Catalysts, Volume 11, Issue 1

There is significant environmental concern about chlorinated organic compounds (COCs) in wastewater, surface water, and groundwater due to their low biodegradability and high persistence. In this work, 1,2,4-trichlorobenzene (124-TCB) was selected as...

Recent studies have highlighted the therapeutic and ergogenic potential of the ketone body ester, (R)-3-hydroxybutyl-(R)-3-hydroxybutyrate. In the present work, the enzymatic synthesis of this biological active compound is reported. The (R)-3-hydroxy...

Molybdenum phosphide (MoP) catalyzes the hydrogenation of CO, CO₂, and their mixtures to methanol, and it is investigated as a high-activity catalyst that overcomes deactivation issues (e.g., formate poisoning) faced by conventional transition metal...

In this work, a detailed computational study on a recently synthetized Mn(I)-dependent complex [(^tBuPNNOP)Mn(CO)₂]⁺ is reported. This species promotes the dehydrogenation of formic acid to carbon dioxide and hydrogen. The here proposed catalytic cycl...

In recent years, we have experienced extreme climate changes due to the global warming, continuously impacting and changing our daily lives. To build a sustainable environment and society, various energy technologies have been developed and introduce...

This article presents an overview of the reports on the doping of TiO₂ with carbon, nitrogen, and sulfur, including single, co-, and tri-doping. A comparison of the properties of the photocatalysts synthesized from various precursors of TiO₂ and C, N...

Rare ginsenoside Rh2 exhibits diverse pharmacological effects. UDP-glycosyltransferase (UGT) catalyzed glycosylation of protopanaxadiol (PPD) has been of growing interest in recent years. UDP-glycosyltransferase Bs-YjiC coupling sucrose synthase in o...

This work focuses on the support effect of the performances of Co based catalysts for acetic acid steam reforming. SBA-15, a well ordered hexagonal mesoporous silica structure, and CeO₂ have been selected as the supports, with the impact of chromium...

A biocatalytic cascade system using a cocktail of oxidoreductase enzymes (2-1B peroxidase and M120 laccase) was designed for the allylic oxidation of (+)-α-pinene into value-added products (e.g., verbenol and verbenone). The oxidative transform...

Novel flower-shaped C-dots/Co₃O₄{111} with dual-reaction centers were constructed to improve the Fenton-like reaction activity and peroxymonosulfate (PMS) conversion to sulfate radicals. Due to the exposure of a high surface area and Co₃O₄{111} facet...

In the synthesis method of a BiVO₄ photoanode via BiOI flakes, a BiOI film is formed by electrochemical deposition in Step 1, and a vanadium (V) source solution is placed by drop-casting on the BiOI film in Step 2. Following this, BiVO₄ particles are...

Four vinyl polymer gels (VPGs) were synthesized by free radical polymerization of divinylbenzene, ethane-1,2-diyl dimethacrylate, and copolymerization of divinylbenzene with styrene, and ethane-1,2-diyl dimethacrylate with methyl methacrylate, as sup...

Improved yields of, and selectivities to, value-added products synthesised from glycerol are shown to be achieved through the judicious selection of dehydrating agents and through the development of improved catalysts. The direct carboxylation of gly...

Catalytic propane dehydrogenation is an attractive method to produce propylene while avoiding the issues of its traditional synthesis via naphtha steam cracking of naphtha. In this contribution, a series of Pt-Sn/SBA-16 catalysts were synthesized and...

Susceptibility of soybean phosphatidylcholine, 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) and its phosphono analogue (R)-2,3-dipalmitoyloxypropylphosphonocholine (DPPnC) towards selected lipases and phospholipases was compared. The ethanolysi...

Multi-metallic Pd@FePt core–shell nanoparticles were synthesized using a direct seed-mediated growth method, consisting of facile and mild procedures, to increase yield. The Fe/Pt ratio in the shell was easily controlled by adjusting the amount...

Carbon monoxide (CO) oxidation is considered an important reaction in heterogeneous industrial catalysis and has been extensively studied. Pd supported on SiO₂ aerogel catalysts exhibit good catalytic activity toward this reaction owing to their CO b...

The current climate crisis warrants investigation into alternative fuel sources. The hydrolysis reaction of an aqueous hydride precursor, and the subsequent production of hydrogen gas, prove to be a viable option. A network of beta-cyclodextrin cappe...

Two different preparation methods, viz. incipient impregnation and mechanical mixing, have been used to prepare V-based oxygen carriers with different V loadings for chemical looping oxidative dehydrogenation of propane. The effect of the preparation...

A facile, sustainable method for the selective modification of aliphatic hydroxy (R–OH) groups in Kraft lignin was developed using an ionic liquid, 1-ethyl-3-methylimidazolium acetate (EmimOAc), as a solvent and catalyst. Selective R–OH m...

Ni-based catalysts are prone to agglomeration and carbon deposition at high temperatures. Therefore, the development of Ni-based catalysts with high activities at low temperatures is a very urgent and challenging research topic. Herein, Ni-based nano...

The first remarkable property associated to metallophthalocyanines (MPcs) was their chemical “inertness”, which made and make them very attractive as stable and durable industrial dyes. Nevertheless, their rich redox chemistry was also ex...

Recently, there have been numerous efforts to develop hydrogen-rich organic materials because hydrogen energy is emerging as a renewable energy source. In this regard, we designed and prepared four new materials based on N-alkyl-bis(carbazole), 9,9&p...

Today, the theme of environmental preservation plays an important role within the activities of the scientific community and influences the choices of politics and the common population. In this context, the use of non-fossil substances should be pro...

In this study, the contamination of H⁺ZSM-5 catalyst by calcium, potassium and sodium was investigated by deactivating the catalyst with various concentrations of these inorganics, and the subsequent changes in the properties of the catalyst are repo...

In this work, the PIL (poly ionic liquid)@TiO₂ composite was designed with two polymerized ionic liquid concentrations (low and high) and evaluated for pollutant degradation activity for benzene and toluene. The results showed that PIL (low)@TiO₂ com...

As a promising material for heterogeneous catalytic applications, layered iron (II) monosulfide (FeS) contains active edges and an inert basal (001) plane. Activating the basal (001) plane could improve the catalytic performance of the FeS material t...

Two different methods of simulating iron contamination in a laboratory were studied. The catalysts were characterized using X-ray diffraction, N₂ adsorption–desorption, and SEM-EDS. The catalyst performance was evaluated using an advanced crack...

In this study, we elucidate the reaction kinetics for the simultaneous hydrodeoxygenation of xylitol to 1,2-dideoxypentitol and 1,2,5-pentanetriol over a ReO_x-Pd/CeO₂ (2.0 weight% Re, 0.30 weight% Pd) catalyst. The reaction was determined to be a zer...

Titanium oxide (TiO₂) is a potential photocatalyst for removing toxic NO_x from the atmosphere. Its practical application is, however, significantly limited by its low absorption into visible light and a high degree of charge recombination. The overal...

The glycerol hydrogenolysis to produce 1,2-propanediol without using externally supplied hydrogen was investigated using methanol present in crude glycerol to provide in situ hydrogen via its steam reforming reaction. This paper focuses on the promot...

One of the challenges of using nanoparticles as catalysts is the presence of reaction-disturbing stabilizers that surround the nanoparticle surface. In this report, we demonstrate a method to synthesize stabilizer-free bismuth oxychloride (BiOCl) nan...

Carbon spheres were applied as templates to synthesize titanium dioxide hollow spheres. The templates were purified with either ethanol or acetone, and the effects of this treatment on the properties of the resulting titania were investigated. The ph...

In the paper, mesopores and macropores are introduced inside the crystals of micrometer microporous titanium silicate-1 (TS-1) to solve the problem of active site coverage and mass transfer during extrusion. Hierarchically porous titanium silicalite-...

Chalcogen-nitrogen chemistry deals with systems in which sulfur, selenium, or tellurium is linked to a nitrogen nucleus. This chemical motif is a key component of different functional structures, ranging from inorganic materials and polymers, to rati...

Oxidation of 5-hydroxymethylfurfural (HMF), a major feedstock derived from waste/fresh biomass, into 2,5-furandicarboxylic acid (FDCA) is an important transformation for the production of biodegradable plastics. Herein, we investigated the effect of...

Infrared spectroscopy is typically not used to establish the oxidation state of metal-based catalysts. In this work, we show that the baseline of spectra collected in diffuse reflectance mode of a series of Pd/Al₂O₃ samples of increasing Pd content v...

Degradation of organic dyes and their byproducts by heterogeneous photocatalysts is an essential process, as these dyes can be potentially discharged in wastewater and threaten aquatic and xerophyte life. Therefore, their complete mineralization into...

Energy policies in the US and in the EU during the last decades have been focused on enhanced oil and gas recovery, including the so-called tertiary extraction or enhanced oil recovery (EOR), on one hand, and the development and implementation of ren...

Co–Fe–Al catalysts prepared using coprecipitation at laboratory scale were investigated and extended to pilot scale for high-calorific synthetic natural gas. The Co–Fe–Al catalysts with different metal loadings were analyzed u...

Well-designed composite photocatalysts are of increasing concern due to their enhanced catalytic performance compared to a single component. Here, a photocatalyst composed of PbMoO₄ (PMO) and poly-benzothiadiazole (BBT, a D-A-conjugated polymer) was...

This work presents a comparative study of the efficiency of two commercial TiO₂ photocatalysts, Aeroxide P25 (ATiO₂) and Sachtleben Hombikat UV100 (HTiO₂), in H₂ production from an aqueous solution of naphthalene. The TiO₂ photocatalysts were platini...

The present work reports the effects of γ-, θ-phase of alumina on the hydrothermal stability and the properties of non- and strongly-interacting Rh species of the Rh/Al₂O₃ catalysts. Comparing to γ-Al₂O₃, θ-Al₂O₃ can not only...

The search for economic and sustainable sources of polyunsaturated fatty acids (PUFAs) within the framework of the circular economy is encouraged by their proven beneficial effects on health. The extraction of monkfish liver oil (MLO) for the synthes...

A novel solvothermal technique has been developed in the presence of C/N/B precursor for synthesizing B-N-coped graphene quantum dots (GQDs) as non-metal electrocatalysts towards the catalytic glucose oxidation reaction (GOR). Both N-doped GQD and B-...

Electrooxidation of urea plays a substantial role in the elimination of urea-containing wastewater and industrial urea. Here, we report the electrodeposition of nickel hydroxide catalyst on commercial carbon paper (CP) electrodes from dimethyl sulpho...

In this study, zeolitic imidazolate framework (ZIF-67) derived nano-porous carbon structures that were further hybridized with MnO₂ were tested for oxygen reduction reaction (ORR) as cathode material for fuel cells. The prepared electrocatalyst was c...

The constant growth of energy demand joined with the adverse effects on the global environment induced by use of fossil fuels is increasingly requiring new routes to obtain clean and renewable energy sources [...]

The crude glycerol is produced during the transesterification of animal fats and vegetable oils, but it is a by-product of this process. Currently, its elimination is a problem in the chemical industry. The main goal of this work was the preparation,...

Metal organic frameworks (MOFs) are porous crystalline solids whose frameworks are constituted by metal ions/nodes with rigid organic linkers leading to the formation of materials having high surface area and pore volume. One of the unique features o...