Skip Content
You are currently on the new version of our website. Access the old version .

Polymers, Volume 11, Issue 8

2019 August - 144 articles

Cover Story: Hydrogen bonding-generating events, including host–guest interactions at material surfaces, should open the door to the next generation of functional materials due to the promise of selective molecular recognition. In this context, we present the novel crown ether installation protocol which realized the attachment of crown ethers onto fluoropolymer surfaces based on the combination of radiation-induced graft polymerization and a subsequent surface Kabachnik–Fields three-component reaction. The obtained crown ether-tethered fluoropolymer films exhibited an ammonium cation-capturing ability, owing to the host–guest interactions (i.e., hydrogen bonding) between the surface-anchored crown ether molecules and the guest ammonium cations. View this paper.
  • Issues are regarded as officially published after their release is announced to the table of contents alert mailing list .
  • You may sign up for email alerts to receive table of contents of newly released issues.
  • PDF is the official format for papers published in both, html and pdf forms. To view the papers in pdf format, click on the "PDF Full-text" link, and use the free Adobe Reader to open them.

Articles (144)

  • Article
  • Open Access
32 Citations
4,684 Views
12 Pages

Impact of CO2 on Pyrolysis Products of Bituminous Coal and Platanus Sawdust

  • Ying Luo,
  • Haoxi Ben,
  • Zhihong Wu,
  • Kai Nie,
  • Guangting Han and
  • Wei Jiang

20 August 2019

Abundant studies have been completed about factors on the pyrolysis of coal and biomass. However, few articles laid emphasis on using CO2 as a carrier gas to explore the compositional changes of pyrolysis products in coal and biomass pyrolysis for in...

  • Review
  • Open Access
86 Citations
11,578 Views
24 Pages

Advances in Biodegradable Nano-Sized Polymer-Based Ocular Drug Delivery

  • Courtney Lynch,
  • Pierre P. D. Kondiah,
  • Yahya E. Choonara,
  • Lisa C. du Toit,
  • Naseer Ally and
  • Viness Pillay

20 August 2019

The effective delivery of drugs to the eye remains a challenge. The eye has a myriad of defense systems and physiological barriers that leaves ocular drug delivery systems with low bioavailability profiles. This is mainly due to poor permeability thr...

  • Article
  • Open Access
19 Citations
5,104 Views
12 Pages

Enhanced l-Lysine into 1,5-Diaminopentane Conversion via Statistical Optimization of Whole-Cell Decarboxylation System

  • Hanyong Kim,
  • Hah Young Yoo,
  • Nohseong Park,
  • Haeun Kim,
  • Jonghwa Lee,
  • Yesol Baek,
  • Taek Lee,
  • Jong-Min Oh,
  • Jaehoon Cho and
  • Chulhwan Park

20 August 2019

The global lysine companies in the feed industry have steadily built their production facilities due to the high demand for l-lysine in animal farms, and in recent years there have been excessive supply problems and the world market price of l-lysine...

  • Article
  • Open Access
24 Citations
7,089 Views
11 Pages

20 August 2019

A simplified radiation-induced emulsion graft polymerization (SREG) method is proposed. This method involves a convenient and easy degassing process of a monomer solution using a commercially available sealed glass jar. A loaded weight on the lid of...

  • Article
  • Open Access
41 Citations
10,201 Views
18 Pages

Preparation and Properties of Rubber Blends for High-Damping-Isolation Bearings

  • Tuo Lei,
  • Yong-Wang Zhang,
  • Dong-Liang Kuang and
  • Yong-Rui Yang

20 August 2019

To improve the energy dissipation capacity of rubber isolation bearings, it is important to find a new rubber material with good applicability and high damping properties. Two types of blends were prepared using nitrile rubber (NBR), brominated butyl...

  • Article
  • Open Access
55 Citations
5,963 Views
11 Pages

19 August 2019

Interfacial interaction is one of the most important factors that affect the mechanical properties of the fiber reinforced composites. The effect of fabrics′ sizing removal from glass fibers’ surface by thermal treatment on the mechanical...

  • Article
  • Open Access
22 Citations
4,384 Views
10 Pages

19 August 2019

Wood plastic composites (WPCs) incorporating graphene nano-platelets (GNPs) were fabricated using hot-pressed technology to enhance thermal and mechanical behavior. The influences of thermal filler content and temperature on the thermal performance o...

  • Article
  • Open Access
5 Citations
6,096 Views
12 Pages

Pyrene-Functionalized Polyacetylenes: Synthesis and Photoluminescence Property

  • Tanxiao Shen,
  • Nan Jiang,
  • Xiao’a Zhang,
  • Lirong He,
  • Xian Hua Lang,
  • Jing Zhi Sun and
  • Hui Zhao

19 August 2019

Four pyrene-functionalized polyacetylenes were designed and prepared through a typical post-polymerization modification route, which is the highly efficient reaction between activated ester and primary anime groups. The chemical structures of the res...

  • Article
  • Open Access
4 Citations
4,069 Views
16 Pages

19 August 2019

After a century of practice, cellulose insulating polymer (insulating paper/pressboard) has been shown to be one of the best and most widely used insulating materials in power transformers. However, with the increased voltage level of the transformer...

  • Article
  • Open Access
14 Citations
5,119 Views
20 Pages

FeNxC Based Catalysts Prepared by the Calcination of Iron-Ethylenediamine@Polyaniline as the Cathode-Catalyst of Proton Exchange Membrane Fuel Cell

  • Yen-Zen Wang,
  • Wen-Yao Huang,
  • Tar-Hwa Hsieh,
  • Li-Cheng Jheng,
  • Ko-Shan Ho,
  • Sin-Wei Huang and
  • Liang Chao

19 August 2019

Calcinated tris(ethylenediamine)iron(III) chloride was used as a non-precious metal catalyst (NPMCs) for a proton exchanged membrane fuel cell (PEMFC) under the protection of polyaniline (PANI), which behaves as both nitrogen source and carbon suppor...

  • Article
  • Open Access
4 Citations
4,022 Views
16 Pages

19 August 2019

Two coordination polymers (CPs) with chemical formulas, [Ho2(C4O4)2(C2O4)(H2O)8]·4H2O (1) and [Ho(C4O4)1.5(H2O)3] (2), (C4O42− = dianion of squaric acid, C2O42− = oxalate), have been synthesized and their structures were determined...

  • Communication
  • Open Access
27 Citations
5,770 Views
7 Pages

Functionalized Cellulose Nanocrystals: A Potential Fire Retardant for Polymer Composites

  • Dilpreet S Bajwa,
  • Chad Rehovsky,
  • Jamileh Shojaeiarani,
  • Nicole Stark,
  • Sreekala Bajwa and
  • Mark A Dietenberger

18 August 2019

The flammability of synthetic thermoplastic polymers has been recognized as an increasingly important safety problem. The goal of this study was to evaluate a green and safe fire-retardant system comprising of cellulose nanocrystals (CNC) and zinc ox...

  • Article
  • Open Access
13 Citations
5,396 Views
13 Pages

18 August 2019

Polyethylene (PE) membranes coated with nano-Al2O3 have been improved with water-dispersed poly(p-phenylene terephthamide) (PPTA). From the scanning electron microscope (SEM) images, it can be seen that a layer with a honeycombed porous structure is...

  • Article
  • Open Access
45 Citations
7,172 Views
21 Pages

Plasticization of Polylactide with Myrcene and Limonene as Bio-Based Plasticizers: Conventional vs. Reactive Extrusion

  • Berit Brüster,
  • Yann-Olivier Adjoua,
  • Reiner Dieden,
  • Patrick Grysan,
  • Carlos Eloy Federico,
  • Vincent Berthé and
  • Frédéric Addiego

18 August 2019

Polylactide (PLA) was blended by conventional and reactive extrusion with limonene (LM) or myrcene (My) as bio-based plasticizers. As-processed blends were carefully analyzed by a multiscale and multidisciplinary approach to tentatively determine the...

  • Article
  • Open Access
10 Citations
5,117 Views
12 Pages

16 August 2019

Graphene/carbon paper is prepared by pyrolyzing graphene modified cellulose filter paper and directly used as a binder-free electrode to assemble a supercapacitor (SC) with a redox active electrolyte, containing a Fe3+/Fe2+ additive. By the graphene...

  • Article
  • Open Access
96 Citations
9,182 Views
18 Pages

Effect of Graphene Oxide Coating on Natural Fiber Composite for Multilayered Ballistic Armor

  • Ulisses Oliveira Costa,
  • Lucio Fabio Cassiano Nascimento,
  • Julianna Magalhães Garcia,
  • Sergio Neves Monteiro,
  • Fernanda Santos da Luz,
  • Wagner Anacleto Pinheiro and
  • Fabio da Costa Garcia Filho

16 August 2019

Composites with sustainable natural fibers are currently experiencing remarkably diversified applications, including in engineering industries, owing to their lower cost and density as well as ease in processing. Among the natural fibers, the fiber e...

  • Article
  • Open Access
29 Citations
5,077 Views
15 Pages

16 August 2019

In this work, the effects of utilizing an Fe2+/Fe3+ redox-active electrolyte and Fe2+-doped polyaniline (PANI) electrode material on the performance of an assembled supercapacitor (SC) were studied. The concentration of the redox couple additive in t...

  • Article
  • Open Access
3 Citations
4,034 Views
11 Pages

16 August 2019

One-atom-thick materials hold promise for the future of membrane-based gas purification and water filtration applications. However, there are a few investigations on the mechanical properties of these materials under pressure-driven condition. Here,...

  • Article
  • Open Access
33 Citations
5,523 Views
13 Pages

Dielectric and Thermal Conductivity of Epoxy Resin Impregnated Nano-h-BN Modified Insulating Paper

  • Hongda Yang,
  • Qingguo Chen,
  • Xinyu Wang,
  • Minghe Chi,
  • Heqian Liu and
  • Xin Ning

16 August 2019

Epoxy resin-impregnated insulation paper (RIP) composites are used as the inner insulation of dry condenser bushing in the ultra-high voltage direct current (UHVDC) power transmission system. To improve the dielectric properties and heat conductivity...

  • Article
  • Open Access
12 Citations
6,065 Views
16 Pages

16 August 2019

We investigated the self-assembled structures and photoresponsive and crystallization behaviors of supramolecules composed of 4-methoxy-4′-hydroxyazobenzene (Azo) molecules and polyethylene glycol (PEG) that were formed through hydrogen-bonding...

  • Article
  • Open Access
17 Citations
4,793 Views
16 Pages

Ultrasonic Thermal-Assisted Extraction of Phosvitin from Egg Yolk and Evaluation of Its Properties

  • Bin Jiang,
  • Linlin Wang,
  • Xiaojing Wang,
  • Shuang Wu,
  • Dongmei Li,
  • Chunhong Liu and
  • Zhibiao Feng

15 August 2019

Phosvitin (Pv) is the principal phosphoprotein in chicken egg yolk and the most highly phosphorylated protein in nature. Pv is a good natural food antioxidant and emulsifier. However, the current extraction methods present disadvantages of complicate...

  • Article
  • Open Access
68 Citations
8,669 Views
15 Pages

Optimization of the Curing and Post-Curing Conditions for the Manufacturing of Partially Bio-Based Epoxy Resins with Improved Toughness

  • Diego Lascano,
  • Luis Quiles-Carrillo,
  • Sergio Torres-Giner,
  • Teodomiro Boronat and
  • Nestor Montanes

15 August 2019

This research deals with the influence of different curing and post-curing temperatures on the mechanical and thermomechanical properties as well as the gel time of an epoxy resin prepared by the reaction of diglycidyl ether of bisphenol A (DGEBA) wi...

  • Article
  • Open Access
39 Citations
7,551 Views
15 Pages

14 August 2019

Injection molding is a mature technology that has been used for decades; factors including processed raw materials, molds and machines, and the processing parameters can cause significant changes in product quality. Traditionally, researchers have at...

  • Article
  • Open Access
60 Citations
6,345 Views
15 Pages

Factorial Design and Optimization of Landfill Leachate Treatment Using Tannin-Based Natural Coagulant

  • Tawfiq J. H. Banch,
  • Marlia M. Hanafiah,
  • Abbas F. M. Alkarkhi and
  • Salem S. Abu Amr

14 August 2019

In this study, tannin-based natural coagulant was used to treat stabilized landfill leachate. Tannin modified with amino group was utilized for the treatment process. Central composite design (CCD) was used to investigate and optimize the effect of t...

  • Article
  • Open Access
23 Citations
6,724 Views
13 Pages

14 August 2019

Raspberry-like hollow-spheres-on-sphere (HSOS) particles with reactive surfaces, uniform sizes and monodisperse properties were rational designed and fabricated to immobilize gold nanoparticles for the catalytic reduction of 4-nitrophenol. HSOS polys...

  • Review
  • Open Access
9 Citations
4,665 Views
15 Pages

14 August 2019

Our experiences concerning fluorescent molecular sensing and logic devices and their intersections with polymer science are the foci of this brief review. Proton-, metal ion- and polarity-responsive cases of these devices are placed in polymeric micr...

  • Article
  • Open Access
19 Citations
4,964 Views
13 Pages

A Tough, Water-Resistant, High Bond Strength Adhesive Derived from Soybean Meal and Flexible Hyper-Branched Aminated Starch

  • Yi Zhang,
  • Jieyu Zhang,
  • Mingsong Chen,
  • Jing Luo,
  • Sheldon Q. Shi,
  • Qiang Gao and
  • Jianzhang Li

14 August 2019

Soybean meal (SM)-based adhesive exhibited a great potential to replace petroleum-derived ones to alleviate the energy crisis and eliminate carcinogenic formaldehyde. However, the bad water resistance (caused by low crosslinking density) and inherent...

  • Article
  • Open Access
44 Citations
9,994 Views
18 Pages

13 August 2019

Through the control of the molecular weight, water content and monomer concentration, polyethylene glycol dimethacrylate (PEGDMA) based hydrogels have been adapted for numerous applications, including as structural scaffolds, drug delivery vehicles a...

  • Article
  • Open Access
45 Citations
5,096 Views
15 Pages

13 August 2019

Excellent thermal resistance and thermal conductivity are preconditions of materials to be used at elevated temperatures. Herein, boron nitride and polyarylene ether nitrile hybrids (PEN-g-BN) with excellent thermal resistance and thermal conductivit...

  • Article
  • Open Access
26 Citations
4,625 Views
11 Pages

Synthesis of Highly Thermally Stable Daidzein-Based Main-Chain-Type Benzoxazine Resins

  • Mengchao Han,
  • Sijia You,
  • Yuting Wang,
  • Kan Zhang and
  • Shengfu Yang

13 August 2019

In recent years, main-chain-type benzoxazine resins have been extensively investigated due to their excellent comprehensive properties for many potential applications. In this work, two new types of main-chain benzoxazine polymers were synthesized fr...

  • Article
  • Open Access
12 Citations
5,725 Views
18 Pages

Modelling the Mechanical and Strain Recovery Behaviour of Partially Crystalline PLA

  • John Sweeney,
  • Paul Spencer,
  • Karthik Nair and
  • Phil Coates

13 August 2019

This is a study of the modelling and prediction of strain recovery in a polylactide. Strain recovery near the glass transition temperature is the underlying mechanism for the shape memory in an amorphous polymer. The investigation is aimed at modelli...

  • Article
  • Open Access
15 Citations
4,002 Views
16 Pages

13 August 2019

Herein, we have used a hollow fiber membrane as a support layer material to encapsulate paraffin in order to prepare a phase change energy storage material. The phase change energy storage materials with three different support layers were successful...

  • Article
  • Open Access
13 Citations
5,127 Views
10 Pages

13 August 2019

The commercialization of Lithium-sulfur batteries was limited by the polysulfide shuttle effect, and modifying the routine separator was an effective method to solve this problem. In this work, a novel hierarchically porous polypyrrole sphere (PPS) w...

  • Article
  • Open Access
16 Citations
4,631 Views
18 Pages

Piezoelectric Films Based on Polyethylene Modified by Aluminosilicate Filler

  • Halina Kaczmarek,
  • Bogusław Królikowski,
  • Marta Chylińska,
  • Ewa Klimiec and
  • Dagmara Bajer

13 August 2019

The development, universality and miniaturization of electronic devices leads to the search for new piezoelectric materials, among which recently, polymers play an increasingly important role. In this work, composites based on two types of polyethyle...

  • Article
  • Open Access
43 Citations
8,021 Views
17 Pages

13 August 2019

The surface of an Au-disc electrode was modified through electro polymerization of aniline, in the presence of dodecyl benzene sulphonic acid (DBSA) and sulphuric acid (H2SO4) solution. The polymerization conditions were pre-optimized so that micelle...

  • Article
  • Open Access
32 Citations
6,082 Views
12 Pages

13 August 2019

This paper presents a method to enhance thermal conductivity using poly(methyl methacrylate)(PMMA), polystyrene(PS) blends, and incorporation of multiwalled carbon nanotubes (MWCNTs). MWCNTs are selectively localized in PMMA phase to improve conducti...

  • Article
  • Open Access
68 Citations
7,407 Views
15 Pages

Structure–Property Relationships in Polyethylene-Based Composites Filled with Biochar Derived from Waste Coffee Grounds

  • Rossella Arrigo,
  • Pravin Jagdale,
  • Mattia Bartoli,
  • Alberto Tagliaferro and
  • Giulio Malucelli

12 August 2019

In this work, biochar (BC) derived from spent coffee grounds has been incorporated into high density polyethylene (PE) through melt mixing. The influence of the filler content on the rheological and thermal behavior of the obtained composites was ass...

  • Article
  • Open Access
6 Citations
5,229 Views
11 Pages

12 August 2019

In this manuscript, we present the successful attachment of crown ether moieties onto fluoropolymer surfaces, via the combination of radiation-induced graft polymerization and a subsequent surface Kabachnik–Fields three-component reaction. The...

  • Article
  • Open Access
6 Citations
5,572 Views
21 Pages

In Situ Modification of Polyisoprene by Organo-Nanoclay during Emulsion Polymerization for Reinforcing Natural Rubber Thin Films

  • Jadsadaporn Chouytan,
  • Ekwipoo Kalkornsurapranee,
  • Christopher M. Fellows and
  • Wisut Kaewsakul

12 August 2019

Nanoclay-modified polyisoprene latexes were prepared and then used as a reinforcing component in natural rubber (NR) thin films. Starve-fed emulsion (SFE) polymerization gives a higher conversion than the batch emulsion (BE), while the gel and coagul...

  • Article
  • Open Access
32 Citations
6,083 Views
14 Pages

12 August 2019

This study created water polyurethane (WPU) prepolymer by using isophorone diisocyanate, castor oil, dimethylolpropionic acid, and triethanolamine (TEA) as the hard segment, soft segment, hydrophilic group, and neutralizer, respectively. TEA, deioniz...

  • Article
  • Open Access
15 Citations
4,587 Views
15 Pages

12 August 2019

A series of conjugated, symmetrical, and ferrocene-containing main-chain monomers was prepared following a gentle coupling reaction. Ferrocene-containing oligomers with all-trans-configured vinylene bonds could be synthesized via acyclic diene metath...

  • Article
  • Open Access
31 Citations
5,485 Views
14 Pages

Optimization of Boron Nitride Sphere Loading in Epoxy: Enhanced Thermal Conductivity and Excellent Electrical Insulation

  • Hua Zhang,
  • Rongjin Huang,
  • Yong Li,
  • Hongbo Li,
  • Zhixiong Wu,
  • Jianjun Huang,
  • Bin Yu,
  • Xiang Gao,
  • Jiangang Li and
  • Laifeng Li

12 August 2019

Thermally conductive but electrically insulating materials are highly desirable for thermal management applications in electrical encapsulation and future energy fields, for instance, superconducting magnet insulation in nuclear fusion systems. Howev...

  • Article
  • Open Access
8 Citations
4,175 Views
11 Pages

11 August 2019

Surface imprinting is an effective and simple method to fabricate and retain imprinted templates and recognizable nanocavities after template extraction. The imprinted effects can be controlled depending on the surface morphological changes. In gener...

  • Communication
  • Open Access
20 Citations
5,397 Views
10 Pages

Hydrogel Functionalized Polyester Fabrics by UV-Induced Photopolymerization

  • Emanuela Lorusso,
  • Wael Ali,
  • Marcus Hildebrandt,
  • Thomas Mayer-Gall and
  • Jochen S. Gutmann

10 August 2019

We address a strategy to graft hydrogels onto polyethylene terephthalate (PET) fabrics using different acrylate-based monomers. The hydrogel-modified fabrics were prepared by a two-step modification. To this end, double functional groups were firstly...

  • Article
  • Open Access
13 Citations
4,454 Views
11 Pages

Graphene Oxide and Oxidized Carbon Black as Catalyst for Crosslinking of Phenolic Resins

  • Maria Rosaria Acocella,
  • Aniello Vittore,
  • Mario Maggio,
  • Gaetano Guerra,
  • Luca Giannini and
  • Luciano Tadiello

10 August 2019

Influence of different graphite-based nanofillers on crosslinking reaction of resorcinol, as induced by hexa(methoxymethyl)melamine, is studied. Curing reactions leading from low molecular mass compounds to crosslinked insoluble networks are studied...

  • Article
  • Open Access
12 Citations
5,500 Views
20 Pages

10 August 2019

This work shows the potential of binary blends composed of partially bio-based poly(ethyelene terephthalate) (bioPET) and fully bio-based poly(amide) 10,10 (bioPA1010). These blends are manufactured by extrusion and subsequent injection moulding and...

  • Article
  • Open Access
32 Citations
4,904 Views
14 Pages

9 August 2019

Chitosan, fucoidan, and polyvinyl alcohol are categorized as polymers with biomedical applications. Ampicillin, on the other hand, is considered as an important antibiotic that has shown effectivity in both gram-positive and gram-negative micro-organ...

  • Review
  • Open Access
58 Citations
9,026 Views
24 Pages

Development of Covalent Triazine Frameworks as Heterogeneous Catalytic Supports

  • Norini Tahir,
  • Chidharth Krishnaraj,
  • Karen Leus and
  • Pascal Van Der Voort

9 August 2019

Covalent triazine frameworks (CTFs) are established as an emerging class of porous organic polymers with remarkable features such as large surface area and permanent porosity, high thermal and chemical stability, and convenient functionalization that...

  • Article
  • Open Access
16 Citations
4,688 Views
11 Pages

9 August 2019

Bone morphogenetic protein 2 (BMP-2) has received considerable attention because of its osteoinductivity, but its use is limited owing to its instability and adverse effects. To reduce the dose of BMP-2, complexation with heparin is a promising appro...

  • Review
  • Open Access
33 Citations
5,235 Views
16 Pages

Polyhydroxyalkanoates Synthesized by Aeromonas Species: Trends and Challenges

  • Justyna Możejko-Ciesielska,
  • Paulina Marciniak and
  • Karolina Szacherska

9 August 2019

The negative effects of petrochemical-derived plastics on the global environment and depletion of global fossil fuel supplies have paved the way for exploring new technologies for the production of bioplastics. Polyhydroxyalkanoates (PHAs) are consid...

of 3

Get Alerted

Add your email address to receive forthcoming issues of this journal.

XFacebookLinkedIn
Polymers - ISSN 2073-4360