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Catalysts, Volume 14, Issue 5

2024 May - 50 articles

Cover Story: Automotive three-way catalysts (TWCs) reduce toxic emissions but need replacing after 8–10 years of use, resulting in substantial amounts of palladium-rich waste. Current pyrometallurgical routes to recycle this precious metal content are very energy-intensive and require the use of hazardous chemicals. More recently, a mild, low-energy process has been reported that can transform model TWC material into the palladium dimer [NnBu4]2[Pd2I6] in high yields and purity. In this contribution, we demonstrate that this dimeric recovery product, and its derivative PdI2(dppf), can be employed as effective (pre)catalysts for the formation of new C-O and C-N bonds in low-impact solvents. [NnBu4]2[Pd2I6] can also be recovered and re-used multiple times after the reaction, providing additional sustainability benefits. View this paper
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Articles (50)

  • Article
  • Open Access
6 Citations
3,157 Views
16 Pages

Enhancing the Visible Light Photocatalytic Activity of TiO2-Based Coatings by the Addition of Exfoliated g-C3N4

  • Ilias Papailias,
  • Nadia Todorova,
  • Tatiana Giannakopoulou,
  • Niki Plakantonaki,
  • Michail Vagenas,
  • Panagiotis Dallas,
  • George C. Anyfantis,
  • Ioannis Arabatzis and
  • Christos Trapalis

20 May 2024

In the last few years, increasing interest from researchers and companies has been shown in the development of photocatalytic coatings for air purification and self-cleaning applications. In order to maintain the photocatalyst’s concentration a...

  • Article
  • Open Access
5 Citations
3,092 Views
17 Pages

18 May 2024

The catalytic isomerization of glucose to fructose plays a pivotal role in the application of biomass as a feedstock for chemicals. Herein, we propose a facile solid-state-grinding strategy to construct ZrO2/MgO mixed oxides, which offered an excelle...

  • Article
  • Open Access
8 Citations
2,460 Views
22 Pages

Controllable Synthesis of Fe2O3/Nickel Cobaltite Electrocatalyst to Enhance Oxidation of Small Molecules

  • Fowzia S. Alamro,
  • Shymaa S. Medany,
  • Nada S. Al-Kadhi,
  • Ayman M. Mostafa,
  • Walaa F. Zaher,
  • Hoda A. Ahmed and
  • Mahmoud A. Hefnawy

17 May 2024

Nickel-based catalysts have been widely recognized as highly promising electrocatalysts for oxidation. Herein, we designed a catalyst surface based on iron oxide electrodeposited on NiCo2O4 spinel oxide. Nickel foam was used as a support for the prep...

  • Feature Paper
  • Article
  • Open Access
1 Citations
6,932 Views
17 Pages

Investigating the Inhibitory Factors of Sucrose Hydrolysis in Sugar Beet Molasses with Yeast and Invertase

  • Mikael Sjölin,
  • Maria Djärf,
  • Mohamed Ismail,
  • Herje Schagerlöf,
  • Ola Wallberg,
  • Rajni Hatti-Kaul and
  • Mahmoud Sayed

17 May 2024

Sugar beet molasses is a low-value byproduct from the sugar industry. It contains significant amounts of sucrose (approx. 50% (w/w)), which can be used for many different applications, for example, as feedstock for the production of fuel (as ethanol)...

  • Review
  • Open Access
11 Citations
6,057 Views
27 Pages

17 May 2024

This review focuses on an extensive synopsis of the recent improvements in CO2 hydrogenation over structured zeolites, including their properties, synthesis methods, and characterization. Key features such as bimodal mesoporous structures, surface ox...

  • Feature Paper
  • Article
  • Open Access
4 Citations
3,134 Views
20 Pages

Study of Oxygen Reduction Reaction on Polycrystalline Rhodium in Acidic and Alkaline Media

  • Jelena Golubović,
  • Miroslava Varničić and
  • Svetlana Štrbac

16 May 2024

This study examines the kinetics and mechanism of the oxygen reduction reaction (ORR) on a polycrystalline rhodium electrode (Rh(poly)) in acidic and alkaline media, using rotating disc electrode measurements. This study found that the ORR activity o...

  • Article
  • Open Access
3 Citations
1,538 Views
11 Pages

16 May 2024

Using a simple acid-base neutralization method, a Ch-PW solid catalyst was synthesized by mixing choline hydroxide (ChOH) and phosphotungstic acid (HPW) at a 2:1 molar ratio in an aqueous solution. This catalyst was combined with a 20 wt.% potassium...

  • Article
  • Open Access
2,266 Views
16 Pages

Nano-Sheets of CsNiVF6 Pyrochlore Electrocatalyst for Enhanced Urea Oxidation and Hydrogen Green Production Reactions

  • Mohamed A. Ghanem,
  • Abdullah M. Al-Mayouf,
  • Khalaf A. Alfudhayli and
  • Mohamed O. Abdelkader

16 May 2024

This study presents the successful synthesis of a cesium–nickel–vanadium fluoride (CsNiVF6) pyrochlore nano-sheet catalyst via solid-phase synthesis and its electrochemical performance in green hydrogen production through urea electrolysi...

  • Article
  • Open Access
1,764 Views
12 Pages

One-Step Synthesis of High-Efficiency Oxygen Evolution Reaction Catalyst FeSx(Y/MB) with High Temperature Resistance and Strong Alkali

  • Jing Wang,
  • Lingling Feng,
  • Zikang Zhao,
  • Yan Wang,
  • Ying Zhang,
  • Shan Song,
  • Shengwei Sun,
  • Junshuang Zhou and
  • Faming Gao

16 May 2024

Given the energy crisis and escalating environmental pollution, the imperative for developing clean new energy is evident. Hydrogen has garnered significant attention owing to its clean properties, high energy density, and ease of storage and transpo...

  • Article
  • Open Access
3 Citations
1,575 Views
9 Pages

14 May 2024

To solve the shuttling effect and transformations of LiPSs in lithium–sulfur batteries, heterostructures have been designed to immobilize LiPSs and boost their reversible conversions. In this paper, we have constructed AlN/InN heterojunctions w...

  • Article
  • Open Access
11 Citations
4,191 Views
21 Pages

14 May 2024

This study examines the catalytic activity of NiFeCoOx catalysts for anion exchange membrane (AEM) water electrolysis. The catalysts were synthesized with a Ni to Co ratio of 2:1 and Fe content ranges from 2.5 to 12.5 wt%. The catalysts were characte...

  • Article
  • Open Access
2,297 Views
15 Pages

13 May 2024

A self-sufficient bifunctional enzyme integrating reductive amination and coenzyme regeneration activities was developed and successfully employed to synthesize (S)-cyclopropylglycine with an improved reaction rate 2.1-fold over the native enzymes an...

  • Article
  • Open Access
4 Citations
4,510 Views
13 Pages

Liquid–Liquid Equilibrium Behavior of Ternary Systems Comprising Biodiesel + Glycerol and Triglyceride + Methanol: Experimental Data and Modeling

  • Lingmei Yang,
  • Shiyou Xing,
  • Xianbin Teng,
  • Rukuan Liu,
  • Zhongming Wang,
  • Baining Lin,
  • Pengmei Lv,
  • Akram Ali Nasser Mansoor Al-Haimi,
  • Fatma Yehia and
  • Wen Luo

12 May 2024

Having a comprehensive knowledge of phase equilibrium is advantageous for industrial simulation and design of chemical processes. For further acquisition of primary data to facilitate the separation and purification of waste oil biodiesel systems, a...

  • Article
  • Open Access
4 Citations
4,527 Views
25 Pages

Methane Combustion Kinetics over Palladium-Based Catalysts: Review and Modelling Guidelines

  • Roshni Sajiv Kumar,
  • Joseph P. Mmbaga,
  • Natalia Semagina and
  • Robert E. Hayes

11 May 2024

Fugitive methane emissions account for a significant proportion of greenhouse gas emissions, and their elimination by catalytic combustion is a relatively easy way to reduce global warming. New and novel reactor designs are being considered for this...

  • Article
  • Open Access
1 Citations
2,109 Views
15 Pages

11 May 2024

Bimetallic AuCu/SiO2 nanosized catalysts were prepared using the wet chemical reduction technique. From among Au0.1–1.5Cu10/SiO2 catalysts, the Au0.5Cu10/SiO2 catalyst gave the highest yield of calcium lactate of 87% at a glycerol conversion of...

  • Review
  • Open Access
11 Citations
6,638 Views
39 Pages

10 May 2024

Fine chemicals are produced in small annual volume batch processes (often <10,000 tonnes per year), with a high associated price (usually >USD 10/kg). As a result of their usage in the production of speciality chemicals, in areas including agro...

  • Article
  • Open Access
11 Citations
2,090 Views
21 Pages

Promoter Impact on 5Ni/SAPO-5 Catalyst for H2 Production via Methane Partial Oxidation

  • Abdulaziz Al-Anazi,
  • Omer Bellahwel,
  • Kavitha C.,
  • Jehad Abu-Dahrieh,
  • Ahmed A. Ibrahim,
  • S. Santhosh,
  • Ahmed E. Abasaeed,
  • Anis H. Fakeeha and
  • Ahmed S. Al-Fatesh

10 May 2024

Compared to steam reforming techniques, partial oxidation of methane (POM) is a promising technology to improve the efficiency of synthesizing syngas, which is a mixture of CO and H2. In this study, partial oxidation of methane (POM) was used to crea...

  • Article
  • Open Access
2,050 Views
20 Pages

10 May 2024

Semi-hydrogenation of acetylene to ethylene over metal oxide-supported Au nanoparticles is an interesting topic. Here, a hydrotalcite-based MMgAlOx (M=Cu, Ni, and Co) composite oxide was exploited by introducing different Cu, Ni, and Co dopants with...

  • Article
  • Open Access
9 Citations
3,188 Views
12 Pages

Metal–Organic Framework Fe-BTC as Heterogeneous Catalyst for Electro-Fenton Treatment of Tetracycline

  • Taylor Mackenzie Fisher,
  • Alexsandro J. dos Santos and
  • Sergi Garcia-Segura

10 May 2024

This study explores the use of the iron-containing metal–organic framework (MOF), Basolite®F300, as a heterogeneous catalyst for electrochemically-driven Fenton processes. Electrochemical advanced oxidation processes (EAOPs) have shown prom...

  • Article
  • Open Access
6 Citations
2,387 Views
17 Pages

Perovskite Oxide Catalysts for Enhanced CO2 Reduction: Embroidering Surface Decoration with Ni and Cu Nanoparticles

  • Andrea Osti,
  • Lorenzo Rizzato,
  • Jonathan Cavazzani,
  • Ambra Meneghello and
  • Antonella Glisenti

10 May 2024

The imperative reduction of carbon dioxide into valuable fuels stands as a crucial step in the transition towards a more sustainable energy system. Perovskite oxides, with their high compositional and property adjustability, emerge as promising catal...

  • Article
  • Open Access
1 Citations
2,445 Views
20 Pages

Increased demand for ethylene has motivated direct ethane dehydrogenation over Pt-based catalysts. PtSn/γ-Al2O3 and PtSnZnCa/γ-Al2O3 catalysts were investigated with the aim of understanding the effect of the pretreatment environment on t...

  • Article
  • Open Access
10 Citations
3,215 Views
22 Pages

Remediation of Polycyclic Aromatic Hydrocarbon-Contaminated Soil by Using Activated Persulfate with Carbonylated Activated Carbon Supported Nanoscale Zero-Valent Iron

  • Changzhao Chen,
  • Zhe Yuan,
  • Shenshen Sun,
  • Jiacai Xie,
  • Kunfeng Zhang,
  • Yuanzheng Zhai,
  • Rui Zuo,
  • Erping Bi,
  • Yufang Tao and
  • Quanwei Song

Soil contamination by polycyclic aromatic hydrocarbons (PAHs) has been an environmental issue worldwide, which aggravates the ecological risks faced by animals, plants, and humans. In this work, the composites of nanoscale zero-valent iron supported...

  • Correction
  • Open Access
2 Citations
1,739 Views
12 Pages

There was an error in the original publication [...]

  • Feature Paper
  • Article
  • Open Access
2 Citations
2,306 Views
13 Pages

Strong and Hierarchical Ni(OH)2/Ni/rGO Composites as Multifunctional Catalysts for Excellent Water Splitting

  • Lixin Wang,
  • Ailing Song,
  • Yue Lu,
  • Manman Duanmu,
  • Zhipeng Ma,
  • Xiujuan Qin and
  • Guangjie Shao

The lack of efficient and non-precious metal catalysts poses a challenge for electrochemical water splitting in hydrogen and oxygen evolution reactions. Here, we report on the preparation of growing Ni(OH)2 nanosheets in situ on a Ni and graphene hyb...

  • Feature Paper
  • Review
  • Open Access
18 Citations
17,679 Views
29 Pages

The main groups of catalytic materials used in the conversion of methanol to dimethyl ether (the MTD process) were presented with respect to their advantages, disadvantages, and the methods of their modifications, resulting in catalysts with improved...

  • Article
  • Open Access
10 Citations
4,421 Views
22 Pages

The combination of water electrolysis and renewable energy to produce hydrogen is a promising way to solve the climate and energy crisis. However, the fluctuating characteristics of renewable energy not only present a significant challenge to the use...

  • Article
  • Open Access
4 Citations
1,952 Views
14 Pages

Study on NH3-SCR Activity and HCl/H2O Tolerance of Titanate-Nanotube-Supported MnOx-CeO2 Catalyst at Low Temperature

  • Qiulin Wang,
  • Feng Liu,
  • Zhihao Wu,
  • Jing Jin,
  • Xiaoqing Lin,
  • Shengyong Lu and
  • Juan Qiu

Manganese oxide-cerium oxide supported on titanate nanotubes (i.e., MnCe/TiNTs) were prepared and their catalytic activities towards NH3-SCR of NO were tested. The results indicated that the MnCe/TiNT catalyst can achieve a high NO removal efficiency...

  • Feature Paper
  • Article
  • Open Access
1 Citations
1,871 Views
13 Pages

A binuclear dioxomolybdenum catalyst [(MoO2Cl2)2(L)] (1) (with L (1S,2S)-N,N′-bis(2-pyridinecarboxamide)-1,2-cyclohexane) was prepared and used as catalyst for the desulfurization of a multicomponent model fuel containing the most refractory su...

  • Article
  • Open Access
15 Citations
3,824 Views
15 Pages

The immobilization of enzymes is an important strategy to improve their stability and reusability. Enzyme immobilization technology has broad application prospects in biotechnology, biochemistry, environmental remediation, and other fields. In this s...

  • Feature Paper
  • Review
  • Open Access
20 Citations
4,320 Views
24 Pages

Recent Advances in the Development of Nanocarbon-Based Electrocatalytic/Electrode Materials for Proton Exchange Membrane Fuel Cells: A Review

  • Adelina A. Zasypkina,
  • Nataliya A. Ivanova,
  • Dmitry D. Spasov,
  • Ruslan M. Mensharapov,
  • Matvey V. Sinyakov and
  • Sergey A. Grigoriev

The global issue for proton exchange membrane fuel cell market development is a reduction in the device cost through an increase in efficiency of the oxygen reduction reaction occurring at the cathode and an extension of the service life of the elect...

  • Article
  • Open Access
22 Citations
2,085 Views
14 Pages

Electrochemical Properties of NiCo2O4/WO3/Activated Carbon Wheat Husk Nano-Electrocatalyst for Methanol and Ethanol Oxidation

  • Mohammad Bagher Askari,
  • Parisa Salarizadeh,
  • Seyed Rouhollah Samareh Hashemi,
  • Mohsen Shojaeifar and
  • Sadegh Azizi

It is common to use efficient catalysts in the anodes and cathodes of methanol and ethanol fuel cells, such as platinum and ruthenium. However, due to their expansivity and rarity, finding a suitable alternative is important. In this work, multi-comp...

  • Article
  • Open Access
2 Citations
2,432 Views
17 Pages

A proton exchange membrane fuel cell (PEMFC) is an efficient and environmentally friendly power production technology that uses hydrogen energy. The cathodic oxygen reduction electrode is a critical component in the development of PEMFC. Most techniq...

  • Article
  • Open Access
1 Citations
1,808 Views
15 Pages

CeO2-ZrO2-La2O3 supported Pt-Pd bimetallic three-way catalysts (0.6Pt-0.4Pd/CZL) were synthesized through the conventional impregnation method and then subjected to severe thermal aging. Reactivating treatments under different temperatures were then...

  • Feature Paper
  • Article
  • Open Access
2 Citations
2,075 Views
11 Pages

Ultrathin-Shelled Zn-AgIn5S8/ZnS Quantum Dots with Partially Passivated Trap States for Efficient Hydrogen Production

  • Yanhong Liu,
  • Xianjin Wang,
  • Guan Gong,
  • Afaq Ullah Khan,
  • Geru Li,
  • Tong Ren,
  • Qitao Chen,
  • Lixia Li and
  • Baodong Mao

30 April 2024

The manipulation of trap states plays a crucial role in the development of efficient photocatalysts. An ultrathin-shelled Zn-AgIn5S8/ZnS quantum dots (QDs) photocatalyst was synthesized via in situ growth using a low-temperature hydrothermal method....

  • Feature Paper
  • Article
  • Open Access
5 Citations
5,051 Views
14 Pages

29 April 2024

High-performance Cu catalysts were developed for the selective hydrogenation of γ-butyrolactone (GBL) to 1,4-butanediol (BDO). Among the various catalysts prepared by ammonia evaporation (AE) and impregnation (IM) methods with silica or MFI zeo...

  • Feature Paper
  • Article
  • Open Access
12 Citations
5,290 Views
12 Pages

29 April 2024

Water electrolysis is a crucial technology in the production of hydrogen energy. Due to the escalating industrial demand for green hydrogen, the required electrode size for a traditional alkaline water electrolyzer has been increasing. Numerous studi...

  • Article
  • Open Access
3 Citations
3,528 Views
17 Pages

Palladium Complexes Derived from Waste as Catalysts for C-H Functionalisation and C-N Bond Formation

  • Khairil A. Jantan,
  • Gregor Ekart,
  • Sean McCarthy,
  • Andrew J. P. White,
  • D. Christopher Braddock,
  • Angela Serpe and
  • James D. E. T. Wilton-Ely

29 April 2024

Three-way catalysts (TWCs) are widely used in vehicles to convert the exhaust emissions from internal combustion engines into less toxic pollutants. After around 8–10 years of use, the declining catalytic activity of TWCs causes them to need re...

  • Feature Paper
  • Article
  • Open Access
1 Citations
3,429 Views
18 Pages

A DFT Study of CO Hydrogenation on Graphene Oxide: Effects of Adding Mn on Fischer–Tropsch Synthesis

  • Hanieh Bakhtiari,
  • Saeedeh Sarabadani Tafreshi,
  • Mostafa Torkashvand,
  • Majid Abdouss and
  • Nora H. de Leeuw

28 April 2024

The hydrogenation of carbon monoxide (CO) offers a promising avenue for reducing air pollution and promoting a cleaner environment. Moreover, by using suitable catalysts, CO can be transformed into valuable hydrocarbons. In this study, we elucidate t...

  • Feature Paper
  • Article
  • Open Access
6 Citations
4,725 Views
19 Pages

26 April 2024

Coke formation poses a significant obstacle in the direct conversion of methane into valuable chemicals such as ethylene, benzene, and hydrogen via methane dehydro-aromatization (MDA). At the elevated temperatures necessary for this reaction, coke is...

  • Article
  • Open Access
10 Citations
3,805 Views
12 Pages

Three-Dimensional Mesoporous Ni-CeO2 Catalyst for Dry Reforming of Methane

  • Huiyao Jin,
  • Yuanqiao Liu,
  • Lizhi Huang,
  • Yali Liu,
  • Sha Cui,
  • Hui Liu,
  • Jing Xu and
  • Luhui Wang

26 April 2024

Using the colloidal solution combustion approach, a three-dimensional mesoporous 5%Ni-CeO2-M catalyst was developed, with Ni incorporated into the pores, and applied in the dry reforming of methane. Comprehensive characterization revealed that the 5%...

  • Feature Paper
  • Review
  • Open Access
13 Citations
3,532 Views
29 Pages

25 April 2024

Mesoporous/hierarchical zeolites (HZs) are a relatively new group of materials, and interest in their application in catalysis is continuously growing. This paper presents recent achievements in the application of mesoporous zeolites in catalytic rea...

  • Article
  • Open Access
1 Citations
2,184 Views
12 Pages

Photoelectrocatalytic Reduction of Cr(VI) in Wastewater with a CuBi2O4 Thin Film Photocathode

  • Sai An,
  • Ying Wang,
  • Huajian Qiao,
  • Hao Xiu,
  • Deyu Liu and
  • Yongbo Kuang

25 April 2024

Photoelectrocatalytic approaches show promise for contaminate removal in wastewater through redox reactions. However, the direct treatment of very low concentration heavy metals is a challenging task. Copper bismuth oxide is considered as a potential...

  • Article
  • Open Access
2,641 Views
20 Pages

One-Step Production of Highly Selective Ethylbenzene and Propylbenzene from Benzene and Carbon Dioxide via Coupling Reaction

  • Tianyun Wang,
  • Yingjie Guan,
  • Haidan Wu,
  • Zhaojie Su,
  • Jianguo Zhuang,
  • Siyan Yan,
  • Xuedong Zhu and
  • Fan Yang

24 April 2024

Utilizing carbon dioxide as a carbon source for the synthesis of olefins and aromatics has emerged as one of the most practical methods for CO2 reduction. In this study, an improved selectivity of 85% for targeting products (ethylbenzene and propylbe...

  • Article
  • Open Access
3 Citations
2,084 Views
17 Pages

Optimizing the Incorporation Modes of TiO2 in TiO2-Al2O3 Composites for Enhancing Hydrodesulfurization Performance of Corresponding NiMoP-Supported Catalysts

  • Ranran Hou,
  • Qinghe Yang,
  • Shuangqin Zeng,
  • Jun Bao,
  • Hong Nie,
  • Chuangchuang Yang,
  • Yanzi Jia,
  • Anpeng Hu and
  • Qiaoling Dai

24 April 2024

TiO2-Al2O3 supports with different incorporation methods of titania were synthesized via three methods: impregnation (TA-I), co-precipitation (TA-CP), and co-precipitation–hydrothermal treatment (TA-HT). And the NiMoP catalysts prepared on the...

  • Feature Paper
  • Article
  • Open Access
5 Citations
2,906 Views
17 Pages

Valorization of Chlorella Microalgae Residual Biomass via Catalytic Acid Hydrolysis/Dehydration and Hydrogenolysis/Hydrogenation

  • Antigoni G. Margellou,
  • Stylianos A. Torofias,
  • Georgios Iakovou and
  • Konstantinos S. Triantafyllidis

23 April 2024

Microalgal biomass can be utilized for the production of value-added chemicals and fuels. Within this research, Chlorella vulgaris biomass left behind after the extraction of lipids and proteins was converted to valuable sugars, organic acids and fur...

  • Article
  • Open Access
2,701 Views
12 Pages

Enhancing Oxygen Evolution Reaction with Two-Dimensional Nickel Oxide on Au (111)

  • Handing Zhang,
  • Haoyu Zhang,
  • Ruijing Wang,
  • Jiayu Lv,
  • Wugen Huang,
  • Chenyan Guo and
  • Fan Yang

23 April 2024

The nature of the active sites of transition metal oxides during the oxygen evolution reaction (OER) has attracted much attention. Herein, we constructed well-defined nickel oxide/Au (111) model catalysts to study the relationship between the structu...

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Catalysts - ISSN 2073-4344