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Molecules, Volume 29, Issue 13

2024 July-1 - 295 articles

Cover Story: The dynamic unusual transformation of Ru-pyrrole carboxylate species is afforded by a long acetonitrile boiling process, satisfying the yield of the heteroleptic k2(N,O)- bonding mode from the original k2(O,O)- coordination. The π-delocalized air- and moisturizing stable solvento-neutral species reveal antimicrobial properties. The proposed DFT-calculated mechanisms disclose low-energy paths, where H2 release plays a crucial role. According to spectroscopic and X-ray structural data, the isolated fused 5-membered Ru-pyrrole aldehyde derivatives shed further light on the constitutional selective formation of ethenoyl azafulvene or cyclized pyrrole aldehyde species. In line with the Pearson’s anti-symbiotic selection, the hetero-anionic N- or O- hard functions both exhibit major stabilization in trans-locating the relative CO-ligands. View this paper
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Articles (295)

  • Article
  • Open Access
3 Citations
2,713 Views
16 Pages

Dextransucrases play a crucial role in the production of dextran from economical sucrose; therefore, there is a pressing demand to explore novel dextransucrases with better performance. This study characterized a dextransucrase enzyme, LmDexA, which...

  • Article
  • Open Access
5 Citations
2,473 Views
13 Pages

Evaluation of Terpene Decomposition in Kaffir Lime Juice during Storage Using Gas Chromatography–Mass Spectrometry and Proton Transfer Reaction–Mass Spectrometry

  • Martyna Lubinska-Szczygeł,
  • Żaneta Polkowska,
  • Blanka Tobolkova,
  • Tomasz Majchrzak,
  • Martin Polovka,
  • Parichart Promchote and
  • Shela Gorinstein

Kaffir lime juice, often treated as production waste, can be a good source of terpenes. These compounds undergo various decomposition processes under the influence of external factors, especially during transportation and storage. In this paper, it w...

  • Article
  • Open Access
3 Citations
1,580 Views
10 Pages

Organic pollutants were one of the main sources of environmental pollutants. The degradation of organic pollutants through photocatalytic technology was one of the effective solutions. By preparing zinc oxide(ZnO) nanowires modified with sodium-doped...

  • Article
  • Open Access
1 Citations
1,656 Views
22 Pages

Encapsulation of Imidazole into Ce-Modified Mesoporous KIT-6 for High Anhydrous Proton Conductivity

  • Agata Tabero,
  • Aldona Jankowska,
  • Adam Ostrowski,
  • Ewa Janiszewska,
  • Jolanta Kowalska-Kuś,
  • Agnieszka Held and
  • Stanisław Kowalak

Imidazole molecules entrapped in porous materials can exhibit high and stable proton conductivity suitable for elevated temperature (>373 K) fuel cell applications. In this study, new anhydrous proton conductors based on imidazole and mesoporous K...

  • Article
  • Open Access
3 Citations
2,081 Views
16 Pages

This paper systematically investigates the structure, stability, and electronic properties of niobium carbide clusters, NbmCn (m = 5, 6; n = 1–7), using density functional theory. Nb5C2 and Nb5C6 possess higher dissociation energies and second-...

  • Article
  • Open Access
4 Citations
3,341 Views
20 Pages

Antiviral and Cytotoxic Activities of Ilex aquifolium Silver Queen in the Context of Chemical Profiling of Two Ilex Species

  • Natalia Pachura,
  • Maciej Włodarczyk,
  • Barbara Bażanów,
  • Aleksandra Pogorzelska,
  • Tomasz Gębarowski,
  • Robert Kupczyński and
  • Antoni Szumny

The leaves of Ilex paraguariensis (known as Yerba mate), used as a popular beverage, are a very well-recognized plant material with various biological activities, including analeptic (because of caffeine), anti-obesity (phenolics, saponins), antimicr...

  • Review
  • Open Access
10 Citations
3,996 Views
15 Pages

High-Throughput Mining of Novel Compounds from Known Microbes: A Boost to Natural Product Screening

  • Surya Nandan Meena,
  • Anna Wajs-Bonikowska,
  • Savita Girawale,
  • Md Imran,
  • Preethi Poduval and
  • Kisan M. Kodam

Advanced techniques can accelerate the pace of natural product discovery from microbes, which has been lagging behind the drug discovery era. Therefore, the present review article discusses the various interdisciplinary and cutting-edge techniques to...

  • Article
  • Open Access
5 Citations
2,694 Views
15 Pages

Panax notoginseng is a highly valued perennial medicinal herb in China and is widely used in clinical treatments. The main purpose of this study was to elucidate the changes in the composition of P. notoginseng saponins (PNSs), which are the main bio...

  • Review
  • Open Access
4 Citations
3,075 Views
18 Pages

Organic room temperature afterglow (ORTA) can be categorized into two key mechanisms: continuous thermally activated delayed fluorescence (TADF) and room-temperature phosphorescence (RTP), both of which involve a triplet excited state. However, tripl...

  • Review
  • Open Access
2 Citations
4,017 Views
24 Pages

In Silico Methods for the Discovery of Kv7.2/7.3 Channels Modulators: A Comprehensive Review

  • Claudio Stagno,
  • Francesca Mancuso,
  • Tania Ciaglia,
  • Carmine Ostacolo,
  • Anna Piperno,
  • Nunzio Iraci and
  • Nicola Micale

The growing interest in Kv7.2/7.3 agonists originates from the involvement of these channels in several brain hyperexcitability disorders. In particular, Kv7.2/7.3 mutants have been clearly associated with epileptic encephalopathies (DEEs) as well as...

  • Review
  • Open Access
11 Citations
4,949 Views
39 Pages

Surfactants play a crucial role in tertiary oil recovery by reducing the interfacial tension between immiscible phases, altering surface wettability, and improving foam film stability. Oil reservoirs have high temperatures and high pressures, making...

  • Article
  • Open Access
8 Citations
3,621 Views
21 Pages

The Recyclability of Fire-Retarded Biobased Polyamide 11 (PA11) Composites Reinforced with Basalt Fibers (BFs): The Influence of Reprocessing on Structure, Properties, and Fire Behavior

  • Mateusz Barczewski,
  • Aleksander Hejna,
  • Jacek Andrzejewski,
  • Joanna Aniśko,
  • Adam Piasecki,
  • Adrian Mróz,
  • Zaida Ortega,
  • Daria Rutkowska and
  • Kamila Sałasińska

The growing requirements regarding the safety of using polymers and their composites are related to the emergence of more effective, sustainable, and hazardous-limited fire retardants (FRs). Significant amounts of FRs are usually required to effectiv...

  • Article
  • Open Access
1 Citations
3,627 Views
14 Pages

An optimal balance between excitatory and inhibitory transmission in the central nervous system provides essential neurotransmission for good functioning of the neurons. In the neurology field, a disturbed balance can lead to neurological diseases li...

  • Article
  • Open Access
3 Citations
2,567 Views
15 Pages

Hydrous Molybdenum Oxide Coating of Zinc Metal Anode via the Facile Electrodeposition Strategy and Its Performance Improvement Mechanisms for Aqueous Zinc−Ion Batteries

  • Jianwei Yuan,
  • Yutao Shi,
  • Weibai Bian,
  • Huaren Wu,
  • Yingjun Chen,
  • Chengcheng Zhou,
  • Xiaohui Chen,
  • Wei Zhang and
  • Hailin Shen

Aqueous zinc−ion batteries (ZIBs) are widely recognized as highly promising energy storage devices because of their inherent characteristics, including superior safety, affordability, eco−friendliness, and various other benefits. However,...

  • Article
  • Open Access
1 Citations
1,772 Views
13 Pages

Lignin, a natural pol2ymer with a complex structure that is difficult to separate, is prone to C-C bond condensation during the separation process. To reduce the condensation of lignin, here, a novel method is proposed for separating the components b...

  • Article
  • Open Access
6 Citations
2,189 Views
12 Pages

Bismuth(III)-Catalyzed Regioselective Selenation of Indoles with Diaryl Diselenides: Synthesis of 3-Selanylindoles

  • Mio Matsumura,
  • Airi Umeda,
  • Yuika Sumi,
  • Naoki Aiba,
  • Yuki Murata and
  • Shuji Yasuike

Heterocyclic aryl selenides have recently attracted considerable research interest owing to their applications in biological and pharmaceutical fields. Herein, we describe a simple and general synthesis of 3-selanylindoles via a novel regioselective...

  • Article
  • Open Access
2 Citations
2,834 Views
18 Pages

A short 19 bp dsRNA with 3′-trinucleotide overhangs acting as immunostimulating RNA (isRNA) demonstrated strong antiproliferative action against cancer cells, immunostimulatory activity through activation of cytokines and Type-I IFN secretion,...

  • Article
  • Open Access
2 Citations
2,656 Views
19 Pages

The food industry uses indigo carmine (IC) extensively as a blue colorant to make processed food for young children and the general population more attractive. Given that IC can act as a ligand, this raises concerns about its interactions with essent...

  • Article
  • Open Access
3 Citations
1,834 Views
13 Pages

Transition metal selenides have the leading position in the field of energy storage and conversion due to their high theoretical capacity, good electrical conductivity, and cycling stability. Nickel is widely used for the construction of positive ele...

  • Article
  • Open Access
7 Citations
5,338 Views
23 Pages

This study investigated a novel probiotic-enriched ice cream containing fermented white kidney bean homogenate to explore its potential health benefits in the future. We assessed the viability of various probiotic strains during ice cream production...

  • Article
  • Open Access
2,221 Views
14 Pages

Ovalbumin (OVA), a protein vital for chick embryo nutrition, hydration, and antimicrobial protection, together with other egg-white proteins, migrates to the amniotic fluid and is orally absorbed by the embryo during embryogenesis. Recently, it has b...

  • Article
  • Open Access
1,536 Views
14 Pages

This article presents cyclic voltammetry, Tafel polarization, and ac. impedance spectroscopy examinations of resorcinol (RC) ion reactivity on Pt(511) single-crystal plane and the effect of surface-electrosorbed RC ions on the kinetics of UPD H (unde...

  • Article
  • Open Access
1 Citations
1,828 Views
18 Pages

A Strategy for Anode Recovery and Upgrading by In Situ Growth of Iron-Based Oxides on Microwave-Puffed Graphite

  • Wenxin Chen,
  • Jing Sun,
  • Pingshan Jia,
  • Wenlong Wang,
  • Zhanlong Song,
  • Ziliang Wang,
  • Xiqiang Zhao and
  • Yanpeng Mao

Faced with the increasing volume of retired lithium-ion batteries (LIBs), recycling and reusing the spent graphite (SG) is of great significance for resource sustainability. Here, a facile method for transforming the SG into a carbon framework as wel...

  • Article
  • Open Access
1,997 Views
12 Pages

[Fe(µ2-OH)6]3− Linked Fe3O Triads: Mössbauer Evidence for Trigonal µ3-O2− or µ3-OH Groups in Bridged versus Unbridged Complexes

  • D. Nirosha T. De Silva,
  • Tyson N. Dais,
  • Geoffrey B. Jameson,
  • Casey G. Davies,
  • Guy N. L. Jameson and
  • Paul G. Plieger

The syntheses, coordination chemistry, and Mössbauer spectroscopy of hepta-iron(III) complexes using derivatised salicylaldoxime ligands from two categories; namely, ‘single-headed’ (H2L) and ‘double-headed’ (H4L) salicyl...

  • Article
  • Open Access
4 Citations
2,394 Views
14 Pages

Preparation and Screening of SRB Gel Particles Used for Deep Purification of Acid Mine Drainage

  • Chunpeng Leng,
  • Xi He,
  • Yukuo Liu,
  • Lifeng Shi,
  • Fuping Li,
  • Hao Wang,
  • Cong Zhao,
  • Siyu Yi and
  • Lei Yu

The progressive decline of the coal industry necessitates the development of effective treatment solutions for acid mine drainage (AMD), which is characterized by high acidity and elevated concentrations of heavy metals. This study proposes an innova...

  • Review
  • Open Access
10 Citations
3,613 Views
24 Pages

Polyoxometalate (POM)-based ionic liquids (POM-ILs) are gaining increasing attention due to their diverse structures and functionalities. POMs in POM-ILs not only act as essential structural building blocks but also play a crucial role in their funct...

  • Article
  • Open Access
6 Citations
4,101 Views
21 Pages

Ruthenium p-Cymene Complexes Incorporating Substituted Pyridine–Quinoline-Based Ligands: Synthesis, Characterization, and Cytotoxic Properties

  • Afroditi Kokkosi,
  • Elpida Garofallidou,
  • Nikolaos Zacharopoulos,
  • Nikolaos Tsoureas,
  • Konstantina Diamanti,
  • Nikolaos S. Thomaidis,
  • Antigoni Cheilari,
  • Christina Machalia,
  • Evangelia Emmanouilidou and
  • Athanassios I. Philippopoulos

Organometallic complexes of the formula [Ru(N^N)(p-cymene)Cl][X] (N^N = bidentate polypyridyl ligands, p-cymene = 1-methyl-4-(1-methylethyl)-benzene, X = counter anion), are currently studied as possible candidates for the potential treatment of canc...

  • Review
  • Open Access
6 Citations
2,897 Views
49 Pages

How the Chemical Properties of Polysaccharides Make It Possible to Design Various Types of Organic–Inorganic Composites for Catalytic Applications

  • Sandugash Akhmetova,
  • Alima Zharmagambetova,
  • Eldar Talgatov,
  • Assemgul Auyezkhanova,
  • Makpal Malgazhdarova,
  • Murat Zhurinov,
  • Arlan Abilmagzhanov,
  • Aigul Jumekeyeva and
  • Alima Kenzheyeva

Recently, the use of plant-origin materials has become especially important due to the aggravation of environmental problems and the shortage and high cost of synthetic materials. One of the potential candidates among natural organic compounds is pol...

  • Article
  • Open Access
15 Citations
3,042 Views
16 Pages

Base-Free Oxidation of HMF to FDCA over Ru/Cu-Co-O·MgO under Aqueous Conditions

  • Shuang Zhang,
  • Guoning Chu,
  • Sai Wang,
  • Ji Ma and
  • Chengqian Wang

The copper–cobalt metal oxide composite magnesium oxide catalyst loaded with Ru has achieved the aerobic oxidation of 5-hydroxymethylfurfural (HMF) to the bio-based polyester monomer 2,5-furandicarboxylic acid (FDCA) under base-free conditions....

  • Communication
  • Open Access
4 Citations
2,830 Views
12 Pages

Nanostructured Glass-Ceramic Materials from Glass Waste with Antimicrobial Activity

  • Juliani P. Caland,
  • João Baptista,
  • Gabrielle Caroline Peiter,
  • Kelen M. F. Rossi de Aguiar,
  • Horácio Coelho-Júnior,
  • João P. Sinnecker,
  • Jorlandio F. Felix and
  • Ricardo Schneider

Modern consumption patterns have led to a surge in waste glass accumulating in municipal landfills, contributing to environmental pollution, especially in countries that do not have well-established recycling standards. While glass itself is 100% rec...

  • Article
  • Open Access
2,360 Views
11 Pages

The dynamic characterization of guest molecules in the metal–organic frameworks (MOFs) can always provide the insightful and inspiring information to facilitate the synthetic design of MOF materials from the bottom-up design of perspective. Her...

  • Article
  • Open Access
2 Citations
2,561 Views
13 Pages

Determination of Aminoglycosides by Ion-Pair Liquid Chromatography with UV Detection: Application to Pharmaceutical Formulations and Human Serum Samples

  • Eliseo Herrero-Hernández,
  • Diego García-Gómez,
  • Irene Ramírez Pérez,
  • Encarnación Rodríguez-Gonzalo and
  • José Luis Pérez Pavón

Aminoglycosides (AGs) represent a prominent class of antibiotics widely employed for the treatment of various bacterial infections. Their widespread use has led to the emergence of antibiotic-resistant strains of bacteria, highlighting the need for a...

  • Article
  • Open Access
2 Citations
2,117 Views
14 Pages

Film Coating of Phosphorylated Mandua Starch on Matrix Tablets for pH-Sensitive Release of Mesalamine

  • Mayank Kumar Malik,
  • Vipin Kumar,
  • Vinoth Kumarasamy,
  • Om Prakash Singh,
  • Mukesh Kumar,
  • Raghav Dixit,
  • Vetriselvan Subramaniyan and
  • Jaspal Singh

Chemically modified mandua starch was successfully synthesized and applied to coat mesalamine-loaded matrix tablets. The coating material was an aqueous dispersion of mandua starch modified by sodium trimetaphosphate and sodium tripolyphosphate. To i...

  • Article
  • Open Access
1 Citations
1,665 Views
10 Pages

Poly(p-phenylene ethynylene) (PPE) molecular wires are one-dimensional materials with distinctive properties and can be applied in electronic devices. Here, the approach called first-principles quantum transport is utilized to investigate the PPE mol...

  • Review
  • Open Access
24 Citations
7,112 Views
16 Pages

The Role of Quercetin as a Plant-Derived Bioactive Agent in Preventive Medicine and Treatment in Skin Disorders

  • Michał Kazimierz Zaborowski,
  • Anna Długosz,
  • Błażej Błaszak,
  • Joanna Szulc and
  • Kamil Leis

Quercetin, a bioactive plant flavonoid, is an antioxidant, and as such it exhibits numerous beneficial properties including anti-inflammatory, antiallergic, antibacterial and antiviral activity. It occurs naturally in fruit and vegetables such as app...

  • Review
  • Open Access
16 Citations
5,612 Views
17 Pages

This review is dedicated to sustainable practices in liquid chromatography. HPLC and UHPLC methods contribute significantly to routine analytical techniques. Therefore, the transfer of classical liquid chromatographic methods into sustainable ones is...

  • Article
  • Open Access
2 Citations
1,586 Views
13 Pages

Heavy metals and organic pollutants are prevalent in water bodies, causing great damage to the environment and human beings. Hence, it is urgent to develop a kind of adsorbent with good performance. Anion interlacing layered double hydroxides (LDHs)...

  • Article
  • Open Access
5 Citations
1,907 Views
15 Pages

The composite photocatalyst FeOOH/g-C3N4 was prepared through thermal polycondensation and co-precipitation methods, followed by XRD, SEM and UV-vis characterization. The stability of FeOOH/g-C3N4 was explored by the recycling test. The active specie...

  • Article
  • Open Access
1 Citations
1,572 Views
13 Pages

Surface Functionalization of Bamboo via Photo-Grafting Tannic Acid for Enhanced Silver Ion Loading Properties

  • Juan Xu,
  • Lanxiang Liu,
  • Jinju Ma,
  • Baoshan Tang,
  • Zhengjun Shi and
  • Hong Zhang

Photo-grafting is a gentle, simple, and precise approach to incorporating specific functional molecules for the surface functionalization of substrates. In this work, ultraviolet (UV)-induced tannic acid (TA) grafting onto the surface of bamboo was p...

  • Article
  • Open Access
2 Citations
1,841 Views
14 Pages

Background: Ophiocordyceps sinensis has long been recognized as a mysterious and valuable traditional Chinese medicine but there has been little research on quality markers for O. sinensis. Purpose: This study looked into the potential of using powde...

  • Article
  • Open Access
2 Citations
1,975 Views
15 Pages

The present work reports the synthesis of indigo-dye-incorporated polyaniline (Indigo-PANI), poly(1-naphthylamine) (Indigo-PNA), poly(o-phenylenediamine) (Indigo-POPD), polypyrrole (Indigo-PPy), and polythiophene (Indigo-PTh) via an ultrasound-assist...

  • Article
  • Open Access
8 Citations
3,837 Views
32 Pages

Serine/threonine protein kinases (CK2, PIM-1, RIO1) are constitutively active, highly conserved, pleiotropic, and multifunctional kinases, which control several signaling pathways and regulate many cellular functions, such as cell activity, survival,...

  • Article
  • Open Access
1 Citations
1,618 Views
12 Pages

Functionalized imidazo[1,2-α]pyridines are important scaffolds in pharmaceuticals. Herein, we present an efficient 3-sulfonylmethylation protocol for imidazo[1,2-α]pyridines by sodium sulfinates in DMA and H2O (2:1) via an FeCl3-catalyzed...

  • Article
  • Open Access
7 Citations
3,414 Views
13 Pages

Five different lignocellulosic raw materials (coconut shells, Moso bamboo, sawtooth oak, Chinese fir, and Masson pine) were used to prepare activated carbons by steam activation at 850 °C to evaluate the effects of their structures on physical ac...

  • Article
  • Open Access
2 Citations
2,473 Views
14 Pages

Hetero-Diels–Alder and CuAAC Click Reactions for Fluorine-18 Labeling of Peptides: Automation and Comparative Study of the Two Methods

  • Timothé Maujean,
  • Sridévi M. Ramanoudjame,
  • Stéphanie Riché,
  • Clothilde Le Guen,
  • Frédéric Boisson,
  • Sylviane Muller,
  • Dominique Bonnet,
  • Mihaela Gulea and
  • Patrice Marchand

Radiolabeled peptides are valuable tools for diagnosis or therapies; they are often radiofluorinated using an indirect approach based on an F-18 prosthetic group. Herein, we are reporting our results on the F-18 radiolabeling of three peptides using...

  • Article
  • Open Access
7 Citations
4,377 Views
13 Pages

Thermal Decomposition of Bio-Based Plastic Materials

  • Inés Oliver,
  • Juan A. Conesa and
  • Andres Fullana

This research delves into a detailed exploration of the thermal decomposition behavior of bio-based polymers, specifically thermoplastic starch (TPS) and polylactic acid (PLA), under varying heating rates in a nitrogen atmosphere. This study employs...

  • Article
  • Open Access
7 Citations
4,227 Views
20 Pages

Optimization of HS-SPME/GC-MS Method for Determining Volatile Organic Compounds and Sensory Profile in Cocoa Honey from Different Cocoa Varieties (Theobroma cacao L.)

  • Manuela B. Nascimento,
  • Lívia R. Amorim,
  • Marcos A. S. Nonato,
  • Mariana N. Roselino,
  • Ligia R. R. Santana,
  • Adriana C. R. Ferreira,
  • Frederico M. Rodrigues,
  • Paulo R. R. Mesquita and
  • Sergio E. Soares

This study aimed to develop an analytical method using HS-SPME/GC-MS to determine the volatile organic compound (VOC) profiles and evaluate the sensory attributes of cocoa honey from four cocoa varieties (CCN51, PS1319, SJ02, and Parazinho). Using a...

  • Article
  • Open Access
2 Citations
1,730 Views
20 Pages

Codonopsis convolvulacea is a highly valued Chinese medicinal plant containing diverse bioactive compounds. While roots/tubers have been the main medicinal parts used in practice, leaves and stems may also harbor valuable phytochemicals. However, res...

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Molecules - ISSN 1420-3049