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Polymers, Volume 15, Issue 6

2023 March-2 - 264 articles

Cover Story: Enzyme-loaded submicrometer-sized polyion complex vesicles with tunable semi-permeability show high potential for enzyme prodrug therapy (EPT) as a nanoreactor. This nanoreactor is suitable for the local activation of prodrugs; however, it suffers from a low loading efficiency, which hinders practical applications. In this study, we developed a stepwise crosslinking (SWCL) method to improve the enzyme loading amount. Enzyme-loaded PICsomes prepared using the SWCL method resulted in several times higher enzyme loading—an increase in double figures—than that obtained through conventional methods. It also showed excellent antitumor efficacy and reduced side effects in tumor-bearing mice, confirming the significance of PICsome-based EPT. View this paper
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Articles (264)

  • Article
  • Open Access
2 Citations
2,759 Views
16 Pages

22 March 2023

A novel phosphorus-containing sorbent (CyP(Ph)4–DVB) was prepared by copolymerizing divinylbenzene (DVB) with bis α,β-unsaturated phosphorylated cyclohexene (CyP(Ph)4). ATR-FT-IR indicated that the phosphinoyl group was introduced in...

  • Review
  • Open Access
39 Citations
11,790 Views
28 Pages

Current State of the Art and Next Generation of Materials for a Customized IntraOcular Lens according to a Patient-Specific Eye Power

  • Martina Vacalebre,
  • Renato Frison,
  • Carmelo Corsaro,
  • Fortunato Neri,
  • Antonio Santoro,
  • Sabrina Conoci,
  • Elena Anastasi,
  • Maria Cristina Curatolo and
  • Enza Fazio

22 March 2023

Intraocular lenses (IOLs) are commonly implanted after surgical removal of a cataractous lens. A variety of IOL materials are currently available, including collamer, hydrophobic acrylic, hydrophilic acrylic, PHEMA copolymer, polymethylmethacrylate (...

  • Article
  • Open Access
32 Citations
9,482 Views
20 Pages

Tailor-Made Bio-Based Non-Isocyanate Polyurethanes (NIPUs)

  • Juan Catalá,
  • Irene Guerra,
  • Jesús Manuel García-Vargas,
  • María Jesús Ramos,
  • María Teresa García and
  • Juan Francisco Rodríguez

22 March 2023

Non-isocyanate polyurethanes (NIPUs) based on biobased polyamines and polycarbonates are a sustainable alternative to conventional polyurethanes (PU). This article discloses a novel method to control the crosslinking density of fully biobased isocyan...

  • Article
  • Open Access
7 Citations
1,915 Views
12 Pages

22 March 2023

An amphiphilic chitosan-loaded bentonite adsorbent (C18CTS−BT) was prepared for the efficient removal of organic matter from coking wastewater. The structure and surface morphology of adsorbents were characterized by FT−IR, XRD, and SEM....

  • Article
  • Open Access
37 Citations
7,391 Views
12 Pages

The Effect of Heat Treatment on a 3D-Printed PLA Polymer’s Mechanical Properties

  • Mariam Shbanah,
  • Márton Jordanov,
  • Zoltán Nyikes,
  • László Tóth and
  • Tünde Anna Kovács

22 March 2023

Three-dimensional printing is a useful and common process in additive manufacturing nowadays. The advantage of additive polymer technology is its rapidity and design freedom. Polymer materials’ mechanical properties depend on the process parame...

  • Article
  • Open Access
7 Citations
2,774 Views
12 Pages

22 March 2023

Discoloration of wood coatings due to fungal growth negatively affects the aesthetic properties of the coatings, and new ways to control fungal growth on coatings are needed. For this reason, silver nanoparticles (AgNPs) have been incorporated in acr...

  • Article
  • Open Access
7 Citations
2,631 Views
12 Pages

A Flexible Bi-Stable Composite Antenna with Reconfigurable Performance and Light-Responsive Behavior

  • Yaoli Huang,
  • Cong Zheng,
  • Jinhua Jiang,
  • Huiqi Shao and
  • Nanliang Chen

22 March 2023

An integrated solution providing a bi-stable antenna with reconfigurable performance and light-responsive behavior is presented in this paper for the first time. The proposed antenna includes a radiation layer with conductivity, which is integrated o...

  • Article
  • Open Access
10 Citations
4,032 Views
11 Pages

The Effect of Various Fillers on the Properties of Methyl Vinyl Silicone Rubber

  • Yun Chen,
  • Kun Wang,
  • Chong Zhang,
  • Wei Yang,
  • Bo Qiao and
  • Li Yin

22 March 2023

Silicone rubber (SIR) has been widely used in electrical insulation fields, and the introduction of new materials is very important for the performance improvement of SIR composites. In this work, four different fillers, including aluminium hydroxide...

  • Article
  • Open Access
8 Citations
3,517 Views
17 Pages

22 March 2023

A series of poly(thiourethanes) (PTUs) from biobased monomers have been synthesized. Limonene and squalene were transformed into polyfunctional thiols by thiol-ene reaction with thioacetic acid and further saponification. They were then reacted in di...

  • Article
  • Open Access
14 Citations
5,198 Views
24 Pages

Fungal Screening for Potential PET Depolymerization

  • Lusiane Malafatti-Picca,
  • Elaine Cristina Bucioli,
  • Michel Ricardo de Barros Chaves,
  • Aline Machado de Castro,
  • Érika Valoni,
  • Valéria Maia de Oliveira,
  • Anita Jocelyne Marsaioli,
  • José Silvio Govone,
  • Dejanira de Franceschi de Angelis and
  • Derlene Attili-Angelis
  • + 1 author

22 March 2023

Approximately 400 billion PET bottles are produced annually in the world, of which from 8 to 9 million tons are discarded in oceans. This requires developing strategies to urgently recycle them. PET recycling can be carried out using the microbial hy...

  • Review
  • Open Access
30 Citations
8,375 Views
23 Pages

A Thermo-Catalytic Pyrolysis of Polystyrene Waste Review: A Systematic, Statistical, and Bibliometric Approach

  • Arantxa M. Gonzalez-Aguilar,
  • Vicente Pérez-García and
  • José M. Riesco-Ávila

22 March 2023

Global polystyrene (PS) production has been influenced by the lightness and heat resistance this material offers in different applications, such as construction and packaging. However, population growth and the lack of PS recycling lead to a large wa...

  • Article
  • Open Access
2,507 Views
12 Pages

22 March 2023

Platelet function testing is essential for the diagnosis of patients with bleeding disorders. Specifically, there is a need for a whole blood assay that is capable of analysing platelet behaviour in contact with a patient-specific autologous von Will...

  • Article
  • Open Access
5 Citations
3,233 Views
11 Pages

22 March 2023

High-energy low-sensitivity explosives are research objectives in the field of energetic materials, and the formation of cocrystals is an important method to improve the safety of explosives. However, the sensitivity reduction mechanism of cocrystal...

  • Article
  • Open Access
18 Citations
3,020 Views
11 Pages

22 March 2023

Corn starch was plasticized by glycerol suspension in a twin-screw extruder, in which the glycerol suspension was the pre-dispersion mixture of glycerol with nano-SiO2. Polylactide (PLA)/thermoplastic starch/SiO2 composites were obtained through melt...

  • Article
  • Open Access
2 Citations
3,025 Views
13 Pages

Synthesis of Sulfonated Polyphenylene Block Copolymers via In Situ Generation of Ni(0)

  • Vikrant Yadav,
  • Farid Wijaya,
  • Hyejin Lee,
  • Byungchan Bae and
  • Dongwon Shin

22 March 2023

Proton exchange membranes (PEMs) fabricated from sulfonated polyphenylenes (sPP) exhibit superior proton conductivity and electrochemical performance. However, the Ni(0) catalyst required for Colon’s cross-coupling reaction for the synthesis of...

  • Article
  • Open Access
19 Citations
3,761 Views
22 Pages

Optimised Sunflower Oil Content for Encapsulation by Vibrating Technology as a Rejuvenating Solution for Asphalt Self-Healing

  • Jose L. Concha,
  • Rodrigo Delgadillo,
  • Luis E. Arteaga-Pérez,
  • Cristina Segura and
  • Jose Norambuena-Contreras

22 March 2023

This study aimed to determine an optimal dosage of sunflower oil (i.e., Virgin Cooking Oil, VCO) as a rejuvenator for asphalt self-healing purposes, evaluating its effect on the chemical (carbonyl, and sulfoxide functional groups), physical (penetrat...

  • Article
  • Open Access
7 Citations
3,250 Views
21 Pages

22 March 2023

Adhesive joints possess a number of advantages over traditional joining methods and are widely used in composite structures. Conventional non-destructive examination techniques do not readily reveal joint degradation before the formation of explicit...

  • Article
  • Open Access
5 Citations
2,602 Views
14 Pages

Effect of Nanometric Particles of Bentonite on the Mechanical Properties of a Thermoset Polymeric Matrix Reinforced with Hemp Fibers

  • Meylí Valin Fernández,
  • María José Ahumada González,
  • Rolando Briones Oyanadel,
  • José Luis Valin Rivera,
  • Angel Rodríguez Soto,
  • Alvaro González Ortega,
  • Cristobal Galleguillos Ketterer,
  • Alexander Alfonso Alvarez,
  • Francisco Rolando Valenzuela Diaz and
  • Gilberto García del Pino

22 March 2023

The influence of the addition of bentonite nanoparticles on the tensile and flexural strength of a thermosetting polymer matrix composite material reinforced with hemp fibers was de-terminated. All composites were manufactured with 5% of bentonite in...

  • Review
  • Open Access
28 Citations
7,417 Views
27 Pages

Electrical Heaters for Anti/De-Icing of Polymer Structures

  • Aleksei V. Shiverskii,
  • Mohammad Owais,
  • Biltu Mahato and
  • Sergey G. Abaimov

22 March 2023

The problem of icing for surfaces of engineering structures requires attention more and more every year. Active industrialization in permafrost zones is currently underway; marine transport in Arctic areas targets new goals; the requirements for aero...

  • Article
  • Open Access
22 Citations
5,107 Views
21 Pages

22 March 2023

The first ever nanofibers produced by the electrospinning of polyvinyl alcohol (PVA) and Spirulina platensis extracts are presented in this article. Spirulina platensis extracts were obtained by ultrasound-assisted extraction (UAE) using two differen...

  • Article
  • Open Access
5 Citations
3,931 Views
19 Pages

A Numerical Thermo-Chemo-Flow Analysis of Thermoset Resin Impregnation in LCM Processes

  • Hatim Alotaibi,
  • Chamil Abeykoon,
  • Constantinos Soutis and
  • Masoud Jabbari

22 March 2023

This paper presents a numerical framework for modelling and simulating convection–diffusion–reaction flows in liquid composite moulding (LCM). The model is developed in ANSYS Fluent with customised user-defined-functions (UDFs), user-defi...

  • Article
  • Open Access
5 Citations
2,700 Views
12 Pages

Influence of Chitosan and Grape Seed Extract on Thermal and Mechanical Properties of PLA Blends

  • Victoria Goetjes,
  • Claudia L. von Boyneburgk,
  • Hans-Peter Heim and
  • Marilia M. Horn

22 March 2023

Blends based on polylactic acid (PLA), chitosan, and grape seed extract (GE) were prepared by extrusion and injection molding. The effect of chitosan (5% and 15% on PLA basis) and natural extract (1% on PLA basis) incorporated into the PLA host matri...

  • Article
  • Open Access
6 Citations
2,698 Views
28 Pages

21 March 2023

Despite a wide set of experimental data and a large number of studies, the quantitative description of the relaxation mechanisms involved in the disorientation process of bidisperse blends is still under discussion. In particular, while it has been s...

  • Review
  • Open Access
16 Citations
5,745 Views
29 Pages

Biodegradable Polymer Electrospinning for Tendon Repairment

  • Yiming Zhang,
  • Yueguang Xue,
  • Yan Ren,
  • Xin Li and
  • Ying Liu

21 March 2023

With the degradation after aging and the destruction of high-intensity exercise, the frequency of tendon injury is also increasing, which will lead to serious pain and disability. Due to the structural specificity of the tendon tissue, the traditiona...

  • Article
  • Open Access
5 Citations
4,002 Views
19 Pages

Influence of Injection Molding Parameters on the Peel Strength between Plasma-Treated Fluoropolymer Films and Polycarbonate

  • Martin Hubmann,
  • Jonas Groten,
  • Martin Pletz,
  • Thomas Grießer,
  • Kateřina Plevová,
  • Wolfgang Nemitz and
  • Barbara Stadlober

21 March 2023

Light guiding is used to direct light from an emitting source to a different location. It is frequently realized through a clad–core structure with a difference in the refractive index of the materials. This paper explores the possibility of co...

  • Review
  • Open Access
6 Citations
2,722 Views
21 Pages

21 March 2023

The development of new scaffolds and materials for tissue engineering is a wide and open realm of material science. Among solutions, the use of biopolymers represents a particularly interesting area of study due to their great chemical complexity tha...

  • Article
  • Open Access
6 Citations
3,962 Views
16 Pages

21 March 2023

As part of this work, polymer composites based on polycarbonate/acrylonitrile-butadiene-styrene (PC/ABS) were obtained and used in 3D printing technology, particularly Melted Extrusion Modeling (MEM) technology. The influence of selected fillers on t...

  • Article
  • Open Access
17 Citations
2,885 Views
14 Pages

21 March 2023

Through a solution method utilizing benzoxazine chemistry, heteroatoms containing porous carbons (HCPCs) were synthesized from melamine, eugenol and formaldehyde, followed by carbonization in a nitrogen atmosphere and chemical activation with KOH at...

  • Article
  • Open Access
11 Citations
3,119 Views
28 Pages

Polyamide 11 Composites Reinforced with Diatomite Biofiller—Mechanical, Rheological and Crystallization Properties

  • Marta Dobrosielska,
  • Renata Dobrucka,
  • Dariusz Brząkalski,
  • Paulina Kozera,
  • Agnieszka Martyła,
  • Ewa Gabriel,
  • Krzysztof J. Kurzydłowski and
  • Robert E. Przekop

21 March 2023

Amorphic diatomaceous earth is derived from natural sources, and polyamide 11 (PA11) is produced from materials of natural origin. Both of these materials show a low harmfulness to the environment and a reduced carbon footprint. This is why the combi...

  • Review
  • Open Access
18 Citations
5,287 Views
32 Pages

21 March 2023

Phase change materials (PCMs) have been extensively utilized in latent thermal energy storage (TES) and thermal management systems to bridge the gap between thermal energy supply and demand in time and space, which have received unprecedented attenti...

  • Article
  • Open Access
13 Citations
2,635 Views
19 Pages

21 March 2023

Fracturing fluids are widely applied in the hydraulic fracturing of shale gas reservoirs, but the fracturing fluid flowback efficiency is typically less than 50%, severely limiting the shale gas recovery. Additionally, the mechanism and main influenc...

  • Article
  • Open Access
3 Citations
2,685 Views
13 Pages

Photocured Poly(Mannitol Sebacate) with Functional Methacrylic Monomer: Analysis of Physical, Chemical, and Biological Properties

  • Víctor Hevilla,
  • Águeda Sonseca,
  • Coro Echeverría,
  • Alexandra Muñoz-Bonilla and
  • Marta Fernández-García

21 March 2023

In this work, we described the formation of polymeric networks with potential antimicrobial character based on an acrylate oligomer, poly(mannitol sebacate) (PMS), and an enzymatically synthesized methacrylic monomer with thiazole groups (MTA). Netwo...

  • Article
  • Open Access
10 Citations
3,761 Views
13 Pages

Recycling of Epoxy/Fiberglass Composite Using Supercritical Ethanol with (2,3,5-Triphenyltetrazolium)2[CuCl4] Complex

  • Alexander E. Protsenko,
  • Alexandra N. Protsenko,
  • Olga G. Shakirova and
  • Victor V. Petrov

21 March 2023

The widespread use of polymer composite materials (PCM) leads to an increase in non-recyclable waste. This paper discusses the feasibility of recycling fiberglass with an epoxy matrix by solvolysis in ethanol under supercritical conditions. The solvo...

  • Feature Paper
  • Article
  • Open Access
16 Citations
5,222 Views
13 Pages

Comparative Large Amplitude Oscillatory Shear (LAOS) Study of Ionically and Physically Crosslinked Hydrogels

  • Thomas B. Goudoulas,
  • Anna Didonaki,
  • Sharadwata Pan,
  • Ehsan Fattahi and
  • Thomas Becker

21 March 2023

Hydrogels are highly versatile and widely applicable materials within various scientific, technological, and food sectors. Alginate and gelatin hydrogels, along with their crafted variations, are possibly the most common ones. However, the ionic cros...

  • Article
  • Open Access
13 Citations
5,383 Views
14 Pages

21 March 2023

The optimization and modeling of the parameters, the concentration of polylactic acid (PLA), sugarcane bagasse cellulose fibers (SBCF), and snail shell nanoparticles (SSNP), were investigated for the development of bioplastic films. With the aid of t...

  • Article
  • Open Access
22 Citations
3,882 Views
12 Pages

Durability, Strength, and Erosion Resistance Assessment of Lignin Biopolymer Treated Soil

  • Pouyan Bagheri,
  • Ivan Gratchev,
  • Suwon Son and
  • Maksym Rybachuk

21 March 2023

To mitigate the negative environmental effects of the overuse of conventional materials—such as cement—in soil improvement, sustainable engineering techniques need to be applied. The use of biopolymers as an alternative, environmentally f...

  • Article
  • Open Access
17 Citations
5,550 Views
12 Pages

Investigation of Fumasep® FAA3-50 Membranes in Alkaline Direct Methanol Fuel Cells

  • Carmelo Lo Vecchio,
  • Alessandra Carbone,
  • Irene Gatto and
  • Vincenzo Baglio

21 March 2023

This paper describes the use of a commercial Fumasep® FAA3-50 membrane as an anion exchange membrane (AEM) in alkaline direct methanol fuel cells (ADMFCs). The membrane, supplied in bromide form, is first exchanged in chloride and successively in...

  • Article
  • Open Access
15 Citations
5,020 Views
20 Pages

Core–Shell Polyvinyl Alcohol (PVA) Base Electrospinning Microfibers for Drug Delivery

  • Sofía Mares-Bou,
  • María-Antonia Serrano and
  • José Antonio Gómez-Tejedor

21 March 2023

In this study, electrospun membranes were developed for controlled drug release applications. Both uniaxial Polyvinyl alcohol (PVA) and coaxial fibers with a PVA core and a poly (L-lactic acid) (PLLA) and polycaprolactone (PCL) coating were produced...

  • Article
  • Open Access
5 Citations
2,060 Views
14 Pages

Arundo donax L Processing in Catalyzed Butanol–Water Media in the Scope of Lignocellulose Biorefineries

  • Sandra Rivas,
  • Rebecca Baldassari,
  • Juan Carlos Parajó and
  • Anna M. Raspolli Galletti

21 March 2023

Arundo donax L samples, before or after aqueous extraction to remove extractives, were subjected to chemical fractionation in H2SO4-catalyzed mixtures of 1-butanol and water. The partial miscibility of 1-butanol and water at room temperature allowed...

  • Article
  • Open Access
16 Citations
5,927 Views
24 Pages

21 March 2023

Materials providing heat dissipation and electrical insulation are required for many electronic and medical devices. Polymer composites with hexagonal boron nitride (hBN) may fulfil such requirements. The focus of this study is to compare composites...

  • Article
  • Open Access
7 Citations
2,961 Views
36 Pages

21 March 2023

The cross-linking of polysaccharides is a universal approach to affect their structure and physical properties. Both physical and chemical methods are used for this purpose. Although chemical cross-linking provides good thermal and mechanical stabili...

  • Article
  • Open Access
13 Citations
5,037 Views
22 Pages

Production and Characterisation of an Exopolysaccharide by Bacillus amyloliquefaciens: Biotechnological Applications

  • Enrique Sánchez-León,
  • Elisa Huang-Lin,
  • Ricardo Amils and
  • Concepción Abrusci

21 March 2023

The Bacillus amyloliquefaciens RT7 strain was isolated from an extreme acidic environment and identified. The biodegradation capabilities of the strain using different carbon sources (glucose, oleic acid, Tween 80, PEG 200, and the combination of glu...

  • Article
  • Open Access
38 Citations
4,853 Views
20 Pages

21 March 2023

Biopolymers have recently shown great potential to replace traditional binding materials in geotechnical engineering; however, more research is required to reach a deeper understanding of biopolymer-treated soil behavior. The objective of this study...

  • Article
  • Open Access
16 Citations
4,206 Views
16 Pages

Processing, Characterization and Disintegration Properties of Biopolymers Based on Mater-Bi® and Ellagic Acid/Chitosan Coating

  • Carolina Villegas,
  • Sara Martínez,
  • Alejandra Torres,
  • Adrián Rojas,
  • Rocío Araya,
  • Abel Guarda and
  • María José Galotto

21 March 2023

Among the most promising synthetic biopolymers to replace conventional plastics in numerous applications is MaterBi® (MB), a commercial biodegradable polymer based on modified starch and synthetic polymers. Actually, MB has important commercial a...

  • Article
  • Open Access
11 Citations
3,499 Views
14 Pages

The Hypervelocity Impact Behavior and Energy Absorption Evaluation of Fabric

  • Huadong Xu,
  • Dong Yu,
  • Jiaxin Cui,
  • Zhixin Shi,
  • Di Song and
  • Changqing Miao

21 March 2023

In this work, the mechanical behavior and energy absorption characteristics of flexible fabric under hypervelocity impact (HVI) were investigated. Basalt fabric, ultra-high molecular weight polyethylene (UHMWPE) fabric, and aluminum alloy (Al) plate...

  • Article
  • Open Access
6 Citations
3,553 Views
16 Pages

The Study of Crystallization Behavior, Microcellular Structure and Thermal Properties of Glass-Fiber/Polycarbonate Composites

  • Xinchao Wang,
  • Yapeng Sun,
  • Jiale Hu,
  • Lan Wu,
  • Tie Geng,
  • Yonggang Guo,
  • Chenhao Zhao,
  • Binbin Dong and
  • Chuntai Liu

21 March 2023

Polycarbonate (PC) foam is a versatile material with excellent properties, but its low thermal stability limits its application in high-temperature environments. The aim of this study was to improve the thermal stability of PC foam by adding glass fi...

  • Review
  • Open Access
21 Citations
7,521 Views
22 Pages

21 March 2023

The production of flexible electronic systems includes stretchable electrical interconnections and flexible electronic components, promoting the research and development of flexible conductors and stretchable conductive materials with large bending d...

  • Article
  • Open Access
8 Citations
4,050 Views
24 Pages

Experimental and Simulative Analysis of the Pressure Development in a Closed Injection Pultrusion Process with Multiple Chamber Geometries

  • Sebastian Strauss,
  • Frederik Wilhelm,
  • Andreas Senz,
  • Herbert Engelen,
  • Simon Boysen,
  • Niko Rilli,
  • Alptekin Celik,
  • Marcel Ratka and
  • Christian Bonten

20 March 2023

The use of innovative higher-performance highly reactive resin systems requires an enhancement of the established method of fiber impregnation (open bath) towards closed resin-injection pultrusion (CIP), due to the short pot life of the resin systems...

  • Article
  • Open Access
6 Citations
2,836 Views
17 Pages

20 March 2023

The development of waterborne polyurethane (WPU) has been stimulated as an alternative to solvent-based polyurethanes due to low-VOC alternatives and reduced exposure to solvents. However, their relatively low mechanical performance and degradation h...

  • Article
  • Open Access
23 Citations
4,465 Views
27 Pages

A Comparison between the Molecularly Imprinted and Non-Molecularly Imprinted Cyclodextrin-Based Nanosponges for the Transdermal Delivery of Melatonin

  • Gjylije Hoti,
  • Riccardo Ferrero,
  • Fabrizio Caldera,
  • Francesco Trotta,
  • Marta Corno,
  • Stefano Pantaleone,
  • Mohamed M. H. Desoky and
  • Valentina Brunella

20 March 2023

Melatonin is a neurohormone that ameliorates many health conditions when it is administered as a drug, but its drawbacks are its oral and intravenous fast release. To overcome the limitations associated with melatonin release, cyclodextrin-based nano...

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Polymers - ISSN 2073-4360