In order to improve the magnetocaloric properties of MnNiSi-based alloys, a new type of high-entropy magnetocaloric alloy was constructed. In this work, Mn
0.6Ni
1−xSi
0.62Fe
0.4Co
xGe
0.38 (
x = 0.4, 0.45, and 0.5) are
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In order to improve the magnetocaloric properties of MnNiSi-based alloys, a new type of high-entropy magnetocaloric alloy was constructed. In this work, Mn
0.6Ni
1−xSi
0.62Fe
0.4Co
xGe
0.38 (
x = 0.4, 0.45, and 0.5) are found to exhibit magnetostructural first-order phase transitions from high-temperature Ni
2In-type phases to low-temperature TiNiSi-type phases so that the alloys can achieve giant magnetocaloric effects. We investigate why
chexagonal/
ahexagonal (
chexa/
ahexa) gradually increases upon Co substitution, while phase transition temperature (
Ttr) and isothermal magnetic entropy change (Δ
SM) tend to gradually decrease. In particular, the
x = 0.4 alloy with remarkable magnetocaloric properties is obtained by tuning Co/Ni, which shows a giant entropy change of 48.5 J∙kg
−1K
−1 at 309 K for 5 T and an adiabatic temperature change (Δ
Tad) of 8.6 K at 306.5 K. Moreover, the
x = 0.55 HEA shows great hardness and compressive strength with values of 552 HV2 and 267 MPa, respectively, indicating that the mechanical properties undergo an effective enhancement. The large Δ
SM and Δ
Tad may enable the MnNiSi-based HEAs to become a potential commercialized magnetocaloric material.
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