCS-directed growth of P(VDF-HFP) around Al NPs further accelerates the whole reaction process. Full article
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15 pages, 7222 KiB  
Article
Recycled-Textile-Waste-Based Sustainable Bricks: A Mechanical, Thermal, and Qualitative Life Cycle Overview
by Hafsa Jamshaid, Ambar Shah, Muhammad Shoaib and Rajesh Kumar Mishra
Sustainability 2024, 16(10), 4036; https://doi.org/10.3390/su16104036 - 11 May 2024
Cited by 4 | Viewed by 12943
Abstract
The textile industry, renowned for its comfort-providing role, is undergoing a significant transformation to address its environmental impact. The escalating environmental impact of the textile industry, characterised by substantial contributions to global carbon emissions, wastewater, and the burgeoning issue of textile waste, demands [...] Read more.
The textile industry, renowned for its comfort-providing role, is undergoing a significant transformation to address its environmental impact. The escalating environmental impact of the textile industry, characterised by substantial contributions to global carbon emissions, wastewater, and the burgeoning issue of textile waste, demands urgent attention. This study aims at identifying the feasibility of the future use of textile scraps in the construction and architecture industry by analysing the effect of different binders. In this study, synthetic knitted post-consumer-waste fabrics were taken from a waste market for use as a reinforcement, and different binders were used as the matrix. In the experiment phase, the waste fabrics were mixed with synthetic binders and hydraulic binders to form brick samples. The mechanical and thermal properties of these samples were tested and compared with those of clay bricks. In terms of mechanical properties, unsaturated polyester resin (UPR) samples showed the highest mechanical strength, while acrylic glue (GL) samples had the lowest mechanical strength. White cement (WC) samples showed moderate mechanical properties. Through several tests, it was observed that UPR samples showed the highest values of tensile, bending, and compressive strengths, i.e., 0.111 MPa, 0.134 MPa, and 3.114 MPa, respectively. For WC, the tensile, bending, and compressive strengths were 0.064 MPa, 0.106 MPa, and 2.670 MPa, respectively. For GL, the least favourable mechanical behaviour was observed, i.e., 0.0162 MPa, 0.0492 MPa, and 1.542 MPa, respectively. In terms of thermal conductivity, WC samples showed exceptional resistance to heat transfer. They showed a minimum temperature rise of 54.3 °C after 15 min, as compared to 57.3 °C for GL-based samples and 58.1 °C for UPR. When it comes to polymeric binders, UPR showed better thermal insulation properties, whereas GL allowed for faster heat transfer for up to 10 min of heating. This study explores a circular textile system by assessing the potential of using textile waste as a building material, contributing to greener interior design. This study demonstrated the usefulness of adding short, recycled PET fibres as a reinforcement in UPR composites. The use of the PET fibre avoids the need to use a surface treatment to improve interfacial adhesion to the UPR matrix because of the chemical affinity between the two polyesters, i.e., the PET fibre and the unsaturated polyester resin. This can find application in the construction field, such as in the reinforcement of wooden structural elements, infill walls, and partition walls, or in furniture or for decorative purposes. Full article
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16 pages, 6505 KiB  
Article
Interfacial Enhancement and Composite Manufacturing of Continuous Carbon-Fiber-Reinforced PA6T Composites via PrePA6T Ultrafine Powder
by Jiahong Yao, Zhao Wang, Jiacao Yang, Xiaojun Wang and Jie Yang
Materials 2024, 17(7), 1557; https://doi.org/10.3390/ma17071557 - 28 Mar 2024
Cited by 1 | Viewed by 1441
Abstract
Semi-aromatic poly (hexamethylene terephthalamide) (PA6T) oligomer (prePA6T) ultrafine powder, with a diameter of <5 μm, was prepared as an emulsion sizing agent to improve the impregnation performance of CF/PA6T composites. The prePA6T hyperfine powder was acquired via the dissolution and precipitation “phase conversion” [...] Read more.
Semi-aromatic poly (hexamethylene terephthalamide) (PA6T) oligomer (prePA6T) ultrafine powder, with a diameter of <5 μm, was prepared as an emulsion sizing agent to improve the impregnation performance of CF/PA6T composites. The prePA6T hyperfine powder was acquired via the dissolution and precipitation “phase conversion” method, and the prePA6T emulsion sizing agent was acquired to continuously coat the CF bundle. The sized CF unidirectional tape was knitted into a fabric using the plain weave method, while the CF/PA6T laminated composites were obtained by laminating the plain weave fabrics with PA6T films. The interfacial shear strength (IFSS), tensile strength (TS), and interlaminar shear strength (ILSS) of prePA6T-modified CF/PA6T composites improved by 54.9%, 125.3%, and 120.9%, respectively. Compared with the commercial polyamide sizing agent product PA845H, the prePA6T sizing agent showed better interfacial properties at elevated temperatures, especially no TS loss at 75 °C. The SEM observations also indicated that the prePA6T emulsion has an excellent impregnation effect on CF, and the fracture mechanism shifted from adhesive failure mode to cohesive failure mode. In summary, a facile, heat-resistant, undamaged-to-fiber environmental coating process is proposed to continuously manufacture high-performance thermoplastic composites, which is quite promising in mass production. Full article
(This article belongs to the Special Issue Advanced Manufacturing Technologies of Thermoplastic Composites)
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