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Ceramics, Volume 6, Issue 3

2023 September - 38 articles

Cover Story: This paper investigates the influence of the morphology of cermet anodes for proton ceramic fuel cells (PCFCs) on their anodic performance. Ni-cermet anode films based on BaCe0.4Zr0.4Y0.2O3−δ (BCZY) and Gd0.1Ce0.9Ox (GDC), that is, 60 wt%Ni–BCZY, 60 wt%Ni–BCZY–GDC, and 60 wt%Ni–GDC, were formed on BCZY electrolyte supports. The Ni grain size in these films after sintering at 1450 °C was around 2 µm. The addition of GDC did not affect the Ni grain size in the case of the porous BCZY matrix. The anodic properties greatly depended on the oxide-phase composition and worsened with an increase in the GDC content. This probably occurred because the addition of GDC, which has low proton conductivity, inhibited the proton conduction path of BCZY, reducing three-phase boundaries in the anode bulk. View this paper
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Articles (38)

  • Article
  • Open Access
2,269 Views
13 Pages

Compositionally Disordered Ceramic (Gd,Y,Tb,Ce)3Al2Ga3O12 Phosphor for an Effective Conversion of Isotopes’ Ionizing Radiation to Light

  • Mikhail V. Korzhik,
  • Petr V. Karpyuk,
  • Aliaksei G. Bondarau,
  • Daria E. Lelecova,
  • Vitaly A. Mechinsky,
  • Vladimir Pustovarov,
  • Vasilii Retivov,
  • Valentina G. Smyslova,
  • Dmitry Tavrunov and
  • Denis N. Yanushevich

21 September 2023

Compositionally disordered crystalline material (Gd,Y,Tb,Ce)3Al2Ga3O12 was demonstrated to be a highly effective converter of corpuscular ionizing radiation into light. The material was found to be radiation-tolerant to an intense 10 MeV electron bea...

  • Communication
  • Open Access
1 Citations
2,461 Views
6 Pages

11 September 2023

Electroluminescence of metal halide perovskites has been widely reported via the fabrication and optimization of light-emitting diodes and light-emitting transistors. Light-emitting transistors are particularly interesting owing to the additional con...

  • Article
  • Open Access
23 Citations
2,596 Views
15 Pages

Analytical Model of Deformation of a Functionally Graded Ceramic Coating under Local Load

  • Ivan Shatskyi,
  • Mykola Makoviichuk,
  • Liubomyr Ropyak and
  • Andrii Velychkovych

7 September 2023

In this article, an analytical approach to the study of the behavior of functionally graded FG coatings under local load is developed. The method is suitable for coatings with a specific structure. We consider that the coating can be conditionally di...

  • Article
  • Open Access
18 Citations
3,838 Views
18 Pages

6 September 2023

Geopolymer concrete is gaining recognition as an environmentally friendly alternative to traditional cement-based materials, offering potential solutions for reducing the carbon emissions of the construction industry. This study aims to develop GGBFS...

  • Article
  • Open Access
2 Citations
3,340 Views
11 Pages

Anodic Performance of Ni–BCZY and Ni–BCZY–GDC Films on BCZY Electrolytes

  • Yoshiteru Itagaki,
  • Yota Kumamoto,
  • Susumu Okayama and
  • Hiromichi Aono

5 September 2023

Cermet films consisting of Ni, BaCe0.4Zr0.4Y0.2O3−δ (BCZY), and Gd0.1Ce0.9Ox (GDC), specifically, 60 wt%Ni–BCZY, 60 wt%Ni–BCZY–GDC, and 60 wt%Ni–GDC, were formed on BCZY electrolyte supports as anodes of proton cer...

  • Article
  • Open Access
1 Citations
2,004 Views
10 Pages

Phase Formation and Properties of Multicomponent Solid Solutions Based on Ba(Ti, Zr)O3 and AgNbO3 for Environmentally Friendly High-Efficiency Energy Storage

  • Dmitry V. Volkov,
  • Ekaterina V. Glazunova,
  • Lydia A. Shilkina,
  • Aleksandr V. Nazarenko,
  • Aleksey A. Pavelko,
  • Vyacheslav A. Bobylev,
  • Larisa A. Reznichenko and
  • Ilya A. Verbenko

26 August 2023

This paper investigates the processes of phase formation of solid solutions of (1 − x)BaTi0.85Zr0.15O3xAgNbO3 where x = 0, 0.03, 0.06, 0.09. The optimal temperatures of synthesis and sintering are determined. From the results of X-ray...

  • Article
  • Open Access
1 Citations
2,294 Views
14 Pages

An Investigation of Iodovanadinite Wasteforms for the Immobilisation of Radio-Iodine and Technetium

  • Daniel J. Bailey,
  • Erik V. Johnstone,
  • Martin C. Stennett,
  • Claire L. Corkhill and
  • Neil C. Hyatt

24 August 2023

99Tc and 129I are two long-lived, highly soluble and mobile fission products that pose a long-term hazard. A proposed wasteform for the disposal of radio-iodine is iodovanadinite (Pb5(VO4)3I), an apatite-structured vanadate. In this investigation, a...

  • Review
  • Open Access
18 Citations
7,187 Views
27 Pages

Nutrient-Doped Hydroxyapatite: Structure, Synthesis and Properties

  • Mohamed Ammar,
  • Sherif Ashraf and
  • Jonas Baltrusaitis

22 August 2023

Complex inorganic powders based on calcium phosphates have found a plethora of practical applications. Of particular interest are the CaO-P2O5 system-based multi-component material powders and granules as the source of major- and micronutrients for t...

  • Article
  • Open Access
9 Citations
3,292 Views
11 Pages

21 August 2023

In the present work, the influence of alkali ions (Li, Na, K) on the structural and spectroscopic properties of silica glasses doped with Sm3+ was investigated. Infrared and Raman spectroscopy techniques were used to investigate the structural proper...

  • Article
  • Open Access
5 Citations
2,825 Views
23 Pages

Alkali-Activated Brick Aggregates as Industrial Valorized Wastes: Synthesis and Properties

  • Abdel Boughriet,
  • Oscar Allahdin,
  • Nicole Poumaye,
  • Gildas Doyemet,
  • Grégory Tricot,
  • Bertrand Revel,
  • Baghdad Ouddane and
  • Michel Wartel

14 August 2023

In recent works, many industrial by-products were employed as solid precursors for the synthesis of alkali-activated binders and as alternatives to Portland cement for the immobilization of hazardous, toxic and nuclear wastes. Among industrial wastes...

  • Review
  • Open Access
22 Citations
5,797 Views
16 Pages

Geopolymer Antimicrobial and Hydrophobic Modifications: A Review

  • Vojtěch Růžek,
  • Jan Novosád and
  • Katarzyna Ewa Buczkowska

11 August 2023

The article summarizes the state of the art in increasing antimicrobial activity and hydrophobic properties of geopolymer materials. Geopolymers are inorganic polymers formed by polycondensation of aluminosilicate precursors in an alkaline environmen...

  • Article
  • Open Access
3 Citations
1,858 Views
14 Pages

Structure and Relaxor Behavior of (0.5 − x)BiFeO3-0.5PbFe0.5Nb0.5O3-xPbTiO3 Ternary Ceramics

  • Nikita A. Boldyrev,
  • Eugene I. Sitalo,
  • Lidia A. Shilkina,
  • Alexander V. Nazarenko,
  • Andrei D. Ushakov,
  • Vladimir Y. Shur,
  • Larisa A. Reznichenko and
  • Ekaterina V. Glazunova

8 August 2023

Ceramics of the quasi-binary concentration section (0.1 ≤ x ≤ 0.2, Δx = 0.025) of the ternary solid solution system (0.5 − x)BiFeO3-0.5PbFe0.5Nb0.5O3-xPbTiO3 were prepared by the conventional solid-phase reaction method. An X-ray st...

  • Review
  • Open Access
14 Citations
4,933 Views
30 Pages

6 August 2023

This review outlines the state of the art, processing techniques, and mechanical testing methods of zirconia (ZrO2)-based composites reinforced by carbon nanotubes (CNTs). The use of CNTs as a secondary phase in a zirconia matrix is motivated by thei...

  • Review
  • Open Access
13 Citations
5,802 Views
23 Pages

3 August 2023

The production of conventional cement involves high energy consumption and the release of substantial amounts of carbon dioxide (CO2), exacerbating climate change. Additionally, the extraction of raw materials, such as limestone and clay, leads to ha...

  • Article
  • Open Access
8 Citations
2,192 Views
15 Pages

Porous Ceramic ZnO Nanopowders: Features of Photoluminescence, Adsorption and Photocatalytic Properties

  • Marianna Gavrilova,
  • Diana Gavrilova,
  • Sergey Evstropiev,
  • Andrey Shelemanov and
  • Igor Bagrov

2 August 2023

The grainy and porous ZnO powders were synthesized by thermal decomposition of zinc nitrate and polymer-salt method. The comparative study of the crystal structure, morphology, luminescence, adsorptive and photocatalytic properties of ZnO powders was...

  • Article
  • Open Access
3 Citations
4,627 Views
12 Pages

Synthesis and Characterization of Nd:YAG Ceramics for Laser Applications

  • Olga Alondra Echartea-Reyes,
  • Gloria Verónica Vázquez,
  • José Adalberto Castillo-Robles,
  • Juan López-Hernández,
  • Carlos Adrián Calles-Arriaga,
  • Wilian Jesús Pech-Rodríguez and
  • Enrique Rocha-Rangel

2 August 2023

Materials known as Nd:YAG are crystalline materials of the cubic system made from the neodymium-doped yttrium aluminum garnet, which, among others, have excellent optical properties. Nd:YAG four-level laser devices are frequently used in both the hea...

  • Article
  • Open Access
4 Citations
3,633 Views
9 Pages

Water-Glass-Assisted Foaming in Foamed Glass Production

  • Sonja Smiljanić,
  • Uroš Hribar,
  • Matjaž Spreitzer and
  • Jakob König

2 August 2023

The energy efficiency of buildings can be greatly improved by decreasing the energy embodied in installed materials. In this contribution, we investigated the possibility of foaming waste bottle glass in the air atmosphere with the addition of water...

  • Article
  • Open Access
7 Citations
2,409 Views
14 Pages

Effect of Diamond Phase Dispersion on the Properties of Diamond-SiC-Si Composites

  • Sergey P. Bogdanov,
  • Andrey S. Dolgin,
  • Sergey N. Perevislov,
  • Nikolay A. Khristyuk and
  • Maxim M. Sychov

28 July 2023

The research aimed at the composition optimization for diamond-SiC-Si composites. The effect of a porous diamond workpiece was studied on the properties (porosity, density, modulus of elasticity, phase composition) of the product of its siliconizatio...

  • Article
  • Open Access
8 Citations
3,483 Views
9 Pages

Phase Composition and Magnetic Properties of Nanoparticles with Magnetite–Maghemite Structure

  • Sergey I. Andronenko,
  • Anton M. Nikolaev,
  • Stanislav M. Suharzhevsky,
  • Alexander A. Sinelnikov,
  • Anastasia S. Kovalenko,
  • Alexandra G. Ivanova and
  • Olga A. Shilova

18 July 2023

Precipitation of nanopowders with mixed magnetite–maghemite composition was carried out under different conditions and with different separation techniques. The exact character of interactions of different iron oxide phases in the nanopowder wa...

  • Review
  • Open Access
13 Citations
3,937 Views
50 Pages

Zirconolite Matrices for the Immobilization of REE–Actinide Wastes

  • Sergey V. Yudintsev,
  • Maximilian S. Nickolsky,
  • Michael I. Ojovan,
  • Olga I. Stefanovsky,
  • Victor I. Malkovsky,
  • Amina S. Ulanova and
  • Lewis R. Blackburn

15 July 2023

The structural and chemical properties of zirconolite (ideally CaZrTi2O7) as a host phase for separated REE–actinide-rich wastes are considered. Detailed analysis of both natural and synthetic zirconolite-structured phases confirms that a selec...

  • Article
  • Open Access
5 Citations
4,239 Views
14 Pages

Bismuth-Germanate Glasses: Synthesis, Structure, Luminescence, and Crystallization

  • Ksenia Serkina,
  • Irina Stepanova,
  • Aleksandr Pynenkov,
  • Maria Uslamina,
  • Konstantin Nishchev,
  • Kirill Boldyrev,
  • Roman Avetisov and
  • Igor Avetissov

13 July 2023

Bismuth-germanate glasses, which are well known as a promising active medium for broadband near-infrared spectral range fiber lasers and as an initial matrix for nonlinear optical glass ceramics, have been synthesized in a 5–50 mol% Bi2O3 wide...

  • Article
  • Open Access
8 Citations
2,646 Views
13 Pages

Formation and Photophysical Properties of Silver Clusters in Bulk of Photo-Thermo-Refractive Glass

  • Leonid Yu. Mironov,
  • Dmitriy V. Marasanov,
  • Mariia D. Sannikova,
  • Ksenia S. Zyryanova,
  • Artem A. Slobozhaninov and
  • Ilya E. Kolesnikov

13 July 2023

The bright luminescence of silver clusters in glass have potential applications in solid-state lighting, optical memory, and spectral converters. In this work, luminescent silver clusters were formed in the bulk of photo-thermo-refractive glass (15Na...

  • Article
  • Open Access
4 Citations
2,347 Views
15 Pages

Magnesium Oxide Powder Synthesis in Cathodic Arc Discharge Plasma in an Argon Environment at Atmospheric Pressure

  • Dmitry Sorokin,
  • Konstantin Savkin,
  • Dmitry Beloplotov,
  • Viktor Semin,
  • Andrey Kazakov,
  • Alisa Nikonenko,
  • Alexander Cherkasov and
  • Konstantin Shcheglov

11 July 2023

Discharges with cathode spots can operate in a wide range of gas pressures. Erosion of the cathode material is an inherent property of such discharges. The erosion products are considered to be ionized atoms and electrically neutral microdroplets. In...

  • Review
  • Open Access
12 Citations
3,257 Views
14 Pages

11 July 2023

Zinc chalcogenides doped with Cr2+ or Fe2+ ions are of considerable interest as active media for IR lasers operating in the 2–5 µm wavelength range. Such lasers are in demand in various fields of medicine, remote sensing and atmospheric m...

  • Article
  • Open Access
2 Citations
1,979 Views
9 Pages

A Study of PbF2 Nanoparticles Crystallization Mechanism in Mixed Oxyde-Fluoride Glasses

  • Saule Dyussembekova,
  • Ekaterina Trusova,
  • Sergey Kichanov,
  • Kiril Podbolotov and
  • Denis Kozlenko

11 July 2023

Samples of nanocrystalline PbF2 glass ceramics were obtained by heat-treating SiO2–GeO2–PbO–PbF2–CdF2 glasses. The Ho2O3 and Tm2O3 doping effects on the structural features of PbF2 nanoparticles were studied using small-angle...

  • Article
  • Open Access
4 Citations
2,679 Views
18 Pages

Phase Transformations upon Formation of Transparent Lithium Alumosilicate Glass-Ceramics Nucleated by Yttrium Niobates

  • Olga Dymshits,
  • Anastasia Bachina,
  • Irina Alekseeva,
  • Valery Golubkov,
  • Marina Tsenter,
  • Svetlana Zapalova,
  • Kirill Bogdanov,
  • Dmitry Danilovich and
  • Alexander Zhilin

6 July 2023

Phase transformations in the lithium aluminosilicate glass nucleated by a mixture of yttrium and niobium oxides and doped with cobalt ions were studied for the development of multifunctional transparent glass-ceramics. Initial glass and glass-ceramic...

  • Article
  • Open Access
5 Citations
2,826 Views
12 Pages

Effect of a Phosphorus Additive on Luminescent and Scintillation Properties of Ceramics GYAGG:Ce

  • Lydia V. Ermakova,
  • Valentina G. Smyslova,
  • Valery V. Dubov,
  • Daria E. Kuznetsova,
  • Maria S. Malozovskaya,
  • Rasim R. Saifutyarov,
  • Petr V. Karpyuk,
  • Petr S. Sokolov,
  • Ilia Yu. Komendo and
  • Mikhail V. Korzhik
  • + 2 authors

6 July 2023

The production of scintillating ceramics can require the utilization of the phosphorus compounds at certain stages of 3D-printing, such as vat polymerization, applied for the formation of green bodies before sintering. The effect of phosphorus additi...

  • Article
  • Open Access
2,094 Views
11 Pages

Magnesium Oxide and Magnesium Fluoride Nanopowders Produced in a Diffuse Nanosecond Discharge in Argon

  • Dmitry Beloplotov,
  • Konstantin Savkin,
  • Viktor Semin and
  • Dmitry Sorokin

6 July 2023

The synthesis of the nanopowders of magnesium oxide and magnesium fluoride during the operation of a repetitive diffuse nanosecond discharge in argon at various pressures was performed. Nanosecond voltage pulses with an amplitude of −70 kV, a r...

  • Article
  • Open Access
26 Citations
16,196 Views
18 Pages

5 July 2023

The thermal insulation properties of building walls are critical to the overall energy efficiency and comfort of a building. One important factor that can affect these properties is the type of bricks used in construction. Bricks can vary in their ge...

  • Article
  • Open Access
3 Citations
2,753 Views
15 Pages

Materials in the CaO-K2O-SO3-H2O System Based on Powder Mixtures including Calciolangbeinite K2Ca2(SO4)3 and Calcium Sulfate Anhydrite CaSO4

  • Alexander I. Kuznetsov,
  • Tatiana V. Safronova,
  • Tatiana B. Shatalova,
  • Yaroslav Y. Filippov,
  • Leonid A. Vaymugin,
  • Vyacheslav S. Vlasenko and
  • Maxim S. Likhanov

5 July 2023

Materials (cement stone samples) in the CaO-K2O-SO3-H2O system with the target phase compositions, including syngenite K2Ca(SO4)2·H2O and calcium sulfate dihydrate CaSO4·2H2O, were prepared from powder mixtures of calcium sulfate anhydr...

  • Article
  • Open Access
4 Citations
2,028 Views
19 Pages

Application the Ion Beam Sputtering Deposition Technique for the Development of Spin-Wave Structures on Ferroelectric Substrates

  • Sergei A. Sharko,
  • Aleksandra I. Serokurova,
  • Nikolay N. Novitskii,
  • Valerii A. Ketsko and
  • Alexandre I. Stognij

5 July 2023

The microwave properties of structures in the form of the 2 μm iron-yttrium garnet (YIG) films, grown by the ion beam sputtering deposition method on epitaxially mismatched substrates of ferroelectric ceramics based on lead zirconate titanate (PZT...

  • Article
  • Open Access
5 Citations
3,681 Views
18 Pages

Carbonate-Hydroxyapatite Cement: The Effect of Composition on Solubility In Vitro and Resorption In Vivo

  • Yulia Lukina,
  • Leonid Bionyshev-Abramov,
  • Sergey Kotov,
  • Natalya Serejnikova,
  • Dmitriiy Smolentsev and
  • Sergey Sivkov

3 July 2023

The rate of resorption of calcium phosphate self-hardening materials for bone regeneration can be changed by changing the phase composition. The Ca3(PO4)2/CaCO3/Ca(H2PO4)2·H2O/Na2HPO4·12H2O system is important for the synthesis of self-...

  • Article
  • Open Access
8 Citations
3,612 Views
13 Pages

An Anode-Supported Solid Oxide Fuel Cell (SOFC) Half-Cell Fabricated by Hybrid 3D Inkjet Printing and Laser Treatment

  • Inna Malbakhova,
  • Artem Bagishev,
  • Alexander Vorobyev,
  • Tatiana Borisenko,
  • Olga Logutenko,
  • Elizaveta Lapushkina and
  • Alexander Titkov

30 June 2023

A NiO-10YSZ/10YSZ half-cell for anode-supported solid oxide fuel cells (SOFCs) was fabricated using 3D inkjet printing and layer-by-layer laser treatment of printing compositions followed by thermal sintering by a co-firing method. The optimal granul...

  • Article
  • Open Access
8 Citations
4,203 Views
19 Pages

28 June 2023

This exploratory study examines the potential of combining clay and natural fiber material in liquid deposition modeling (LDM) to enhance the structural integrity of the soft-bodied print during the additive manufacturing (AM) process. For this purpo...

  • Article
  • Open Access
12 Citations
2,844 Views
17 Pages

New Glasses in the PbCl2–PbO–B2O3 System: Structure and Optical Properties

  • Dmitry Butenkov,
  • Anna Bakaeva,
  • Kristina Runina,
  • Igor Krol,
  • Maria Uslamina,
  • Aleksandr Pynenkov,
  • Olga Petrova and
  • Igor Avetissov

27 June 2023

New oxychloride lead borate glasses in the xPbCl2–(50-0.5x)PbO–(50-0.5x)B2O3 system were synthesized with a maximum lead chloride content of 40 mol%. The characteristic temperatures and mechanical and optical properties were studied. The...

  • Review
  • Open Access
6 Citations
3,761 Views
18 Pages

22 June 2023

Should the decision be made to immobilise the UK Pu inventory through a campaign of Hot Isostatic Pressing (HIP) in a zirconolite matrix, prior to placement in a geological disposal facility (GDF), a suite of disposability criteria must be satisfied....

  • Article
  • Open Access
3 Citations
3,427 Views
16 Pages

Barium Silicate Glasses and Glass–Ceramic Seals for YSZ-Based Electrochemical Devices

  • Alyona Vepreva,
  • Dmitry Dubovtsev,
  • Daria Krainova,
  • Yulia Chetvertnykh,
  • Semyon Belyakov,
  • Nailya Saetova and
  • Anton Kuzmin

22 June 2023

The effect of partial SiO2 substitution with Al2O3 and B2O3 on the thermal properties and crystallization of glass sealants in the (50 − x)SiO2–30BaO–20MgO–xAl2O3(B2O3) (wt %) system is studied. It is established that the coef...

  • Article
  • Open Access
1 Citations
2,199 Views
12 Pages

Fabrication of Segments for ZnO-Based Tube Ceramic Targets by the Spark Plasma Sintering Method

  • Akhmed K. Akhmedov,
  • Abil Sh. Asvarov,
  • Soslan Sh. Makhmudov and
  • Vladimir M. Kanevsky

21 June 2023

In this article, problems associated with the fabrication of ZnO-based ceramics in the form of large-diameter hollow cylinders with a large ratio of height h to wall thickness ∆r (h/∆r ≥ 3) by the spark plasma sintering (SPS) method we...

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Ceramics - ISSN 2571-6131