Water, Volume 16, Issue 11 (June-1 2024) – 136 articles

Microplastics are widely present worldwide and are of great concern to scientists and governments due to their toxicity and ability to serve as carriers of other environmental pollutants. The abundance of microplastics in different water bodies varied significantly, mainly attributed to the initial emission concentration of pollutants and the migration ability of pollutants. The migration process of microplastics determines the abundance, fate, and bioavailability of microplastics in water. Previous studies have proved that the physicochemical properties of water bodies and the properties of microplastics themselves are important factors affecting their migration, but the change in external environmental conditions is also one of the main factors controlling the migration of microplastics. In this paper, we focus on the effects of meteorological factors (rainfall, light, and wind) on the distribution and migration of microplastics and conclude that the influence of meteorological factors on microplastics mainly affects the inflow abundance of microplastics, the physical and chemical properties of water, and the dynamics of water. At the same time, we briefly summarized the effects of aquatic organisms, water substrates, and water topography on microplastics. It is believed that aquatic organisms can affect the physical and chemical properties of microplastics through the physical adsorption and in vivo transmission of aquatic plants, through the feeding behavior, swimming, and metabolism of animals, and through the extracellular polymers formed by microorganisms, and can change their original environmental processes in water bodies. A full understanding of the influence and mechanism of external environmental factors on the migration of microplastics is of great theoretical significance for understanding the migration law of microplastics in water and comprehensively assessing the pollution load and safety risk of microplastics in water. Full article

Hazardous debris flows are common in the tectonically active young Himalayas. The present study is focused on the recurrent, almost seasonal, landslides and debris flows initiated from Kalli village in Achham District of Nepal, located in the Lesser Himalayas. Such geological hazards pose a significant threat to the neighboring communities. The field survey reveals vulnerable engineering geological conditions and adverse environmental factors in the study area. It is found that a typical complete debris transport process may consist of two stages depending on the rainfall intensity. In the first stage, debris flows mobilized from a landslide have low mobility and their runout distance is quite modest; in the second stage, with an increase in water content they are able to travel a longer distance. Numerical simulations based on a multi-phase flow model are conducted to analyze the characteristics of the debris flows in motion, including the debris deposition profiles and runout distances in both stages. Overall, the numerical results are reasonably consistent with relevant field observations. Future debris flows may likely occur again in this area due to the presence of large soil blocks separated by tension cracks, rampant in the field; numerical simulations predict that these potential debris flows may exhibit similar characteristics to past events. Full article

This study aimed to investigate and develop a cost-effective and superhydrophobic ceramic membrane for direct contact membrane distillation (DCMD) applications. Two types of mullite-based composite membranes were prepared via extrusion and sintering techniques. To create a small and narrow pore diameter distribution on the membrane surface, the dip-coating technique with 1 µm alumina was employed. The hexadecyltrimethoxysilane eco-friendly grafting agent was adopted to modify low-cost multilayer mullite-based composite membranes, transforming them from hydrophilic to superhydrophobic. The prepared membranes were characterized via field emission scanning electron microscopy (FESEM), energy-dispersive spectrometry (EDS), Fourier Transform Infrared Spectroscopy (FT-IR), X-ray diffraction (XRD), liquid entire pressure (LEP), contact angle, atomic force microscopy (AFM), porosity, and membrane permeability. The results of the prepared membranes validate the appropriateness of the material for membrane distillation applications. The optimized membrane, with a contact angle of 160° and LEP = 1.5 bar, was tested under DCMD using a 3.5 wt.% sodium chloride (NaCl) synthetic solution and Persian Gulf seawater as a feed. Based on the acquired results, an average permeate flux of 3.15 kg/(m²·h) and salt rejection (R%) of 99.62% were found for the 3.5 wt.% NaCl solution. Moreover, seawater desalination showed an average permeate flux of 2.37 kg/(m²·h) and salt rejection of 99.81% for a 20-h test without any pore wetting. Membrane distillation with a hydrophobic membrane decreased the turbidity of seawater by 93.13%. Full article

In communities where people lack on-demand, safely managed drinking water, stored household water often becomes contaminated by fecal bacteria, regardless of the source-water quality. The objectives of this paper are to assess and control bacterial contamination in stored household water in Toamasina, a rapidly urbanizing city in eastern coastal Madagascar. We collected samples of source water and stored household water from 10 representative households that use different water sources and different storage strategies, and we analyzed the samples for several fecal indicator bacteria. We also tested three methods that residents of Toamasina could realistically employ for cleaning their household water storage vessels, assessing the effect of the cleaning methods on measured bacterial levels in the water. Consistent with the previous literature, we found that concentrations of total coliforms in stored household water were significantly higher than in the corresponding source water (p < 0.05). In 100% of households that stored their water in 20 L polyethylene jerrycans (n = 4), biofilms on the walls of the jerrycan harbored total coliforms and Enterococcus. The use of a closed storage container was, on its own, not found to provide a meaningful protective effect against bacterial regrowth; to be protective, closed storage containers must be combined with high-quality source water and/or with adequate cleaning to prevent biofilm formation. A dilute solution of sodium hypochlorite, known locally as Sûr’Eau or Manadio Rano, was both the most effective and the least expensive method for cleaning household water storage containers. We conclude that regular and effective cleaning of storage containers is an essential component of safe water storage. Because household storage of collected water is common in many low- and middle-income countries, these results are important towards the worldwide achievement of the United Nations’ Sustainable Development Goal 6. Full article

In this paper, a novel numerical model for characterizing the seepage and dissolution coupling effect on the durability of anti-seepage walls of earth-rock dams is proposed. The model considers the influence of hydraulic gradient-driven seepage on the non-equilibrium decomposition of the calcium dissolution in concrete, as well as the effects of seepage dissolution on pore structure, permeability, and diffusivity. The reasonableness of the model is validated by experimental and literature data, which is then applied to analyze the deterioration and failure processes of a concrete cutoff wall of an earth-rock dam in Zhejiang Province, China. On this basis, the seepage dissolution durability control indices of anti-seepage walls are identified. The findings demonstrate that the suggested method accurately explains the calcium leaching process in concrete. Under the seepage and dissolution coupling effect, calcium in the wall continuously decomposes and precipitates, leading to varying degrees of increases in structural performance parameters, which weaken the seepage control performance of the walls and consequently result in an increase in seepage discharge and hydraulic gradient. By proposing the critical hydraulic gradient as a criterion, the service life of the wall is projected to be 42.8 years. Additionally, the upstream hydraulic head, the initial permeability coefficient, and the calcium hydroxide (CH) content are three crucial indices affecting the durability of walls, and these indices should be reasonably controlled during the engineering design, construction, and operational phases. Full article

Accurate forecasting of monthly runoff is essential for efficient management, allocation, and utilization of water resources. To improve the prediction accuracy of monthly runoff, the long and short memory neural networks (LSTM) coupled with variational mode decomposition (VMD) and principal component analysis (PCA), namely VMD-PCA-LSTM, was developed and applied at the Waizhou station in the Ganjiang River Basin. The process begins with identifying the main forecasting factors from 130 atmospheric circulation indexes using the PCA method and extracting the stationary components from the original monthly runoff series using the VMD method. Then, the correlation coefficient method is used to determine the lag of the above factors. Lastly, the monthly runoff is simulated by combining the stationary components and key forecasting factors via the LSTM model. Results show that the VMD-PCA-LSTM model effectively addresses the issue of low prediction accuracy at high flows caused by a limited number of samples. Compared to the single LSTM and VMD-LSTM models, this comprehensive approach significantly enhances the model’s predictive accuracy, particularly during the flood season. Full article

Photocatalytic degradation technology has received much attention from researchers in the last few decades, due to its easy and cost-effective nature. A lot of review articles have been published on dyes via photocatalytic degradation, but most of the review articles lack a detailed and in-depth photocatalytic degradation mechanism of dyes. Numerous review articles are available on photocatalysis. Here, in this review article, we are mainly focused on the complete and in-depth photocatalytic degradation mechanism of four commonly used dyes such as Malachite Green, Methylene Blue, Congo Red and Rhodamine B, which will be highly useful for the new researchers that work on dyes’ photocatalytic degradation. Initially, various aspects of dyes have been included in this review article, comprehensively. The main focus was on the covalent organic framework-based photocatalysts for dyes’ photocatalytic degradation, due to their porous nature and various unique properties. Various synthesis routes and the photocatalytic performance of covalent organic frameworks and composite of covalent organic frameworks have been highlighted in this review article. In the last section of this review article, the main stimulus was the four mentioned dyes’ properties, uses, and toxicity, and the photocatalytic degradation mechanism through various paths into environmentally friendly and less-harmful compounds in the presence of photocatalysts. Factors effecting the photocatalytic degradation, economic cost, challenges and future aspects of photocatalytic technology were also included in this review article. This review article will be highly useful for those researchers that work on the photocatalytic degradation of various dyes and search for the complete degradation of complex dye molecules. Full article

Reliance on groundwater is outpacing natural replenishment, a growing imbalance that requires detailed and multi-faceted water resource understanding. This study integrated water-stable isotopes and hydrogeochemical species to examine hydrogeochemical processes during groundwater recharge and evolution in the Lake Malawi basin aquifer systems. The findings provide insights into groundwater source provenance, with non-evaporated modern precipitation dominating recharge inputs. Grouped hydrochemical facies exhibit five groundwater water types, prominently featuring Ca-Mg-HCO₃. Modelled hydrogeochemical data underscore dominant silicate dissolution reactions with the likely precipitation of calcite and/or high-Mg dolomitic carbonate constrained by ion exchange. Isotope hydrology reinforces water resource system conceptualisation. Coupled isotopic-hydrogeochemical lines of evidence reveal a discernible spatial-seasonal inhomogeneity in groundwater chemical character, revealing a complex interplay of meteoric water input, evaporative effects, recharge processes, and mixing dynamics. Findings show that measurable nitrate across Malawi highlights a widespread human impact on groundwater quality and an urgent need for detailed modelling to predict future trends of nitrate in groundwater with respect to extensive fertiliser use and an ever-increasing number of pit latrines and septic systems arising from rapid population growth. This study not only refined the Lake Malawi basin aquifer systems conceptualisation but also provided isotopic evidence of groundwater and lake water mixing. This study sets a base for groundwater management and policy decisions in support of the Integrated Water Resources Management principles and Sustainable Development Goal 6 objectives for groundwater sustainability in the transboundary Lake Malawi basin. Full article

Amidst rapid urbanization and escalating environmental degradation in China’s urban areas due to climate change, traditional drainage systems struggle to cope with rainfall, resulting in frequent flood disasters. In response, rain gardens have emerged as ecologically practical stormwater management solutions that integrate urban flood control with landscape design. Leveraging the dual benefits of rainwater purification and aesthetic enhancement provided by vegetation, herbaceous plant-based rain gardens have assumed a pivotal role in green infrastructure. However, dedicated research on the application of herbaceous plants in rain garden design is limited, especially within China’s water-stressed context. This study employs a literature review and case analysis to explore this critical issue. Initially, it delineates the concept of the sponge city introduced by the Chinese government. Subsequently, it reviews concepts and methods of plant biodiversity design in urban settings and rain gardens and elucidates the structure and function of rain gardens. Four Chinese rain gardens in different urban environments (old industrial areas, university campuses, urban villages, and urban highway green belts) were selected to examine the selection and arrangement of herbaceous plants while identifying deficiencies in their designs. Finally, feasibility suggestions are provided for the design of herbaceous plant diversity in Chinese rain gardens. This study’s findings can provide a reference for the planting design of herbaceous plants in rain gardens for other countries and regions with similar climates and environmental conditions. Full article

In the context of ever-increasing water demand and pressures on natural resources, efficient water management is becoming a major priority for contemporary society. Since nitrogen and phosphorus, as essential nutrients, play a crucial role in the dynamics of aquatic ecosystems, but excessive concentrations can cause eutrophication of receptors, they need to be eliminated as completely as possible while respecting the principles of a sustainable economy, efficiency, and quality. In this study, the efficiency of optimizing the technological process of wastewater treatment by dosing FeCl₃ 40% solution to reduce nitrogen and phosphorus concentrations in treated water was investigated. The results obtained revealed that the use of this type of flocculant resulted in an increase in the efficiency of the removal process of total N by an average of 35.57 mg/L and total P by an average of 3.89 mg/L. Also, the results, which are interpreted by mathematical modeling, show that the optimal use of FeCl₃ 40% solution leads to a significant reduction in pollutants, well below the maximum permitted values (according to Romanian regulations, the maximum value for total phosphorus is 2 mg/L and total nitrogen is 15 mg/L for localities with a population between 10,000 and 100,000 inhabitants). This technical approach not only improves the quality of treated water but also contributes to minimizing the impact on aquatic ecosystems and promotes the principles of circular economy in water resource management. By optimizing the dosage of FeCl₃ 40% solution in the treatment process, the efficiency of the coagulation and flocculation processes is maximized, thus providing a viable and sustainable solution for reducing the environmental impact of nitrogen and phosphorus and promoting responsible and sustainable water resource management. Full article

Climate change is increasing air temperatures and altering the precipitation and hydrological regime on a global scale. Challenges arise when assessing the impacts of climate change on the local scale for water resource management purposes, especially for low-mountain headwater catchments that not only serve as important water towers for local communities but also have distinct hydrological characteristics. Until now, no low-flow or hydrological drought studies had been carried out on the Lauter River. This study is unique in that it compares the Lauter River, a transboundary Rhine tributary, with a nearby station on the Rhine River just below its confluence at the French–German border. The Lauter catchment is a mostly natural, forested catchment; however, its water course has been influenced by past and present cultural activities. Climate change disturbances cascade through the hydrologic regime down to the local scale. As we are expecting more low-flow events, the decrease in water availability could cause conflicts between different water user groups in the Lauter catchment. However, the choice among different methods for identifying low-flow periods may cause confusion for local water resource managers. Using flow-rate time series of the Lauter River between 1956 and 2022, we compare for the first time three low-flow identification methods: the variable-threshold method (VT), the fixed-threshold method (FT), and the Standardized Streamflow Index (SSI). Similar analyses are applied and compared to the adjacent Maxau station on the Rhine River for the same time period. This study aims at (1) interpreting the differences amongst the various low-flow identification methods and (2) revealing the differences in low-flow characteristics of the Lauter catchment compared to that of the Rhine River. It appears that FT reacts faster to direct climate or anthropogenic impacts, whereas VT is more sensitive to indirect factors such as decreasing subsurface flow, which is typical for small headwater catchments such as the Lauter where flow dynamics react faster to flow disturbances. Abnormally low flow during the early spring in tributaries such as the Lauter can help predict low-flow conditions in the Rhine River during the following half-year and especially the summer. The results could facilitate early warning of hydrological droughts and drought management for water users in the Lauter catchment and further downstream along some of the Rhine. Full article

Groundwater contamination with per- and polyfluoroalkyl compounds (PFASs) has become a growing worldwide environmental issue. The current review comprehensively evaluates the global perspective of PFAS pollution in groundwater. Data from 224 recent research articles covering various land use and source types were reviewed, including industrial facilities, landfills, biosolids applications, and firefighting training sites. The bibliographic analysis shows an exponential increase in publications on PFAS pollution in groundwater in the last five years, with more than 50% coming from the USA, followed by Australia, Canada, China, and Sweden. The recent groundwater PFAS pollution research provides insight into the analytical techniques, absorbing materials, treatment strategies, field tests, and enhanced natural attenuation. Nevertheless, the current review identified significant research gaps in the areas of precursor characterization, subsurface behavior, model validation with field data, and long-term and sustainable solutions. Moreover, a global cross-disciplinary approach is required to reduce and regulate PFASs’ risks to humans and the ecological system. This review presents a case study of PFASs in Saudi Arabian groundwater, revealing elevated levels of PFOA and PFOS and highlighting the need for region-specific studies and remediation strategies. The review results will guide global efforts to protect drinking water supplies from life-threatening contaminants. Full article

The purpose of this research is to solve the complex long-distance and high-lift water supply engineering accident water hammer protection problem. Taking the Zhaojinzhuang water supply project as an example, based on the method of characteristics (MOC), the water hammer of the pumping station under the combined action of a water hammer relief valve, hydraulic-control butterfly valve, air vessel, air valve, and other water hammer protection measures is numerically simulated and calculated, and the effectiveness of the range method is analyzed, to ensure a waterproof hammer in pump stop accidents. The results show that the main factors affecting the effect of water hammer protection under the two-stage valve-closing parameters of the hydraulic-control butterfly valve are the fast-closing angle and the slow-closing time. The arrangement of the air vessel behind the pump can effectively increase the minimum water hammer pressure in the climbing section, and with the increase of the volume of the air vessel, the pump reverse speed and the maximum positive pressure increase slightly, but the overall water hammer protection effect is better. With the increase of the moment of inertia of the motor, the maximum positive pressure and minimum negative pressure of the pipeline still do not meet the requirements of the specification, and the modification cost is relatively large. The combination of the one-stage hydraulic-control butterfly valve, the air valve, the air vessel, and the water hammer relief valve can effectively reduce the volume of the air vessel. Under the optimal method, the maximum positive pressure head is 236.61 m, and the minimum negative pressure head is −3.18 m. Compared with the original method, the maximum positive pressure head is increased by 1.18%, the minimum negative pressure head is reduced by 95.78%, the maximum reverse speed of the pump is reduced by 100%, and the maximum reverse flow of the pump is reduced by 70.27%, meeting the requirements of water hammer protection. This is a safe and economical protection method. Full article

Multi-stakeholder participation processes in watershed management face challenges due to limited monitoring and baseline data, resulting in a lack of awareness among stakeholders about the current state of the watershed. This knowledge gap often leads to conflicts of interest, wherein the broader impacts of individual decisions are overlooked. To overcome these limitations, this paper explores the design and implementation of a Serious Game (SG) aimed at coproducing a watershed management plan at the basin scale within the specific context of the Campoalegre River basin in Colombia. By providing an interactive platform, the SG facilitates collaboration between local actors, who may be unfamiliar with existing watershed plans, and decision-makers. The goal is to create a participatory space where stakeholders can comprehend the watershed management plan structure and prioritize actions based on various climatic, social, and economic conditions. Following the application of the SG, stakeholders demonstrated an improved understanding of the basin, fostering increased participation, open debate, and the proposal of actions. These outcomes serve as valuable inputs for the implementation of water management planning policies, showcasing the potential of SGs in bridging knowledge gaps, and fostering effective multi-stakeholder engagement. Full article

This study aimed to evaluate the financial feasibility of rainwater harvesting and greywater reuse in a multifamily building located in Florianópolis, Brazil. A building, consisting of two blocks with 60 flats each, was chosen to obtain data about the number of residents, building characteristics, potable water consumption, and rainwater and greywater demands (obtained by means of questionnaires and water measurements). The financial feasibility analyses considered rainwater and greywater systems separately and together. The impact on the urban stormwater drainage system was evaluated through the reduction of stormwater runoff. The energy consumption in the operational phase of each system was estimated through the amount of energy consumed by the motor pumps to supply one cubic meter of water. The potential for potable water savings through the use of rainwater—that supplies water for washing machines—was approximately 6.9%. The potential for potable water savings through the use of greywater—that supplies water to toilets—was approximately 5.7%. Both systems were feasible. The payback period for rainwater harvesting systems ranged from 57 to 76 months. For greywater systems, the payback period ranged from 127 to 159 months. When considering both systems working together, the payback period ranged from 89 to 132 months. The rainwater harvesting system can reduce 11.8% the stormwater volume destined to the urban stormwater drainage system in relation to the current contribution volume. Energy consumption was approximately 0.56 kWh/m³ of treated water for the rainwater harvesting system and 0.89 kWh/m³ of treated water for the greywater system. Rainwater and greywater were considered economically feasible, especially for higher inflation scenarios. Furthermore, such systems are interesting alternatives in terms of impacts considering urban drainage and energy consumption. Full article

Nanling County, situated on the southern bank of the Yangtze River’s middle and lower reaches in China, and has not yet carried out hydrogeochemical geological surveys. This study is pivotal in ensuring the reliability of the drinking water supply, particularly during emergencies. Utilizing an array of analytical methods—statistical analysis, Shularev classification, Piper trilinear diagram, Gibbs diagram, ion ratio method, and mineral saturation index—this research elucidates the hydrogeochemical characteristics and principal water–salt interactions in Nanling’s shallow groundwater. Our findings, derived from the Shularev classification and Piper trilinear diagram, reveal that, in the southern mountainous and river valley plain regions, the primary hydrogeochemical type of groundwater is HCO₃-Ca. Conversely, in the northern area of Sanli Town and the adjoining plain, groundwater predominantly falls under the HCO₃-Na•Ca category, with some regions showing the characteristics of HCO₃•Cl-Ca, HCO₃•Cl-Na•Ca, and, occasionally, HCO₃•SO₄-Na•Ca. According to the Gibbs diagram analysis, the predominant source of groundwater in this region is attributed to water–rock dissolution processes occurring during groundwater runoff. The increase in Na⁺, Ca²⁺, Cl⁻, HCO₃⁻, and SO₄²⁻ concentrations in the water–rock interaction in the study area is mainly due to the dissolution of rock salt, gypsum, calcite, and dolomite, and the alternating cation adsorption occurs during the reaction. Finally, the mineral saturation index points to the ongoing dissolution of gypsum, calcite, and dolomite, until a state of precipitation–dissolution equilibrium is reached. This comprehensive study provides vital insights into the hydrogeochemical dynamics of Nanling County’s groundwater, contributing significantly to our understanding of regional water quality and its management. Full article

Identifying the source and impact pathways of soil heavy-metal pollution is critical for its assessment and remediation. Numerical simulation has been widely used to simulate soil heavy-metal pollution processes and predict risks. However, traditional numerical simulation software requires a large number of parameters, which are difficult to obtain in site-scale studies. This study proposes a rapid method for identifying soil heavy-metal pollution processes using the TOUGH2/EOS7 software. It has automatic calibration and uncertainty analysis capabilities, which can effectively reduce the demand for parameters. This study established a method, including model selection, simulation, validation, and error analysis, to verify the effectiveness of the proposed method. This study identified the most realistic scenario for chromium pollution and simulated its release over 20 years, and the results met accuracy requirements with a best-case fit of 0.9998. The results showed that the method can quickly identify the source and impact pathways of soil heavy-metal pollution, providing strong evidence for environmental damage assessment. Full article

This study explores the effects of alternating current-induced electromagnetic field (EMF) on mitigating brackish water irrigation and soil salinization impacts. Greenhouse experiments were conducted to evaluate the effect of EMF on plant growth, soil properties, and leaching of ions under different conditions, including using brackish water and desalinated water for irrigation and soil compost incorporation. The experiment was performed with four types of irrigation water using soil columns representing field soil layers. EMF-treated brackish water maintained a sodium adsorption ratio of 2.7 by leaching Na⁺ from the soil. EMF-treated irrigation columns showed an increase in soil organic carbon by 7% over no EMF-treated columns. Compost treatment reduced the leaching of NO₃⁻ from the soil by more than 15% using EMF-treated irrigation water. EMF-treated brackish water and compost treatment enhanced plant growth by increasing wet weight by 63.6%, dry weight by 71.4%, plant height by 22.8%, and root length by 115.8% over no EMF and compost columns. EMF-treated agricultural water without compost also showed growth improvements. The findings suggest that EMF treatment, especially combined with compost, offers an effective, low-cost, and eco-friendly solution to mitigate soil salinization, promoting plant growth by improving nutrient availability and soil organic carbon. Full article

Water intrusion into a building envelope describes the unwanted movement of water or vapor into a building, where it causes damage. Various factors dictate water intrusion category determination and classification. These factors include, but are not limited to, the type and degree of water intrusion, the source and route of the contamination, and exposure time, as well as geographical environmental conditions. This comprehensive research paper looked at the literature and the science to explore the bases for indoor environmental professional (IEP) classification and category determination, but also the science behind the effects of water intrusion on building materials (BM). The efficacy of building materials once degradation has occurred and any accelerating effects impacting the efficiency of building materials and their loss of integrity were closely examined in terms of material microstructural and compositional changes. The damaging effects of moisture and heat on building materials are called hygrothermal damage, which compromises the properties and use of materials. Both aspects of building integrity, i.e., water intrusion and structural deterioration, should be of concern when mitigating and remediating the intrusion of moisture. Previous research on the clarification of water categories for water intrusions is lacking. Past approaches to water classification have lacked universal scientific clarity and understanding. In addition to a need to understand the effects that water category might have on building materials and their corresponding degree of degradation, more science and reviews are needed. The need for proper class and category determination for the remediation of water intrusion within buildings is the first step toward achieving correct mitigation to ensure human health and safety. The possible adverse health effects of water intrusion need focus and cohesion for the determination of categories. We know that the final determination of water categories differs according to the degree of contamination over time and the degree of a given class of water intrusion; however, what role do the route and initial water contamination play in the determination of the category? The following paper aims to provide not only a review of the science but also an elaboration of the category determination process and the degradation effects on building materials which should be considered, as well as possible avenues of scientific research. Full article

The overuse of antibiotics has resulted in the prevalence of antibiotic resistance genes (ARGs) and antibiotic resistance bacteria (ARB) in the environment. High-density livestock farming is one of the major industries for antibiotic overuse. In this study, we sampled wastewater and manure at different stages of the feces treatment process from a dairy farm, as well as the soil in the farmland where the treated wastewater was being used for irrigation purpose. High-throughput Illumina sequencing was used to analyze the profiles of bacteria communities and ARGs. The results showed that the main ARG types were multidrug, aminoglycoside, glycopeptide, and tetracycline resistance genes, and Actinobacteria, Proteobacteria and Firmicutes were the main host bacteria phyla of these ARGs. The genus Nocardioides sp. and Ornithinimicrobium sp. were closely associated with the ARGs in the investigated samples. The relative abundances of ARGs in wastewater and manure were reduced by 68.5% and 62.1%, respectively, by the existing feces treatment process. Anaerobic fermentation and high-temperature fermentation were the most efficient treatment steps; the relative abundances of ARGs were reduced by 29.3% and 33.6% in the treated wastewater and manure, respectively. Irrigation with the treated wastewater significantly increased the abundance and diversity of ARGs and ARB in the surface soil of the farmland. The residual ARGs were found to transit through vertical gene transfer (VGT) and horizontal gene transfer (HGT) in soil. Therefore, the direct application of this inadequately treated wastewater and/or manure could risk spreading ARGs into the environment, and potentially impact human health. In order to effectively restrain the spread of ARGs, it is necessary to modify the wastewater and manure treatment processes and improve the regulations and guidelines of applying treated wastewater for irrigation. Full article

For flood discharge structures with high water heads, aeration facilities are usually installed in engineering to promote water flow aeration and prevent cavitation damage to the overflow surface. Actual engineering has shown that as the slope of the discharge channel bottom decreases or water level changes lead to a decrease in the Froude number, the cavity morphology after conventional aeration facilities or allotype aerators is poor. This article proposes a curved aeration facility scheme based on the idea of locally increasing the bottom slope to reduce the impact angle, which is formed by the convex parabolic bottom plate and concave parabolic bottom plate. The convex parabolic bottom plate is tangent to a flat bottom plate behind the offset, and the concave parabolic bottom plate is tangent to the downstream. The jet landing point is controlled at the junction of the convex parabolic bottom plate and the concave parabolic bottom plate, and the lower jet trajectory is in line with the parabolic bottom plate. The corresponding parabolic bottom plate calculation formulas were theoretically derived, and the design method of the shape parameters of the aeration facility was provided. Through specific engineering case studies, it was found that: (1) As the Z_AC/Z_AG value increases, point C becomes closer to point G, the slope of the water tongue landing point C becomes steeper, and the cavity is less likely to return water. (2) When the position of the water tongue landing point is 0.5–0.8 times the height of the water tongue impact point, there is almost no water accumulation in the calculated cavity. At this time, the platform length L_AB = 0.5L_AF, the convex parabolic section length L_BC = (0.45–0.6) L_AG, the concave parabolic section length L_CD = (0.43–0.11) L_AG, the convex parabolic section calculation formula is z (x) = −A₁x₂ (A₁ = 0.0059–0.00564), and the concave parabolic section calculation formula is A₂x₂ − B₂x₂ (A₂ = 0.003347–0.01927).This solved the problem of aeration and corrosion reduction under small bottom slope, large-unit discharge, and low Froude number engineering conditions. Full article

Heavy metals play a crucial role in the environment due to their toxicity, persistence, and bioaccumulation ability, which can lead to severe ecological and health risks. This study aimed to investigate the impact of urbanization and agricultural practices on the heavy metal content in the sediments of the Bug River catchment. To this end, 96 surface sediment samples were collected from various points in the Bug River catchment, including from urban, agricultural, and forested areas. The samples for laboratory analysis were collected in July 2018, 2019, and 2020 in the Polish part of the Bug River watershed. Heavy metal (Zn, Pb, Cr, Ni, Cu, Fe, Mn, and Cd) concentrations were determined using atomic absorption spectroscopy (AAS). The geoaccumulation index (I_geo)_, contamination factor (CF), and pollution load index (PLI) were used to assess the degree of sediment contamination. The results indicate higher concentrations of heavy metals in urban sediments, where cadmium concentrations reached up to 2.5 mg/kg, compared to agricultural and forested areas, where concentrations were significantly lower. The average I_geo value for cadmium was 0.24 in agricultural areas and 0.15 in urban areas, suggesting the predominance of anthropogenic influences over natural sources. The highest PLI values were found in urban areas, reaching a maximum of 0.33, indicating higher pollution levels. Statistical analysis revealed that urban emissions and agricultural activities significantly influenced the presence of these metals in the Bug River sediments. This study’s conclusions emphasize that effective river water quality management requires continuous monitoring and an understanding of anthropogenic and natural pollution sources. The results contribute to a better understanding the interactions between human activities and water quality, crucial for planning protection and remediation strategies. Additionally, this study provides critical insights into optimizing pollution management strategies and developing remediation methods, serving local and regional policymakers in planning protective actions. Full article

In accordance with the programme of closure works and the implementation of ecological spatial rehabilitation in the area of the Slovenian coal mine Trbovlje–Hrastnik (RTH), there is a great opportunity to exploit shallow geothermal energy from water and ground sources. In the RTH area, there is great energy potential in the utilisation of underground water and heat from the earth. In our research, we have focussed on the use of geothermal energy with heat pumps from groundwater (water/water system) and from ground collectors and wells up to a depth of 150 m (rock/water system). With the water/water system, we have an average of 2.7 MW of thermal energy available, with the rock/water system having 7.5 kW of thermal energy from a 150 m deep well. With the rock/water system in particular, the development of an industrial zone in the RTH area can also provide for a greater demand for thermal energy. The thermal energy obtained in this way is utilised via heat pumps to heat and cool commercial, residential and industrial buildings. The utilisation of shallow geothermal energy can make a major contribution to carbon neutrality, as the use of geothermal energy has no negative impact on the environment and causes no greenhouse gas emissions. The aim of the paper is to provide an overview of the methods used to analyse heat storage in aquifers of abandoned coal mines, to represent these storages in RTH with a basic mathematical–statistical inventory of what is happening in the aquifer, and to investigate the possibility of using shallow geothermal energy with the help of modelling the use of shallow geothermal energy. The results and analyses obtained can make an important scientific contribution to the use of geothermal energy from abandoned and closed mines. Full article

Climate change severely affects urban water systems (UWSs). Infrastructure historically designed for milder conditions cannot manage growing water demands and extreme events. To obtain a resilient water sector, adaptation and mitigation strategies must address rising water challenges while striving for net-zero emissions. Researchers have noted that extreme decentralization is positively associated with closing cycles while reducing transport costs. However, part of the scientific community defends centralized schemes due to economies of scale. The objective of this systematic review is to understand the trade-offs associated with the adoption of different scales at UWSs design and how this impacts system resilience. This process includes identifying different scale trade-offs and unique environmental aspects that influence the optimal scale suitability. A clear distinction was made in terms of scale concept and classification, considering different design levels. That is, considering the UWS at the city level and water management units (WMUs) at the local level. Similarly, a classification of different scales for each level, covering all water streams—supply, wastewater, and stormwater—was introduced. We defined the key environmental aspects that influence the optimal scale and location suitability: ten at the city-catchment level and eleven at the site-neighbourhood level. Scale impacts three major UWSs functionalities that have repercussions on urban resilience: net energy, net water, and ecosystem services (ES). Full article

This study aimed to characterize the chemical composition and spatial distribution of groundwater in the Kızılırmak Delta of Turkey and to evaluate the suitability of groundwater in the Kızılırmak Delta for drinking water use through a Water Quality Index (WQI) assessment. Eleven water parameters, including nitrate (NO₃⁻), calcium (Ca²⁺), magnesium (Mg²⁺), sodium (Na⁺), chloride (Cl⁻), potassium (K⁺), bicarbonate (HCO₃⁻), sulfate (SO₄²⁻), hardness (measured as CaCO₃), electrical conductivity (EC), and pH were analyzed to determine the water quality of each groundwater sample. The WQI was determined using the weighted arithmetic index method and the method specified by the Canadian Council of Ministers of the Environment (CCME). The spatial distribution of the result for all observation wells was plotted. Principal Component Analysis (PCA) was generated utilizing the analytical data from eleven selected samples. As a result of the study, according to the calculated WQI values, the water in most of the wells was not suitable for drinking purposes. The minimum Ca²⁺ concentration in the study area was 108,817 mg/L, and the maximum was 692,382 mg/L, which showed that the samples in all wells exceeded the WHO limit. The same situation is valid for Mg²⁺, and the values vary between 100.383 and 5183.026 mg/L. From the spatial distribution of the water quality parameters it has been understood that the eastern part of the region is more suitable than the western part for drinking purposes. The results from correlation analysis showed the strongest positive correlation between Mg²⁺ and Na⁺ and Na⁺ and EC as 0.989. The present study shows that the groundwater of the delta, which has deteriorating water quality, should be treated before it is used for drinking water and protected from contamination hazards. Full article

With renewed interest in the optimisation of the hydraulic performance of new and existing culverts, particularly relevant to South Africa’s evolving road network and anticipated climate-induced rainfall changes, this research investigated the benefit of angled wingwall and headwall combinations and considered the installation of a ventilation device in order to improve culvert performances. Through experimental modelling at the University of Pretoria Water Laboratory, the angled wingwall and headwall combinations demonstrated significant flow improvements compared to square inlets. It was also demonstrated that a ventilation device could cause flow through culverts to flow under inlet control conditions where it would otherwise have flowed under outlet control conditions. Additionally, the study proposes design coefficient adjustments for square inlet culverts operating under inlet control conditions. The proposed improvements can be applied during design stages, but the findings also propose prefabricated inlet elements as cost-effective solutions for existing culverts, thereby facilitating quick upgrades without the need for lengthy road closures while potentially enabling benefits for pedestrian traffic. Ultimately, this study underscores the potential of innovative and novel design modifications to enhance culvert performance, offering sustainable and economical alternatives to conventional replacement practices while advancing hydraulic engineering resilience in response to evolving infrastructural and environmental demands. Full article

The first systematic attempts to straighten the River Inn in Tyrol for shipping and land reclamation date back to the middle of the 18th century. A dedicated hydraulic engineering authority—the so-called Main Ark Inspection—was established to realize this challenging task. The one-man authority was unable to straighten the Alpine river through the period of its existence up to 1792. The reasons for this were by no means related to a lack of technical resources and knowledge. On the contrary, a micro- and environmental-historical analysis of the attempts to straighten the River Inn highlights the complexity of the causes, which were mutually reinforcing and multifactorial. In this paper, four key causes are examined in more detail: (1) the social organization of water engineering, (2) social conflicts between riparian communities among themselves and with the hydraulic engineering authority, (3) conflicts between Tyrol and Bavaria at the wet border downstream of Kufstein, and (4) increased bedload discharge into the main river by tributaries. To illustrate the causes mentioned above, historical river maps are analyzed in great detail, drawing on contemporaneous written sources. The approach thereby highlights the overall complexity of pre-modern hydraulic engineering in all its facets, be they social, technical, natural, administrative, or organizational. To conclude, the results of this environmental history research are embedded and discussed in the context of integrated river management in the Anthropocene. Full article

Microplastics in drinking water have attracted increasing global concerns due to their potential adverse impacts on human health. However, there needs to be more knowledge of the occurrence and distribution of microplastics in drinking water systems from water sources to household tap water. Herein, laser direct infrared spectroscopy is used to investigate the occurrence of microplastics in a typical drinking water plant with different water sources. Microplastic information is further used to understand microplastic fates during drinking water supply, including microplastic abundance, size, shape, and polymer type. Overall, the microplastic abundance in treated water ranges from 12.00 to 25.33 particles/L, higher than those in raw water (RW; 2.33–17.33 particles/L) and household water (HW; 8.00–19.67 particles/L), which shows that microplastics are not removed from RW. The main polymers in these microplastics are polyethylene terephthalate, polyvinyl chloride, polyethylene, and polypropylene. At the same time, the main microplastic shapes are fragments and fibers. Small-sized microplastics of 20–100 μm account for up to 76.74% and 79.30% of microplastics during the dry and wet seasons, respectively. Additionally, more microplastics are detected in RW from rivers than those from reservoirs and lakes, and the microplastic abundance in the wet season is higher than that in the dry season. As expected, the potential ecological risk of microplastics in all waters is the I level, which is the lowest level. Most importantly, the annual microplastic intake of an adult via drinking water is 5063–18,301 microplastics, less than that reported in previous studies. These results provide valuable data on the fates of microplastics in drinking water supply systems from water sources to HW and promote authorities to update the treatment technologies for drinking water in the future to remove microplastics efficiently. Full article

The transition from the linear economy paradigm to the circular economy in industrial wastewater treatment is on the global agenda. The search for new simple, eco-innovative and low-cost processes for treating industrial wastewater, which can also be used by small- and medium-sized industries, has been a constant challenge to ensure environmental sustainability in all types of industries. The present work aimed to evaluate the suitability of the treated slaughterhouse wastewater (SWW) obtained by the integrated process composed of immediate one-step lime precipitation (IOSLM) and atmospheric carbonation (AC) for the production of aromatic plants by hydroponics. Results showed a significant increase in plant height of 177 and 147% and root length of 64 and 37% for Pennyroyal and Chocolate Peppermint plants, respectively, after 26 days. No signs of toxicity or symptoms of micronutrient deficiency were detected in aromatic plants. Full article